Retrieval of B1 phase from high-pressure B2 phase for CdO nanoparticles by electronic excitations in Cd_xZn_1−xO composite thin films

• Arkaprava Das,
• Marcin Zając and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2025, 16, 551–560, doi:10.3762/bjnano.16.43

• diameter in CdO subjected to 120 MeV silver ion irradiation is calculated to be approximately 8 nm using an inelastic thermal spike simulation code. This study elucidates the intriguing reappearance of the B1 phase under oxygen ion irradiation and highlights the radiation stability of the B2 phase through

• , we reported a local pressure-driven structural phase transformation (PT) from B1 (NaCl) to B2 (CsCl) in CdxZn1−xO (x = 0.4) composite binary oxide thin films [1]. The radiation stability of these phases is crucial for optoelectronic applications in space, where the exposure to high-energy particles

• and gamma radiation can induce lattice defects and lower the device efficiency [7]. Swift heavy ion (SHI) irradiation experiments provide valuable insights into the radiation stability of the transformed B2 phase, which is essential for the future utilization of these composite materials in space

Functionalized gold nanoflowers on carbon screen-printed electrodes: an electrochemical platform for biosensing hemagglutinin protein of influenza A H1N1 virus

• Carlos Enrique Torres-Méndez,
• Sharmilee Nandi,
• Klara Martinovic,
• Patrizia Kühne,
• Yifan Liu,
• Sam Taylor,
• Maria Lysandrou,
• Maria Ines Berrojo Romeyro Mascarenhas,
• Viktoria Langwallner,
• Javier Enrique Sebastián Alonso,
• Ivana Jovanovic,
• Maike Lüftner,
• Georgia-Vasiliki Gkountana,
• David Bern,
• Abdul-Raouf Atif,
• Ehsan Manouchehri Doulabi,
• Gemma Mestres and
• Masood Kamali-Moghaddam

Beilstein J. Nanotechnol. 2025, 16, 540–550, doi:10.3762/bjnano.16.42

• improved; the challenge is to create portable devices that overcome drawbacks related to long incubation times, unsatisfactory limits of detection, low stability, and short shelf life of the biosensor. To address the current challenges, in this study, we built an electrochemical biosensor to detect and

• , electrode stability in different solvents, and circuit fitting for the EIS data. Acknowledgements The authors acknowledge SensUs organization for technical discussions on biosensors development, Dr. Quentin Palomar-Marchand for the technical advice provided on electrochemical measurements, and Jayendra

Electron beam-based direct writing of nanostructures using a palladium β-ketoesterate complex

• Chinmai Sai Jureddy,
• Krzysztof Maćkosz,
• Aleksandra Butrymowicz-Kubiak,
• Iwona B. Szymańska,
• Patrik Hoffmann and
• Ivo Utke

Beilstein J. Nanotechnol. 2025, 16, 530–539, doi:10.3762/bjnano.16.41

• ligands are typically used as a metal source. Metalorganic precursors are preferred because of their vacuum stability and volatility. Achieving pure metal deposits requires the complete dissociation of all ligands from the metal atom and their desorption without producing further nonvolatile fragments

Zeolite materials with Ni and Co: synthesis and catalytic potential in the selective hydrogenation of citral

• Inocente Rodríguez-Iznaga,
• Yailen Costa Marrero,
• Tania Farias Piñeira,
• Céline Fontaine,
• Lexane Paget,
• Beatriz Concepción Rosabal,
• Arbelio Penton Madrigal,
• Vitalii Petranovskii and
• Gwendoline Lafaye

Beilstein J. Nanotechnol. 2025, 16, 520–529, doi:10.3762/bjnano.16.40

• elements, as well as the Si/Al ratios for the obtained materials are shown in Table 1 and/or Figure 3. The Si/Al ratio shows no significant change (Table 1), indicating a high degree of stability for the clinoptilolite–heulandite and mordenite phases after the applied hydrothermal treatments. Additionally

Water in nanoporous hexagonal boron nitride nanosheets: a first-principles study

• Juliana A. Gonçalves,
• Ronaldo J. C. Batista and
• Marcia C. Barbosa

Beilstein J. Nanotechnol. 2025, 16, 510–519, doi:10.3762/bjnano.16.39

• deformations. Surprisingly, the stability of triangular pores with N–H termination is significantly increased by the addition of B–H pairs, whereas the stability of triangular pores with B–H termination is decreased by the addition of N–H pairs, indicating a distinct evolution of the pore shape based on the

• boron nitride (h-BN) [19]. Among these materials, h-BN stands out because of its properties, which are similar to those of graphene. It is composed of alternating boron and nitrogen atoms arranged in a honeycomb-like crystalline structure, characterized by high thermal stability, low dielectric constant

• passage of ions and polar molecules. However, the use of h-BN as a membrane for water desalination is still a relatively new area of research. In this paper we propose an analysis using first-principles calculations to understand the stability of pores in monolayer h-BN and their interaction with water

N₂⁺-implantation-induced tailoring of structural, morphological, optical, and electrical characteristics of sputtered molybdenum thin films

• Usha Rani,
• Kafi Devi,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 495–509, doi:10.3762/bjnano.16.38

• remarkable thermal stability, high melting point, and chemical inertness. In the present study, Mo thin films of different thicknesses (150, 200, 250, and 300 nm) have been deposited on Si(100) substrates via radio frequency sputtering in an argon atmosphere at room temperature. Some of these films have been

• technological applications owing to their outstanding characteristics. The high melting point and stability of molybdenum ensure that it remains structurally intact under the harsh operating conditions of solar cells [1][2]. This stability is essential for long-term reliability and performance. The low

• range of applications [23][24][25][26][27][28]. Kim et al. [23] examined the impact of a 3 × 1017 N2+·cm−2 ion fluence on the structural characteristics, surface morphology, and thermal stability of Mo thin films. The internal stress of these films transitioned from strongly compressive to weakly

Impact of adsorbate–substrate interaction on nanostructured thin films growth during low-pressure condensation

• Alina V. Dvornichenko,
• Vasyl O. Kharchenko and
• Dmitrii O. Kharchenko

Beilstein J. Nanotechnol. 2025, 16, 473–483, doi:10.3762/bjnano.16.36

• interactions in a homogeneous system. Next, we perform stability analysis and define a range of the strength of adsorbate–substrate interaction responsible for pattern formation during deposition. Finally, we present results of numerical simulations and discuss dynamics of surface patterns formation and

• deposition. Results and Discussion First-order transitions in a homogeneous system First, let us discuss homogeneous states xst and analyze their stability by setting ∇J = 0 in Equation 2. Stationary states xst correspond to ∂tx = 0 giving R(x) = 0 with Dependencies of the homogeneous stationary states xst

• and ε. By analysis of the dependencies xst(δ) for different ε, one can obtain the stability diagram δ(ε) at different α, shown in Figure 2a. Let us consider the case α = 0.03. It follows that the bistability domain (between the solid curves) is bounded by the critical values of ε for the fixed

Effect of additives on the synthesis efficiency of nanoparticles by laser-induced reduction

• Rikuto Kuroda,
• Takahiro Nakamura,
• Hideki Ina and
• Shuhei Shibata

Beilstein J. Nanotechnol. 2025, 16, 464–472, doi:10.3762/bjnano.16.35

• two methyl groups in IPA, so the stability of the radicals is higher than in ethanol, which has only one methyl group. However, there was no significant difference in the synthesis efficiency when using these additives. So, the stability of the radical has little effect on the synthesis efficiency of

Synthetic-polymer-assisted antisense oligonucleotide delivery: targeted approaches for precision disease treatment

• Ana Cubillo Alvarez,
• Dylan Maguire and
• Ruairí P. Brannigan

Beilstein J. Nanotechnol. 2025, 16, 435–463, doi:10.3762/bjnano.16.34

• potential in precision disease treatment. Synthetic polymers have shown significant promise in enhancing the delivery, stability, and therapeutic efficacy of ASOs by addressing key challenges such as cellular uptake, endosomal escape, and reducing cytotoxicity. The review highlights key studies from the

• target diseases and genetic variations. However, the lack of disease-specific biomarkers, which facilitate the identification of disease phenotypes, the poor chemical stability of nucleotide-based molecules and their inefficient biodistribution and targeted delivery result in insufficient biological

• into three generations based on their structural modifications (Figure 1) [17]. First-generation ASOs are characterised by having an altered phosphate backbone. This chemical modification increases their stability against nucleases, extending their half-life, and promotes the degradation of transcripts

Quantification of lead through rod-shaped silver-doped zinc oxide nanoparticles using an electrochemical approach

• Ravinder Lamba,
• Gaurav Bhanjana,
• Neeraj Dilbaghi,
• Vivek Gupta and
• Sandeep Kumar

Beilstein J. Nanotechnol. 2025, 16, 422–434, doi:10.3762/bjnano.16.33

• NRs were studied using dynamic light scattering analysis, and their zeta potential was determined. Figure 5 represents the zeta potential of Ag@ZnO NRs. The samples were collected in the liquid state and the Ag@ZnO NRs zeta potential of ≈30 mV accounts for the stability of the nanoparticles in water

Size control of nanoparticles synthesized by pulsed laser ablation in liquids using donut-shaped beams

• Abdel Rahman Altakroury,
• Oleksandr Gatsa,
• Farbod Riahi,
• Zongwen Fu,
• Miroslava Flimelová,
• Andrei Samokhvalov,
• Stephan Barcikowski,
• Carlos Doñate-Buendía,
• Alexander V. Bulgakov and
• Bilal Gökce

Beilstein J. Nanotechnol. 2025, 16, 407–417, doi:10.3762/bjnano.16.31

• ][26], ligands [27], and low-salinity ions [28], or by choosing different liquid media [29]. Nevertheless, the addition of molecular stabilizers or the use of liquids that increase the stability reduces the versatility of the technique and limits the applicability of the produced colloidal NPs. The

ReactorAFM/STM – dynamic reactions on surfaces at elevated temperature and atmospheric pressure

• Tycho Roorda,
• Hamed Achour,
• Matthijs A. van Spronsen,
• Marta E. Cañas-Ventura,
• Sander B. Roobol,
• Willem Onderwaater,
• Mirthe Bergman,
• Peter van der Tuijn,
• Gertjan van Baarle,
• Johan W. Bakker,
• Joost W. M. Frenken and
• Irene M. N. Groot

Beilstein J. Nanotechnol. 2025, 16, 397–406, doi:10.3762/bjnano.16.30

• hall. The AFM/STM is contained in a high-pressure cell and sealed off from the UHV chamber by a Kalrez elastomer seal, which exhibits outstanding thermal stability and chemical resistance together with improved sealing performance in both high-pressure and high-temperature environments. Being in direct

• developments of the ReactorAFM/STM could benefit from increasing the temperature range of the quartz tuning forks. This could be achieved by further investigating the temperature limitation and considering one designed with a higher T0, offering greater stability at elevated temperatures. Additionally

Engineered PEG–PCL nanoparticles enable sensitive and selective detection of sodium dodecyl sulfate: a qualitative and quantitative analysis

• Soni Prajapati and
• Ranjana Singh

Beilstein J. Nanotechnol. 2025, 16, 385–396, doi:10.3762/bjnano.16.29

• negative surface charge. The zeta potential is a critical parameter for evaluating the stability of colloidal dispersions; typically, values greater than ±30 mV are associated with high stability due to strong electrostatic repulsion between particles [31]. Despite the zeta potential being less than ±30 mV

• elemental changes occurred during the synthesis process, suggesting the stability and integrity of the PEG–PCL NPs. This consistency in elemental composition further supports the use of these nanoparticles in various applications, as it ensures that the nanoparticles retain their designed properties without

• monitoring of SDS contamination in various sources. The developed method offers several key advantages: it is simple, rapid, cost-effective, and it has high stability. These findings highlight the potential of this method for SDS detection from different sources, providing a valuable tool for routine

Development of a mucoadhesive drug delivery system and its interaction with gastric cells

• Ahmet Baki Sahin,
• Serdar Karakurt and
• Deniz Sezlev Bilecen

Beilstein J. Nanotechnol. 2025, 16, 371–384, doi:10.3762/bjnano.16.28

• , effective encapsulation, pH-responsive release, and enhanced stability. Eudragit RS 100 is a copolymer of ethyl acrylate, methyl methacrylate, and a low proportion of methacrylic acid ester with quaternary ammonium groups. It is known for its mucoadhesive properties [16], which are independent of the site

Pulsed laser in liquid grafting of gold nanoparticle–carbon support composites

• Madeleine K. Wilsey,
• Teona Taseska,
• Qishen Lyu,
• Connor P. Cox and
• Astrid M. Müller

Beilstein J. Nanotechnol. 2025, 16, 349–361, doi:10.3762/bjnano.16.26

• -term stability. A widely used ionomer binder is Nafion, which is highly acidic [11] and can corrode earth-abundant catalysts that are not acid-stable [12]. Ionomer binders can additionally lead to undesired side reactions, thus reducing the energy efficiency for the desired transformation [13

• reactions and can create unwanted side products [7]. Long-term surfactant stability and associated catalyst agglomeration or detachment are another issue. Post-synthetic attachment of catalyst nanoparticles is poorly scalable, creates large amounts of organic hazardous waste, and results in wastage of

• pulsed laser-grafted over conventionally prepared cathodes. Chronoamperometry data, collected at a constant applied potential of −1.3 V vs RHE, showed enhanced stability and mass activity of the pulsed laser-grafted gold nanoparticle–carbon fiber paper composite, compared to an analogous conventionally

Tailoring of physical properties of RF-sputtered ZnTe films: role of substrate temperature

• Kafi Devi,
• Usha Rani,
• Arun Kumar,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 333–348, doi:10.3762/bjnano.16.25

• ) compounds have numerous applications in optoelectronic devices such as light-emitting diodes [1], display devices [2], infrared detectors [3], and terahertz emitters [4]. Owing to their suitable physical properties (deposition at low temperatures and good thermal stability) and unique optical properties due

Fabrication and evaluation of BerNPs regarding the growth and development of Streptococcus mutans

• Tuyen Huu Nguyen,
• Hong Thanh Pham,
• Kieu Kim Thanh Nguyen,
• Loan Hong Ngo,
• Anh Ngoc Tuan Mai,
• Thu Hoang Anh Lam,
• Ngan Thi Kim Phan,
• Dung Tien Pham,
• Duong Thuy Hoang,
• Thuc Dong Nguyen and
• Lien Thi Xuan Truong

Beilstein J. Nanotechnol. 2025, 16, 308–315, doi:10.3762/bjnano.16.23

• each other, reducing the likelihood of agglomeration and deposition, and enhancing the stability of the suspension [21][22]. Consequently, a suspension of the BerNPs was produced with uniform particle sizes, predominantly ranging from 40 to 65 nm (Figure 1B,C). In our study, the rotary grinding method

• particle sizes results in a larger total surface area, thus significantly increasing biological activity and stability [20][28]. Compared to other studies, the size of the berberine nanoparticles obtained in this study was smaller, highlighting the significant application potential of the material. UV–vis

Enhancing mechanical properties of chitosan/PVA electrospun nanofibers: a comprehensive review

• Nur Areisman Mohd Salleh,
• Amalina Muhammad Afifi,
• Fathiah Mohamed Zuki and
• Hanna Sofia SalehHudin

Beilstein J. Nanotechnol. 2025, 16, 286–307, doi:10.3762/bjnano.16.22

• adsorbing heavy metals and radionuclides [16]. However, chitosan exhibits limited mechanical stability, is sensitive to pH variations, and tends to swell [17]. To improve the spinnability of chitosan during the electrospinning process, it is commonly blended with other polymers, such as PVA [18

• atom backbone ensures chemical stability and compatibility with diverse environments. Figure 3 shows the chemical structure of PVA. PVA is known for its biodegradability, allowing it to disintegrate in both aerobic and anaerobic environments. This feature is crucial for industries concerned about the

• hydrophilicity, and low thermal stability [106][107]. The disadvantages often necessitate the combination of PVA with other materials or the application of post-processing techniques such as cross-linking or coating for performance improvement [108]. As a countermeasure, Rafieian et al. [109] proposed

Emerging strategies in the sustainable removal of antibiotics using semiconductor-based photocatalysts

• Yunus Ahmed,
• Keya Rani Dutta,
• Parul Akhtar,
• Md. Arif Hossen,
• Md. Jahangir Alam,
• Obaid A. Alharbi,
• Hamad AlMohamadi and
• Abdul Wahab Mohammad

Beilstein J. Nanotechnol. 2025, 16, 264–285, doi:10.3762/bjnano.16.21

• capacity to absorb light and concerns about catalytic stability, photocatalysis outperforms other advanced oxidation processes in multiple aspects. This study focuses on summarizing recent advances in the sustainable removal of antibiotics using semiconductor-based photocatalysts. By reviewing the latest

• heterojunctions are classified based on their charge transfer mechanism and the presence or absence of mediators. The direct Z-scheme relies on the direct electron transfer between photocatalysts; eliminating the electron mediator simplifies the design and enhances stability but may suffer from higher charge

• more complicated to fabricate and possibly beset by stability problems due to mediator degradation, indirect Z-schemes are nevertheless often used in applications that demand high charge separation performance. In contrast, direct Z-schemes are best suited for systems where robustness and simplicity

Preferential enrichment and extraction of laser-synthesized nanoparticles in organic phases

• Theo Fromme,
• Maximilian L. Spiekermann,
• Florian Lehmann,
• Stephan Barcikowski,
• Thomas Seidensticker and
• Sven Reichenberger

Beilstein J. Nanotechnol. 2025, 16, 254–263, doi:10.3762/bjnano.16.20

• ) functionalization of the nanoparticles have been observed, which ultimately should affect their lipophilicity and, hence, colloidal stability in apolar or polar solvents. Two-phase liquid systems and the possibility to transfer the surfactant-free nanoparticles from one liquid phase into another remain practically

• parameters. As such, nanoparticle size [32][33], colloidal stability [33], gas formation [11][34], degree of oxidation [35][36][37], and nanoparticle productivity [11][32][33][34] can be influenced and tailored to specific needs. Although it may be expected that the particles’ reactivity with the solvent and

• synthesize heterogeneous catalysts by deposition of nanoparticles, the specific nanoparticle solubility, and eventually also the colloidal stability of the individual nanoparticles, in different solvents is required [47][48]. If the colloid does not possess required properties such as colloidal stability

Radiosensitizing properties of dual-functionalized carbon nanostructures loaded with temozolomide

• Radmila Milenkovska,
• Nikola Geskovski,
• Dushko Shalabalija,
• Ljubica Mihailova,
• Petre Makreski,
• Dushko Lukarski,
• Igor Stojkovski,
• Maja Simonoska Crcarevska and
• Kristina Mladenovska

Beilstein J. Nanotechnol. 2025, 16, 229–251, doi:10.3762/bjnano.16.18

• enable transport and delivery to brain tumors. Inorganic nanostructures as TMZ carriers have shown several advantages compared to organic ones with respect to physicochemical stability and potency/cytotoxic activity, overcoming their main disadvantages, that is, hydrophobicity/fluidity and toxicity by

• characterization of all formulations regarding interactions of the components and their stability during the preparation procedures, different techniques were used including infrared (IR), ultraviolet–visible (UV–vis), and Raman spectroscopy as well as TGA. For analyzing potential structural changes in the CNs

• after exposure to irradiation, X-ray powder diffraction (XRPD) was used. The stability of TMZ under these conditions was determined unsing attenuated total reflectance Fourier-transform infrared (ATR-FTIR) and UV–vis spectroscopy. Most of the procedures and techniques were used in our previous study [43

Synthesis and the impact of hydroxyapatite nanoparticles on the viability and activity of rhizobacteria

• Bedah Rupaedah,
• Indrika Novella,
• Atiek Rostika Noviyanti,
• Diana Rakhmawaty Eddy,
• Anna Safarrida,
• Abdul Hapid,
• Zhafira Amila Haqqa,
• Suryana Suryana,
• Irwan Kurnia and
• Fathiyah Inayatirrahmi

Beilstein J. Nanotechnol. 2025, 16, 216–228, doi:10.3762/bjnano.16.17

• , making them ideal candidates for serving as carrier materials [6]. Additionally, nanoscale carrier materials offer the advantage of high loading capacity, remarkable stability, and the ability to enhance rhizobacterial resilience against drought conditions. Moreover, they provide convenience in both

• can affect the stability of a substance, ion interactions, and molecular ionization in a solution. However, the effect of pH and EC values on the psychochemical properties highly depends on the material’s application [28][29]. Pd rhizobacterium typically thrives optimally at pH 7.5 and exhibits

Recent advances in photothermal nanomaterials for ophthalmic applications

• Jiayuan Zhuang,
• Linhui Jia,
• Chenghao Li,
• Rui Yang,
• Jiapeng Wang,
• Wen-an Wang,
• Heng Zhou and
• Xiangxia Luo

Beilstein J. Nanotechnol. 2025, 16, 195–215, doi:10.3762/bjnano.16.16

• , and inorganic semiconductor materials that absorb light through bandgap transitions [25]. The specific photothermal properties of these materials, encompassing aspects such as range and rate of light absorption, photothermal conversion efficiency, heat transfer capability, and photothermal stability

• photothermal agents [61]. Organic small molecule dyes are easy to remove from the eye, however, they suffer from low photothermal conversion efficiency, easy photobleaching, low water solubility, and low stability [39]. Common organic small molecule dyes include cyanine dyes (e.g., indocyanine green (ICG

• molecule dyes can be modulated by intramolecular rotation or intermolecular interactions [63]. By using nanocarrier encapsulation and self-assembly strategies, the water solubility and stability of organic small molecule dyes can be improved, and photobleaching can be reduced [64]. Materials that undergo

A review of metal-organic frameworks and polymers in mixed matrix membranes for CO₂ capture

• Charlotte Skjold Qvist Christensen,
• Nicholas Hansen,
• Mahboubeh Motadayen,
• Nina Lock,
• Martin Lahn Henriksen and
• Jonathan Quinson

Beilstein J. Nanotechnol. 2025, 16, 155–186, doi:10.3762/bjnano.16.14

• , including regenerative solvent-based absorption [2][6], fixed-bed adsorption [7], cryogenic separation techniques [8], and membrane separation methods [9][10][11][12]. Of these, membrane technology offers advantages such as exceptional stability, high efficiency, low energy consumption, and ease of

• membranes exhibit superior thermal, chemical, and mechanical stability compared to organic membranes [72][73][74]. However, inorganic membranes tend to be brittle, which can lead to crack formation in the finalized membrane, thereby reducing their selective properties. While organic membranes typically

• balance both membrane permeability and selectivity while achieving better overall stability. This is achieved through the addition of inorganic fillers into organic membrane matrices leading to MMM systems. Nevertheless, incorporating inorganic additives into organic polymer membranes is complex

Comparison of organic and inorganic hole transport layers in double perovskite material-based solar cell

• Deepika K and
• Arjun Singh

Beilstein J. Nanotechnol. 2025, 16, 119–127, doi:10.3762/bjnano.16.11

• -based PSCs as a promising photovoltaic material. The double perovskite layer is a remarkable choice as active layer because of intrinsic carrier stability, low exciton binding energy, and low toxicity. Herein, the optimization of a planar DPSC with a multifunctional double perovskite absorber layer

• -circuit current density (JSC) of 13.26 mA/cm2, and a fill factor (FF) of 66%. The PCE is close to that of the Pt-based counter electrode (PCE = 6.86%). Akman [3] used hydrothermal methods to synthesize the photoanodes with different doping sources to further improve the stability of DSSCs. For 1.0 mol

• under ambient conditions with humidity levels of 35–40%. Here, 3,4-dihydroxyphenethylamine hydrochloride (3,4-DpACl) was used as an additive during perovskite fabrication. Despite significant research efforts, there are stability issues when working under critical environmental conditions, which is an