Gap-directed chemical lift-off lithographic nanoarchitectonics for arbitrary sub-micrometer patterning

• Chang-Ming Wang,
• Hong-Sheng Chan,
• Chia-Li Liao,
• Che-Wei Chang and
• Wei-Ssu Liao

Beilstein J. Nanotechnol. 2023, 14, 34–44, doi:10.3762/bjnano.14.4

• moieties are conjugated with streptavidin followed by FITC-labeled anti-streptavidin antibody recognition (Figure 1A). This process results in obvious contrast in fluorescence images, allowing the visualization of biorecognition processes at post lift-off regions. XPS spectroscopy is utilized to monitor

Two-step single-reactor synthesis of oleic acid- or undecylenic acid-stabilized magnetic nanoparticles by thermal decomposition

• Mykhailo Nahorniak,
• Pamela Pasetto,
• Jean-Marc Greneche,
• Volodymyr Samaryk,
• Sandy Auguste,
• Anthony Rousseau,
• Nataliya Nosova and
• Serhii Varvarenko

Beilstein J. Nanotechnol. 2023, 14, 11–22, doi:10.3762/bjnano.14.2

• , and composition via several techniques, such as transmission electron microscopy, dynamic light scattering, thermogravimetric analysis, Fourier-transform infrared spectroscopy/attenuated total reflectance, 57Fe Mössbauer spectroscopy, and X-ray diffraction. The effect of unsaturated oleic (OA) and

• oleate and formation of undecylate complexes, Fourier-transform infrared spectroscopy (FTIR) studies of the reaction mixtures were carried out at the beginning and at the end of the first stage of NPM synthesis prior to removing acetylacetone under vacuum (see Figures S2 and S3 in Supporting Information

• standards. However, it must be noted that these iron oxides are characterized by spinal structures and very close lattice parameters, which makes their distinction using XRD very troublesome [38]. Unlike XRD, 57Fe Mössbauer spectroscopy allows one to distinguish between magnetite and maghemite, since the

From a free electron gas to confined states: A mixed island of PTCDA and copper phthalocyanine on Ag(111)

• Alfred J. Weymouth,
• Emily Roche and
• Franz J. Giessibl

Beilstein J. Nanotechnol. 2022, 13, 1572–1577, doi:10.3762/bjnano.13.131

• spectroscopy experiments [6][7][8], and has been studied with density functional theory (DFT) [9][10]. Previous work [11] has used dI/dV spectroscopy as a measurement of the density of electronic states [12] and identified this interface state starting at 0.6 eV. One characteristic of a two-dimensional

• oscillation amplitude of 50 pm. The resonance frequency of the sensor is 38819 Hz, which is much higher than the modulation voltage used for spectroscopy data. Results and Discussion Figure 1a is an AFM image of an island showing both PC and P2C phases. The internal structure of the molecules appears similar

Single-step extraction of small-diameter single-walled carbon nanotubes in the presence of riboflavin

• Polina M. Kalachikova,
• Anastasia E. Goldt,
• Eldar M. Khabushev,
• Timofei V. Eremin,
• Timofei S. Zatsepin,
• Elena D. Obraztsova,
• Konstantin V. Larionov,
• Liubov Yu. Antipina,
• Pavel B. Sorokin and
• Albert G. Nasibulin

Beilstein J. Nanotechnol. 2022, 13, 1564–1571, doi:10.3762/bjnano.13.130

• between the SWCNTs and gel media. Our experimental findings are supported by ab initio calculations demonstrating the impact of the riboflavin wrapping pattern around the SWCNTs on their interaction with the allyl dextran gel. Keywords: carbon nanotubes; photoluminescence spectroscopy; riboflavin; size

• as the first fraction. Optical characterization UV–vis–NIR spectroscopy measurements were performed using a Perkin-Elmer Lambda 1050 spectrophotometer in the wavelength range of 400–1300 nm to avoid the immense absorption of water in the NIR and minimize the interference of riboflavin absorption with

Photoelectrochemical water oxidation over TiO₂ nanotubes modified with MoS₂ and g-C₃N₄

• Phuong Hoang Nguyen,
• Thi Minh Cao,
• Tho Truong Nguyen,
• Hien Duy Tong and
• Viet Van Pham

Beilstein J. Nanotechnol. 2022, 13, 1541–1550, doi:10.3762/bjnano.13.127

• of materials The morphology, the phase, and the vibrational characteristics of the surface functional groups of the materials were observed by field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR). Diffuse reflectance

• spectroscopy (DRS) was carried out to measure the optical bandgap of the semiconductor materials through the Tauc method using the absorption coefficient α of the material, according to Equation 1 [42]: where h, ν, Eg, and B are the Planck constant, the frequency of the photon, the bandgap energy, and a

• determined by using FTIR spectroscopy, as shown in Figure 3b. The formation of TiO2 on the Ti foil is indicated by the vibrations of the Ti–O bond in the wavenumber region from 450 to 750 cm−1 [47]. The bonding characteristics in the MoS2 material are presented by Mo–S vibration peaks between 1620 and 420 cm

A TiO₂@MWCNTs nanocomposite photoanode for solar-driven water splitting

• Anh Quynh Huu Le,
• Ngoc Nhu Thi Nguyen,
• Hai Duy Tran,
• Van-Huy Nguyen and
• Le-Hai Tran

Beilstein J. Nanotechnol. 2022, 13, 1520–1530, doi:10.3762/bjnano.13.125

• diffraction (XRD, D2 PHASER). The chemical structure of the samples is characterized using Fourier-transform infrared spectroscopy (FTIR, Brucker 27). The electrochemical measurements are carried out on a MPG2 Biologic system with a three-electrode cell controlled by ECLab® software. Diffuse reflectance

• MWCNTs and TiO2@MWCNTs, which could result from the catalyzed synthesis of MWCNTs [14]. Raman spectroscopy is applied for phase characterization of MWCNTs and TiO2@MWCNTS, as shown in Figure 5. The peaks at 178, 424, and 609 cm−1 are characteristic of the TiO2 phase in the TiO2@MWCNTs catalyst [21]. In

• electrode [35]. Based on the cyclic voltammetry results, it could be suggested that the TiO2@MWCNTs electrode is superior regarding photoelectrochemical application compared to TiO2 and MWCNTs electrodes. Electrochemical impedance spectroscopy (EIS) is applied to characterize the electron-transfer property

In search of cytotoxic selectivity on cancer cells with biogenically synthesized Ag/AgCl nanoparticles

• Mitzi J. Ramírez-Hernández,
• Mario Valera-Zaragoza,
• Omar Viñas-Bravo,
• Ariana A. Huerta-Heredia,
• Miguel A. Peña-Rico,
• Erick A. Juarez-Arellano,
• David Paniagua-Vega,
• Eduardo Ramírez-Vargas and
• Saúl Sánchez-Valdes

Beilstein J. Nanotechnol. 2022, 13, 1505–1519, doi:10.3762/bjnano.13.124

• pineapple peel extracts and their behavior on the breast cancer cell line MCF-7 is shown. Bioreactions were monitored at different temperatures. Fourier-transform infrared spectroscopy (FTIR), ultraviolet–visible spectroscopy (UV–vis), thermogravimetric analysis (TGA), X-ray diffraction (XRD), energy

• -dispersive X-ray spectroscopy (EDX), and transmission electron microscopy (TEM) techniques were used to characterize nanoparticle development. The breast cancer cell line MCF-7 was used as a test model to study the cytotoxic behavior of Ag/AgCl nanoparticles and, as a counterpart, the nanoparticles were also

• give rise to a collective oscillation known as surface plasmon effect [34]. This effect can be monitored by UV–vis spectroscopy, where metal nanoparticles absorb radiation at different wavelengths depending on their size [36]. The UV–vis absorption spectra of the reactions at different temperatures are

Frequency-dependent nanomechanical profiling for medical diagnosis

• Santiago D. Solares and
• Alexander X. Cartagena-Rivera

Beilstein J. Nanotechnol. 2022, 13, 1483–1489, doi:10.3762/bjnano.13.122

• nanomechanical measurements into medical diagnosis, which includes specialized in vivo sensing, computer analysis (AFM force spectroscopy analysis), communication with the healthcare provider, and mining of the aggregate community database. Given the mechanical nature of AFM, the above strategy naturally fits

• tension. These additional multidimensional biophysical parameters could be inferred from the AFM spectroscopy data as well, and could be correlated with the frequency-dependent nanomechanical parameters previously described to provide richer mechanistic knowledge of the genesis of a complex disease and

Structural studies and selected physical investigations of LiCoO₂ obtained by combustion synthesis

• Monika Michalska,
• Paweł Ławniczak,
• Tomasz Strachowski,
• Adam Ostrowski and
• Waldemar Bednarski

Beilstein J. Nanotechnol. 2022, 13, 1473–1482, doi:10.3762/bjnano.13.121

• investigated by using impedance spectroscopy. Comparison of the effect of annealing temperature on electrical conductivity shows a very interesting behavior. As the annealing temperature increases, the DC conductivity value increases, reaching a maximum at a temperature of 500 °C. However, further increase in

• conductivity and comparison of electrical properties of LCO powders) by using impedance spectroscopy (IS). Our studies provide important information on the mechanism of formation, particle growth, size, shape, and the control of these parameters during synthesis. Materials and Methods Synthesis of LiCoO2

• with Mn were studied using impedance spectroscopy. For conductivity measurements, pellets of ca. 1.5 mm thickness and 5.15 mm in diameter were prepared from the synthesized material. The powder was pressed at 20 MPa pressure for 1 min at room temperature. The round surfaces of the samples were covered

Rapid and sensitive detection of box turtles using an electrochemical DNA biosensor based on a gold/graphene nanocomposite

• Abu Hashem,
• M. A. Motalib Hossain,
• Ab Rahman Marlinda,
• Mohammad Al Mamun,
• Khanom Simarani and
• Mohd Rafie Johan

Beilstein J. Nanotechnol. 2022, 13, 1458–1472, doi:10.3762/bjnano.13.120

• scanning electron microscopy and structural characteristics were analysed by using energy-dispersive X-ray, UV–vis, and Fourier-transform infrared spectroscopy. The electrochemical characteristics of the modified electrodes were studied by cyclic voltammetry, differential pulse voltammetry (DPV), and

• electrochemical impedance spectroscopy. The thiol-modified synthetic DNA probe was immobilised on modified SPCEs to facilitate hybridisation with the reverse complementary DNA. The turtle DNA was distinguished based on hybridisation-induced electrochemical change in the presence of methylene blue compared to

• with graphene. The spectrum of Gr in Figure 2c obtained by energy dispersive X-ray spectroscopy (EDX) clearly demonstrates the presence of a high amount of carbon with a minimum amount of oxygen, indicating the purity of Gr. Figure 2d clearly shows the presence of carbon, oxygen, and AuNPs in the

Facile preparation of Au- and BODIPY-grafted lipid nanoparticles for synergized photothermal therapy

• Yuran Wang,
• Xudong Li,
• Haijun Chen and
• Yu Gao

Beilstein J. Nanotechnol. 2022, 13, 1432–1444, doi:10.3762/bjnano.13.118

• –visible (UV–vis) absorption spectra were measured with an UV–vis spectrometer (Q-5000, Quawell, America). The amounts of BDP in AB-LNPs were analyzed using UV–vis spectroscopy after the dissolution of AB-LNPs in DMSO by measuring the absorbance at a wavelength of 600 nm. The loading efficiency (LE, %) was

• taken out to measure the amount of the released drug by UV–vis spectroscopy, and an equal volume of fresh release medium was added to keep the volume constant. Photothermal measurement for AB-LNPs To study the photothermal properties of AB-LNPs, different concentrations of AB-LNPs with BDP

• characteristics could reduce the systemic toxicity of AB-LNPs on normal tissues. To check whether free BDP is stable during the release experiment, the content of BDP in PBS (pH 7.4 or 5.4) was measured using UV–vis spectroscopy. The content of free BDP showed little change over a period of 36 h (Figure 3d

LED-light-activated photocatalytic performance of metal-free carbon-modified hexagonal boron nitride towards degradation of methylene blue and phenol

• Nirmalendu S. Mishra and
• Pichiah Saravanan

Beilstein J. Nanotechnol. 2022, 13, 1380–1392, doi:10.3762/bjnano.13.114

• . The Mott–Schottky (MS) analysis was performed at a frequency of 1 kHz while the electrochemical impedance spectroscopy (EIS) studies were conducted at 0 V DC under a frequency range of 105 to 100 Hz. The open circuit potential as a function of time (OCPT) was performed under alternating light and dark

Supramolecular assembly of pentamidine and polymeric cyclodextrin bimetallic core–shell nanoarchitectures

• Alexandru-Milentie Hada,
• Nina Burduja,
• Marco Abbate,
• Claudio Stagno,
• Guy Caljon,
• Louis Maes,
• Nicola Micale,
• Massimiliano Cordaro,
• Angela Scala,
• Antonino Mazzaglia and
• Anna Piperno

Beilstein J. Nanotechnol. 2022, 13, 1361–1369, doi:10.3762/bjnano.13.112

• during the reduction/stabilization of metal NPs was investigated for the first time by NMR spectroscopy. Keywords: antimicrobial agents; bimetallic nanoparticles; gold/silver core–shell; Leishmania; pentamidine; polycyclodextrin; Introduction Noble metal nanoparticles (NPs), in particular those

• spectroscopy, DLS, and ζ potential measurements. The UV–vis spectra clearly indicated strong interactions between nanoGS and Pent (Figure 4B). Specifically, we can observe: i) the red shift in the LSPR band from 402 nm (nanoGS) to 409 nm (nanoGSP); (ii) the presence of the Pent band centred at 262 nm in

• antileishmanial drug pentamidine with Au@Ag NPs produced the nanosystem nanoGSP endowed with excellent stability as evidenced by UV–vis, DLS, and ζ-potential analyses. The role of PolyCD in the reduction/stabilization of NPs processes was investigated by NMR spectroscopy. The analyses of DEPT-edited HSQC NMR

Near-infrared photoactive Ag-Zn-Ga-S-Se quantum dots for high-performance quantum dot-sensitized solar cells

• Roopakala Kottayi,
• Ilangovan Veerappan and
• Ramadasse Sittaramane

Beilstein J. Nanotechnol. 2022, 13, 1337–1344, doi:10.3762/bjnano.13.110

• nanocrystals. The X-ray diffraction pattern confirms the hexagonal structure. Due to the near-infrared light absorption capability, the synthesized QDs were used as the sensitizer to fabricate QDSCs. The fabricated QDSCs were characterized by using electrochemical impedance spectroscopy and photovoltaic

Recent trends in Bi-based nanomaterials: challenges, fabrication, enhancement techniques, and environmental applications

• Vishal Dutta,
• Ankush Chauhan,
• Ritesh Verma,
• C. Gopalkrishnan and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 1316–1336, doi:10.3762/bjnano.13.109

• X-ray photoelectron spectroscopy revealed the coexistence of self-doped Bi5+ and in situ deposited Bi(M). Compared to Bi/BiOBr or BiOBr–Bi5+, the photocatalytic activity of Bi/BiOBr-Bi5+ regarding RhB degradation under visible light was significantly increased. OVs helped in separating photoexcited

Enhanced electronic transport properties of Te roll-like nanostructures

• E. R. Viana,
• N. Cifuentes and
• J. C. González

Beilstein J. Nanotechnol. 2022, 13, 1284–1291, doi:10.3762/bjnano.13.106

• under mild conditions. A large quantity of these polycrystalline nanostructures with a diameter between 100 and 900 nm and a wall thickness around 50 nm were synthesized and characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), transmission electron microscopy

Studies of probe tip materials by atomic force microscopy: a review

• Ke Xu and
• Yuzhe Liu

Beilstein J. Nanotechnol. 2022, 13, 1256–1267, doi:10.3762/bjnano.13.104

• interaction force between the particle and the surface. A new colloidal AFM probe was proposed by Daboss et al. [14]. These conductive spherical boron-doped diamond (BDD)-AFM probes allow electrochemical force spectroscopy. The physical robustness of these bifunctional probes and the excellent electrochemical

• -enhanced Raman spectroscopy and fluorescence microscopy. They can open new avenues for characterizing nano-objects and make it possible to study chemical and physical phenomena occurring at the nanoscale. Following the preparation and application of monometallic nanowire probes, Fang et al. [36] proposed a

• such as electrochemical impedance spectroscopy, where the AC potential is applied to eCPs, and where such first tests are promising. Most importantly, eCPs are extremely stable and can be applied to electrochemically controlled tribology or nanoindentation experiments. With these foundations, eCPs will

Design of surface nanostructures for chirality sensing based on quartz crystal microbalance

• Yinglin Ma,
• Xiangyun Xiao and
• Qingmin Ji

Beilstein J. Nanotechnol. 2022, 13, 1201–1219, doi:10.3762/bjnano.13.100

• outstanding sensing properties, with real-time, sensitive and selective chiral detection, high durability, and easy recovery. To understand the chiral recognition between calixarenes and analytes, Zoya I. Kazantseva et al. combined QCM and proton magnetic resonance spectroscopy (1H NMR) techniques to study

• promoted the combination of S-1-phenethylamine, while the ortho-position may combine with R-1-phenethylamine. The QCM results were consistent with the data from 1H NMR spectroscopy. Moreover, the QCM method may also allow for the detection of weak interactions of amides and esters with amines and a slight

• chiral anion induction and combined with CD spectroscopy to achieve chiral recognition with a relatively larger size of poly(propiolic acid) sodium salt [116]; He et al. used chiral mesoporous SiO2 and combined with gas chromatography (GC) achieved chiral separation of amino acid derivatives and other

Application of nanoarchitectonics in moist-electric generation

• Jia-Cheng Feng and
• Hong Xia

Beilstein J. Nanotechnol. 2022, 13, 1185–1200, doi:10.3762/bjnano.13.99

• bonding near the cathode, measured by infrared spectroscopy (Figure 8f,g). Under moist conditions, a voltage signal could be measured in the gradient structure device, while the PDA film without polarization treatment did not produce an obvious voltage or current signal. This lateral gradient

Rapid fabrication of MgO@g-C₃N₄ heterojunctions for photocatalytic nitric oxide removal

• Minh-Thuan Pham,
• Duyen P. H. Tran,
• Xuan-Thanh Bui and
• Sheng-Jie You

Beilstein J. Nanotechnol. 2022, 13, 1141–1154, doi:10.3762/bjnano.13.96

• spectroscopy (DRS) was used to determine the optical properties and bandgap energies of the material. The bandgap of the material decreases with increasing amounts of MgO. The photoluminescence spectra indicate that the recombination of electron–hole pairs is hindered by doping MgO onto g-C3N4. Also, NO

• -transform infrared spectroscopy (FTIR) was used to determine the chemical bond composition of the materials. Differential reflectance spectroscopy (DRS) determined the change in the bandgap of the materials. The elements of the materials were identified by high-resolution X-ray photoelectron spectroscopy

Green synthesis of zinc oxide nanoparticles toward highly efficient photocatalysis and antibacterial application

• Vo Thi Thu Nhu,
• Nguyen Duy Dat,
• Le-Minh Tam and
• Nguyen Hoang Phuong

Beilstein J. Nanotechnol. 2022, 13, 1108–1119, doi:10.3762/bjnano.13.94

• centrifuged at 6000 rpm to measure the dye concentrations. The dye concentration was analyzed by UV–vis spectroscopy (Hitachi U2900) with maximum adsorption wavelengths of MB and MO of 664 nm and 464 nm, respectively [29][30]. The degradation efficiency was calculated using Equation 3. where c0 is the initial

Recent advances in green carbon dots (2015–2022): synthesis, metal ion sensing, and biological applications

• Aisha Kanwal,
• Naheed Bibi,
• Sajjad Hyder,
• Arif Muhammad,
• Hao Ren,
• Jiangtao Liu and
• Zhongli Lei

Beilstein J. Nanotechnol. 2022, 13, 1068–1107, doi:10.3762/bjnano.13.93

• source). They showed that luminous impurities formed as byproducts during the synthesis of CDs mostly contribute to fluorescence emission by eliminating the molecular fluorophores [133]. By using fluorescence correlation spectroscopy and time-resolved electron paramagnetic resonance spectroscopy

Spindle-like MIL101(Fe) decorated with Bi₂O₃ nanoparticles for enhanced degradation of chlortetracycline under visible-light irradiation

• Chen-chen Hao,
• Fang-yan Chen,
• Kun Bian,
• Yu-bin Tang and
• Wei-long Shi

Beilstein J. Nanotechnol. 2022, 13, 1038–1050, doi:10.3762/bjnano.13.91

• , FEI-quanta 200, Japan Electronics, Japan), transmission electron microscopy (TEM, FEI-Tecnai F20, USA) and high-resolution transmission electron microscopy (HRTEM, JEOL 2100F, Japan). The element valence and chemical composition was investigated using X-ray photoelectron spectroscopy (XPS, Axis ultra

• photocatalytic activity of the Bi2O3/MIL101(Fe) composite. X-ray photoelectron spectroscopy was performed to explore the elemental compositions and the surface chemical states of BOM-20 and the results are presented in Figure 4. The XPS survey spectrum (Figure 4a) indicates the existence of Fe, Bi, O, and C in

• photocatalytic mechanism, the band structure was measured by UV–vis DRS and valence band X-ray photoelectron spectroscopy (VB-XPS). UV–vis DRS spectra and the bandgap (Eg) of Bi2O3 and MIL101(Fe) were discussed in Figure 5a, and the obtained bandgap of Bi2O3 and MIL101(Fe) are 2.78 and 2.75 eV, respectively

Electrocatalytic oxygen reduction activity of AgCoCu oxides on reduced graphene oxide in alkaline media

• Iyyappan Madakannu,
• Indrajit Patil,
• Bhalchandra Kakade and
• Kasibhatta Kumara Ramanatha Datta

Beilstein J. Nanotechnol. 2022, 13, 1020–1029, doi:10.3762/bjnano.13.89

• the trimetallic oxide NPs. The graphene oxide support provides the necessary functional groups for the cohesion of binary and ternary metallic oxide NPs (Figure S2a, Supporting Information File 1). The functional groups and the metal oxygen bonds were determined by FTIR spectroscopy, besides the

• the electrode/electrolyte interface during the ORR, electrochemical impedance spectroscopy was performed. The Nyquist plot was acquired at 5 mV as AC amplitude between 100 kHz and 100 mHz with 0 V as a bias potential (Figure 4d). It is important to note that the prepared electrocatalysts displayed a

• important binding sites, oxidation states, and the elemental composition using X-ray photoelectron spectroscopy. The survey scan of ACC-2 revealed C, O, Cu, Co, and Ag with 54.7, 29.9, 1.0, 8.1, and 6.3 atom % respectively (Figure S10a, Supporting Information File 1). The Ag 3d3/2 and Ag 3d5/2 peaks in the

Numerical study on all-optical modulation characteristics of quantum cascade lasers

• Biao Wei,
• Haijun Zhou,
• Guangxiang Li and
• Bin Tang

Beilstein J. Nanotechnol. 2022, 13, 1011–1019, doi:10.3762/bjnano.13.88

• have been reported, including thermal [8], electrical [9], acousto-optic [10], Faraday rotation effect spectroscopy [11], and all-optical methods [12]. The unipolar characteristics of QCLs provide them with unique advantages for all-optical modulation. All-optical modulation can avoid parasitic effects