Nanostructured and oriented metal–organic framework films enabling extreme surface wetting properties

• Andre Mähringer,
• Julian M. Rotter and
• Dana D. Medina

Beilstein J. Nanotechnol. 2019, 10, 1994–2003, doi:10.3762/bjnano.10.196

• due to the required growth conditions for maintaining key features such as homogeneity, crystallinity and crystal orientation on the surface. In our previous reports, we have demonstrated that the use of a modulator in combination with the choice of a substrate play a crucial role in VAC synthesis and

• the formation of a crystalline MOF film [71]. In the present study, we introduce the use of a crystallization promoter in the VAC process, solely for inducing distinct film morphology while maintaining crystallinity and crystal orientation on a preselected substrate. Accordingly, we employed VAC

• , 12 h), and mechanical impact (sonication in water, 20 min). GIWAXS analysis in addition to WCA and OCA measurements after the respective treatment confirmed that the crystallinity, crystal orientation and extreme wetting properties were preserved (see Figures S8.1, S8.2, Supporting Information File 1

The influence of porosity on nanoparticle formation in hierarchical aluminophosphates

• Matthew E. Potter,
• Lauren N. Riley,
• Alice E. Oakley,
• Panashe M. Mhembere,
• June Callison and
• Robert Raja

Beilstein J. Nanotechnol. 2019, 10, 1952–1957, doi:10.3762/bjnano.10.191

• , with the powder XRD patterns showing no significant variation in crystallinity or signal width (Figure 2 and Figure S4 and Figure S5, Supporting Information File 1). Nanoparticle deposition was found to greatly reduce the porosity of both the hierarchical and microporous supports. For MP-SAPO-5 the

Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal–organic framework

• Manuel Souto,
• Joaquín Calbo,
• Samuel Mañas-Valero,
• Aron Walsh and
• Guillermo Mínguez Espallargas

Beilstein J. Nanotechnol. 2019, 10, 1883–1893, doi:10.3762/bjnano.10.183

• ° confirming that crystallinity is maintained after encapsulation of C60 and removal of the solvent (Figure 2). It is important to note that the principal peak is slightly shifted when comparing the experimental and simulated PXRD patterns. This can be explained by the breathing behaviour of MUV-2 [53]. The

Fabrication and characterization of Si_1−xGe_x nanocrystals in as-grown and annealed structures: a comparative study

• Muhammad Taha Sultan,
• Adrian Valentin Maraloiu,
• Ionel Stavarache,
• Jón Tómas Gudmundsson,
• Andrei Manolescu,
• Valentin Serban Teodorescu,
• Magdalena Lidia Ciurea and
• Halldór Gudfinnur Svavarsson

Beilstein J. Nanotechnol. 2019, 10, 1873–1882, doi:10.3762/bjnano.10.182

• target is pulsed with short unipolar voltage pulses at low frequency and short duty cycle, achieving high discharge current densities leading to a high ionization fraction of the sputtered material [27][28]. This approach gives denser films [29] of higher crystallinity [30] than conventional direct

• , three separate and distinctive peaks are evident (Figure 1a). An increase in the XRD peak intensity was observed along with a decrease in full width at half maximum (FWHM), indicating an increased crystallinity. The size of the NCs was determined, using the (111) peak using the multiple peak feature of

• amorphous but with crystalline regions (nanoparticles) (as seen in TEM images later in Figure 5a and Figure 5c). With increased annealing temperature, peaks corresponding to the (111), (220) and (311) planes get sharper and narrower as a sign of increased crystallinity of the SiGe layer. Moreover, a small

Long-term entrapment and temperature-controlled-release of SF₆ gas in metal–organic frameworks (MOFs)

• Hana Bunzen,
• Andreas Kalytta-Mewes,
• Leo van Wüllen and
• Dirk Volkmer

Beilstein J. Nanotechnol. 2019, 10, 1851–1859, doi:10.3762/bjnano.10.180

• ) vibrational modes in SF6 [32]. To check that the sample crystallinity was preserved, we measured powder XRD patterns before and after the loading (Figure 3). The recorded powder XRD patterns did not reveal any changes in the diffraction peak positions, but there were differences in the peak intensities

Biocatalytic oligomerization-induced self-assembly of crystalline cellulose oligomers into nanoribbon networks assisted by organic solvents

• Yuuki Hata,
• Yuka Fukaya,
• Toshiki Sawada,
• Masahito Nishiura and
• Takeshi Serizawa

Beilstein J. Nanotechnol. 2019, 10, 1778–1788, doi:10.3762/bjnano.10.173

• cm−1 (Figure 8). The cellulose II allomorph is the most stable allomorph of cellulose [19] and is typical of the cellulose oligomer assemblies formed in aqueous solution [31][42]. The degree of crystallinity (χc) values of the gelled products were calculated from the XRD profiles and found to be

• higher than those of the products in aqueous solution [42] (Table 1). The higher crystallinity with the organic solvents was attributed to the lower polydispersity in the DP, which would decrease the amount of the amorphous-like assembled structures of the terminal residues of relatively long oligomer

Synthesis of nickel/gallium nanoalloys using a dual-source approach in 1-alkyl-3-methylimidazole ionic liquids

• Ilka Simon,
• Julius Hornung,
• Juri Barthel,
• Jörg Thomas,
• Maik Finze,
• Roland A. Fischer and
• Christoph Janiak

Beilstein J. Nanotechnol. 2019, 10, 1754–1767, doi:10.3762/bjnano.10.171

• different dispersion times before microwave-induced decomposition of the precursors on the phase purity, as well as the influence of the time of microwave-induced decomposition on the crystallinity of the NiGa nanoparticles. Microwave-induced co-decomposition of all-hydrocarbon precursors [Ni(COD)2] (COD

• , Figure S2 and Figure S3). Annealing of nanoparticle samples is known to improve the crystallinity of the nanoparticles [47][48]. The decomposition of Ni(COD)2 and GaCp* in [BMIm][NTf2] was repeated under the same conditions, but with a longer decomposition time of 30 min, in order to induce annealing in

TiO₂/GO-coated functional separator to suppress polysulfide migration in lithium–sulfur batteries

• Ning Liu,
• Lu Wang,
• Taizhe Tan,
• Yan Zhao and
• Yongguang Zhang

Beilstein J. Nanotechnol. 2019, 10, 1726–1736, doi:10.3762/bjnano.10.168

• crystallized with a low degree of crystallinity after spray drying. Thermogravimetric analysis (TGA) of the TiO2/GO composite is presented in Figure 2c. When the temperature was increased from room temperature to 120 °C, a weight decrease of 8.8% was noticed due to the elimination of a small amount of adsorbed

• nanoporous TiO2 has been completely wrapped by wrinkled GO nanosheets (Figure 3d and 3e). As displayed in the high-resolution TEM (HRTEM) images (Figure 3f and 3g), the TiO2/GO composite reveals no clear lattice fringe for TiO2, indicating poor crystallinity. It is clear that the GO sheets have a flake-like

Nanoporous smartPearls for dermal application – Identification of optimal silica types and a scalable production process as prerequisites for marketed products

• David Hespeler,
• Sanaa El Nomeiri,
• Jonas Kaltenbach and
• Rainer H. Müller

Beilstein J. Nanotechnol. 2019, 10, 1666–1678, doi:10.3762/bjnano.10.162

• (20% loading), and the curve with peaks are plotted (system overloaded, 25%). For AL-1 FP samples (the silica with the smallest pore size of 3 nm) only the overloaded curves are shown (12% and 15%). The comparison between DSC and XRD reveals that XRD was more sensitive to detecting crystallinity. In

• with completely filled pores (filled volume 1.8 mL), which additionally have rutin on the surface. This implies that the rutin volume per gram of particles for these samples is >1.8 mL/g (Figure 7, middle). This surface material is amorphous, since no evidence of crystallinity was detected. If too much

• samples with a certain crystallinity is remarkable. This could explain the higher recovery rate at higher loadings of 28–30%. The silica sample with the smaller pores (3 nm, AL-1 FP) showed at low maximum loading (12%) and a recovery rate of only about 35%. The recovery rate was also analyzed by HPLC, and

Kelvin probe force microscopy work function characterization of transition metal oxide crystals under ongoing reduction and oxidation

• Dominik Wrana,
• Karol Cieślik,
• Wojciech Belza,
• Christian Rodenbücher,
• Krzysztof Szot and
• Franciszek Krok

Beilstein J. Nanotechnol. 2019, 10, 1596–1607, doi:10.3762/bjnano.10.155

• ]. The high level of crystallinity of these nanowires is the result of the formation mechanism, which comprises incongruent strontium effusion from SrTiO3 and then a TiO structure growth via crystallographic shearing and diffusion (more details can be found in [12]). The abrupt TiO/SrTiO3 interface and

Materials nanoarchitectonics at two-dimensional liquid interfaces

• Katsuhiko Ariga,
• Michio Matsumoto,
• Taizo Mori and
• Lok Kumar Shrestha

Beilstein J. Nanotechnol. 2019, 10, 1559–1587, doi:10.3762/bjnano.10.153

• ., crystallinity controlled two-dimensional patterns based on guanidinium/carboxylate molecular recognition [196] and the two-dimensional assembly of one-dimensional supramolecular polymers formed between alkylated melamine and aqueous barbiturate [197] have been also accomplished. Oishi and co-workers utilized

• ]. Interfacial polymerization at liquid interfaces is an already industrialized technique to produce conventional cross-linked polymer films/membranes. Interfacial polymerization of 2DCP films still remains in its infant stage in terms of controlling crystallinity, domain sizes, and generalities. However, the

Rapid thermal annealing for high-quality ITO thin films deposited by radio-frequency magnetron sputtering

• Petronela Prepelita,
• Ionel Stavarache,
• Doina Craciun,
• Florin Garoi,
• Catalin Negrila,
• Beatrice Gabriela Sbarcea and
• Valentin Craciun

Beilstein J. Nanotechnol. 2019, 10, 1511–1522, doi:10.3762/bjnano.10.149

• impurities from degassing of the deposition chamber takes place. At the same time, the improvement of surface crystallinity (Figure 2), annealing of surface structural defects and achievement of uniform films on the entire deposited surface (Figure 1) are obtained [33]. Using these structural and

• size and the improvement of crystallinity led to the decrease in defects in the films, thus resulting in higher conductivity. Adding oxygen leads to improved transmission and conductivity in the ITO thin films. The conductive ITO thin films (ρ = 8.4 × 10−5 Ω cm to ρ = 7.4 × 10−5 Ω cm) were obtained by

• crystallinity by increasing the crystallite size (from 12.7 nm to 34.3 nm). Also, it was found from SEM investigations (cross-sections) that films subjected to such a thermal treatment show good adhesion to the substrate. Based on XPS investigations, it was evidenced that stoichiometric thin films were obtained

BiOCl/TiO₂/diatomite composites with enhanced visible-light photocatalytic activity for the degradation of rhodamine B

• Minlin Ao,
• Kun Liu,
• Xuekun Tang,
• Zishun Li,
• Qian Peng and
• Jing Huang

Beilstein J. Nanotechnol. 2019, 10, 1412–1422, doi:10.3762/bjnano.10.139

• with the SEM results. The obvious lattice fringes can be observed in Figure 6b, indicating that the crystallinity of the composites is improved. The lattice fringes of 0.352 nm and 0.281 nm are matched with anatase TiO2 (101) and BiOCl (110) planes, respectively. The results show that diatomite in BTD

• that BTD has obvious advantages over pure BiOCl and other complexes. As shown in Figure 7b, the sample with a BiOCl to TiO2 molar ratio of 1:1 shows the best visible-light photocatalytic activity, and at the same time, the highest crystallinity and the most active sites were found. Figure 7c shows the

Gas sensing properties of individual SnO₂ nanowires and SnO₂ sol–gel nanocomposites

• Alexey V. Shaposhnik,
• Dmitry A. Shaposhnik,
• Sergey Yu. Turishchev,
• Olga A. Chuvenkova,
• Stanislav V. Ryabtsev,
• Alexey A. Vasiliev,
• Xavier Vilanova,
• Francisco Hernandez-Ramirez and
• Joan R. Morante

Beilstein J. Nanotechnol. 2019, 10, 1380–1390, doi:10.3762/bjnano.10.136

• of the coherence area, which is determined by the crystallinity of the structure. Nanowires formed by the vapor–liquid–solid mechanism have high and narrow peaks, confirming their monocrystalline structure. In contrast, the nanopowders exhibit low and wide peaks, demonstrating their disordered

Tailoring the magnetic properties of cobalt ferrite nanoparticles using the polyol process

• Malek Bibani,
• Romain Breitwieser,
• Alex Aubert,
• Vincent Loyau,
• Silvana Mercone,
• Souad Ammar and
• Fayna Mammeri

Beilstein J. Nanotechnol. 2019, 10, 1166–1176, doi:10.3762/bjnano.10.116

• crystallinity, with NPs acting as nucleating points. Also, as established by Costa et al., the presence of these NPs promotes the crystallization of PVDF in its β-phase, the most electroactive one, instead of its other allotropic forms [10]. Finally, another improvement consists in making the size of the

• the samples was found to be between 141 K (smallest NPs) and 315 K (biggest NPs). Moreover, the biggest NPs exhibited a saturation magnetization very close to that of the bulk (85 emu·g−1 vs 90–95 emu·g−1) indicating a very high crystallinity despite the small size of the NPs. Baldi et al. prepared

A highly efficient porous rod-like Ce-doped ZnO photocatalyst for the degradation of dye contaminants in water

• Binjing Hu,
• Qiang Sun,
• Chengyi Zuo,
• Yunxin Pei,
• Siwei Yang,
• Hui Zheng and
• Fangming Liu

Beilstein J. Nanotechnol. 2019, 10, 1157–1165, doi:10.3762/bjnano.10.115

• 3 h. Characterization The XRD patterns of pure ZnO and CZO-4 are given in Figure 3. It can be found that the sharp peaks of ZnO, which indicates a high degree of crystallinity, are located at 2θ values of 31.5, 34.05, 35.9, 47.2, 56.3, 62.6, 66.08, 67.64, 68.84 finely corresponding to the (100

Photoactive nanoarchitectures based on clays incorporating TiO₂ and ZnO nanoparticles

• Eduardo Ruiz-Hitzky,
• Pilar Aranda,
• Marwa Akkari,
• Nithima Khaorapapong and
• Makoto Ogawa

Beilstein J. Nanotechnol. 2019, 10, 1140–1156, doi:10.3762/bjnano.10.114

• . Synthesis strategies of hierarchically designed TiO2 and ZnO nanoarchitectures with controlled morphology, crystallinity, anisotropic shape, and composition have been investigated recently. The aim was to obtain accessible and interconnected porous networks with increased specific surface area for the

CuInSe₂ quantum dots grown by molecular beam epitaxy on amorphous SiO₂ surfaces

• Henrique Limborço,
• Pedro M.P. Salomé,
• Rodrigo Ribeiro-Andrade,
• Jennifer P. Teixeira,
• Nicoleta Nicoara,
• Kamal Abderrafi,
• Joaquim P. Leitão,
• Juan C. Gonzalez and
• Sascha Sadewasser

Beilstein J. Nanotechnol. 2019, 10, 1103–1111, doi:10.3762/bjnano.10.110

• confirmed the crystallinity of the nanodots as well as chemical composition and structure compatible with tetragonal CuInSe2. Photoluminescence measurements of CdS-passivated nanodots showed that the nanodots are optoelectronically active with a broad emission extending to energies above the CuInSe2 bulk

Co-doped MnFe₂O₄ nanoparticles: magnetic anisotropy and interparticle interactions

• Bagher Aslibeiki,
• Parviz Kameli,
• Hadi Salamati,
• Giorgio Concas,
• Maria Salvador Fernandez,
• Alessandro Talone,
• Giuseppe Muscas and
• Davide Peddis

Beilstein J. Nanotechnol. 2019, 10, 856–865, doi:10.3762/bjnano.10.86

• low temperature, not higher than 350 °C) allows nanoparticles to be produced with good control of size and crystallinity in large scale (i.e., tens of grams), much more than can be provided by conventional chemical approaches (usually limited to 100–300 mg). Therefore this method can be easily

Synthesis of MnO₂–CuO–Fe₂O₃/CNTs catalysts: low-temperature SCR activity and formation mechanism

• Yanbing Zhang,
• Lihua Liu,
• Yingzan Chen,
• Xianglong Cheng,
• Chengjian Song,
• Mingjie Ding and
• Haipeng Zhao

Beilstein J. Nanotechnol. 2019, 10, 848–855, doi:10.3762/bjnano.10.85

• shown in the results of NO conversion (Figure 1) and our previous studies [6][16][17]. In the case of Mn–Cu–FeOx/CNTs-IWIM, a series of peaks corresponding to Mn3O4 (PDF#18-0803) can be seen. Metal oxide catalysts with higher crystallinity show a smaller catalytic activity [20]. This is corroborated by

On the transformation of “zincone”-like into porous ZnO thin films from sub-saturated plasma enhanced atomic layer deposition

• Alberto Perrotta,
• Julian Pilz,
• Stefan Pachmajer,
• Antonella Milella and
• Anna Maria Coclite

Beilstein J. Nanotechnol. 2019, 10, 746–759, doi:10.3762/bjnano.10.74

• . Moreover, the crystallinity and crystallite orientation could be tuned, ranging from a powder-like to a (100) preferential growth in the out-of-plane direction, as measured by synchrotron-radiation grazing incidence XRD. Calcination temperature ranges were identified in which pore formation and subsequent

• 400 °C, showing significant loss of material starting from 200 °C. However, the crystallinity and crystal growth of the resulting porous ZnO structure were not investigated. In different systems, studying the evolution of Ti alkoxide upon pyrolysis in inert atmosphere, Abdulagatov et al. [11] showed

• an inhibition of the crystal formation in the resulting TiO2 layers, and the authors attributed this to the amorphous titania being constrained in the organic matrix. As a consequence, an investigation of the crystallinity of Zn-alkoxide layers would shed a light on the evolution of the ZnO crystals

Outstanding chain-extension effect and high UV resistance of polybutylene succinate containing amino-acid-modified layered double hydroxides

• Adam A. Marek,
• Vincent Verney,
• Christine Taviot-Gueho,
• Grazia Totaro,
• Laura Sisti,
• Annamaria Celli and
• Fabrice Leroux

Beilstein J. Nanotechnol. 2019, 10, 684–695, doi:10.3762/bjnano.10.68

• -acid-modified Mg2Al LDHs and Mg2Al LDH nitrate were prepared by melt extrusion. The XRD patterns are presented in Figure 6 together with PBS without filler as a reference. The diffraction peaks located at 2θ = 18–30°, which are characteristic for the crystallinity of PBS, seem to not be affected by the

• filler structure can be explained by their lower crystallinity or by a partial exfoliation occurring during thermal processing. For PBS–LDH/HIS, there is an additional peak at 2θ = 18° that is difficult to assign. Its associated small full width at half maximum (FWHM) may be attributed to rather

Ultrathin hydrophobic films based on the metal organic framework UiO-66-COOH(Zr)

• Miguel A. Andrés,
• Clemence Sicard,
• Christian Serre,
• Olivier Roubeau and
• Ignacio Gascón

Beilstein J. Nanotechnol. 2019, 10, 654–665, doi:10.3762/bjnano.10.65

• position and cover MOF particles. Moreover, the presence of MOF particles significantly enhances the surface roughness and allows ultrathin, hydrophobic coverage to be obtained. Finally, it has been shown that the crystallinity and the porosity of the MOF remains almost unaltered in MOF/ODP films

• similar to that of mixed film UiO-66-COOH(Zr) + 10 wt % ODP, which is in good agreement with the results reported for other Zr-based MOFs that do not result in significantly reduced adsorption capacity after modification with ODP [34]. To confirm that the addition of ODP does not alter the crystallinity

• particles without significantly affecting the porosity or crystallinity since both properties are intimately linked in a MOF. Finally, it should also be mentioned that the CO2 adsorption capacity at 1 bar for an LB film is similar to that of drop-cast samples but the relative deviations in the measurements

Hydrophilicity and carbon chain length effects on the gas sensing properties of chemoresistive, self-assembled monolayer carbon nanotube sensors

• Juan Casanova-Cháfer,
• Carla Bittencourt and
• Eduard Llobet

Beilstein J. Nanotechnol. 2019, 10, 565–577, doi:10.3762/bjnano.10.58

• will be discussed in detail below. The crystallinity of oxygen-plasma-treated MWCNTs decorated with gold nanoparticles was characterized by Raman spectroscopy. Taking the intensity ratio of the D/G bands into consideration, the material presents a low level of crystallinity with defects caused by the

Nanocomposite–parylene C thin films with high dielectric constant and low losses for future organic electronic devices

• Marwa Mokni,
• Gianluigi Maggioni,
• Abdelkader Kahouli,
• Sara M. Carturan,
• Walter Raniero and
• Alain Sylvestre

Beilstein J. Nanotechnol. 2019, 10, 428–441, doi:10.3762/bjnano.10.42

• modifies the film density as well as the degree of crystallinity and the size of parylene C crystallites. Moreover, silver is incorporated in the parylene matrix as an oxide phase. The average size of the Ag oxide nanoparticles is lower than 20 nm and influences the roughness of the NCPC films. Samples

• crystallinity than sample O, as highlighted by the shift of the (020) peak to a larger 2θ angle (Figure 3, left) and by the larger nanocrystallite size (reduction in the FWHM, see Table 2). Typically, when comparing two similar polymers with just a change in the degree of crystallinity, the most important

• number of dipoles participating in the β-relaxation process: the higher the degree of crystallinity for a given polymer, the lower the number of dipoles involved in the relaxation mechanism (as these dipoles are ‘frozen’ in the semi-crystalline state). Consequently, Δε decreases at increasing degrees of