Electron-induced deposition using Fe(CO)₄MA and Fe(CO)₅ – effect of MA ligand and process conditions

• Hannah Boeckers,
• Atul Chaudhary,
• Petra Martinović,
• Amy V. Walker,
• Lisa McElwee-White and
• Petra Swiderek

Beilstein J. Nanotechnol. 2024, 15, 500–516, doi:10.3762/bjnano.15.45

• ascribed to C–H bond cleavage within the MA ligand or in potential products formed from MA during electron irradiation. A second ESD experiment was performed under the same conditions to record the time evolution of specific m/z ratios during irradiation (Figure 3). Three irradiation steps of 2000 µC/cm2

Sidewall angle tuning in focused electron beam-induced processing

• Sangeetha Hari,
• Willem F. van Dorp,
• Johannes J. L. Mulders,
• Piet H. F. Trompenaars,
• Pieter Kruit and
• Cornelis W. Hagen

Beilstein J. Nanotechnol. 2024, 15, 447–456, doi:10.3762/bjnano.15.40

• etching the deposit from below, resulting in under-etched structures. The evolution of the sidewall angle during etching has also been experimentally observed in a scanning electron microscope by continuously monitoring the secondary electron detector signal. Keywords: electron lithography; FEBID; FEBIE

• incidence x [9]; thus, the etching is enhanced by the same factor. Directing the beam to a fixed position on the sloped sidewall, the Gaussian profile, multiplied by the local SE-yield enhancement factor, governs the etching of the deposit, given a fixed etching strength. Figure 2b illustrates the evolution

• , section S1 for more details on the simulation). Sidewall slope evolution under FEBIE To experimentally study the modification of the sidewalls of a FEBID structure, carbon structures were first deposited on a silicon substrate with a 20 nm gold–palladium layer and a 5 nm titanium adhesion layer. The

Heat-induced morphological changes in silver nanowires deposited on a patterned silicon substrate

• Elyad Damerchi,
• Sven Oras,
• Edgars Butanovs,
• Allar Liivlaid,
• Mikk Antsov,
• Boris Polyakov,
• Annamarija Trausa,
• Veronika Zadin,
• Andreas Kyritsakis,
• Loïc Vidal,
• Karine Mougin,
• Siim Pikker and
• Sergei Vlassov

Beilstein J. Nanotechnol. 2024, 15, 435–446, doi:10.3762/bjnano.15.39

• affect the outcome of the experiment since in any case defects caused by heating/cooling (hence, tensile compression) cycles will result in reduced thermal stability of the suspended part compared to the adhered part. Note that, as mentioned earlier, the morphology evolution in the adhered parts is

• of the NW with subsequent evolution into necking and finally splitting (Figure 9b, Figure 9c). It should be noted that the goal of the MD simulations was only to qualitatively evaluate the role of the thermomechanically induced defects in the fragmentation of five-fold twinned Ag NWs. Therefore, the

Unveiling the nature of atomic defects in graphene on a metal surface

• Karl Rothe,
• Nicolas Néel and
• Jörg Kröger

Beilstein J. Nanotechnol. 2024, 15, 416–425, doi:10.3762/bjnano.15.37

• presence of graphene [48]. The -shaped feature with minimum signal slightly below zero bias may be associated with the Dirac cone at the BZ -point. Figure 1d reveals the spatial evolution of the spectra, which shows a gradual quenching of the Ir(111) surface resonance signal accompanied by a small shift

• ). The lateral evolution of the dI/dV spectra hints at a markedly different character of defects 1 and 2, which will further be explored on the basis of the AFM results to be discussed below. They will clarify structural aspects of the defects and help understand the different spectroscopic properties

• an Ar+-induced Ir(111) surface defect [57]. In a next step, AFM imaging of the defects at different tip–surface distances was complemented by spatially resolved Δf(Δz) measurements (Figure 4). Figure 4a shows the evolution of the total vertical force recorded along the path across a type-1 defect

Classification and application of metal-based nanoantioxidants in medicine and healthcare

• Nguyen Nhat Nam,
• Nguyen Khoi Song Tran,
• Tan Tai Nguyen,
• Nguyen Ngoc Trai,
• Nguyen Phuong Thuy,
• Hoang Dang Khoa Do,
• Nhu Hoa Thi Tran and
• Kieu The Loan Trinh

Beilstein J. Nanotechnol. 2024, 15, 396–415, doi:10.3762/bjnano.15.36

• nanotechnology, especially for reducing oxidative stress. Review Metal-based nanomaterials exhibiting antioxidant activities Preventive metal-based nanoantioxidants Along the evolution, the human body has naturally developed a complex antioxidant defense system, which uses endogenous non-enzymatic and enzymatic

Investigating ripple pattern formation and damage profiles in Si and Ge induced by 100 keV Ar⁺ ion beam: a comparative study

• Indra Sulania,
• Harpreet Sondhi,
• Tanuj Kumar,
• Sunil Ojha,
• G R Umapathy,
• Ambuj Mishra,
• Ambuj Tripathi,
• Richa Krishna,
• Devesh Kumar Avasthi and
• Yogendra Kumar Mishra

Beilstein J. Nanotechnol. 2024, 15, 367–375, doi:10.3762/bjnano.15.33

• displays two steps corresponding to the backscattering from Si and Ar for channel numbers ≈1050 and ≈1275, respectively. Defect clustering may lead to a subsequent increase of the damage peak in irradiated samples as compared to that of pristine Si and Ge samples. To understand the evolution of the lattice

Nanomedicines against Chagas disease: a critical review

• Maria Jose Morilla,
• Kajal Ghosal and
• Eder Lilia Romero

Beilstein J. Nanotechnol. 2024, 15, 333–349, doi:10.3762/bjnano.15.30

• 2025 driven by the evolution of vaccines against COVID-19 based on nanomedicines and the projected huge global demand for these products [105]. However, the clinical translatability of nanomedicines is still complex. Consider, for instance, the liposomal formulation of the antifungal amphotericin B

Investigating structural and electronic properties of neutral zinc clusters: a G₀W₀ and G₀W₀Г₀⁽¹⁾ benchmark

• Sunila Bakhsh,
• Muhammad Khalid,
• Sameen Aslam,
• Muhammad Sohail,
• Muhammad Aamir Iqbal,
• Mujtaba Ikram and
• Kareem Morsy

Beilstein J. Nanotechnol. 2024, 15, 310–316, doi:10.3762/bjnano.15.28

• PBE functional. The binding energies show the two-knee behavior also seen in metal clusters of various species. Electronic properties, such as IP, EA, and the relative hardness of the clusters, have been obtained using the G0W0@PBE in FHI-aims. The IP benchmark shows the size evolution behavior of the

Determining by Raman spectroscopy the average thickness and N-layer-specific surface coverages of MoS₂ thin films with domains much smaller than the laser spot size

• Felipe Wasem Klein,
• Jean-Roch Huntzinger,
• Vincent Astié,
• Damien Voiry,
• Romain Parret,
• Houssine Makhlouf,
• Sandrine Juillaguet,
• Jean-Manuel Decams,
• Sylvie Contreras,
• Périne Landois,
• Ahmed-Azmi Zahab,
• Jean-Louis Sauvajol and
• Matthieu Paillet

Beilstein J. Nanotechnol. 2024, 15, 279–296, doi:10.3762/bjnano.15.26

• Supporting Information File 1, the frequency and the linewidth of the Si mode as functions of the laser power are displayed (Figure S2). These two parameters are found to be insensitive to Pλ below 0.5 mW. More intriguing is the evolution of the frequency (Figure 2a) and width (Figure 2b) of the phonon modes

• expected by considering a simple thermal effect. Consequently, the results reported in Figure 2c clearly evidence photo-doping of 1L-MoS2 concomitant with a thermal effect, as already observed for MoS2 on SiO2/Si [45] as well as for graphene [42]. Furthermore, the evolution of the A′1 and E′ widths with Pλ

Ultrasensitive and ultrastretchable metal crack strain sensor based on helical polydimethylsiloxane

• Shangbi Chen,
• Dewen Liu,
• Weiwei Chen,
• Huajiang Chen,
• Jiawei Li and
• Jinfang Wang

Beilstein J. Nanotechnol. 2024, 15, 270–278, doi:10.3762/bjnano.15.25

• Figure 1c. Concurrently, the microcracks propagate into channel cracks that traverse the entire width of the sample, as illustrated in Figure 1d. The crack structure evolution of the helix metal film under tensile strain ranging from 0 to 300% was observed using an optical microscope, as depicted in

Ion beam processing of DNA origami nanostructures

• Leo Sala,
• Agnes Zerolová,
• Violaine Vizcaino,
• Alain Mery,
• Alicja Domaracka,
• Hermann Rothard,
• Philippe Boduch,
• Dominik Pinkas and
• Jaroslav Kocišek

Beilstein J. Nanotechnol. 2024, 15, 207–214, doi:10.3762/bjnano.15.20

• , respectively. In vacuum, material from the structures may sublime. In air, it is plausible that the stochastic irradiation transforms into uniform changes on the structure, which can be controlled by DNA origami design. Supporting Information Height evolution upon thermal processing of DNA origami deposited

Exploring disorder correlations in superconducting systems: spectroscopic insights and matrix element effects

• Vyacheslav D. Neverov,
• Alexander E. Lukyanov,
• Andrey V. Krasavin,
• Alexei Vagov,
• Boris G. Lvov and
• Mihail D. Croitoru

Beilstein J. Nanotechnol. 2024, 15, 199–206, doi:10.3762/bjnano.15.19

• the corresponding DOS; the graphs are shifted vertically for clarity. Dependence of the spectral gap on the disorder for various correlation strengths α. The evolution of the gap depends significantly on the level of correlations in the disorder. Notably, the gap’s dependence curve aligns closely with

Influence of conductive carbon and MnCo₂O₄ on morphological and electrical properties of hydrogels for electrochemical energy conversion

• Sylwia Pawłowska,
• Karolina Cysewska,
• Yasamin Ziai,
• Jakub Karczewski,
• Piotr Jasiński and
• Sebastian Molin

Beilstein J. Nanotechnol. 2024, 15, 57–70, doi:10.3762/bjnano.15.6

• composite acted as an electrocatalyst in the oxygen evolution reaction. Morphological studies confirmed that the added particles were incorporated and, in the case of a higher concentration of cCB particles, also bound to the surface of the structure of the hydrogel matrix. The produced composite materials

• catalytic activity of the electrode in the oxygen evolution reaction. The use of a hydrogel as a matrix to suspend the catalyst particles, and thus increase their availability through the electrolyte, seems to be an interesting and promising application approach. Keywords: electrical properties; energy

• ; hydrogel; hydrogen; oxygen evolution reaction; polymer composites; Introduction Hydrogels are defined as a group of polymeric materials with an insoluble hydrophilic structure which gives them the ability to absorb and hold large amounts of water (up to over 99 wt %) in their three-dimensional network

Measurements of dichroic bow-tie antenna arrays with integrated cold-electron bolometers using YBCO oscillators

• Leonid S. Revin,
• Dmitry A. Pimanov,
• Alexander V. Chiginev,
• Anton V. Blagodatkin,
• Viktor O. Zbrozhek,
• Andrey V. Samartsev,
• Anastasia N. Orlova,
• Dmitry V. Masterov,
• Alexey E. Parafin,
• Victoria Yu. Safonova,
• Anna V. Gordeeva,
• Andrey L. Pankratov,
• Leonid S. Kuzmin,
• Anatolie S. Sidorenko,
• Silvia Masi and
• Paolo de Bernardis

Beilstein J. Nanotechnol. 2024, 15, 26–36, doi:10.3762/bjnano.15.3

• . Keywords: cosmic microwave background; B mode; cold-electron bolometer; dichroic antenna array; dipole bow-tie antenna; Josephson junction; LSPE; Introduction The cosmic microwave background (CMB) radiation contains a lot of information about origin and evolution of our universe. The temperature and

• polarization patterns of the CMB give us an accurate picture of the age of the universe and the evolution after the Big Bang [1]. It is currently assumed that the polarization of the CMB radiation can be decomposed into an E mode and a B mode. The more interesting part of the CMB radiation polarization is the

• Chile in the Atacama desert to study the evolution of the late universe using the Sunyaev–Zeldovich effects. Three frequency bands are used in the Simons Observatory: 30/40, 90/150, and 220/280 GHz. They will be separated by universal focal-plane modules consisting of 432 pixels. It is planned to use

Fluorescent bioinspired albumin/polydopamine nanoparticles and their interactions with Escherichia coli cells

• Eloïse Equy,
• Jordana Hirtzel,
• Sophie Hellé,
• Béatrice Heurtault,
• Eric Mathieu,
• Morgane Rabineau,
• Vincent Ball and
• Lydie Ploux

Beilstein J. Nanotechnol. 2023, 14, 1208–1224, doi:10.3762/bjnano.14.100

• with a molecular weight cut-off at 8–10 kDa to eliminate unbound labelling molecules. The dialysis was done in the dark and repeated three times yielding a total dilution of the dialysate by a factor of 106. The evolution of the dialysis was followed by measuring the absorption spectrum of the

A bifunctional superconducting cell as flux qubit and neuron

• Dmitrii S. Pashin,
• Pavel V. Pikunov,
• Marina V. Bastrakova,
• Andrey E. Schegolev,
• Nikolay V. Klenov and
• Igor I. Soloviev

Beilstein J. Nanotechnol. 2023, 14, 1116–1126, doi:10.3762/bjnano.14.92

• l). Here and further, we use magnetic fluxes normalised by the quantum value, Φ0. To investigate the flux-to-flux transfer characteristics of such a system, it is convenient to interpret its evolution as the movement of a particle with “mass” M = and “momentum” p = in the potential profile defined

• , localised at the level with energy E0. The evolution of energy level population and instantaneous energy levels was numerically calculated for the n = 10 lowest energy levels of the quantum interferometer. As shown in Figure 2a,b, during rise and fall of the field, the instantaneous energy levels are

• , another important factor (in addition to relaxation) that influences the evolution of observable quantities for an interferometer is thermal fluctuations. It is known that the operating temperature, T, of quantum circuits with Josephson junctions is chosen much smaller than the characteristic temperature

Properties of tin oxide films grown by atomic layer deposition from tin tetraiodide and ozone

• Kristjan Kalam,
• Peeter Ritslaid,
• Tanel Käämbre,
• Aile Tamm and
• Kaupo Kukli

Beilstein J. Nanotechnol. 2023, 14, 1085–1092, doi:10.3762/bjnano.14.89

• about two times larger than for a process using SnI4 and O2. Dependence of SnO2 film GPC on the evaporation temperature of the SnI4 precursor. The cycle times were set at 5-2-5-5 s for the sequence SnI4 pulse, purge, O3 pulse, and purge. Time evolution of the QCM mass sensor signal during five

Spatial mapping of photovoltage and light-induced displacement of on-chip coupled piezo/photodiodes by Kelvin probe force microscopy under modulated illumination

• Zeinab Eftekhari,
• Nasim Rezaei,
• Hidde Stokkel,
• Jian-Yao Zheng,
• Andrea Cerreta,
• Ilka Hermes,
• Minh Nguyen,
• Guus Rijnders and
• Rebecca Saive

Beilstein J. Nanotechnol. 2023, 14, 1059–1067, doi:10.3762/bjnano.14.87

• indicates the temporal evolution of this timeline throughout the measurement process. These scans indicate the reproducibility of acquired displacement and photovoltage under modulated illumination at a single point. To analyze them, we extracted 10 line profiles depicted in blue and red for topography and

Low temperature atomic layer deposition of cobalt using dicobalt hexacarbonyl-1-heptyne as precursor

• Mathias Franz,
• Mahnaz Safian Jouzdani,
• Lysann Kaßner,
• Marcus Daniel,
• Frank Stahr and
• Stefan E. Schulz

Beilstein J. Nanotechnol. 2023, 14, 951–963, doi:10.3762/bjnano.14.78

• growth rate (blue diamonds) extracted by using a linear growth approximation. XPS measurements of the CVD film deposited at 150 °C. Growth per cycle of ALD processes with [Co2(CO)6HC≡CC5H11] precursor at various temperatures. Film thickness evolution measured by in line spectroscopic ellipsometry for a

Biomimetics on the micro- and nanoscale – The 25th anniversary of the lotus effect

• Matthias Mail,
• Kerstin Koch,
• Thomas Speck,
• William M. Megill and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2023, 14, 850–856, doi:10.3762/bjnano.14.69

• prevent insects from climbing out. This surface structure is the opposite of adhesive surfaces. e) A dragonfly. Archetype for robotic applications but also known for their superhydrophobic and transparent wings. f) An example of the early evolution of superhydrophobic surfaces: the leaf of a ginkgo tree

Ultralow-energy amorphization of contaminated silicon samples investigated by molecular dynamics

• Grégoire R. N. Defoort-Levkov,
• Alan Bahm and
• Patrick Philipp

Beilstein J. Nanotechnol. 2023, 14, 834–849, doi:10.3762/bjnano.14.68

• implantation of higher-energy argon ions. To elaborate the analysis of the amorphization coefficient, we plotted the variation of the thickness for each region of interest for all simulation conditions. In Figure 3, we show the evolution of the slab thickness for the amorphous and partially amorphous regions

• , and so is the implantation of the atoms from the water molecules. Their implantation depends on the energy transmitted to the water molecules via elastic collisions with argon atoms or other species in the sample. Figure 5 shows the evolution of the implantation depth of argon atoms for the different

• detailed information on the sputtering processes, and in particular on the sputtering of clusters and on the evolution of the fraction of intact water molecules can be found in Supporting Information File 1. Conclusion From all the observations made before we can distinguish several interesting cases for

A wearable nanoscale heart sound sensor based on P(VDF-TrFE)/ZnO/GR and its application in cardiac disease detection

• Yi Luo,
• Jian Liu,
• Jiachang Zhang,
• Yu Xiao,
• Ying Wu and
• Zhidong Zhao

Beilstein J. Nanotechnol. 2023, 14, 819–833, doi:10.3762/bjnano.14.67

• bottle was sealed and placed in a shaking mixer and shaken for 3 h. Next, ZnO nanoparticles (Shanghai Keyan Industrial Co., Ltd., particle size 3 ± 5 nm, content ≥99.8%) and GR filler (Shenzhen Turing Evolution Technology Co., Ltd., carbon content 98%, average diameter/thickness ratio = 9500) were added

In situ magnesiothermic reduction synthesis of a Ge@C composite for high-performance lithium-ion batterie anodes

• Ha Tran Huu,
• Ngoc Phi Nguyen,
• Vuong Hoang Ngo,
• Huy Hoang Luc,
• Minh Kha Le,
• Minh Thu Nguyen,
• My Loan Phung Le,
• Hye Rim Kim,
• In Young Kim,
• Sung Jin Kim,
• Van Man Tran and
• Vien Vo

Beilstein J. Nanotechnol. 2023, 14, 751–761, doi:10.3762/bjnano.14.62

• carried out for structural and phase information. Infrared (IR, Shimadzu IRAffinity-1S) and Raman (LabRAM HR evolution confocal Raman microscope) spectra were measured for bond analysis. Field-emission scanning electron microscopy (FE-SEM, Hitachi S-4800) and high-resolution transmission electron

Cross-sectional Kelvin probe force microscopy on III–V epitaxial multilayer stacks: challenges and perspectives

• Mattia da Lisca,
• José Alvarez,
• James P. Connolly,
• Nicolas Vaissiere,
• Karim Mekhazni,
• Jean Decobert and
• Jean-Paul Kleider

Beilstein J. Nanotechnol. 2023, 14, 725–737, doi:10.3762/bjnano.14.59

• the narrower interlayers and of the position of the metallurgical junctions at the InP:nid/InP:Zn and the InP:Zn/GaInAsP:Zn interfaces, which were more undefined in the previous VCPD/dark image. Overall, the VCPD/light profile follows the same evolution as the profile of VCPD/dark; also in this case

• profile at equilibrium of the surface band energies (black: valence band maximum, EV, and red: conduction band minimum, EC) along the structure assumed free of any surface defects. The constant Fermi level, EF, is taken as the energy reference (blue horizontal line). (b) VCPD evolution along the same

Nanomaterials for photocatalysis and applications in environmental remediation and renewable energy

• Viet Van Pham and
• Wee-Jun Ong

Beilstein J. Nanotechnol. 2023, 14, 722–724, doi:10.3762/bjnano.14.58

• Wee-Jun Ong Ho Chi Minh City and Sepang, June 2023. A general photocatalytic mechanism for several possible target processes: (1) NOx degradation, (2) water splitting for hydrogen and oxygen evolution reactions, (3) degradation of organic pollutants, and (4) solar cell application. Acknowledgements