Impact of electron–phonon coupling on electron transport through T-shaped arrangements of quantum dots in the Kondo regime

• Patryk Florków and
• Stanisław Lipiński

Beilstein J. Nanotechnol. 2021, 12, 1209–1225, doi:10.3762/bjnano.12.89

• for ω = 0 for the main peaks (see inset) and for ω = nω0 for the satellites, exhibit Fano shape corresponding to a given qeff. For λO = 0.22, where qeff = 0, the line is symmetric. It is worth to stress that the widths of the dips in the main peak are the same as in the satellites, which proves that

A new method for obtaining model-free viscoelastic material properties from atomic force microscopy experiments using discrete integral transform techniques

• Berkin Uluutku,
• Enrique A. López-Guerra and
• Santiago D. Solares

Beilstein J. Nanotechnol. 2021, 12, 1063–1077, doi:10.3762/bjnano.12.79

• excitation of stress. Our proposed model-free approach follows the spirit of related Fourier-based methods, where viscoelastic material extraction has been achieved under some limited circumstances [29][30][31]. However, in this work, we exploit the advantages of the Z-transform, which we believe is more

•  2), for which we carry out the force analysis in the complex domain (force spectroscopy). Theoretical Background It is well known that the behavior of viscoelastic materials is history-dependent, as a result of which, the stress–strain relationships governing their deformation are functionals (not

• functions). More specifically, the stress at a given instant depends on the total previous history of strain and vice versa [13]. This history dependence is often expressed in the form of convolution integrals: where Q(t) and U(t) are known as relaxance and retardance, respectively. As already stated

An overview of microneedle applications, materials, and fabrication methods

• Zahra Faraji Rad,
• Philip D. Prewett and
• Graham J. Davies

Beilstein J. Nanotechnol. 2021, 12, 1034–1046, doi:10.3762/bjnano.12.77

• penetration are obviously dependent on microneedle tip dimensions and skin puncture stress. Consequently, there is increased interest in ultrasharp microneedles with tips having minimum lateral dimensions below 1 µm. The penetration force linearly increases with array size and the use of controlled force

Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries

• Marina Tabuyo-Martínez,
• Bernd Wicklein and
• Pilar Aranda

Beilstein J. Nanotechnol. 2021, 12, 995–1020, doi:10.3762/bjnano.12.75

• the nanometer scale in form of nanoparticles, nanorods, nanofibers, nanoarrays, and nanosheets, which are more tolerant to dilative stress [75][76]. In addition, these nanostructures can be incorporated into a flexible carbon matrix for further accommodation of mechanical strain (Figure 10A) [74][77

• . Nanostructured and nanoparticulated sulfur is easily entrapped in electroconducting matrices, which reduces the shuttle effect, increases the cathode conductivity, accommodates mechanical stress from volume expansion. Also, the high surface area accelerates reaction kinetics. A similar strategy can be pursued at

Is the Ne operation of the helium ion microscope suitable for electron backscatter diffraction sample preparation?

• Annalena Wolff

Beilstein J. Nanotechnol. 2021, 12, 965–983, doi:10.3762/bjnano.12.73

• electropolishing protocol induced some artefacts in this sample which could lead to misinterpretation for stress/strain analysis of the sample. The forward scatter diffraction (FSD) image (Figure 4e) shows void formation on the sample surface and significant sample surface alterations close to the area that was

• electropolishing protocol not feasible for stress and strain analysis of the Cu sample. Argon ion polishing of the Cu sample produced better results than electropolishing. The FSD image (Figure 4j) reveals grains and does not show obvious sample surface alterations in comparison to the electropolishing approaches

• challenging stress/strain analysis. Irradiation of copper at 0° incidence angle To assess the effect of ion irradiation, the copper TEM lamella grids were irradiated with Ga ions using a Ga FIB/SEM or Ne ions using HIM. An ion dose of 3371 ions/nm2 was chosen to allow a comparison with a previously reported

Self-assembly of Eucalyptus gunnii wax tubules and pure ß-diketone on HOPG and glass

• Miriam Anna Huth,
• Axel Huth and
• Kerstin Koch

Beilstein J. Nanotechnol. 2021, 12, 939–949, doi:10.3762/bjnano.12.70

• protect plants from environmental stress [4]. Waxes are, thereby, essential for a variety of functions, especially in the wettability and self-cleaning ability of plant surfaces [5][6]. Plant waxes consist of a complex mixture of aliphatic and aromatic compounds. The exact chemical composition of the wax

Effects of temperature and repeat layer spacing on mechanical properties of graphene/polycrystalline copper nanolaminated composites under shear loading

• Chia-Wei Huang,
• Man-Ping Chang and
• Te-Hua Fang

Beilstein J. Nanotechnol. 2021, 12, 863–877, doi:10.3762/bjnano.12.65

• as the temperature increases, the content of Shockley dislocations will increase and the maximum shear stress of the zigzag and armchair directions also decreases. The mechanical strength of the zigzag direction is more dependent on the temperature than that of the armchair direction. Moreover, self

• -healing occurs in the armchair direction, which causes the shear stress to increase after failure. Furthermore, the maximum shear stress and the shear strength of the composites decrease with an increase of the repeat layer spacing. Also, the shear modulus increases by increasing the grain size of copper

• the mechanical properties of carbon materials [31]. In this study, graphene with zigzag and armchair chirality is considered while simulating different properties of graphene monolayers and copper layers, including stress–strain curve variations, the distribution of von Mises stress, the evolution of

Comprehensive review on ultrasound-responsive theranostic nanomaterials: mechanisms, structures and medical applications

• Sepand Tehrani Fateh,
• Lida Moradi,
• Elmira Kohan,
• Michael R. Hamblin and
• Amin Shiralizadeh Dezfuli

Beilstein J. Nanotechnol. 2021, 12, 808–862, doi:10.3762/bjnano.12.64

• proximity to the cell membrane. It has been shown that during inertial cavitation, in addition to direct oscillating MB–cell membrane interactions, a fluid microjet formed around the MBs can be responsible for providing secondary mechanical stress on the cell membrane and create transient disruption. In

• . reported that when the distance between the cell and the MB was increased to 5.5 µm, the exerted shear stress on the cell membrane suddenly decreased [78]. Schlicher et al. exposed prostate cancer cells (DU145) to 24 kHz US irradiation to investigate the cavitation events and the changes in the cell

• further suggested that the same results would be obtained if a higher frequency US was employed [79]. Both mechanical stress and chemical effects induced by US could be responsible for the formation of repairable cell membrane pores [74]. Van Wamel et al. reported that the mechanism leading to enhanced

Silver nanoparticles nucleated in NaOH-treated halloysite: a potential antimicrobial material

• Yuri B. Matos,
• Rodrigo S. Romanus,
• Mattheus Torquato,
• Edgar H. de Souza,
• Rodrigo L. Villanova,
• Marlene Soares and
• Emilson R. Viana

Beilstein J. Nanotechnol. 2021, 12, 798–807, doi:10.3762/bjnano.12.63

• aluminosilicate sheet that folds over itself in virtue of the internal stress inherent to the crystalline structure of the material, forming nanotubes [25]. As shown in Figure 1, it folds with a silicate phase facing outwards (Si-O), and an aluminol phase facing inwards (Al-OH). Since the internal and external

Electromigration-induced formation of percolating adsorbate islands during condensation from the gaseous phase: a computational study

• Alina V. Dvornichenko,
• Vasyl O. Kharchenko and
• Dmitrii O. Kharchenko

Beilstein J. Nanotechnol. 2021, 12, 694–703, doi:10.3762/bjnano.12.55

• include the formation of surface steps [28][29][30][31], faceting of the surface [32][33][34][35][36][37], elimination of instability of surface morphology caused by stress and wetting of the substrate [38][39][40][41], the evolution of contact irregularities in switches of microelectromechanical systems

A review of defect engineering, ion implantation, and nanofabrication using the helium ion microscope

• Frances I. Allen

Beilstein J. Nanotechnol. 2021, 12, 633–664, doi:10.3762/bjnano.12.52

• Irradiation-induced restructuring The following applications have used localized helium ion irradiation in the HIM to change the morphology and/or internal structure of a material by ion-induced mass transport along surfaces, ion-induced collisional atomic mixing, and through stress gradients induced in

• stress gradients across the membrane that lead to deformation by buckling [101]. Various intricate 3D structures have been created following this approach. Interestingly, right at the beginning of HIM-based research, membrane folding using localized helium ion irradiation was also demonstrated [99

Stability and activity of platinum nanoparticles in the oxygen electroreduction reaction: is size or uniformity of primary importance?

• Kirill O. Paperzh,
• Anastasia A. Alekseenko,
• Vadim A. Volochaev,
• Ilya V. Pankov,
• Olga A. Safronenko and
• Vladimir E. Guterman

Beilstein J. Nanotechnol. 2021, 12, 593–606, doi:10.3762/bjnano.12.49

• obtained during accelerated stress tests and the use of fuel cells in real practice is far from being perfect. Therefore, along with the study of how certain factors influence on the catalyst stability, the search for optimal methods and conditions for stress tests in an electrochemical cell is still

• increasing NP size [14][22][32][33][34][35][36]. The probability of agglomeration and coalescence of NPs during a stress test also decreases with an increase in the average distance between platinum NPs in catalysts, which results in an increase of their stability [14]. Apparently, a relatively high

• series G40 < G35 < G30 < G25 < G20, the mass activity of the synthesized catalysts also increases (Table 2). Note that the mass activity of the sample G20 is almost 1.5 times higher than that of JM20, a commercial analog with a similar platinum content (Table 2). During the stress test of the catalysts

The preparation temperature influences the physicochemical nature and activity of nanoceria

• Robert A. Yokel,
• Wendel Wohlleben,
• Johannes Georg Keller,
• Matthew L. Hancock,
• Jason M. Unrine,
• D. Allan Butterfield and
• Eric A. Grulke

Beilstein J. Nanotechnol. 2021, 12, 525–540, doi:10.3762/bjnano.12.43

• have adverse consequences and raised the question whether its method of preparation and solubility are contributing factors. In contrast to the results with NM-212, other nanoceria have been demonstrated to have therapeutic potential for multiple conditions with an oxidative stress/inflammation

• ). The initial experiment was repeated with as-prepared and 75, 102, and 152 day partially dissolved nanoceria. Nanoceria reactivity Oxidative stress, as mass-based biological oxidative damage (mBOD), and surface-based biological oxidative damage (sBOD), of NM-211, NM-212, and the solvothermally

• more available oxygen on the surface of nanoceria not exposed to high temperature. Biological identity of as-prepared and partially dissolved nanoceria Nanoceria has the potential to act as a pro- or antioxidant, depending on its valence, and the oxidative stress level of the system under study

A review on nanostructured silver as a basic ingredient in medicine: physicochemical parameters and characterization

• Gabriel M. Misirli,
• Kishore Sridharan and
• Shirley M. P. Abrantes

Beilstein J. Nanotechnol. 2021, 12, 440–461, doi:10.3762/bjnano.12.36

• considered the ion content (Ag+) of those nanoparticles. Toxicity assays could be performed by using oxidative stress and other reliable markers, such as 8-oxoguanine DNA glycosylase 1 (OGG1) and nuclear factor erythroid 2-related factor 2 (Nrf2) [132] or 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium

Spontaneous shape transition of Mn_xGe_1−x islands to long nanowires

• S. Javad Rezvani,
• Luc Favre,
• Gabriele Giuli,
• Yiming Wubulikasimu,
• Isabelle Berbezier,
• Augusto Marcelli,
• Luca Boarino and
• Nicola Pinto

Beilstein J. Nanotechnol. 2021, 12, 366–374, doi:10.3762/bjnano.12.30

• = α0, with: where e is the Neper number, ϕ = e−3/2cot(θ), with θ the contact angle of the island facet with the substrate. Γ = γecsc(θ) − γscot(θ) with γe and γs are the surface energy per unit area of the edge facet and the substrate, respectively. , where σb, ν and μ are the stress tensor in the

Structural and optical characteristics determined by the sputtering deposition conditions of oxide thin films

• Petronela Prepelita,
• Florin Garoi and
• Valentin Craciun

Beilstein J. Nanotechnol. 2021, 12, 354–365, doi:10.3762/bjnano.12.29

• substrates. In the diffractogram of the 200 nm thick film, diffraction peaks corresponding to a single-phase growth of the film were initially identified. Low intensities of the diffraction lines (004) are due to growth stress, which is unevenly distributed in the film. In the diffractogram corresponding to

• thermal treatment, which induces an internal stress in the ZnO thin films. To the same extent, with the depositions made at room temperature on all SiO2 thin films, their structure proved to be essentially amorphous [28][37] with no sharp XRD reflection lines and featuring a matte surface. Based on XPS

• . The obtained values were between 3.92–4.0 eV for the SiO2 samples and between 3.2–3.3 eV for ZnO films. The band difference of the ZnO films indicated a direct band-to-band transition between the valence and conduction band, while the film stress determined the improvement of the bandgap. The obtained

Differences in surface chemistry of iron oxide nanoparticles result in different routes of internalization

• Barbora Svitkova,
• Vlasta Zavisova,
• Veronika Nemethova,
• Martina Koneracka,
• Miroslava Kretova,
• Filip Razga,
• Monika Ursinyova and
• Alena Gabelova

Beilstein J. Nanotechnol. 2021, 12, 270–281, doi:10.3762/bjnano.12.22

• -independent endocytic pathways by exposure to PEG-SO-MNPs, on the other hand, could compromise cellular homeostasis and result in cellular stress. A close relation between endocytosis and cellular stress has been highlighted in several publications [63]. We can hypothesize that under such conditions either

The nanomorphology of cell surfaces of adhered osteoblasts

• Christian Voelkner,
• Mirco Wendt,
• Regina Lange,
• Max Ulbrich,
• Martina Gruening,
• Susanne Staehlke,
• Barbara Nebe,
• Ingo Barke and
• Sylvia Speller

Beilstein J. Nanotechnol. 2021, 12, 242–256, doi:10.3762/bjnano.12.20

• . 10 Hz m approaches a value around 4/3, which has been associated to the physical effect of hydrodynamic bending of the membrane [60]. As reference we used glass substrates and fixed osteoblasts, which exhibited m values of 2 in accordance with viscous stress of the liquid [59]. Subtle deviations from

Determination of elastic moduli of elastic–plastic microspherical materials using nanoindentation simulation without mechanical polishing

• Hongzhou Li and
• Jialian Chen

Beilstein J. Nanotechnol. 2021, 12, 213–221, doi:10.3762/bjnano.12.17

• computational study regarding the instrumented nanoindentation of elastic–plastic microspherical materials. The ratio between elastic modulus of the microsphere and the initial yield stress of the microsphere was systematically varied from 10 to 1000 to cover the mechanical properties of most materials

• here. Yan established a set of non-dimensional relations for conical indentation on a homogeneous, isotropic semi-infinite flat substrate, including the quantity E/σy [15]. σy is the initial yield stress of a linear elastic, perfectly plastic material. σy/E is the initial yield strain. Phadikar showed

• elastic modulus and yield stress of a microsphere, E/σy, was systematically varied between 10 and 1000 to cover the mechanical properties of the materials most commonly encountered in engineering. For example, an elastic–plastic material with E/σy = 70 and E/σy = 300 is fairly typical for a polymer and

TiO_x/Pt₃Ti(111) surface-directed formation of electronically responsive supramolecular assemblies of tungsten oxide clusters

• Marco Moors,
• Yun An,
• Agnieszka Kuc and
• Kirill Yu. Monakhov

Beilstein J. Nanotechnol. 2021, 12, 203–212, doi:10.3762/bjnano.12.16

• different surface coverages. While the rectangular z’-TiOx phase is a typical island structure, whose number and size increase with the oxygen dosage, the hexagonal w’-TiOx phase always covers the entire surface. In the latter case, the surface stress would be too high to engage the usually favored

• combination of these two species forms the characteristic stripe pattern of the z’-TiOx phase. Inside the trenches between the stripes, several holes in the film can be found, which are probably caused by the stress release during the film growth. These defects permit a direct contact with the underlying

A review on the biological effects of nanomaterials on silkworm (Bombyx mori)

• Sandra Senyo Fometu,
• Guohua Wu,
• Lin Ma and
• Joan Shine Davids

Beilstein J. Nanotechnol. 2021, 12, 190–202, doi:10.3762/bjnano.12.15

• to generate more reactive oxygen species (ROS) and to induce oxidative stress could be a reason for their antibacterial activity against R. solanacearum in tobacco plants [23]. Aside from MgO NPs, other nanomaterials, including titanium dioxide (TiO2 NPs), zinc oxide (ZnO NPs), copper oxide (CuO NPs

• oxidative stress response, which makes the p-translucent silkworm a good model to study Parkinson’s disease [92][93]. Mammalian model organisms are mostly used to study the efficacy of new drugs for human-related diseases and also in the screening of antimicrobial drugs [94]. Recent reports indicate

• concentrations of Ag NPs [122]. Reactive oxygen species (ROS), which are involved in cell signaling and homeostasis [123], are considered a characteristic side-effect of oxygen metabolism. High levels of ROS in living organisms induce oxidative stress, which results in damage to the DNA, proteins, and lipids

Effect of different silica coatings on the toxicity of upconversion nanoparticles on RAW 264.7 macrophage cells

• Cynthia Kembuan,
• Helena Oliveira and
• Christina Graf

Beilstein J. Nanotechnol. 2021, 12, 35–48, doi:10.3762/bjnano.12.3

• oxidative stress and cause apoptosis. In addition, intracellular redox homeostasis and gene expression can be modulated [26]. Lanthanide ions are usually not reported as highly toxic. However, they can interact with proteins, enzymes, and other biomolecules [27][28] and might also cause oxidative damage or

Free and partially encapsulated manganese ferrite nanoparticles in multiwall carbon nanotubes

• Saja Al-Khabouri,
• Salim Al-Harthi,
• Toru Maekawa,
• Mohamed E. Elzain,
• Ashraf Al-Hinai,
• Ahmed D. Al-Rawas,
• Abbsher M. Gismelseed,
• Ali A. Yousif and
• Myo Tay Zar Myint

Beilstein J. Nanotechnol. 2020, 11, 1891–1904, doi:10.3762/bjnano.11.170

• manganese ferrite nanoparticles inside the tubes is observed as a shift in the X-ray diffraction peaks and as an increase in stress, hyperfine field, and coercivity when compared to free manganese ferrite nanoparticles. On the other hand, a strong charge transfer from the multiwall carbon nanotubes is

• ferrite nanoparticles in comparison to free manganese ferrite nanoparticles, which leads to an enhancement of the metallic properties. Keywords: carbon nanotubes; charge transfer; manganese ferrite; metallic nanoparticles; partial encapsulation; stress; surface; Introduction Since the discovery of

Kondo effects in small-bandgap carbon nanotube quantum dots

• Patryk Florków,
• Damian Krychowski and
• Stanisław Lipiński

Beilstein J. Nanotechnol. 2020, 11, 1873–1890, doi:10.3762/bjnano.11.169

• exhibiting non-zero spin magnetic moment. Kondo SU(3) resonances have non-zero orbital and spin moments, and in the Kondo SU(4) state both moments are quenched. By changing the value of the bandgap energy by stress, one can move high-symmetry points between different Coulomb valleys. The SU(4) point occurs

Towards 3D self-assembled rolled multiwall carbon nanotube structures by spontaneous peel off

• Jonathan Quinson

Beilstein J. Nanotechnol. 2020, 11, 1865–1872, doi:10.3762/bjnano.11.168

• is observed, by the naked eye, that layers peel off from the MWCNT forests after synthesis. This is observed without the need to apply any mechanical stress. However, when this phenomenon occurs, it is not possible to identify an area without MWCNTs. In other words, despite the peeling off the