Light–matter interactions in two-dimensional layered WSe₂ for gauging evolution of phonon dynamics

• Avra S. Bandyopadhyay,
• Chandan Biswas and
• Anupama B. Kaul

Beilstein J. Nanotechnol. 2020, 11, 782–797, doi:10.3762/bjnano.11.63

• , calculated from the slope of the low-energy edge of the excitonic mode of the PL spectra. The theory of spectral line shape in the Raman spectrum predicts a Lorentzian distribution of a collected signal in a dispersive medium, where the full-width-half-maximum (FWHM) scales as 1/τ, and not surprisingly, τ is

• for the so-called Urbach formulism. Ramos and Luzzi [49] used this Urbach formulism to explain the behavior displayed in the radiation emission band of semiconductors at high-excitation levels, and the slope of the low-energy edge of the spectrum was characterized with an empirical parameter E0 on a

• , from this low-energy edge due to excitons [51] and using Urbach formulism, the slope of the low-energy edge of the excitonic A-peak (Figure 2e) is calculated by the following Equation 5 [49], where I(ω) is the intensity, and E0 is in units of meV and is the so-called characteristic energy parameter [50

Hexagonal boron nitride: a review of the emerging material platform for single-photon sources and the spin–photon interface

• Stefania Castelletto,
• Faraz A. Inam,
• Shin-ichiro Sato and
• Alberto Boretti

Beilstein J. Nanotechnol. 2020, 11, 740–769, doi:10.3762/bjnano.11.61

• complexes, it is shown they are low-energy formation defects in h-BN. This suggests that the assignment is presently controversial also considering the successive verification of SPEs as discussed in the following. In [45] h-BN exfoliated flakes, monolayer chemical vapor deposition (CVD) and in-house h-BN

Atomic-resolution imaging of rutile TiO₂(110)-(1 × 2) reconstructed surface by non-contact atomic force microscopy

• Daiki Katsube,
• Shoki Ojima,
• Eiichi Inami and
• Masayuki Abe

Beilstein J. Nanotechnol. 2020, 11, 443–449, doi:10.3762/bjnano.11.35

• , because it cannot be clarified whether the (1 × 2) structure is formed over a wide area or only locally using macroscopic analysis methods such as diffraction. We used non-contact atomic force microscopy, scanning tunneling microscopy, and low-energy electron diffraction at room temperature to

• clean surface is relatively easy. A well-known rutile TiO2(110) surface is the (1 × 1) structure [2]. The (1 × 1) surface has been studied using low-energy electron diffraction (LEED) [3][4], surface X-ray diffraction [5], non-contact atomic force microscopy (NC-AFM) [6][7][8][9], scanning tunneling

Formation of nanoripples on ZnO flat substrates and nanorods by gas cluster ion bombardment

• Xiaomei Zeng,
• Vasiliy Pelenovich,
• Bin Xing,
• Rakhim Rakhimov,
• Wenbin Zuo,
• Alexander Tolstogouzov,
• Chuansheng Liu,
• Dejun Fu and
• Xiangheng Xiao

Beilstein J. Nanotechnol. 2020, 11, 383–390, doi:10.3762/bjnano.11.29

• and ion fluence are qualitatively the same as those of the flat targets. The obtained result can be compared with a study by Ghoniem et al. on the sputtering of Re and W nanorods with low-energy argon ions in which the authors have found the formation of rather weak ripple structures on the stem side

• direction of the wave vector k of the ripples is not parallel to the nanorod axis. Hence, it can be concluded that in the case of low energy and fluence the ripple formation is controlled by the orientation of the ion incidence projection on the facet surface under irradiation, analogously to the flat

• becomes impossible from this point of view. In our experiment we also use binary materials and a defect-free ripple formation is observed, but only for nanorods. However, here, the scenario described in [10] seems unlikely due to a very low energy per atom in the cluster (a few electronvolts) and a

Nonequilibrium Kondo effect in a graphene-coupled quantum dot in the presence of a magnetic field

• Levente Máthé and
• Ioan Grosu

Beilstein J. Nanotechnol. 2020, 11, 225–239, doi:10.3762/bjnano.11.17

• [52]. The points where the conduction and valence bands touch each other in momentum space are the Dirac points. The Dirac points play an important role in the electronic properties of graphene because around these points low-energy excitations can be achieved. Furthermore, the motion of the charge

Phase inversion-based nanoemulsions of medium chain triglyceride as potential drug delivery system for parenteral applications

• Eike Folker Busmann,
• Dailén García Martínez,
• Henrike Lucas and
• Karsten Mäder

Beilstein J. Nanotechnol. 2020, 11, 213–224, doi:10.3762/bjnano.11.16

• as the flexibility of the nanoparticles [6][7][8][9]. Shock dilution with ice-cold water during phase inversion of the emulsion gives the opportunity to produce nanocapsules without the use of any potentially toxic organic solvent at low energy cost [10][11]. The choice and the amount of the

Nanosecond resistive switching in Ag/AgI/PtIr nanojunctions

• Botond Sánta,
• Dániel Molnár,
• Patrick Haiber,
• Agnes Gubicza,
• Edit Szilágyi,
• Zsolt Zolnai,
• András Halbritter and
• Miklós Csontos

Beilstein J. Nanotechnol. 2020, 11, 92–100, doi:10.3762/bjnano.11.9

• distances granting metallic conductance also in this ultimate scaling limit. (iii) The device conductance is largely determined by the rearrangement of only a few atoms in this narrowest cross section, which can take place at a very large bandwidth and unprecedentedly low energy cost [5][6][7][8][9

Synthesis of amorphous and graphitized porous nitrogen-doped carbon spheres as oxygen reduction reaction catalysts

• Maximilian Wassner,
• Markus Eckardt,
• Andreas Reyer,
• Thomas Diemant,
• Michael S. Elsaesser,
• R. Jürgen Behm and
• Nicola Hüsing

Beilstein J. Nanotechnol. 2020, 11, 1–15, doi:10.3762/bjnano.11.1

• support to the C 1s signal of the carbon-containing catalyst film. The spectra showed minor charging effects, which were compensated by a neutralizer (low-energy electron flood gun). The C 1s peak was set to 284.8 eV for binding energy calibration [50]. Evaluation and deconvolution of the measured signals

Ultrathin Ni_1−xCo_xS₂ nanoflakes as high energy density electrode materials for asymmetric supercapacitors

• Xiaoxiang Wang,
• Teng Wang,
• Rusen Zhou,
• Lijuan Fan,
• Shengli Zhang,
• Feng Yu,
• Tuquabo Tesfamichael,
• Liwei Su and
• Hongxia Wang

Beilstein J. Nanotechnol. 2019, 10, 2207–2216, doi:10.3762/bjnano.10.213

• ]. Currently, carbon-based electrical double-layer capacitors (EDLCs) are commercially available, but they exhibit only a low energy density because of physical charge storage processes due to the adsorption/desorption of ions at the electrode–electrolyte interfaces [3]. These drawbacks have hindered further

Improvement of the thermoelectric properties of a MoO₃ monolayer through oxygen vacancies

• Wenwen Zheng,
• Wei Cao,
• Ziyu Wang,
• Huixiong Deng,
• Jing Shi and
• Rui Xiong

Beilstein J. Nanotechnol. 2019, 10, 2031–2038, doi:10.3762/bjnano.10.199

• of utilizing waste heat without generating any greenhouse gas, thermoelectric technology has attracted increasing attention [1]. Nevertheless, the application of thermoelectric materials is limited by the low energy conversion efficiency. The performance of thermoelectric materials is usually

Facile synthesis of carbon nanotube-supported NiO//Fe₂O₃ for all-solid-state supercapacitors

• Shengming Zhang,
• Xuhui Wang,
• Yan Li,
• Xuemei Mu,
• Yaxiong Zhang,
• Jingwei Du,
• Guo Liu,
• Xiaohui Hua,
• Yingzhuo Sheng,
• Erqing Xie and
• Zhenxing Zhang

Beilstein J. Nanotechnol. 2019, 10, 1923–1932, doi:10.3762/bjnano.10.188

• supercapacitors. Keywords: aqueous reduction; carbon nanotubes; iron oxide; nickel oxide; supercapacitors; Introduction Supercapacitors offer long cycling life, superior charge–recharge ability, high power density, and wide operating temperature [1][2][3]. However, the low energy density limits their

Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal–organic framework

• Manuel Souto,
• Joaquín Calbo,
• Samuel Mañas-Valero,
• Aron Walsh and
• Guillermo Mínguez Espallargas

Beilstein J. Nanotechnol. 2019, 10, 1883–1893, doi:10.3762/bjnano.10.183

• ) nicely agrees with the low-energy broad band that appears in the experimental absorption spectrum of C60@MUV-2, centred at 550 nm and expanding up to 800 nm. In fact, theoretical calculations indicate that the intensity and energy of the S1 CT transition in C60@TTFTB is significantly affected by the

Tuning the performance of vanadium redox flow batteries by modifying the structural defects of the carbon felt electrode

• Ditty Dixon,
• Deepu Joseph Babu,
• Aiswarya Bhaskar,
• Hans-Michael Bruns,
• Joerg J. Schneider,
• Frieder Scheiba and
• Helmut Ehrenberg

Beilstein J. Nanotechnol. 2019, 10, 1698–1706, doi:10.3762/bjnano.10.165

• samples were analyzed using a focused (30–400 µm spot size), monochromatic Al Kα X-ray source. The Kα charge compensation system was employed during the experiment, using electrons of 8 eV energy and low-energy argon ions to prevent any localized charge build-up. The spectra were fitted with one or more

Kelvin probe force microscopy work function characterization of transition metal oxide crystals under ongoing reduction and oxidation

• Dominik Wrana,
• Karol Cieślik,
• Wojciech Belza,
• Christian Rodenbücher,
• Krzysztof Szot and
• Franciszek Krok

Beilstein J. Nanotechnol. 2019, 10, 1596–1607, doi:10.3762/bjnano.10.155

• the present case of thermally reduced SrTiO3(100), the dominant reconstruction is (√5×√5)R26.6°, which forms on the TiO2 termination, as proved by the scanning tunneling microscopy (STM) and low-energy electron diffraction (LEED) investigations (see Figure 5g,h). The surface is composed of two

Kelvin probe force microscopy of the nanoscale electrical surface potential barrier of metal/semiconductor interfaces in ambient atmosphere

• Petr Knotek,
• Tomáš Plecháček,
• Jan Smolík,
• Petr Kutálek,
• Filip Dvořák,
• Milan Vlček,
• Jiří Navrátil and
• Čestmír Drašar

Beilstein J. Nanotechnol. 2019, 10, 1401–1411, doi:10.3762/bjnano.10.138

• filtering effect [15][16][17]. The potential energy barrier connected with a metallic NP (Schottky barrier) or a multi-phase interface could scatter low-energy electrons more effectively than high-energy electrons [18]. This, in turn, results in an enhancement of the Seebeck coefficient with virtually no

Luminescence of Tb₃Al₅O₁₂ phosphors co-doped with Ce³⁺/Gd³⁺ for white light-emitting diodes

• Yu-Guo Yang,
• Lei Wei,
• Jian-Hua Xu,
• Hua-Jian Yu,
• Yan-Yan Hu,
• Hua-Di Zhang,
• Xu-Ping Wang,
• Bing Liu,
• Cong Zhang and
• Qing-Gang Li

Beilstein J. Nanotechnol. 2019, 10, 1237–1242, doi:10.3762/bjnano.10.123

• correlated colour temperature (CCT) [1][2]. At the same time, this type of WLEDs has the advantages of long lifetime, eco-friendliness, high luminous efficiency and low energy consumption, which helps to mitigate two serious issues in the world, namely ecological crisis and energy dilemma. As a result

Pure and mixed ordered monolayers of tetracyano-2,6-naphthoquinodimethane and hexathiapentacene on the Ag(100) surface

• Robert Harbers,
• Timo Heepenstrick,
• Dmitrii F. Perepichka and
• Moritz Sokolowski

Beilstein J. Nanotechnol. 2019, 10, 1188–1199, doi:10.3762/bjnano.10.118

• structures are formed on a surface by molecules that are otherwise typically used for the synthesis of bulk charge-transfer materials. The layers were obtained by vacuum deposition on the Ag(100) surface and analyzed by low-energy electron diffraction (LEED) and scanning tunneling microscopy (STM). The

• a planar orientation on the surface. We discuss the influence of intermolecular charge transfer on the ordering in the mixed structure. Keywords: charge transfer; low-energy electron diffraction; hexathiapentacene; scanning tunneling microscopy; tetracyano-2,6-naphthoquinodimethane; Introduction

• :1 stoichiometry. Experimental The experiments were conducted in an ultra-high vacuum (UHV) chamber with a base pressure of 10−10 mbar. The chamber was equipped with a variable-temperature scanning tunneling microscope STM (type RHK UHV 300) from RHK Technologies and a multi-channel plate (MCP) low

Electroluminescence and current–voltage measurements of single-(In,Ga)N/GaN-nanowire light-emitting diodes in a nanowire ensemble

• David van Treeck,
• Johannes Ledig,
• Gregor Scholz,
• Jonas Lähnemann,
• Mattia Musolino,
• Abbes Tahraoui,
• Oliver Brandt,
• Andreas Waag,
• Henning Riechert and
• Lutz Geelhaar

Beilstein J. Nanotechnol. 2019, 10, 1177–1187, doi:10.3762/bjnano.10.117

• was found that the different emission lines in the spectra and their observed evolution with increasing injection current result from different emission energies and intensities of the four (In,Ga)N insertions. The low-energy line was attributed to the EL of the first insertion (QW 1) next to the n

Co-doped MnFe₂O₄ nanoparticles: magnetic anisotropy and interparticle interactions

• Bagher Aslibeiki,
• Parviz Kameli,
• Hadi Salamati,
• Giorgio Concas,
• Maria Salvador Fernandez,
• Alessandro Talone,
• Giuseppe Muscas and
• Davide Peddis

Beilstein J. Nanotechnol. 2019, 10, 856–865, doi:10.3762/bjnano.10.86

• , we investigate the structural and magnetic properties of ensembles of ferrite nanoparticles with formula Mn1−xCoxFe2O4, (0 ≤ x ≤ 1) prepared by a combined low-energy ball milling and self-combustion method. This simple and low cost synthesis approach (i.e., the synthesis is performed at a relatively

• on the magnetic properties of Mn1−xCoxFe2O4 nanoparticles prepared by low-energy ball milling was investigated. Small effects are observed regarding the structure of the sample, while the average particle size and shape remain almost constant. All samples systematically show a lattice parameter

An efficient electrode material for high performance solid-state hybrid supercapacitors based on a Cu/CuO/porous carbon nanofiber/TiO₂ hybrid composite

• Mamta Sham Lal,
• Thirugnanam Lavanya and
• Sundara Ramaprabhu

Beilstein J. Nanotechnol. 2019, 10, 781–793, doi:10.3762/bjnano.10.78

• only the physical processes are involved in separating the charges, and thus the surface area and porous nature of the electrode materials play the main role. However, charge stored only through electrostatic ion adsorption causes a relatively low energy density (<10 Wh kg−1), which leads to

On the transformation of “zincone”-like into porous ZnO thin films from sub-saturated plasma enhanced atomic layer deposition

• Alberto Perrotta,
• Julian Pilz,
• Stefan Pachmajer,
• Antonella Milella and
• Anna Maria Coclite

Beilstein J. Nanotechnol. 2019, 10, 746–759, doi:10.3762/bjnano.10.74

• charging was compensated using a dual beam charge neutralization, with a flux of low-energy electrons (ca. 1 eV) combined with positive Ar ions of very low energy (10 eV). Samples were sputter cleaned for 1 min with an Ar ion beam of 1 kV, 1 µA (raster size: 2 × 2 cm2). The acquired spectra were processed

• justified with the formation of more Zn–OH groups due to the removal of the organic ligands. Furthermore, room-temperature PE-ALD processes have often shown in the literature the inclusion of chain-terminating –OH groups in the inorganic matrix, due to the low energy provided during the growth [47][57]. The

Deposition of metal particles onto semiconductor nanorods using an ionic liquid

• Michael D. Ballentine,
• Elizabeth G. Embry,
• Marco A. Garcia and
• Lawrence J. Hill

Beilstein J. Nanotechnol. 2019, 10, 718–724, doi:10.3762/bjnano.10.71

• expanded upon by Pyun et al. [27][28]. Our CdSe quantum dots had an average diameter of 2.4 nm as determined using the correlation of particle diameter with the wavelength of the low energy absorbance peak (λmax = 509 nm) [29]. The CdSe@CdS nanorods had an average length of 50 ± 10 nm and an average

Enhancement in thermoelectric properties due to Ag nanoparticles incorporated in Bi₂Te₃ matrix

• Srashti Gupta,
• Dinesh Chandra Agarwal,
• Bathula Sivaiah,
• Sankarakumar Amrithpandian,
• Kandasami Asokan,
• Ajay Dhar,
• Binaya Kumar Panigrahi,
• Devesh Kumar Avasthi and
• Vinay Gupta

Beilstein J. Nanotechnol. 2019, 10, 634–643, doi:10.3762/bjnano.10.63

• theoretical calculations for the introduction of metal nano-inclusions in TE materials. This theory predicts the band bending at the metal–semiconductor interface will allow for the transmission of high energy electrons along with a blocking of low energy electrons. This electron energy filter results in

• method and the incorporation in Bi2Te3 synthesized by ball milling, which yielded a significant enhancement in power factor and ZT in Bi/Bi2Te3 due to the scattering of low-energy electrons by a barrier potential at the Bi–Bi2Te3 interface [15]. Improvement in TE properties has also been observed after

• a future study. The enhancement of the Seebeck coefficient can be attributed to carrier filtering. Band bending at the metal–semiconductor interfaces leads to a strong scattering of low-energy electrons whereas high-energy electrons remain unaffected [20][21]. The energy-dependent scattering of

Direct observation of the CVD growth of monolayer MoS₂ using in situ optical spectroscopy

• Claudia Beatriz López-Posadas,
• Yaxu Wei,
• Wanfu Shen,
• Daniel Kahr,
• Michael Hohage and
• Lidong Sun

Beilstein J. Nanotechnol. 2019, 10, 557–564, doi:10.3762/bjnano.10.57

• contrast, the features associated with MoS2 vanish. The decrease of the transmittance (the increase of DTS) over the low-energy range could be attributed to the increase of the scattering of the MoO3 thin film deposited on the quartz window. In order to understand the observed evolution of the DT

Choosing a substrate for the ion irradiation of two-dimensional materials

• Egor A. Kolesov

Beilstein J. Nanotechnol. 2019, 10, 531–539, doi:10.3762/bjnano.10.54

• the latter, the maximum values of transferred energy are up to an order of magnitude larger. The insets in Figure 1 show details of the low-energy region (10−1–100 keV) of the dependencies presented. As the incident ion energy increases, the energy transferred to both substrate sputtering and recoils

• reaching the interface begins to increase notably starting from 10−1–100 keV where the ion has enough energy to activate these processes. As seen in the insets, the energy transferred to recoils reaching the interface seems to dominate over sputtering in the low-energy range. However, it should be noted

• crystal lattice, leading to ion implantation (doping) [25]. For the latter to occur, the ion should have a considerably low energy – of about 20–200 eV, with the most effective implantation occurring at 25–75 eV [1][25][26][27][28][29]. The process peaks in the lower part of this region for 2D TMDs and in