Electrical and optical enhancement of ITO/Mo bilayer thin films via laser annealing

• Abdelbaki Hacini,
• Ahmad Hadi Ali,
• Nurul Nadia Adnan and
• Nafarizal Nayan

Beilstein J. Nanotechnol. 2022, 13, 1589–1595, doi:10.3762/bjnano.13.133

• to improve the performance of optoelectronic devices. One of these materials is indium tin oxide (ITO), which combines high transparency with high conductivity [7][8]. However, a single layer of as-deposited ITO shows a high resistivity. Consequently, inserting a very thin metal film layer can

• adherence to the substrate, very high thermal stability (up to 600 °C), and high electrical conductivity [14]. Over the last decades, the development of solar cells has grown dramatically. The cells have become larger, thinner, and lighter. This increases the electrical resistivity, which is undesirable

• boundaries lead to a decrease in resistivity. Moreover, the annealing treatment minimizes the trade-off between transparency and conductivity [9]. The sheet resistance of the ITO/Mo films can be expressed as [29]: where Rs is the sheet resistance, ρ is the resistivity, and t is the thickness (=135 nm). The

Induced electric conductivity in organic polymers

• Konstantin Y. Arutyunov,
• Anatoli S. Gurski,
• Vladimir V. Artemov,
• Alexander L. Vasiliev,
• Azat R. Yusupov,
• Danfis D. Karamov and
• Alexei N. Lachinov

Beilstein J. Nanotechnol. 2022, 13, 1551–1557, doi:10.3762/bjnano.13.128

• ; thin films; Introduction Most polymers can be classified as organic dielectrics. However, there exists a specific class of polymers, typically characterized by the existence of conjugated π-bonds, which enable delocalization of electrons leading to electric conductivity in the ground state of the

• system. Relatively recently it was found that finite electric current can pass also through non-conjugated polymers. In the ground state they are wide-band dielectrics, but can exhibit high electric conductivity under the influence of such external parameters as mechanical stress and/or electric field [1

• ]. The effect is interpreted as stimulation of metallic state [2]. Poly(diphenylene phthalide) (PDP) was chosen as the object of study being a representative electro-active polymer demonstrating induced electric conductivity. PDP is a carbocyclic polymer with high chemical and thermal stability

Photoelectrochemical water oxidation over TiO₂ nanotubes modified with MoS₂ and g-C₃N₄

• Phuong Hoang Nguyen,
• Thi Minh Cao,
• Tho Truong Nguyen,
• Hien Duy Tong and
• Viet Van Pham

Beilstein J. Nanotechnol. 2022, 13, 1541–1550, doi:10.3762/bjnano.13.127

• conductivity have been widely used in water splitting reactions [10][11]. However, noble metals are still rare and expensive materials, and their application as electrode materials is considered to be not optimal [10]. Therefore, the study of a materials with high-performance in PEC water splitting, which

Non-stoichiometric magnetite as catalyst for the photocatalytic degradation of phenol and 2,6-dibromo-4-methylphenol – a new approach in water treatment

• Joanna Kisała,
• Anna Tomaszewska and
• Przemysław Kolek

Beilstein J. Nanotechnol. 2022, 13, 1531–1540, doi:10.3762/bjnano.13.126

• igneous and metamorphic rocks [12]. It is also found in sediments and soils. Magnetite has the smallest energy gap, the highest conductivity, and one of the lowest reduction potentials among natural minerals. It is an important reducer of heavy metals and organic pollutants in aquatic environments. Due to

• octahedral iron chain handles its conductivity and redox properties, causing the magnetite to initialize oxidation/reduction reactions. Fe3O4 nanoparticles have been used as a photocatalyst for the degradation of azo dyes [15], for wastewater treatment [16][17], for water decomposition, and for Cr(VI

A TiO₂@MWCNTs nanocomposite photoanode for solar-driven water splitting

• Anh Quynh Huu Le,
• Ngoc Nhu Thi Nguyen,
• Hai Duy Tran,
• Van-Huy Nguyen and
• Le-Hai Tran

Beilstein J. Nanotechnol. 2022, 13, 1520–1530, doi:10.3762/bjnano.13.125

• been developed to increase the absorption of visible solar light [6][7]. Notably, carbon nanotubes (CNTs) are a promising material for visible-light absorption [8]. A combination of TiO2 with CNTs can effectively enhance the separation of e−/h+ pairs based on the high electric conductivity of CNTs

• conductivity of TiO2 [37]. Table 1 shows the EIS parameters obtained from fitting the measured results with equivalent circuits. The R1 values illustrate a low electrical resistance of the 0.1 M KCl solution, while the R2 values show that the TiO2 electrode has the highest resistance among the prepared

• electrodes [38]. The results reveal a significant improvement in the electrical conductivity for the TiO2@MWCNTs electrode. The result agrees well with a previous study on TiO2@graphene composite electrodes [37]. Among the electrodes, the EDL capacitance (C2) at the TiO2 electrode surface is the lowest (1.32

Structural studies and selected physical investigations of LiCoO₂ obtained by combustion synthesis

• Monika Michalska,
• Paweł Ławniczak,
• Tomasz Strachowski,
• Adam Ostrowski and
• Waldemar Bednarski

Beilstein J. Nanotechnol. 2022, 13, 1473–1482, doi:10.3762/bjnano.13.121

• investigated by using impedance spectroscopy. Comparison of the effect of annealing temperature on electrical conductivity shows a very interesting behavior. As the annealing temperature increases, the DC conductivity value increases, reaching a maximum at a temperature of 500 °C. However, further increase in

• the annealing temperature causes a steady decrease in the DC conductivity. Keywords: lithium cobalt oxide; lithium-ion battery; nanocrystalline powder; solution combustion synthesis; Introduction Lithium cobalt oxide (LiCoO2, LCO) of hexagonal structure () was first used as cathode material in

• improve electrical conductivity and electrochemical performance [5][6][7][9][13][14][15][16][23][24][25][26][27][28][29][30][31][32]. Nanostructured materials can reduce the specific surface current rate as well as improve stability and specific capacity [23][24][25][26][27][28][29]. LiCoO2 has been

Rapid and sensitive detection of box turtles using an electrochemical DNA biosensor based on a gold/graphene nanocomposite

• Abu Hashem,
• M. A. Motalib Hossain,
• Ab Rahman Marlinda,
• Mohammad Al Mamun,
• Khanom Simarani and
• Mohd Rafie Johan

Beilstein J. Nanotechnol. 2022, 13, 1458–1472, doi:10.3762/bjnano.13.120

• large surface area, high electrical conductivity and electron transfer rate, and it can immobilise diverse molecules, which is ideal for biosensor design [37][38][42]. On the other hand, AuNPs offer outstanding characteristics such as biocompatibility, conductivity, catalytic efficiency, density, and

• increased, indicating that Gr and AuNPs had very good conductivity and catalytic functions. The peak currents on AuNPs/Gr/SPCE were higher and more reversible when the Gr/AuNPs nanocomposite was deposited on the surface of SPCE, suggesting that the Gr/AuNPs nanocomposite was an excellent electric conductor

• active surface area and conductivity of the modified SPCE and also enhanced its electrochemical capacity. The attachment of the thiol group to the probe facilitated covalent attachment with AuNPs, and the carbon spacer arm facilitated protrusion from the electrode surface, which enables proper

Density of states in the presence of spin-dependent scattering in SF bilayers: a numerical and analytical approach

• Tairzhan Karabassov,
• Valeriia D. Pashkovskaia,
• Nikita A. Parkhomenko,
• Anastasia V. Guravova,
• Elena A. Kazakova,
• Boris G. Lvov,
• Alexander A. Golubov and
• Andrey S. Vasenko

Beilstein J. Nanotechnol. 2022, 13, 1418–1431, doi:10.3762/bjnano.13.117

• is the conductivity of the F layer [88][89], ξf = Df is the diffusion coefficient in the ferromagnetic metal, and Tc is the critical temperature of the superconductor [1][2]. We assume ℏ = kB = 1. We also assume that the SF interface is not magnetically active. We will consider the diffusive limit

• ferromagnet, and the Kupriyanov–Lukichev boundary conditions at the FS interface [83], Here γ = ξsσn/ξfσs, σs is the conductivity of the S layer, and ξs = is the superconducting coherence length. The indices of the θ-parameterized Green’s functions are omitted, since there is no mixing between the components

Dry under water: air retaining properties of large-scale elastomer foils covered with mushroom-shaped surface microstructures

• Matthias Mail,
• Stefan Walheim,
• Thomas Schimmel,
• Wilhelm Barthlott,
• Stanislav N. Gorb and
• Lars Heepe

Beilstein J. Nanotechnol. 2022, 13, 1370–1379, doi:10.3762/bjnano.13.113

• allow for a persistent air layer. The jar was closed and stored on a rack in the office. After one month, the samples were taken out of the water and dried in air. The dried samples were mounted to aluminum stubs and fixated using silver paste. To enhance the conductivity, the samples were sputtered

Straight roads into nowhere – obvious and not-so-obvious biological models for ferrophobic surfaces

• Wilfried Konrad,
• Christoph Neinhuis and
• Anita Roth-Nebelsick

Beilstein J. Nanotechnol. 2022, 13, 1345–1360, doi:10.3762/bjnano.13.111

• tuyère’s water cooling system and to prevent heat damage to the tuyère. Since the heat conductivity of gas layers is about five orders of magnitude lower than that of copper, gas layers trapped in structured tuyère surfaces should substantially reduce the overall heat flow into the tuyère, and its outer

Recent trends in Bi-based nanomaterials: challenges, fabrication, enhancement techniques, and environmental applications

• Vishal Dutta,
• Ankush Chauhan,
• Ritesh Verma,
• C. Gopalkrishnan and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 1316–1336, doi:10.3762/bjnano.13.109

• -based semiconductors, especially oxide semiconductors such as Bi2O3, BiVO4, and Bi2WO6, have n-type properties with electrons as the majority carrier. Recent research suggests that the synthesis route can shift the conductivity types of Bi-based materials [45][51]. Fabrication routes Synthesis

Enhanced electronic transport properties of Te roll-like nanostructures

• E. R. Viana,
• N. Cifuentes and
• J. C. González

Beilstein J. Nanotechnol. 2022, 13, 1284–1291, doi:10.3762/bjnano.13.106

• by a facile synthesis and extensively studied by scanning and transmission electron microscopy. The nanostructures are made of pure and crystalline Tellurium with trigonal structure (t-Te), and exhibit p-type conductivity with enhanced field-effect hole mobility between 273 cm2/Vs at 320 K and 881

• ]. In this case, conduction is realized through NNH of charge carriers with small activation energy directly over impurity states. The conductivity in the NNH model is given by [35]: where σ3 is a constant, ENNH is the activation energy for NNH conduction, NA is the acceptor concentration, and εr = 53.5

• -nanobelt back-gated FET devices on SiO2/Si substrates. These nanostructures exhibit p-type conductivity with superior room temperature field-effect hole mobility compared to bulk and nanostructures of Te previously synthesized by other methods. The analysis of the temperature dependence of the electrical

Studies of probe tip materials by atomic force microscopy: a review

• Ke Xu and
• Yuzhe Liu

Beilstein J. Nanotechnol. 2022, 13, 1256–1267, doi:10.3762/bjnano.13.104

• resolution and durability or wear and tear and conductivity requirements must be considered before selecting a probe. Metal-coated probes are generally suitable for high-resolution or high conductivity test experiments. Metal nanoclusters adsorbed on two-dimensional materials grown on metal substrates are an

• of the internal Pd nanowires will help probe more surface conductivity measurement, the nanowires with nanostructure or form good ohmic contact to the characterization of surface, external carbon nanotubes provide higher mechanical stability, can make the probe after many times of measuring still

• keep its original shape. Low-resistance ohmic contacts between the metal surface and the PdNWCNT probe were confirmed. Moreover, repeated current flow and surface contact did not cause any damage to PdNWCNTs, indicating that the PdNWCNT probe is suitable for multi-probe conductivity measurement. In the

Application of nanoarchitectonics in moist-electric generation

• Jia-Cheng Feng and
• Hong Xia

Beilstein J. Nanotechnol. 2022, 13, 1185–1200, doi:10.3762/bjnano.13.99

• nanoarchitectonics concept in functional devices has been a hot research topic in recent years, and nanoarchitectonics has a significant impact on the improvement of mechanical structural strength, electrical conductivity, and optoelectronic properties [1][2][3]. The high porosity of nanostructured materials has a

• have superior electrical conductivity and provide better electron transfer properties. Organic nanomaterials are complementary to inorganic nanomaterials in terms of physical properties. Although organic nanomaterials are usually poor in electrical conductivity, they have better properties in terms of

• MEGs. Among them, carbon materials are favored by researchers due to their good electrical conductivity and mature preparation technologies. In addition, surface modification of materials is an important part of research for MEGs. The surface functional groups of inorganic nanomaterials are easy to

A cantilever-based, ultrahigh-vacuum, low-temperature scanning probe instrument for multidimensional scanning force microscopy

• Hao Liu,
• Zuned Ahmed,
• Sasa Vranjkovic,
• Manfred Parschau,
• Andrada-Oana Mandru and
• Hans J. Hug

Beilstein J. Nanotechnol. 2022, 13, 1120–1140, doi:10.3762/bjnano.13.95

• nitrogen (LN2) container and an additional heat shield, which is passively cooled by the evaporating He gases of the LHe tank (Figure 2a). The microscope is surrounded by two shields (a Au-plated oxygen-free high thermal conductivity (OFHC) copper LHe shield and an Al LN2 shield) of which there is an inner

Green synthesis of zinc oxide nanoparticles toward highly efficient photocatalysis and antibacterial application

• Vo Thi Thu Nhu,
• Nguyen Duy Dat,
• Le-Minh Tam and
• Nguyen Hoang Phuong

Beilstein J. Nanotechnol. 2022, 13, 1108–1119, doi:10.3762/bjnano.13.94

• ) and sodium hydroxide (NaOH) were provided by Xilong Scientific Co., Ltd. Methylene blue and methyl orange were purchased from Merck Co., Ltd. Nutrients and agar powder were provided by Titan Co., Ltd. All reagents were of analytical grade. ZnCl2 and NaOH were diluted in DI water with low conductivity

Spindle-like MIL101(Fe) decorated with Bi₂O₃ nanoparticles for enhanced degradation of chlortetracycline under visible-light irradiation

• Chen-chen Hao,
• Fang-yan Chen,
• Kun Bian,
• Yu-bin Tang and
• Wei-long Shi

Beilstein J. Nanotechnol. 2022, 13, 1038–1050, doi:10.3762/bjnano.13.91

• ][21][35]. However, pure phase MIL101(Fe), like most semiconductor photocatalysts, has inherent defects, such as low conductivity and high recombination efficiency of photogenerated electron–hole pairs [26][36]. To overcome these shortcomings, several strategies have been developed. One approach is to

• use carbon nanotubes or carbon quantum dots to modify MIL101(Fe) to enhance its conductivity and broaden its visible-light response [37][38]. Another strategy is to construct MIL101-based heterostructures with the aid of narrow-gap semiconductors to promote the separation and transfer of

Electrocatalytic oxygen reduction activity of AgCoCu oxides on reduced graphene oxide in alkaline media

• Iyyappan Madakannu,
• Indrajit Patil,
• Bhalchandra Kakade and
• Kasibhatta Kumara Ramanatha Datta

Beilstein J. Nanotechnol. 2022, 13, 1020–1029, doi:10.3762/bjnano.13.89

• attributes include high electrical conductivity, cost-effectiveness (50 times lower than Pt), and the ability to execute the ORR via a single step (four-electron transfer). Thus, Ag and its bi- and trimetallic alloys, with and without supporting matrices, have been extensively researched as potential ORR

• and lower Tafel slope (giving rise to better electrokinetics) are the main reasons for the superior ORR performance of the ACC-2 sample. In addition to the catalyst size, morphology, conductivity, and the exposure of active sites, the surface wettability of the electrocatalyst significantly governs

Temperature and chemical effects on the interfacial energy between a Ga–In–Sn eutectic liquid alloy and nanoscopic asperities

• Yujin Han,
• Pierre-Marie Thebault,
• Corentin Audes,
• Xuelin Wang,
• Haiwoong Park,
• Jian-Zhong Jiang and
• Arnaud Caron

Beilstein J. Nanotechnol. 2022, 13, 817–827, doi:10.3762/bjnano.13.72

• -temperature-liquid Ga-based alloys have been attracting interest from various scientific communities, including chemical [1], biomimetic [2], microfluidic [3], electrical [4], and materials science [5]. This increased interest is due to the low viscosity and high and electrical conductivity of these alloys

Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly

• Lingling Xia,
• Qinyue Wang and
• Ming Hu

Beilstein J. Nanotechnol. 2022, 13, 763–777, doi:10.3762/bjnano.13.67

• nanosheets spontaneously and precisely organized into films at the interface laminarly. The films could be easily transferred to other substrates, and showed superprotonic conductivity, which may be promising for fuel cells. The assembly process of 2D coordination polymer nanosheets could be confined inside

A nonenzymatic reduced graphene oxide-based nanosensor for parathion

• Sarani Sen,
• Anurag Roy,
• Ambarish Sanyal and
• Parukuttyamma Sujatha Devi

Beilstein J. Nanotechnol. 2022, 13, 730–744, doi:10.3762/bjnano.13.65

• graphite nature of GO. This confirms that the oxygen functional groups were removed from the graphene layers by electrochemical reduction of GO, decreasing the interspacing distance between graphene layers which facilitates electron transport. Thus, the conductivity of ERGO was enhanced compared to that of

• depend on the number of layers and the distance between the layers, which can be changed by a variation of the synthesis protocol to achieve a higher electroactive surface area and electrical conductivity. Figure 4A displays a higher oxidation/reduction peak current of Fe2+/3+ redox couple for the

Modeling a multiple-chain emeraldine gas sensor for NH₃ and NO₂ detection

• Hana Sustkova and
• Jan Voves

Beilstein J. Nanotechnol. 2022, 13, 721–729, doi:10.3762/bjnano.13.64

• conductivity of PANI [2]. PANI can be synthesized chemically or electrochemically, with different results in terms of polymer conductivity [3]. There are three different ground states of oxidation, which leads to a large spectrum of the electric properties of PANI. First, leucoemeraldine, the fully reduced

• base has to be reduced by electrons (Figure 1). Emeraldine base or leucoemeraldine base salts of green color and with conductivity values of up to 400 S/m can be obtained through synthesis [4]. Recently, the polyaniline emeraldine salt has been studied for sensor applications for various gases because

• 100 μm wide and overlaying molecules contributed to the conductivity, sharing their charge carriers and allowing for carrier hopping, while the numerical experiment consisted of only one, 166 Å long molecule with non-interacting charge carriers. Considering these limitations, the agreement between the

Nanoarchitectonics of the cathode to improve the reversibility of Li–O₂ batteries

• Hien Thi Thu Pham,
• Jonghyeok Yun,
• So Yeun Kim,
• Sang A Han,
• Jung Ho Kim,
• Jong-Won Lee and
• Min-Sik Park

Beilstein J. Nanotechnol. 2022, 13, 689–698, doi:10.3762/bjnano.13.61

• electrical conductivity further, ultimately leading to better electrochemical stability in the cathode. As a result, the optimized bimetallic ZIF–carbon/CNT composite exhibits a high discharge capacity of 16,000 mAh·g−1, with a stable cycling performance of up to 137 cycles. This feature is also beneficial

• physicochemical properties of Li2O2 are reported to be dependent on many factors, including the pore structure of cathode. The electrical conductivity of the cathode is also essential for securing long-term cyclability as well as rate capability [12]. In this respect, various types of carbon materials have been

• explored as advanced cathode materials for LOBs, owing to their controllable pore structure with a high surface-to-volume ratio and excellent electrical conductivity [13][14]. In particular, nitrogen-doped carbon materials have shown electrocatalytic activity towards the ORR and/or OER, which would be a

Experimental and theoretical study of field-dependent spin splitting at ferromagnetic insulator–superconductor interfaces

• Peter Machon,
• Michael J. Wolf,
• Detlef Beckmann and
• Wolfgang Belzig

Beilstein J. Nanotechnol. 2022, 13, 682–688, doi:10.3762/bjnano.13.60

• = e2/h is the conductance quantum, and G = σNA/d is the conductance of the film (in the direction perpendicular to the interface of cross section A). D and σN are the diffusion constant and the normal-state conductivity of the film, respectively. Note, that due to the normalization condition for

• is the Boltzmann constant, and Tc is the critical temperature of the bulk superconductor. Using the conductivity the density of states at the Fermi energy of the free electron gas, and for the number of channels per area, we can simplify this to where vF is the Fermi velocity. With the definition

Tunable high-quality-factor absorption in a graphene monolayer based on quasi-bound states in the continuum

• Jun Wu,
• Yasong Sun,
• Feng Wu,
• Biyuan Wu and
• Xiaohu Wu

Beilstein J. Nanotechnol. 2022, 13, 675–681, doi:10.3762/bjnano.13.59

• structure, graphene supports much stronger binding of surface plasmon polaritons (SPPs) with less loss, which leads to a longer propagation distance compared with traditional metal SPPs [35]. In addition, its conductivity can be dynamically controlled by chemical doping or electrostatic fields owing to the

• . TM polarized (the magnetic field is along the direction of the y-axis) monochromatic plane waves are incident from the substrate at an angle θ. In our simulation, we set d = 3.3 μm, w = 2.31 μm, h = 3.5 μm, nh = 3.48, ns = 1.45, and θ = 0.1°. The surface conductivity of graphene has intraband and

• interband contributions and is described by: Here, σintra and σinter are the intraband and interband conductivity, respectively. In the mid-infrared wavelength region considered in this work, the Fermi level is greater than half of the photon energy, that is, ℏω < 2Ef. Thus, the intraband contribution will