Controlled graphene oxide assembly on silver nanocube monolayers for SERS detection: dependence on nanocube packing procedure

• Martina Banchelli,
• Bruno Tiribilli,
• Roberto Pini,
• Luigi Dei,
• Paolo Matteini and
• Gabriella Caminati

Beilstein J. Nanotechnol. 2016, 7, 9–21, doi:10.3762/bjnano.7.2

• molecules to large proteins by means of surface-enhanced Raman spectroscopy (SERS) [8][9]. Furthermore, these arrays offer additional sensing capabilities based on the localized surface plasmon resonance (LSPR) sensitivity to subtle changes in the refractive index of the surrounding molecular environment

• new peak at 412 nm and a broader signal centred at 640 nm; similar spectral features were already reported for metal nanoparticles on dielectric support [31][43]. These experimental and theoretical studies demonstrate that the degeneracy of the localized surface plasmon resonance (LSPR) mode is split

Chemiresistive/SERS dual sensor based on densely packed gold nanoparticles

• Sanda Boca,
• Cosmin Leordean,
• Simion Astilean and
• Cosmin Farcau

Beilstein J. Nanotechnol. 2015, 6, 2498–2503, doi:10.3762/bjnano.6.259

• plasmon resonance, surface-enhanced fluorescence or surface-enhanced Raman spectroscopy (SERS) [2][3]. Among these analytical techniques, SERS is particularly interesting because it can specifically identify the analyte by the unique vibrational signature of chemical groups. Another class of promising

• type of optical sensor must be able to identify and quantify the investigated analyte, ideally by the use of a low-cost chip made by simple manufacturing procedures. Noble metal nanoparticles (NPs) demonstrated repeatedly their effectiveness as transducing elements in optical sensors based on surface

Surface-enhanced Raman scattering by colloidal CdSe nanocrystal submonolayers fabricated by the Langmuir–Blodgett technique

• Alexander G. Milekhin,
• Larisa L. Sveshnikova,
• Tatyana A. Duda,
• Ekaterina E. Rodyakina,
• Volodymyr M. Dzhagan,
• Ovidiu D. Gordan,
• Sergey L. Veber,
• Cameliu Himcinschi,
• Alexander V. Latyshev and
• Dietrich R. T. Zahn

Beilstein J. Nanotechnol. 2015, 6, 2388–2395, doi:10.3762/bjnano.6.245

• deposited NCs was less than one monolayer, as determined by transmission and scanning electron microscopy. SERS by optical phonons in CdSe nanocrystals showed a significant enhancement that depends resonantly on the Au nanocluster and dimer size, and thus on the localized surface plasmon resonance (LSPR

• ; localized surface plasmon resonance; metal nanoclusters; phonons; surface-enhanced Raman spectroscopy; Introduction Since its observation in 1974 [1], surface-enhanced Raman scattering (SERS) has become a powerful technique for detecting and studying ultra-low quantities of organic and biological

• rough metal surfaces. The locally enhanced electromagnetic field induced by the localized surface plasmon resonance (LSPR) in the vicinity of metal surface is responsible for the Raman scattering intensity enhancement, which is proportional to the fourth power of the enhancement of the local field [3][4

Green and energy-efficient methods for the production of metallic nanoparticles

• Mitra Naghdi,
• Mehrdad Taheran,
• Satinder K. Brar,
• M. Verma,
• R. Y. Surampalli and
• J. R. Valero

Beilstein J. Nanotechnol. 2015, 6, 2354–2376, doi:10.3762/bjnano.6.243

• range of 40–200 nm [86]. Also, Wei et al. used CTS in aqueous solution of AgNO3 and HAuCl4 to act as reducing agent and scaffold for the formation of Au and Ag NPs. They used surface plasmon resonance (SPR) analysis to confirm the formation of NPs [29]. In related reports, they used TEM analysis and

Self-organization of gold nanoparticles on silanated surfaces

• Htet H. Kyaw,
• Salim H. Al-Harthi,
• Azzouz Sellai and
• Joydeep Dutta

Beilstein J. Nanotechnol. 2015, 6, 2345–2353, doi:10.3762/bjnano.6.242

• are fundamentally important and also can be applied for designing and modelling of surface plasmon resonance based sensor applications. Keywords: 3-aminopropyletriethoxysilane; electrostatic interaction; functionalization; gold nanoparticles; self-assembled monolayer; self-organization; Introduction

• structures [8]. AuNPs have been studied intensively for a wide range of applications such as catalysis [9], biosensing [10], colorimetric sensing [11], optical sensing (surface plasmon resonance (SPR) and surface-enhanced Raman scattering (SERS)) [12][13], photonics [13][14], photovoltaic devices [15] and

• photothermal therapy [16]. AuNPs exhibit well-defined optical properties such as surface plasmon resonance, which depends on the size and shape of nanoparticles, interparticle distance and the effective refractive index of the surrounding medium [17]. Different techniques have been used to assemble AuNPs on

Orthogonal chemical functionalization of patterned gold on silica surfaces

• Francisco Palazon,
• Didier Léonard,
• Thierry Le Mogne,
• Francesca Zuttion,
• Céline Chevalier,
• Magali Phaner-Goutorbe,
• Éliane Souteyrand,
• Yann Chevolot and
• Jean-Pierre Cloarec

Beilstein J. Nanotechnol. 2015, 6, 2272–2277, doi:10.3762/bjnano.6.233

• with the development of localized surface plasmon resonance (LSPR) biosensors, this topic has become a major focus [2][3][4][5][6][7][8]. Indeed, LSPR transduction is expected to yield enhanced signal as compared to classical SPR transduction. However, the enhancement of the LSPR limit of detection is

Au nanoparticle-based sensor for apomorphine detection in plasma

• Chiara Zanchi,
• Andrea Lucotti,
• Matteo Tommasini,
• Sebastiano Trusso,
• Ugo de Grazia,
• Emilio Ciusani and
• Paolo M. Ossi

Beilstein J. Nanotechnol. 2015, 6, 2224–2232, doi:10.3762/bjnano.6.228

•  1A show typical average sizes of such inter-island channels. SERS hinges on the strong interaction between noble metal NPs and visible light through the resonant collective excitation of NP conduction electrons. The resulting surface plasmon resonance peak [28] displays a maximum at about 780 nm

Conformational switching of ethano-bridged Cu,H₂-bis-porphyrin induced by aromatic amines

• Simona Bettini,
• Emanuela Maglie,
• Rosanna Pagano,
• Victor Borovkov,
• Yoshihisa Inoue,
• Ludovico Valli and
• Gabriele Giancane

Beilstein J. Nanotechnol. 2015, 6, 2154–2160, doi:10.3762/bjnano.6.221

• bis-porphyrin derivative. The Langmuir–Schaefer technique has been used to transfer the floating bis-porphyrin film (when using pure water as a subphase) to a surface plasmon resonance (SPR) substrate and the resulting device was able to detect the presence of aniline at concentrations as low as 1 nM

• -porphyrin Langmuir film was transferred onto an SPR substrate and the host–guest interaction with amines in aqueous solution was investigated. Interestingly, the preliminary sensor tests evidenced that a significant angle shift of the surface plasmon resonance was recorded when only 1 nM of aniline was

• in aqueous solution. The high selectivity of the SPR sensing device has been verified by checking the spectral response of the active layer towards other analytes dissolved in the aqueous solutions. Keywords: aromatic amines; bis-porphyrin; conformational switching; Langmuir film; surface plasmon

Possibilities and limitations of advanced transmission electron microscopy for carbon-based nanomaterials

• Xiaoxing Ke,
• Carla Bittencourt and
• Gustaaf Van Tendeloo

Beilstein J. Nanotechnol. 2015, 6, 1541–1557, doi:10.3762/bjnano.6.158

• defect, as imaged by STEM, can act as an atomic antenna in the frequency range of petahertz, and thus enhance the surface plasmon resonance locally. However, more recently, Nelson et al., after extracting the dielectric function from STEM–EELS spectra and comparing it with the calculated results [103

Formation of substrate-based gold nanocage chains through dealloying with nitric acid

• Ziren Yan,
• Ying Wu and
• Junwei Di

Beilstein J. Nanotechnol. 2015, 6, 1362–1368, doi:10.3762/bjnano.6.140

• to their solid counterparts because of the high surface area, low density, and near-infrared localized surface plasmon resonance (LSPR). All these make Au NC an attractive material for various applications in optical [4][5] and electrochemical sensing [6], immunoassay [7], drug release [8], surface

• solution on a copper grid. X-ray diffraction (XRD) analysis was performed by X’Pert-Pro MPD (Panalytical, Holland). The localized surface plasmon resonance (LSPR) spectra of nanoparticles were measured with a Shimadzu UV–vis–NIR 3600 Spectrophotometer against a bare ITO slide as the reference. SEM images

Improved optical limiting performance of laser-ablation-generated metal nanoparticles due to silica-microsphere-induced local field enhancement

• Zheren Du,
• Lianwei Chen,
• Tsung-Sheng Kao,
• Mengxue Wu and
• Minghui Hong

Beilstein J. Nanotechnol. 2015, 6, 1199–1204, doi:10.3762/bjnano.6.122

• nanoparticles exhibit localized surface plasmon resonance (LSPR), which is another possible way for local field enhancement to influence the light absorption and scattering [25]. Conclusion In this paper, we have studied that LAL is a promising technique to generate nanoparticles for various target materials

Patterning technique for gold nanoparticles on substrates using a focused electron beam

• Takahiro Noriki,
• Shogo Abe,
• Kotaro Kajikawa and
• Masayuki Shimojo

Beilstein J. Nanotechnol. 2015, 6, 1010–1015, doi:10.3762/bjnano.6.104

• plasmon resonance (LSPR) are attracting attention for future optical transmission, sensor, and data processing devices. The development of these LSPR-based structures would lead to a reduction in the size of optical circuits and devices [1][2]. Light energy can be propagated through nanometer-sized wires

• substrate. This technique could contribute to the fabrication of plasmonic devices and other applications that require the controlled placement of gold nanoparticles on substrates. Keywords: electron beam; gold; nanoparticle array; Introduction Plasmonic waveguides and circuits utilizing localized surface

Protein corona – from molecular adsorption to physiological complexity

• Lennart Treuel,
• Dominic Docter,
• Michael Maskos and
• Roland H. Stauber

Beilstein J. Nanotechnol. 2015, 6, 857–873, doi:10.3762/bjnano.6.88

• adsorption such as isothermal titration calorimetry (ITC) [82][83], and surface plasmon resonance (SPR) [22][84]. Moreover, techniques based on the size of proteins and protein–NP complexes have been utilized such as size-exclusion chromatography (SEC) [85][86][87][88][89][90] or one- and two-dimensional

Combination of surface- and interference-enhanced Raman scattering by CuS nanocrystals on nanopatterned Au structures

• Alexander G. Milekhin,
• Nikolay A. Yeryukov,
• Larisa L. Sveshnikova,
• Tatyana A. Duda,
• Ekaterina E. Rodyakina,
• Victor A. Gridchin,
• Evgeniya S. Sheremet and
• Dietrich R. T. Zahn

Beilstein J. Nanotechnol. 2015, 6, 749–754, doi:10.3762/bjnano.6.77

• surface plasmon resonance energy enabling resonance SERS in absorbates deposited on the arrays [13][14][15][16][17]. Moreover, CuS NCs are resistant against intense laser excitation even under resonant conditions. This is important for micro-Raman experiments with the NCs on nanostructured Au arrays under

Electromagnetic enhancement of ordered silver nanorod arrays evaluated by discrete dipole approximation

• Guoke Wei,
• Jinliang Wang and
• Yu Chen

Beilstein J. Nanotechnol. 2015, 6, 686–696, doi:10.3762/bjnano.6.69

• shows a similar trend against AR as EFavg does. Effect of the excitation wavelength Since the SERS effect is a near-field phenomenon and related to the localized surface plasmon resonance (LSPR) of the nanostructures, it is expected to exhibit a behavior that depends on the excitation wavelength. Here

• the vertical AgNR arrays. It has been revealed that different modes of surface plasmon resonance can only be excited by certain angles of incidence, leading to different near-field enhancements [23][33]. Effect of incident polarization Figure 9a shows the polarization dependence of EFavg from S42 AgNR

Influence of gold, silver and gold–silver alloy nanoparticles on germ cell function and embryo development

• Ulrike Taylor,
• Daniela Tiedemann,
• Christoph Rehbock,
• Wilfried A. Kues,
• Stephan Barcikowski and
• Detlef Rath

Beilstein J. Nanotechnol. 2015, 6, 651–664, doi:10.3762/bjnano.6.66

• nanotoxicology on reproductive cells provides an ideal tool. Schematic representation of experiments conducted within the collaboration project REPROTOX. (A) Exemplary AuAg colloids with different molar fractions. (B) Correlation of gold molar fraction with the maximum surface plasmon resonance extinction peak

Synergic combination of the sol–gel method with dip coating for plasmonic devices

• Cristiana Figus,
• Maddalena Patrini,
• Francesco Floris,
• Lucia Fornasari,
• Paola Pellacani,
• Gerardo Marchesini,
• Andrea Valsesia,
• Flavia Artizzu,
• Daniela Marongiu,
• Michele Saba,
• Franco Marabelli,
• Andrea Mura,
• Giovanni Bongiovanni and
• Francesco Quochi

Beilstein J. Nanotechnol. 2015, 6, 500–507, doi:10.3762/bjnano.6.52

• an extended time and inducing a suitable reduction of the regeneration time of the chip. Keywords: biosensors; nanodevices; plasmonics; sol–gel; thin films; Introduction Plasmonic nanostructures have gained increasing attention for their surface plasmon resonance (SPR)-related properties, which can

Hollow plasmonic antennas for broadband SERS spectroscopy

• Gabriele C. Messina,
• Mario Malerba,
• Pierfrancesco Zilio,
• Ermanno Miele,
• Michele Dipalo,
• Lorenzo Ferrara and
• Francesco De Angelis

Beilstein J. Nanotechnol. 2015, 6, 492–498, doi:10.3762/bjnano.6.50

• based on surface enhanced Raman scattering (SERS) enhancement [1][2][3], fluorescence [4][5], the surface plasmon resonance effect [6][7], mapping and imaging [8][9][10], to nanotechnology, with several works related to nanolithography [11][12], nanofocusing [13][14], nanolasers [15][16], waveguides [17

Palladium nanoparticles anchored to anatase TiO₂ for enhanced surface plasmon resonance-stimulated, visible-light-driven photocatalytic activity

• Kah Hon Leong,
• Hong Ye Chu,
• Shaliza Ibrahim and
• Pichiah Saravanan

Beilstein J. Nanotechnol. 2015, 6, 428–437, doi:10.3762/bjnano.6.43

• with controlled Pd NPs size ranging between 17 and 29 nm onto the surface of TiO2. Thus, it gives the characteristic for Pd NPs to absorb light in the visible region obtained through localized surface plasmon resonance (LSPRs). Apparently, the photocatalytic activity of the prepared photocatalysts was

• most promising strategy to defeat the limitations of TiO2. This is due to the characteristics of noble metals, which can drastically enhance the absorption of visible light through localized surface plasmon resonance effects (LSPRs) [23][24]. The LSPR absorption in noble metal NPs arise from the

• efficiency was achieved by depositing Pd NPs on the surface of TiO2. This immense progress was attributed to the localized surface plasmon resonance that enables Pd NPs to absorb light in the visible region. This is attributed to an optical excitation that produces a coherent oscillation of free electrons in

Influence of size, shape and core–shell interface on surface plasmon resonance in Ag and Ag@MgO nanoparticle films deposited on Si/SiO_x

• Sergio D’Addato,
• Daniele Pinotti,
• Maria Chiara Spadaro,
• Guido Paolicelli,
• Vincenzo Grillo,
• Sergio Valeri,
• Luca Pasquali,
• Luca Bergamini and
• Stefano Corni

Beilstein J. Nanotechnol. 2015, 6, 404–413, doi:10.3762/bjnano.6.40

• atmosphere gave rise to formation of a MgO shell matrix surrounding the Ag NPs. The behaviour of the surface plasmon resonance (SPR) excitation in surface differential reflectivity (SDR) spectra with p-polarised light was investigated for bare Ag and Ag@MgO NPs. It was shown that the presence of MgO around

• ; surface differential reflectivity; surface plasmon resonance; Introduction Nanoparticles (NPs) deposited on surfaces constitute a vast and important research field in material science having many applications in magnetic recording [1][2], catalysis [3], and photovoltaics [4][5][6][7][8][9]. For instance

• , it was found that Au NPs [5] and Ag NPs [6] deposited on thin film- and wafer-based Si solar cells can enhance their photon absorption due to the occurrence of surface plasmon resonance (SPR), which serves to scatter the incident radiation in the UV–vis region and to increase the light trapping

Green preparation and spectroscopic characterization of plasmonic silver nanoparticles using fruits as reducing agents

• Jes Ærøe Hyllested,
• Marta Espina Palanco,
• Nicolai Hagen,
• Klaus Bo Mogensen and
• Katrin Kneipp

Beilstein J. Nanotechnol. 2015, 6, 293–299, doi:10.3762/bjnano.6.27

• relatively simple way by using extracts of oranges and pineapples as reducing agents. Size and shape of the particles depend mainly on the kind of fruit used in the chemical preparation process. The UV–vis absorption spectrum displays the surface plasmon resonance and also features in the UV, which can be

Tunable light filtering by a Bragg mirror/heavily doped semiconducting nanocrystal composite

• Ilka Kriegel and
• Francesco Scotognella

Beilstein J. Nanotechnol. 2015, 6, 193–200, doi:10.3762/bjnano.6.18

• : active optical component; electronic band gap nanostructure; localized surface plasmon resonance; photonic crystal; Introduction Optical filters are fundamental components employed in almost all optical setups and devices. For example, they play a very important role in microfluidic devices, which are

The fate of a designed protein corona on nanoparticles in vitro and in vivo

• Denise Bargheer,
• Julius Nielsen,
• Gabriella Gébel,
• Markus Heine,
• Sunhild C. Salmen,
• Roland Stauber,
• Horst Weller,
• Joerg Heeren and
• Peter Nielsen

Beilstein J. Nanotechnol. 2015, 6, 36–46, doi:10.3762/bjnano.6.5

• experimental setups. Various techniques such as ITC (isothermal titration calorimetry), SPR (surface plasmon resonance), DCS (differential centrifugal sedimentation), QCM (quartz crystal microbalance), and FCS (fluorescence correlation spectroscopy) have been used to monitor the affinities of proteins for

Exploring plasmonic coupling in hole-cap arrays

• Thomas M. Schmidt,
• Maj Frederiksen,
• Vladimir Bochenkov and
• Duncan S. Sutherland

Beilstein J. Nanotechnol. 2015, 6, 1–10, doi:10.3762/bjnano.6.1

• compared to separated arrays of holes or caps. Optical spectroscopy and FDTD simulations reveal strong coupling between the gold caps and both Bloch Wave-surface plasmon polariton (BW-SPP) modes and localized surface plasmon resonance (LSPR)-type resonances in hole arrays when they are in close proximity

• . The interesting and complex coupling between caps and hole arrays reveals the details of the field distribution for these simple to fabricate structures. Keywords: caps; colloidal lithography; hybridization; localized surface plasmon resonance; near field; SRO hole arrays; Introduction The

Proinflammatory and cytotoxic response to nanoparticles in precision-cut lung slices

• Stephanie Hirn,
• Nadine Haberl,
• Kateryna Loza,
• Matthias Epple,
• Wolfgang G. Kreyling,
• Barbara Rothen-Rutishauser,
• Markus Rehberg and
• Fritz Krombach

Beilstein J. Nanotechnol. 2014, 5, 2440–2449, doi:10.3762/bjnano.5.253

• muscle of living mice [44]. This technique allowed us to record images of Ag-NPs and lung tissue without additional labelling, since Ag-NPs exhibit strong two-photon-induced photoluminescence and enhanced THG signals through surface plasmon resonance [45][46]. As shown by multiphoton microscopy, the Ag