Electron-beam induced deposition and autocatalytic decomposition of Co(CO)₃NO

• Florian Vollnhals,
• Martin Drost,
• Fan Tu,
• Esther Carrasco,
• Andreas Späth,
• Rainer H. Fink,
• Hans-Peter Steinrück and
• Hubertus Marbach

Beilstein J. Nanotechnol. 2014, 5, 1175–1185, doi:10.3762/bjnano.5.129

• contaminants in the deposit [21]. Based on the irradiation of cold (105 K) Co(CO)3NO films of about 2.5 nm thickness on amorphous carbon and Au substrates with 500 eV electrons under UHV conditions, the following decomposition mechanism was proposed [22]: At a low electron dose (<5 × 1016 e−/cm2), one or two

Highly NO₂ sensitive caesium doped graphene oxide conductometric sensors

• Carlo Piloto,
• Marco Notarianni,
• Mahnaz Shafiei,
• Elena Taran,
• Dilini Galpaya,
• Cheng Yan and
• Nunzio Motta

Beilstein J. Nanotechnol. 2014, 5, 1073–1081, doi:10.3762/bjnano.5.120

• ) confirms that the GO does not contain any contaminants and is largely oxidised with an oxygen content of ≈32%. A reduction of the oxygen content down to ≈24% is observed in the GO-Cs (Figure 3a, red line) survey spectrum, which confirm the presence of ≈5% Cs. In the high resolution XPS spectra of the C

Pyrite nanoparticles as a Fenton-like reagent for in situ remediation of organic pollutants

• Carolina Gil-Lozano,
• Elisabeth Losa-Adams,
• Alfonso F.-Dávila and
• Luis Gago-Duport

Beilstein J. Nanotechnol. 2014, 5, 855–864, doi:10.3762/bjnano.5.97

• growing interest in nanomaterials for green environmental remediation. For example, catalytically active synthetic nanoparticles inspired by natural minerals have been combined with in situ advanced oxidation processes (AOPs) as a potential strategy to remediate contaminants [1][2][3]. These AOPs generate

• ]. Practical interest in pyrite as a Fenton-type reagent depends on its capability to efficiently and sustainably generate H2O2 for oxidative degradation of contaminants. Figure 9 summarizes the proposed reaction mechanisms which are involved in the H2O2 generation and in the subsequent degradation of CuPc by

• 7, below [33]. In this sequence, Equation 5 and Equation 6 are the slowest and diminish the recycling between Fe2+ and Fe3+. Consequently, they form the rate-limiting step in the generation of free radical species and decrease the efficiency of the oxidative degradation of contaminants. When pyrite

Shape-selected nanocrystals for in situ spectro-electrochemistry studies on structurally well defined surfaces under controlled electrolyte transport: A combined in situ ATR-FTIR/online DEMS investigation of CO electrooxidation on Pt

• Sylvain Brimaud,
• Zenonas Jusys and
• R. Jürgen Behm

Beilstein J. Nanotechnol. 2014, 5, 735–746, doi:10.3762/bjnano.5.86

• reaction vessel was first cleaned by aqua regia to remove metal traces which could act as nucleation center, then with saturated alkaline solution to remove organic contaminants which could influence the growth process, and finally boiled in ultrapure water (MilliQ®, 18 MΩ cm). Briefly, the synthesis

A visible-light-driven composite photocatalyst of TiO₂ nanotube arrays and graphene quantum dots

• Donald K. L. Chan,
• Po Ling Cheung and
• Jimmy C. Yu

Beilstein J. Nanotechnol. 2014, 5, 689–695, doi:10.3762/bjnano.5.81

• % deionized (DI) water was used as electrolyte. Ti foil (2 cm × 3 cm) was used as a working electrode, and a Pt foil (1 cm × 1 cm) served as a counter electrode. Prior to anodization, Ti foils were washed with ethanol, acetone by ultrasonication to remove contaminants, subsequently rinsed with DI water and

Effects of the preparation method on the structure and the visible-light photocatalytic activity of Ag₂CrO₄

• Difa Xu,
• Shaowen Cao,
• Jinfeng Zhang,
• Bei Cheng and
• Jiaguo Yu

Beilstein J. Nanotechnol. 2014, 5, 658–666, doi:10.3762/bjnano.5.77

• contaminants both in air and aqueous solution. However, Ag2CrO4 is neglected although it has been explored as cathode for lithium cells in early years [37][38][39]. Actually, the band gap of Ag2CrO4 is narrow enough (about 1.75 eV) to obtain strong absorption in visible-light region [40], and thus may enable

Artificial sunlight and ultraviolet light induced photo-epoxidation of propylene over V-Ti/MCM-41 photocatalyst

• Van-Huy Nguyen,
• Shawn D. Lin,
• Jeffrey Chi-Sheng Wu and
• Hsunling Bai

Beilstein J. Nanotechnol. 2014, 5, 566–576, doi:10.3762/bjnano.5.67

• electron–hole generation and consequently enhance the efficiency of the catalyst. This has been observed in the CO2 photo-reduction over Ag/TiO2 or TiO2 [11], the photo-degradation of 4-chlorophenol over TiO2 [12] and the photo-decomposition of organic contaminants over CaBi2O4 [13]. No previous study

Applicability and costs of nanofiltration in combination with photocatalysis for the treatment of dye house effluents

• Wolfgang M. Samhaber and
• Minh Tan Nguyen

Beilstein J. Nanotechnol. 2014, 5, 476–484, doi:10.3762/bjnano.5.55

• membrane separation. Photocatalysis as the master process responsible for the reduction of organic and fouling matter with a nanofiltration and RO-step for further removal of residual contaminants. Nanofiltration as the master process responsible for the major reduction of colour and organic compounds

Plasma-assisted synthesis and high-resolution characterization of anisotropic elemental and bimetallic core–shell magnetic nanoparticles

• M. Hennes,
• A. Lotnyk and
• S. G. Mayr

Beilstein J. Nanotechnol. 2014, 5, 466–475, doi:10.3762/bjnano.5.54

• ) and a transfer chamber (C), connected by two nozzles n1 and n2. Argon 5.0 (99.999%) is used as inert gas and additionally cleaned with an O2 purifier (Air Liquide) so that the final oxygen content in the stream falls below 0.1 ppm, the partial pressure of contaminants therefore being roughly the same

Extracellular biosynthesis of gadolinium oxide (Gd₂O₃) nanoparticles, their biodistribution and bioconjugation with the chemically modified anticancer drug taxol

• Shadab Ali Khan,
• Sanjay Gambhir and
• Absar Ahmad

Beilstein J. Nanotechnol. 2014, 5, 249–257, doi:10.3762/bjnano.5.27

• bioconjugate by HPLC The bioconjugate from other chemical contaminants was purified by HPLC (Waters model 2489 with UV–vis detector) by using Acetonitrile 5–95% on a C18 symmetry column. The compounds eluted from the columns were detected at 227 nm and 325 nm by using a dual wavelength detector. Results and

Study of mesoporous CdS-quantum-dot-sensitized TiO₂ films by using X-ray photoelectron spectroscopy and AFM

• Mohamed N. Ghazzal,
• Robert Wojcieszak,
• Gijo Raj and
• Eric M. Gaigneaux

Beilstein J. Nanotechnol. 2014, 5, 68–76, doi:10.3762/bjnano.5.6

• under magnetic stirring at room temperature for 3 h before the films were spin-coated onto soda lime glass (SLG). Prior to use, the substrates were cleaned by ultrasonication (detergent, distilled water, acetone, ethanol, for 15 min in each medium) to remove hydrophobic contaminants at the surface and

Some reflections on the understanding of the oxygen reduction reaction at Pt(111)

• Ana M. Gómez-Marín,
• Ruben Rizo and
• Juan M. Feliu

Beilstein J. Nanotechnol. 2013, 4, 956–967, doi:10.3762/bjnano.4.108

• in alkaline solutions deals with solution contaminants, which are more difficult to control than those in acidic solutions. This has been discussed in several cases and various interpretations were given. The first report on this problem was the result of a joint effort between Ulm and Alicante and

Evolution of microstructure and related optical properties of ZnO grown by atomic layer deposition

• Adib Abou Chaaya,
• Roman Viter,
• Mikhael Bechelany,
• Zanda Alute,
• Donats Erts,
• Anastasiya Zalesskaya,
• Kristaps Kovalevskis,
• Vincent Rouessac,
• Valentyn Smyntyna and
• Philippe Miele

Beilstein J. Nanotechnol. 2013, 4, 690–698, doi:10.3762/bjnano.4.78

• obtained from the Korean MEMC company, ITO substrates from Sigma Aldrich, and glass substrates from RS (France) were used to prepare the samples for this study. In order to remove organic contaminants the substrates were pre-cleaned in acetone, ethanol and de-ionized water for 5 min. A tailored ALD reactor

Preparation of electrochemically active silicon nanotubes in highly ordered arrays

• Tobias Grünzel,
• Young Joo Lee,
• Karsten Kuepper and
• Julien Bachmann

Beilstein J. Nanotechnol. 2013, 4, 655–664, doi:10.3762/bjnano.4.73

• contaminants. The Si 2p peak position of 102.2 eV (Figure 6b) unambiguously excludes a significant presence of either crystalline Si (99.3 eV) or SiO2 (103.3 eV) [25], in agreement with the 29Si NMR data. The peak position is compatible with amorphous silicon, the Si 2p XPS line of which has been found at a

Routes to rupture and folding of graphene on rough 6H-SiC(0001) and their identification

• M. Temmen,
• O. Ochedowski,
• B. Kleine Bussmann,
• M. Schleberger,
• M. Reichling and
• T. R. J. Bollmann

Beilstein J. Nanotechnol. 2013, 4, 625–631, doi:10.3762/bjnano.4.69

• ] imaging is performed simultaneously by applying an AC voltage of 1 V amplitude at a frequency of 1.2 kHz added to the DC bias regulated to minimize electrostatic forces. To remove volatile surface contaminants that can significantly influence LCPD measurements [25], the sample is heated in UHV to 500 K

Kelvin probe force microscopy of nanocrystalline TiO₂ photoelectrodes

• Alex Henning,
• Gino Günzburger,
• Res Jöhr,
• Yossi Rosenwaks,
• Biljana Bozic-Weber,
• Catherine E. Housecroft,
• Edwin C. Constable,
• Ernst Meyer and
• Thilo Glatzel

Beilstein J. Nanotechnol. 2013, 4, 418–428, doi:10.3762/bjnano.4.49

• , appear for both samples and are visible as dark regions in the measurements. They are highlighted in the cross sections in the lower part of the image. Such a local work function shift can be attributed to local variations of chemisorbed contaminants resulting in a decrease of the local vacuum energy

• , Evac, and the electron affinity, χ. A thin water layer consisting of chemisorbed and physisorbed H2O molecules on the nc-TiO2 is known to be present even inside a dry nitrogen glove box [44]. Solvent residues are further possible contaminants that can be locally attached to the TiO2 surface, or the

• -thienyl)-2,2′-bipyridine)2]+ [43]. In order to remove weakly adsorbed contaminants, the sensitized TiO2 was rinsed with ethanol and dried under nitrogen. Kelvin probe force microscopy AFM measurements were carried out inside a glove box (labmaster 130, mBraun) maintaining a dry nitrogen atmosphere (<1 ppm

Catalytic activity of nanostructured Au: Scale effects versus bimetallic/bifunctional effects in low-temperature CO oxidation on nanoporous Au

• Lu-Cun Wang,
• Yi Zhong,
• Haijun Jin,
• Daniel Widmann,
• Jörg Weissmüller and
• R. Jürgen Behm

Beilstein J. Nanotechnol. 2013, 4, 111–128, doi:10.3762/bjnano.4.13

• activation to the removal of moisture in the pores or of contaminants stemming from the leaching process. The first suggestion, removal of moisture, appears to be unlikely considering the results of additional kinetic measurements performed in our laboratory, in which we used an additional drying

Growth behaviour and mechanical properties of PLL/HA multilayer films studied by AFM

• Cagri Üzüm,
• Johannes Hellwig,
• Narayanan Madaboosi,
• Dmitry Volodkin and
• Regine von Klitzing

Beilstein J. Nanotechnol. 2012, 3, 778–788, doi:10.3762/bjnano.3.87

• order to get rid of any organic contaminants on their surface so that the glue spreads and adheres better. A two-component epoxy adhesive (UHU plus endfest 300, UHU GmbH, Bühl, Germany) was prepared and stored for 20 min under ambient conditions so that it is less fluid and easier to handle. The silica

Effect of spherical Au nanoparticles on nanofriction and wear reduction in dry and liquid environments

• Dave Maharaj and
• Bharat Bhushan

Beilstein J. Nanotechnol. 2012, 3, 759–772, doi:10.3762/bjnano.3.85

• include, but are not limited to, their use in targeted drug delivery and chemical sensors in the identification of oil, removal of contaminants and enhanced oil recovery (EOR). Au, iron oxide, polymer and silica nanoparticles have been studied in targeted drug delivery [3][4][5][6][7][8]. In cancer

Polymer blend lithography: A versatile method to fabricate nanopatterned self-assembled monolayers

• Cheng Huang,
• Markus Moosmann,
• Jiehong Jin,
• Tobias Heiler,
• Stefan Walheim and
• Thomas Schimmel

Beilstein J. Nanotechnol. 2012, 3, 620–628, doi:10.3762/bjnano.3.71

• ]: The wafers were exposed to a jet of CO2 ice crystals, which were produced by expanding CO2 through a nozzle (Snow Jet model K4-05, Tectra Frankfurt/Germany). In this way, surface contaminants are removed either by mechanical impact or by dissolution in CO2. Preparation of a polymer-blend lithographic

Nano-structuring, surface and bulk modification with a focused helium ion beam

• Daniel Fox,
• Yanhui Chen,
• Colm C. Faulkner and
• Hongzhou Zhang

Beilstein J. Nanotechnol. 2012, 3, 579–585, doi:10.3762/bjnano.3.67

• silicon lamella leaving the subsurface structure intact for further analysis. Surface roughness and contaminants were both reduced by the irradiation process. Fabrication is also realized with a high level of patterning acuity. Implantation of helium beneath the surface of the sample is visualized in

• quality; however the HIM polishing step has many benefits over the relatively broad beam of low energy FIB due to the its small probe size and the ion species used. The helium ion beam is non-contaminating and can even be used to selectively remove surface contaminants, such as the gallium contamination

FTIR nanobiosensors for Escherichia coli detection

• Stefania Mura,
• Gianfranco Greppi,
• Maria Laura Marongiu,
• Pier Paolo Roggero,
• Sandeep P. Ravindranath,
• Lisa J. Mauer,
• Nicoletta Schibeci,
• Francesco Perria,
• Massimo Piccinini,
• Plinio Innocenzi and
• Joseph Irudayaraj

Beilstein J. Nanotechnol. 2012, 3, 485–492, doi:10.3762/bjnano.3.55

• contaminants in food systems. Microscopically ordered structure of a mesoporous titania film observed by AFM analysis. (a) FTIR spectrum of mesoporous titania thin films (solid line) and films functionalized with APTES (dashed line). The reference spectrum of APTES is reported in the inset. (b) FTIR spectrum

Models of the interaction of metal tips with insulating surfaces

• Thomas Trevethan,
• Matthew Watkins and
• Alexander L. Shluger

Beilstein J. Nanotechnol. 2012, 3, 329–335, doi:10.3762/bjnano.3.37

• contaminants. This layer can be removed in situ inside the ultrahigh vacuum chamber, by sputtering and/or annealing. However there is no guarantee that the tip apex is pure silicon, and contaminant atoms or molecules may remain. The tip can also be contaminated by material from the surface during imaging; in

• to more freedom in choosing the tip material, as a tip can be manually attached to the tuning-fork prong [5]. However, the problem of keeping the tip apex free of contaminants remains. One approach to deal with the problem of tip–apex control is to employ a tip material that is easy to prepare and

• layer) [6], resulting in a high confidence that the metallic tip apex is free from airborne contaminants. Secondly, it is possible to judge based on the conductivity of the tip as to whether the tip apex is metallic or terminated with contaminant atoms. This can be achieved by recording the resonant

Dipole-driven self-organization of zwitterionic molecules on alkali halide surfaces

• Laurent Nony,
• Franck Bocquet,
• Franck Para,
• Frédéric Chérioux,
• Eric Duverger,
• Frank Palmino,
• Vincent Luzet and
• Christian Loppacher

Beilstein J. Nanotechnol. 2012, 3, 285–293, doi:10.3762/bjnano.3.32

• constants of ≈50 N/m, and quality factors of ≈35,000. Typical oscillation amplitudes were 5–10 nm (10–20 nm peak-to-peak). The cantilevers were heated in situ to ≈150 °C for one hour in order to remove contaminants from the tip. In NC-AFM, the oscillation amplitude of the cantilever is kept constant by an

Variations in the structure and reactivity of thioester functionalized self-assembled monolayers and their use for controlled surface modification

• Inbal Aped,
• Yacov Mazuz and
• Chaim N. Sukenik

Beilstein J. Nanotechnol. 2012, 3, 213–220, doi:10.3762/bjnano.3.24

• , the surfaces achieved were not as hydrophilic as expected. The unexpectedly high contact angles after oxidation, and their possible relationship to solvent induced surface reorganization and/or residual long-chain contaminants, will be addressed in the Discussion section. The irradiation with 254 nm