SERS performance of GaN/Ag substrates fabricated by Ag coating of GaN platforms

• Magdalena A. Zając,
• Bogusław Budner,
• Malwina Liszewska,
• Bartosz Bartosewicz,
• Łukasz Gutowski,
• Jan L. Weyher and
• Bartłomiej J. Jankiewicz

Beilstein J. Nanotechnol. 2023, 14, 552–564, doi:10.3762/bjnano.14.46

• substrates using pulsed laser deposition (PLD) and magnetron sputtering (MS) and their evaluation as potential substrates for surface-enhanced Raman spectroscopy (SERS) are reported. Ag layers of comparable thicknesses were deposited using PLD and MS on nanostructured GaN platforms. All fabricated SERS

• plasmonic metals or their alloys [23][24][25][26][27][28][29][30][31][32]. The chemical and electrochemical etching of GaN heteroepitaxial layers leads to various nanostructures formed on line defects (dislocations), such as straight nanopillars, bunches of nanopillars, and pits [31][32]. The nanostructured

• morphology of fabricated Ag layers examined by scanning electron microscopy (SEM). Then, we present the results of their optical properties determined using UV–vis spectroscopy. Finally, we compare the SERS performance of the GaN/Ag substrates toward 4-mercaptobenzoic acid (pMBA) molecules adsorbed on them

Observation of multiple bulk bound states in the continuum modes in a photonic crystal cavity

• Rui Chen,
• Yi Zheng,
• Xingyu Huang,
• Qiaoling Lin,
• Chaochao Ye,
• Meng Xiong,
• Martijn Wubs,
• Yungui Ma,
• Minhao Pu and
• Sanshui Xiao

Beilstein J. Nanotechnol. 2023, 14, 544–551, doi:10.3762/bjnano.14.45

• along the z direction was applied as the source. Perfectly matched layers are used at all boundaries of the simulation region. The mode patterns are captured by adding a field monitor at the middle plane of the structure. An apodization window is utilized in the monitor to filter out the incident power

Carbon nanotube-cellulose ink for rapid solvent identification

• Tiago Amarante,
• Thiago H. R. Cunha,
• Claudio Laudares,
• Ana P. M. Barboza,
• Ana Carolina dos Santos,
• Cíntia L. Pereira,
• Vinicius Ornelas,
• Bernardo R. A. Neves,
• André S. Ferlauto and
• Rodrigo G. Lacerda

Beilstein J. Nanotechnol. 2023, 14, 535–543, doi:10.3762/bjnano.14.44

• changing the number of painted layers. Figure 1b shows a histogram of the initial resistance distribution of the sensors averaged over around 400 devices, demonstrating the system’s robustness for large-scale production. The resistance distribution was fitted using an exponentially modified Gaussian (EMG

• ) and the calculated mean resistance (with standard deviation) is 1.26 ± 0.07 kΩ. A geometry optimization was also performed to find out the maximum gain response as a function of width, length, and number of painted layers (see Supporting Information File 1 for details). To better understand how MWCNTs

On the use of Raman spectroscopy to characterize mass-produced graphene nanoplatelets

• Keith R. Paton,
• Konstantinos Despotelis,
• Naresh Kumar,
• Piers Turner and
• Andrew J. Pollard

Beilstein J. Nanotechnol. 2023, 14, 509–521, doi:10.3762/bjnano.14.42

• these two extremes, the peak shape evolves gradually, and while the 2D peak from bilayer graphene has been shown to comprise four components, deconvolution for higher layer numbers has not been reliably carried out. The spectrum recorded from flakes with ten or more layers is typically indistinguishable

• from that of bulk graphite. However, it is important to note that this behaviour can be affected by the stacking order. For example, for turbostratic graphite, where there is random rotational alignment between the layers, the 2D band also has the shape of a single Lorentzian line [21]. However, it

• lateral size of 218 nm. We did not attempt to give a number of layers for these flakes. Yet, we do note that while the natural interlayer spacing for graphite is 0.34 nm, it has been reported previously that for similarly produced flakes, monolayer flakes had a measured thickness of 2 nm, with each

Conjugated photothermal materials and structure design for solar steam generation

• Chia-Yang Lin and
• Tsuyoshi Michinobu

Beilstein J. Nanotechnol. 2023, 14, 454–466, doi:10.3762/bjnano.14.36

• the spectral range of terrestrial solar irradiation (Figure 6b and Figure 6c). Single-layer PPy nanosheets transmit 0.2–0.3% of light, while two or more layers of the PPy nanosheets exhibit a very low transmittance over the entire solar spectrum. It is interesting to note that the light absorption

• depends on the number of layers, which was caused by the surface structure of the multilayer PPy nanosheets. The high roughness and sharp local curvature of the multilayer PPy nanosheets were retained and incident light was effectively redistributed. In other words, transmitted light is confined in the

• multilayer PPy nanosheets, and this results in internal light scattering between the layers (Figure 6d). These multilayer nanosheets promote a broadband and wide-angle light absorption across the entire solar spectrum, thus increasing the solar thermal conversion efficiency to 95.33%. Polyaniline

Plasmonic nanotechnology for photothermal applications – an evaluation

• A. R. Indhu,
• L. Keerthana and
• Gnanaprakash Dharmalingam

Beilstein J. Nanotechnol. 2023, 14, 380–419, doi:10.3762/bjnano.14.33

• interaction between inner-core and outer-shell plasmons, PT energy transduction is significantly more effective. The absorption coefficient (Cabs) of the nanomatryushka (NM) can be calculated by varying the volumetric factor of the different layers of the nanostructures and the refractive index of the

Quercetin- and caffeic acid-functionalized chitosan-capped colloidal silver nanoparticles: one-pot synthesis, characterization, and anticancer and antibacterial activities

• Akif Hakan Kurt,
• Elif Berna Olutas,
• Fatma Avcioglu,
• Hamza Karakuş,
• Mehmet Ali Sungur,
• Cansu Kara Oztabag and
• Muhammet Yıldırım

Beilstein J. Nanotechnol. 2023, 14, 362–376, doi:10.3762/bjnano.14.31

• acid, and chitosan) used in the structure of the shell layers. In the FTIR spectrum of pure quercetin (Figure 3a) the bands observed at about 3408 and 3292 cm−1 correspond to phenolic O–H stretching [64]. The peak at 1671 cm−1 stems from the stretching of the C=O carbonyl functional group. The

• Figure 4a and Figure 4b, the Ag NPs covered by chitosan layers comprising quercetin or caffeic acid have mostly spherical shapes. However, both samples also include nanostructures with different shapes, such as rods and triangles, in smaller numbers than the spherical particles. This also resulted in

Biocatalytic synthesis and ordered self-assembly of silica nanoparticles via a silica-binding peptide

• Mustafa Gungormus

Beilstein J. Nanotechnol. 2023, 14, 280–290, doi:10.3762/bjnano.14.25

• structure of silica particles, in which the alternate layers differ in refractive index. The periodic difference in the refractive index creates photonic band gaps, in which certain wavelengths of the light cannot propagate, depending on the size of the periodic structures and the differences in the

Nanotechnology – a robust tool for fighting the challenges of drug resistance in non-small cell lung cancer

• Filip Gorachinov,
• Fatima Mraiche,
• Diala Alhaj Moustafa,
• Ola Hishari,
• Yomna Ismail,
• Jensa Joseph,
• Maja Simonoska Crcarevska,
• Marija Glavas Dodov,
• Nikola Geskovski and
• Katerina Goracinova

Beilstein J. Nanotechnol. 2023, 14, 240–261, doi:10.3762/bjnano.14.23

• nanosized drug delivery carriers: Mixed-layer and multilayered nanocarriers with bioresponsive and cleavable layers, possessing different functional properties for improving the enhanced permeability and retention (EPR) effect, diffusion in the tumor microenvironment, cellular internalization and

Concentration-dependent photothermal conversion efficiency of gold nanoparticles under near-infrared laser and broadband irradiation

• Vikas,
• Raj Kumar and
• Sanjeev Soni

Beilstein J. Nanotechnol. 2023, 14, 205–217, doi:10.3762/bjnano.14.20

• GNPs, the scattering increases in relation to the absorption [30]. Also, with an increase in the concentration of GNPs, the absorption of the incident radiation occurs predominantly in the first few layers of the suspension [31], and there may be interparticle coupling of plasmon reponses, which can be

A novel approach to pulsed laser deposition of platinum catalyst on carbon particles for use in polymer electrolyte membrane fuel cells

• Bogusław Budner,
• Wojciech Tokarz,
• Sławomir Dyjak,
• Andrzej Czerwiński,
• Bartosz Bartosewicz and
• Bartłomiej Jankiewicz

Beilstein J. Nanotechnol. 2023, 14, 190–204, doi:10.3762/bjnano.14.19

• to deposit Pt for the cathode of PEM fuel cells only in a few studies, and in all of them only on gas diffusion layers of carbon fabric or on proton conductive Nafion membrane [27][32][33]. According to our knowledge, no studies have been reported on the PLD deposition of Pt catalyst on carbon

• , Figure S2) were recorded from an area of about 1.5 × 3.5 mm for materials prepared in the form of layers with a thickness of about 0.4 mm. However, due to the small depth of collecting the photoelectrons in XPS (about 3 to 10 nm), the recorded signal comes only from the material’s surface. Consequently

• result mean that the PLD-deposited Pt on the carbon support is oxidized to a higher extent than the reference Pt catalyst. Based on our experience with Pt deposited by PLD as thick continuous layers, slightly oxidized Pt layers can be deposited by the PLD method under vacuum conditions. Thus, we suspect

High–low Kelvin probe force spectroscopy for measuring the interface state density

• Ryo Izumi,
• Masato Miyazaki,
• Yan Jun Li and
• Yasuhiro Sugawara

Beilstein J. Nanotechnol. 2023, 14, 175–189, doi:10.3762/bjnano.14.18

• the localized energy levels of insulating layers on semiconductor surfaces has been reported to be feasible [22]. Therefore, we can expect that the KPFS method described above can be combined with high–low KPFM to measure the energy distribution of the interface states. In this study, we propose high

Combining physical vapor deposition structuration with dealloying for the creation of a highly efficient SERS platform

• Adrien Chauvin,
• Walter Puglisi,
• Damien Thiry,
• Cristina Satriano,
• Rony Snyders and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2023, 14, 83–94, doi:10.3762/bjnano.14.10

• dealloying was performed in HCl for 10, 30, 60, and 120 min. The lamellar structure in the as-prepared sample is due to the rotation of the substrate during deposition. The film presents a multilayer structure composed of Ag-rich and Ag-poor layers which are formed due to distance variation between the

• rotating substrate and the Ag target (i.e., Ag-rich layers are formed when the substrate is close to the Ag target while Ag-poor layers are formed when the substrate is far from the Ag target). The formation of these nanolayers has already been reported in the literature [24][37]. Higher magnification SEM

• ). These small pores highlight the early dealloying stage and the propagating front at the grain boundaries [38]. After 30 min in HCl, bigger pores are formed (Figure 2b) and the cross-section image shows structures made of a porous and full layers (Figure 2f). After 60 min of dealloying, the initial

Liquid phase exfoliation of talc: effect of the medium on flake size and shape

• Samuel M. Sousa,
• Helane L. O. Morais,
• Joyce C. C. Santos,
• Ana Paula M. Barboza,
• Bernardo R. A. Neves,
• Elisângela S. Pinto and
• Mariana C. Prado

Beilstein J. Nanotechnol. 2023, 14, 68–78, doi:10.3762/bjnano.14.8

• substrate appears in black to dark blue. Following previous works, we consider flakes with ten or less layers as “few-layer” [25]. Since talc has a layer thickness of approximately 1 nm [12], we did not convert the height to the number of layers as it is a direct conversion. Few-layer flakes appear in light

• Fernandes and co-workers [24], simply looking at mean flake thickness and standard deviation of a sample does not account well for the volume (or mass) of few-layer flakes versus bulk flakes (thicker than 10.5 nm for talc, which represents 10 or more layers). We calculated the mass ratio of bulk (M) and few

• offer a comparison of the characteristics of the sample. The samples differ more in thickness-related parameters (thus, the number of layers) than in the lateral size-related parameters. To further compare shape-related features of the samples, we plotted topological vectors of pairwise ratios among

Gap-directed chemical lift-off lithographic nanoarchitectonics for arbitrary sub-micrometer patterning

• Chang-Ming Wang,
• Hong-Sheng Chan,
• Chia-Li Liao,
• Che-Wei Chang and
• Wei-Ssu Liao

Beilstein J. Nanotechnol. 2023, 14, 34–44, doi:10.3762/bjnano.14.4

• ) was obtained from the ELGA PURELAB classic system (Taipei, Taiwan). CLL operation processes and bioactive substrates preparation In a manner similar to a previous study [26], silicon substrates with 100 nm thick Au and 5 nm Cr adhesive layers were prepared by thermal evaporation. To prepare a SAM

The influence of structure and local structural defects on the magnetic properties of cobalt nanofilms

• Alexander Vakhrushev,
• Aleksey Fedotov,
• Olesya Severyukhina and
• Anatolie Sidorenko

Beilstein J. Nanotechnol. 2023, 14, 23–33, doi:10.3762/bjnano.14.3

• properties of the nanomaterial were investigated in this work using a promising nanocomposite formed by alternating layers of cobalt and niobium. The proposed composite has potentially promising functional properties and can be used in magnetic systems with controlled effective energy exchange in Josephson

• of the sample. The results of numerical experiments are described in the literature [37][38][39]. The next stage of sample study involved the optimization of the nanofilm interface. The basic magnetic properties of the nanocomposite depend on the quality of the interface between the layers, so the

• problem of obtaining clearly separated contact layers is highly relevant. Using simulations, it was demonstrated that optimization of the nanofilm interface can be obtained either by introducing additional intermediate thin layers neutral to the original composition, such as aluminum oxide, or by

Electrical and optical enhancement of ITO/Mo bilayer thin films via laser annealing

• Abdelbaki Hacini,
• Ahmad Hadi Ali,
• Nurul Nadia Adnan and
• Nafarizal Nayan

Beilstein J. Nanotechnol. 2022, 13, 1589–1595, doi:10.3762/bjnano.13.133

• significantly improve the electrical properties without affecting the optical transmission [9]. Several metals have been used for such thin layers, including silver [10], aluminium [11], copper [12], and gold [13]. Molybdenum thin films are another choice for the application in solar cells because of good

Induced electric conductivity in organic polymers

• Konstantin Y. Arutyunov,
• Anatoli S. Gurski,
• Vladimir V. Artemov,
• Alexander L. Vasiliev,
• Azat R. Yusupov,
• Danfis D. Karamov and
• Alexei N. Lachinov

Beilstein J. Nanotechnol. 2022, 13, 1551–1557, doi:10.3762/bjnano.13.128

• without exposure to room atmosphere between cycles of formation of different layers. Glass or oxidized silicon were used as substrates. The substrates were preliminarily cleaned in ethanol and distilled water in an ultrasonic bath. The surfaces were hydrophilized by treating the substrates with

Photoelectrochemical water oxidation over TiO₂ nanotubes modified with MoS₂ and g-C₃N₄

• Phuong Hoang Nguyen,
• Thi Minh Cao,
• Tho Truong Nguyen,
• Hien Duy Tong and
• Viet Van Pham

Beilstein J. Nanotechnol. 2022, 13, 1541–1550, doi:10.3762/bjnano.13.127

• filter cutting at 380 nm. Results and Discussion Characterizations of materials Figure 1a displays the morphology of TNAs, which have a uniform distribution of nanotubes with average diameters ranging from 80–100 nm and a length of 500 nm (Figure 1b). The MoS2 material exhibits the stacked layers of 2D

A TiO₂@MWCNTs nanocomposite photoanode for solar-driven water splitting

• Anh Quynh Huu Le,
• Ngoc Nhu Thi Nguyen,
• Hai Duy Tran,
• Van-Huy Nguyen and
• Le-Hai Tran

Beilstein J. Nanotechnol. 2022, 13, 1520–1530, doi:10.3762/bjnano.13.125

• 42.6° correspond to the d-spacing between graphene sheets and the lateral correlation of graphite layers, which is presentative for MWCNTs [27]. Additionally, the XRD pattern of TiO2 exhibits peaks at 25.4° and 48.2°, ascribed to the anatase phase, while the other peaks at 27.6° and 36.2° are

Frequency-dependent nanomechanical profiling for medical diagnosis

• Santiago D. Solares and
• Alexander X. Cartagena-Rivera

Beilstein J. Nanotechnol. 2022, 13, 1483–1489, doi:10.3762/bjnano.13.122

• deeper layers of the sample. In contrast, as the length scale of the probe decreases, the mechanical information obtained is restricted to thinner and thinner regions near the sample surface. In order to address the measurement ambiguity described in the previous section, we propose that the result of

Density of states in the presence of spin-dependent scattering in SF bilayers: a numerical and analytical approach

• Tairzhan Karabassov,
• Valeriia D. Pashkovskaia,
• Nikita A. Parkhomenko,
• Anastasia V. Guravova,
• Elena A. Kazakova,
• Boris G. Lvov,
• Alexander A. Golubov and
• Andrey S. Vasenko

Beilstein J. Nanotechnol. 2022, 13, 1418–1431, doi:10.3762/bjnano.13.117

• in this model and neglect the nonequilibrium effects in the structure [90][91][92]. Our goal is to find the DOS of a single SF bilayer, which can be done by solving the Usadel equations in the ferromagnetic and superconducting layers. We employ the θ parametrization of the normal and anomalous

• sum of all the scattering rates. The above solution is true for thin ferromagnetic layers in the low-proximity limit. A more general analytical solution can be obtained for arbitrary thicknesses using the linearized Usadel equations. In order to find the DOS in the proposed limit, we expand the θ

• influence of the scattering rates on the peak at E = h. Moreover, we provide a relatively simple expression to calculate the DOS analytically in the presence of magnetic scattering αz for thin F layers. In addition, the analytic solution for the anomalous Green’s function has been derived in the limit of

Double-layer symmetric gratings with bound states in the continuum for dual-band high-Q optical sensing

• Chaoying Shi,
• Jinhua Hu,
• Xiuhong Liu,
• Junfang Liang,
• Jijun Zhao,
• Haiyan Han and
• Qiaofen Zhu

Beilstein J. Nanotechnol. 2022, 13, 1408–1417, doi:10.3762/bjnano.13.116

• , Hebei 056038, P. R. China 10.3762/bjnano.13.116 Abstract Herein, we theoretically demonstrate that a double-layer symmetric gratings (DLSG) resonator consisting of a low-refractive-index layer sandwiched between two high-contrast gratings (HCG) layers, can host dual-band high-quality (Q) factor

• symmetric gratings (DLSG) structure supporting artificial BIC and FP-BIC, which is composed of highly reflecting HCG layers surrounding a low refractive index layer. The artificial BIC was excited by tuning the spacing between two adjacent dielectric gratings. More importantly, we found that the modes can

• symmetrical structure in vacuum which allows the optical field to be uniformly located in the grating and environment layers. This way, the confinement ability of the grating to the optical field is achieved while enhancing the relationship between light and matter. Finally, the performance of the DLSG-based

Orally administered docetaxel-loaded chitosan-decorated cationic PLGA nanoparticles for intestinal tumors: formulation, comprehensive in vitro characterization, and release kinetics

• Sedat Ünal,
• Osman Doğan and
• Yeşim Aktaş

Beilstein J. Nanotechnol. 2022, 13, 1393–1407, doi:10.3762/bjnano.13.115

• have to cross several barriers in the GIT in order to exhibit an effect. Among them are mucosae, producing layers of complex aqueous mixtures covering epithelial surfaces including that of the GIT. For oral drugs, rapid elimination from the GIT by intestinal motility is among the most important

Dry under water: air retaining properties of large-scale elastomer foils covered with mushroom-shaped surface microstructures

• Matthias Mail,
• Stefan Walheim,
• Thomas Schimmel,
• Wilhelm Barthlott,
• Stanislav N. Gorb and
• Lars Heepe

Beilstein J. Nanotechnol. 2022, 13, 1370–1379, doi:10.3762/bjnano.13.113

• Effect, the capability to keep a stable air layer when submerged under water. Such air layers are of great importance, e.g., for drag reduction (passive air lubrication), antifouling, sensor applications or oil–water separation. Some biological models, e.g., the floating fern Salvinia or the backswimmer

• chemistry of the hierarchically structured surfaces water cannot penetrate and air remains trapped in between the structures [1], which is indicated by a silvery shine of the submerged surface (See Figure 1a). For technical applications, the Salvinia effect bears an immense potential, as air layers kept

• between water and a solid surface might serve as friction reduction agents, fouling protectors, corrosion protectors or for other applications, such as sensors [11][12][13][14]. Biological examples for such air retaining surfaces with most stable and persistent air layers were found on the floating ferns