Liver-targeting iron oxide nanoparticles and their complexes with plant extracts for biocompatibility

• Shushanik A. Kazaryan,
• Seda A. Oganian,
• Gayane S. Vardanyan,
• Anatolie S. Sidorenko and
• Ashkhen A. Hovhannisyan

Beilstein J. Nanotechnol. 2024, 15, 1593–1602, doi:10.3762/bjnano.15.125

• MassLynx data processing software. Separation was done on a C-18 column (Knauer, Germany, 250 × 4 mm, particle size 4.5 nm) at an elution rate of 1 mL/min with the following gradient elution system: HPLC-grade water with 0.1% orthophosphoric acid (solution A, Carlo Erba, France), acetonitrile (solution B

Strain-induced bandgap engineering in 2D ψ-graphene materials: a first-principles study

• Kamal Kumar,
• Nora H. de Leeuw,
• Jost Adam and
• Abhishek Kumar Mishra

Beilstein J. Nanotechnol. 2024, 15, 1440–1452, doi:10.3762/bjnano.15.116

• ), with finite states present at the Fermi level (Ef). The dominant energy orbitals in the projected density of states (PDOS) of ψ-graphene and ψ-graphone are the outermost C 2p orbitals. In the fully hydrogenated form, that is, in ψ-graphane, we note a discernible separation of 3.78 eV between the

• applied to ψ-graphone sheets. Beyond the +10% strain level, suddenly, the separation between the bands increases to 2.00 eV, and on further increasing the magnitude of applied positive strain, it reduces to 1.50 eV at +16% strain value. Negative strain A remarkable observation is made regarding the

• electrical properties (Supporting Information File 1, Figures S9 and S10) when ψ-graphone undergoes negative mechanical strain ranging from −1% to −16% in its lattice plane. ψ-Graphone maintains its semiconducting nature within this negative strain range, and random separation is found between the valence

Out-of-plane polarization induces a picosecond photoresponse in rhombohedral stacked bilayer WSe₂

• Guixian Liu,
• Yufan Wang,
• Zhoujuan Xu,
• Zhouxiaosong Zeng,
• Lanyu Huang,
• Cuihuan Ge and
• Xiao Wang

Beilstein J. Nanotechnol. 2024, 15, 1362–1368, doi:10.3762/bjnano.15.109

• research on internal carrier dynamics. Ultrafast photoresponse in the vertical graphene/3R WSe2/graphene heterojunction Theoretically, the OOP polarization in 3R WSe2 accelerates the separation of photogenerated carriers, suggesting that the vertical heterojunction may exhibit a fast photoresponse. We

• ultrashort channel length in the vertical direction but also from the OOP polarization of WSe2. In 3R WSe2, polarization accumulates with increasing layer thickness, resulting in a higher polarization value in thicker multilayered 3R WSe2 nanoflakes, which will accelerate the separation of photogenerated

Investigation of Hf/Ti bilayers for the development of transition-edge sensor microcalorimeters

• Victoria Y. Safonova,
• Anna V. Gordeeva,
• Anton V. Blagodatkin,
• Dmitry A. Pimanov,
• Anton A. Yablokov and
• Andrey L. Pankratov

Beilstein J. Nanotechnol. 2024, 15, 1353–1361, doi:10.3762/bjnano.15.108

• regions the critical temperature is different. Furthermore, such a protracted transition can be explained by the effect of phase separation in a film of large size, that is, it becomes superconducting in parts. The film sample C1, unlike samples A1–A4 and B1, shows thermal hysteresis, which is expressed

Nanoarchitectonics with cetrimonium bromide on metal nanoparticles for linker-free detection of toxic metal ions and catalytic degradation of 4-nitrophenol

• Akash Kumar and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2024, 15, 1312–1332, doi:10.3762/bjnano.15.106

• of 190–800 nm, a degreaser (DGU-20A5R), autosampler (SIL-30AD), and quaternary pump (LC-30AD). The separation peak for CTAB was analyzed using HpersilGoldTM C18 (100 × 2.1 mm, 10 μm) with a pore diameter of 1.9 μm. The injection volume was 5 µL, and the wavelength was 208 nm for CTAB quantification

Mn-doped ZnO nanopowders prepared by sol–gel and microwave-assisted sol–gel methods and their photocatalytic properties

• Cristina Maria Vlăduț,
• Crina Anastasescu,
• Silviu Preda,
• Oana Catalina Mocioiu,
• Simona Petrescu,
• Jeanina Pandele-Cusu,
• Dana Culita,
• Veronica Bratan,
• Ioan Balint and
• Maria Zaharescu

Beilstein J. Nanotechnol. 2024, 15, 1283–1296, doi:10.3762/bjnano.15.104

• catalyst is generally associated with low photocatalytic activity. Accordingly, various modifiers of semiconductor nanomaterials are used to enhance separation of the photogenerated charges, causing a corresponding decrease of PL emission. The correlation between photoluminescence and photocatalytic

Photocatalytic methane oxidation over a TiO₂/SiNWs p–n junction catalyst at room temperature

• Qui Thanh Hoai Ta,
• Luan Minh Nguyen,
• Ngoc Hoi Nguyen,
• Phan Khanh Thinh Nguyen and
• Dai Hai Nguyen

Beilstein J. Nanotechnol. 2024, 15, 1132–1141, doi:10.3762/bjnano.15.92

• crucial in photogenerated charge separation and adsorption enhancement under UV–vis light. In other words, the ethane productivity of TiO2/Si NWs was five times higher (210 µmol/cm2) than that of pure p-Si NWs (20 µmol/cm2) and glass/TiO2 (30 µmol/cm2). Photocatalytic OCM over TiO2/Si NWs catalysts was

Effect of wavelength and liquid on formation of Ag, Au, Ag/Au nanoparticles via picosecond laser ablation and SERS-based detection of DMMP

• Sree Satya Bharati Moram,
• Chandu Byram and
• Venugopal Rao Soma

Beilstein J. Nanotechnol. 2024, 15, 1054–1069, doi:10.3762/bjnano.15.86

• . Ablation experiments were performed at a pulse energy of 12 mJ with the corresponding laser fluence of ≈30 mJ/cm2. The moving target was irradiated using a separation of 50 μm between two adjacent lines at a translation speed of 1 mm/s along both directions. The total laser-processing area on the target

Electrospun nanofibers: building blocks for the repair of bone tissue

• Tuğrul Mert Serim,
• Gülin Amasya,
• Tuğba Eren-Böncü,
• Ceyda Tuba Şengel-Türk and
• Ayşe Nurten Özdemir

Beilstein J. Nanotechnol. 2024, 15, 941–953, doi:10.3762/bjnano.15.77

• the literature including inter-surface polymerization, phase separation, drawing, self-assembly, melt blowing, template melt extrusion, forcespinning, and electrospinning [36][37][38][39][40]. Only electrospinning will be further explained in detail in order to remain within the scope. Electrospinning

• produced using various production techniques such as self-coupling and phase separation, and especially electrospinning. Electrospinning is a simple, scalable and versatile fabrication method for the production of various nanofiber formulations from a large number of different polymers. Polymer fiber

Facile synthesis of Fe-based metal–organic frameworks from Fe₂O₃ nanoparticles and their application for CO₂/N₂ separation

• Van Nhieu Le,
• Hoai Duc Tran,
• Minh Tien Nguyen,
• Hai Bang Truong,
• Toan Minh Pham and
• Jinsoo Kim

Beilstein J. Nanotechnol. 2024, 15, 897–908, doi:10.3762/bjnano.15.74

• separation performance of the as-prepared MIL-100(Fe) samples were investigated. Using 1.80 g of trimesic acid in the reaction system yielded the sample M-100Fe@Fe2O3#1.80, which proved to be the optimal sample. This choice struck a balance between the amount of required trimesic acid and the quality of the

• resulting material, resulting in a high yield of 81% and an impressive BET surface area of 1365.4 m2·g−1. At 25 °C and 1 bar, M-100Fe@Fe2O3#1.80 showed a CO2 adsorption capacity of 1.10 mmol·g−1 and an IAST-predicted CO2/N2 selectivity of 18, outperforming conventional adsorbents in CO2/N2 separation

• . Importantly, this route opens a new approach to utilizing Fe2O3-based waste materials from the iron and steel industry in manufacturing Fe-based MIL-100 materials. Keywords: CO2/N2 separation; Fe2O3 nanoparticles; hydrothermal reaction; IAST-predicted CO2/N2 selectivity; MIL-100(Fe); Introduction Metal

Investigation on drag reduction on rotating blade surfaces with microtextures

• Qinsong Zhu,
• Chen Zhang,
• Fuhang Yu and
• Yan Xu

Beilstein J. Nanotechnol. 2024, 15, 833–853, doi:10.3762/bjnano.15.70

• ]. Lang et al. [8] constructed rectangular and sinusoidal grooves with 2 mm in width, 3 mm in depth, and 1 mm in spacing, thus mimicking the transverse grooves on the surface of dolphin skin. They observed the effect of the grooves on flow separation and boundary layer using digital particle image

• and outward dimple-like structures on the upper surface of a NACA 4415 airfoil. The results from wind tunnel experiments showed that the dimples on the airfoil surface delayed flow separation; the inward dimples increased lift by 16.43% and reduced drag by 46.66%. However, while these researches have

• reasons: (1) There is a lack of analysis on the flow field over smooth blades. The phenomenon of flow separation on blades occurs because of the complex curved surface in the air flow. The placement position of microstructures needs to be determined based on the locations of flow separation on blade

Intermixing of MoS₂ and WS₂ photocatalysts toward methylene blue photodegradation

• Maryam Al Qaydi,
• Nitul S. Rajput,
• Michael Lejeune,
• Abdellatif Bouchalkha,
• Mimoun El Marssi,
• Steevy Cordette,
• Chaouki Kasmi and
• Mustapha Jouiad

Beilstein J. Nanotechnol. 2024, 15, 817–829, doi:10.3762/bjnano.15.68

• cocatalysts. Their catalytic properties can be tailored based on their crystal structure, their surface area, and their morphology [12][13]. When TMD catalysts are intermixed, they form semiconductor–semiconductor junctions, enhancing their photocatalytic properties by promoting charge separation and electron

• valence band of MoS2 to WS2, potentially being captured by water molecules to form hydroxyl radicals. These hydroxyl radicals, in conjunction with valence band holes, contribute to the degradation of MB molecules into CO2 and H2O, as reported in different studies [42][43][44]. The effective separation of

Electron-induced ligand loss from iron tetracarbonyl methyl acrylate

• Hlib Lyshchuk,
• Atul Chaudhary,
• Thomas F. M. Luxford,
• Miloš Ranković,
• Jaroslav Kočišek,
• Juraj Fedor,
• Lisa McElwee-White and
• Pamir Nag

Beilstein J. Nanotechnol. 2024, 15, 797–807, doi:10.3762/bjnano.15.66

• and Technology, Technická 5, 16628 Prague, Czech Republic Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, United States 10.3762/bjnano.15.66 Abstract We probe the separation of ligands from iron tetracarbonyl methyl acrylate (Fe(CO)4(C4H6O2) or Fe(CO)4MA) induced by

• fragmentation pattern increases, and more complete ligand separation occurs. It is particularly interesting that, with increasing electron energy, the loss of the MA ligand (formation of m/z = 168, Fe(CO)4−) is becoming dominant over the loss of one carbonyl ligand (m/z = 226). There are also fragments visible

Laser synthesis of nanoparticles in organic solvents – products, reactions, and perspectives

• Theo Fromme,
• Sven Reichenberger,
• Katharine M. Tibbetts and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2024, 15, 638–663, doi:10.3762/bjnano.15.54

• structures on top of surfactant-free gold, silver, and copper nanoparticles after adding polyynes, while Zhang et al. performed ablation of silver in acetone with long-term storage, which resulted in shape alteration, size separation, and changes in the carbon shells. As such, molecular hydrocarbons with

Radiofrequency enhances drug release from responsive nanoflowers for hepatocellular carcinoma therapy

• Yanyan Wen,
• Ningning Song,
• Yueyou Peng,
• Weiwei Wu,
• Qixiong Lin,
• Minjie Cui,
• Rongrong Li,
• Qiufeng Yu,
• Sixue Wu,
• Yongkang Liang,
• Wei Tian and
• Yanfeng Meng

Beilstein J. Nanotechnol. 2024, 15, 569–579, doi:10.3762/bjnano.15.49

• solution was then put into a microwave reactor at 200 °C for 2 h. After the reactants cooled to room temperature, Fe3O4 NCs were obtained by magnetic separation followed by vacuum drying at 60 °C for 24 h. Synthesis of CUR-Fe NPs Fe3O4 NCs (12 mg) were dispersed into acetonitrile (60 mL) with

• -Fe NPs were subsequently collected by magnetic separation and stored for the next step. In addition, the content of CUR in the supernatant was detected by a microplate reader (SPECTRAMAX190, Molecular Devices, USA) at 426 nm. DLE and DEE were calculated according to the following equations: where

• CUR-Fe@MnO2 NFs were collected by magnetic separation and washed 3 times with deionized water. Characterization of the synthesized nanomaterials The morphology and size of Fe3O4 NCs, CUR-Fe NPs, and CUR-Fe@MnO2 NFs were determined via transmission electron microscopy (Tecnai F20, FEI, USA). The TEM

Photocatalytic degradation of methylene blue under visible light by cobalt ferrite nanoparticles/graphene quantum dots

• Vo Chau Ngoc Anh,
• Le Thi Thanh Nhi,
• Le Thi Kim Dung,
• Dang Thi Ngoc Hoa,
• Nguyen Truong Son,
• Nguyen Thi Thao Uyen,
• Nguyen Ngoc Uyen Thu,
• Le Van Thanh Son,
• Le Trung Hieu,
• Tran Ngoc Tuyen and
• Dinh Quang Khieu

Beilstein J. Nanotechnol. 2024, 15, 475–489, doi:10.3762/bjnano.15.43

• nanoparticles of around 9.2 nm are obvious on the GQDs. Such a good interfacial contact between CF and GQDs is favourable for the separation of the photogenerated charge carriers in the CF/GQDs. The elemental distribution of CF/GQDs was studied by EDX mapping. The elements Fe, Co, O, and C are present, as

• nanoparticles exhibit a significantly lower PL emission intensity than CF alone because of the higher separation efficiency of charge carriers of the CF/GQDs sample. The UV–vis DRS spectra of CF and CF/GQDs (Figure 6b) show that the absorption intensity becomes stronger after grafting the GQDs on CF, indicating

Sidewall angle tuning in focused electron beam-induced processing

• Sangeetha Hari,
• Willem F. van Dorp,
• Johannes J. L. Mulders,
• Piet H. F. Trompenaars,
• Pieter Kruit and
• Cornelis W. Hagen

Beilstein J. Nanotechnol. 2024, 15, 447–456, doi:10.3762/bjnano.15.40

• separation of 700 nm. The height of the deposits was approximately 40 nm. An etch pattern comprising nine lines of 400 nm length was defined to etch the right sidewall of each deposit. This array was aligned such that each subsequent etch was positioned 20 nm farther away from the centre of the corresponding

Unveiling the nature of atomic defects in graphene on a metal surface

• Karl Rothe,
• Nicolas Néel and
• Jörg Kröger

Beilstein J. Nanotechnol. 2024, 15, 416–425, doi:10.3762/bjnano.15.37

• inversion is induced by the reduction of the tip–graphene separation. As will be shown below, the involved junction currents correspond to a separation that is still larger than, but close to, the point of maximum attractive force. Therefore, a tentative rationale to the observed contrast inversion is the

Insect attachment on waxy plant surfaces: the effect of pad contamination by different waxes

• Elena V. Gorb and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2024, 15, 385–395, doi:10.3762/bjnano.15.35

• particles forming a separation layer between insect pads and the plant surface and serving as a kind of lubricant (separation layer hypothesis) [7][13]. To date, several experimental studies have been performed to test the first three hypotheses. As for the roughness hypothesis, it was revealed in

Determining by Raman spectroscopy the average thickness and N-layer-specific surface coverages of MoS₂ thin films with domains much smaller than the laser spot size

• Felipe Wasem Klein,
• Jean-Roch Huntzinger,
• Vincent Astié,
• Damien Voiry,
• Romain Parret,
• Houssine Makhlouf,
• Sandrine Juillaguet,
• Jean-Manuel Decams,
• Sylvie Contreras,
• Périne Landois,
• Ahmed-Azmi Zahab,
• Jean-Louis Sauvajol and
• Matthieu Paillet

Beilstein J. Nanotechnol. 2024, 15, 279–296, doi:10.3762/bjnano.15.26

• layers and does not depend on the SiO2 thickness (Figure 3a). The separation between N and N + 1 values are larger than the experimental uncertainties (error bars in the graph) up to N = 3. The error bars start to overlap between N = 4 and N = 5. Comparison with data from the literature (see inset in

• Figure 3a) shows that this overlap occurs even between N = 3 and N = 4 when additional variability due to setup and samples is taken into account. Above N = 4, the separation becomes too small compared to the uncertainty. Thus, the measurement of ΔωA−E in exfoliated MoS2 flakes allows one to evaluate

Ultrasensitive and ultrastretchable metal crack strain sensor based on helical polydimethylsiloxane

• Shangbi Chen,
• Dewen Liu,
• Weiwei Chen,
• Huajiang Chen,
• Jiawei Li and
• Jinfang Wang

Beilstein J. Nanotechnol. 2024, 15, 270–278, doi:10.3762/bjnano.15.25

• microcracks in the Au thin film. The resistance of the sensor is altered when strain is applied because of the separation of overlapping scales and the generation of cracks in the gold thin film. The strain sensor is fabricated through a straightforward preparation method, resulting in an exceptionally high

Vinorelbine-loaded multifunctional magnetic nanoparticles as anticancer drug delivery systems: synthesis, characterization, and in vitro release study

• Zeynep Özcan and
• Afife Binnaz Hazar Yoruç

Beilstein J. Nanotechnol. 2024, 15, 256–269, doi:10.3762/bjnano.15.24

• temperature induced by the thermosensitive Fe3O4 NPs. Furthermore, the enhanced heating due to the photothermal properties of PDA facilitated the separation of VNB from the structure [45]. As shown in Figure 5c, it is worth noting that the temperature of PDA/Fe3O4 NPs increased from 25 to 45 °C in 3 min

Multiscale modelling of biomolecular corona formation on metallic surfaces

• Parinaz Mosaddeghi Amini,
• Ian Rouse,
• Julia Subbotina and
• Vladimir Lobaskin

Beilstein J. Nanotechnol. 2024, 15, 215–229, doi:10.3762/bjnano.15.21

• -tempered metadynamics (AWT-MetaD) simulations, the adsorption energy was calculated at a temperature of 300 K, a pressure of 1.0 bar, and a neutral pH within the NVT ensemble. Additionally, we measured the interaction energy as a function of surface separation distance (SSD) as a collective variable

• , and a CG competitive adsorption model. The figure provides an overview of input and output data at each scale. Adsorption free energy profiles of SCAs on three aluminum fcc slabs as a function of the surface separation distance (SSD). These profiles were calculated using all-atom AWT-MetaD. The

Development and characterization of potential larvicidal nanoemulsions against Aedes aegypti

• Jonatas L. Duarte,
• Leonardo Delello Di Filippo,
• Anna Eliza Maciel de Faria Mota Oliveira,
• Rafael Miguel Sábio,
• Gabriel Davi Marena,
• Tais Maria Bauab,
• Cristiane Duque,
• Vincent Corbel and
• Marlus Chorilli

Beilstein J. Nanotechnol. 2024, 15, 104–114, doi:10.3762/bjnano.15.10

• containing cymene with HLB values of 10–13 showed a yellowish layer on the surface, which may be an indication of phase separation (Figure S1, Supporting Information File 1). Formulations with HLB values of 16 and 16.7 showed a milky appearance and slight creaming, which may be indicative of Ostwald

• , and 21 days after preparation. Signs of instability such as creaming, sedimentation, and phase separation were recorded, as well as physical aspects such as color, transparency, and fluidity. Dynamic light scattering analysis The average hydrodynamic diameter and polydispersity index (PdI) of the NEs

New application of bimetallic Ag/Pt nanoplates in a colorimetric biosensor for specific detection of E. coli in water

• Azam Bagheri Pebdeni,
• Mohammad N. AL-Baiati and
• Morteza Hosseini

Beilstein J. Nanotechnol. 2024, 15, 95–103, doi:10.3762/bjnano.15.9

• assay with the goal of producing a fast and portable biosensor. The paper-based microfluidic system can result in an increased sensitivity due to the shorter amount of sample used without any need for dilution, separation, or pre-treatment through various stages. Conclusion In this research, Ag/Pt NPLs