Two-step single-reactor synthesis of oleic acid- or undecylenic acid-stabilized magnetic nanoparticles by thermal decomposition

• Mykhailo Nahorniak,
• Pamela Pasetto,
• Jean-Marc Greneche,
• Volodymyr Samaryk,
• Sandy Auguste,
• Anthony Rousseau,
• Nataliya Nosova and
• Serhii Varvarenko

Beilstein J. Nanotechnol. 2023, 14, 11–22, doi:10.3762/bjnano.14.2

• . Keywords: Fe(III) acetylacetonate; iron oxide nanoparticles; maghemite; magnetic nanoparticles; magnetite; thermal decomposition synthesis; Introduction Magnetic nanoparticles are increasingly being used in various fields thanks to the recent progress in their controlled synthesis and knowledge of their

• makes them ideal candidates for magnetic-assisted targeted drug delivery [12]. Nanoscale magnetite can be obtained through well-known synthesis routes, such as hydrothermal synthesis, thermal decomposition, or co-precipitation [10][11]. Each of these synthetic approaches has certain advantages and

• disadvantages. One of the essential issues in many biomedical applications is the synthesis of magnetic nanoparticles with uniform size, chemical composition, and superparamagnetic properties. These requirements can be met by applying thermal decomposition, which is based on the decay of organic iron salts with

Atmospheric water harvesting using functionalized carbon nanocones

• Fernanda R. Leivas and
• Marcia C. Barbosa

Beilstein J. Nanotechnol. 2023, 14, 1–10, doi:10.3762/bjnano.14.1

• illustrating the two types of thermal control used in the simulation. The red area represents region 1 with a temperature dynamically changing between 800 and 300 K while the blue area is region 2 with a fixed temperature of 300 K. Carbon nanocone with 26 Å length, 8.2 Å tip diameter, and 17 Å of base diameter

Electrical and optical enhancement of ITO/Mo bilayer thin films via laser annealing

• Abdelbaki Hacini,
• Ahmad Hadi Ali,
• Nurul Nadia Adnan and
• Nafarizal Nayan

Beilstein J. Nanotechnol. 2022, 13, 1589–1595, doi:10.3762/bjnano.13.133

• adherence to the substrate, very high thermal stability (up to 600 °C), and high electrical conductivity [14]. Over the last decades, the development of solar cells has grown dramatically. The cells have become larger, thinner, and lighter. This increases the electrical resistivity, which is undesirable

Induced electric conductivity in organic polymers

• Konstantin Y. Arutyunov,
• Anatoli S. Gurski,
• Vladimir V. Artemov,
• Alexander L. Vasiliev,
• Azat R. Yusupov,
• Danfis D. Karamov and
• Alexei N. Lachinov

Beilstein J. Nanotechnol. 2022, 13, 1551–1557, doi:10.3762/bjnano.13.128

• ]. The effect is interpreted as stimulation of metallic state [2]. Poly(diphenylene phthalide) (PDP) was chosen as the object of study being a representative electro-active polymer demonstrating induced electric conductivity. PDP is a carbocyclic polymer with high chemical and thermal stability

• methods [8][9]. Quantum chemical studies of PDP [10] have shown that its molecular structure is unstable with regard to interaction with an excess (thermal) electron and can result in a transition to a metastable state. However, in that state, e.g. induced by external electric field, the system is

• of thin-film lead electrodes with thicknesses from 50 nm to 200 nm was carried out by thermal evaporation in vacuum. The critical temperature of bulk lead is Тс(Pb3D) = 7.2 K. However, in the form of a thin film, the critical temperature of a superconductor can differ significantly from the tabulated

Photoelectrochemical water oxidation over TiO₂ nanotubes modified with MoS₂ and g-C₃N₄

• Phuong Hoang Nguyen,
• Thi Minh Cao,
• Tho Truong Nguyen,
• Hien Duy Tong and
• Viet Van Pham

Beilstein J. Nanotechnol. 2022, 13, 1541–1550, doi:10.3762/bjnano.13.127

• chemical, thermal, and charge transport properties, which can shift the light absorption of TiO2 to the visible region [29][30][31][32]. An emerging new material in optoelectronics is g-C3N4 (bandgap of 2.65–2.7 eV) because it has an appropriate band structure with suitable energy levels regarding TiO2

A TiO₂@MWCNTs nanocomposite photoanode for solar-driven water splitting

• Anh Quynh Huu Le,
• Ngoc Nhu Thi Nguyen,
• Hai Duy Tran,
• Van-Huy Nguyen and
• Le-Hai Tran

Beilstein J. Nanotechnol. 2022, 13, 1520–1530, doi:10.3762/bjnano.13.125

• reagent grade. Preparation of photocatalyst and photoelectrode TiO2 powders TiO2 powders were simply prepared from a violent hydrolysis reaction of TiCl4 vapor in humid air. Precipitated fine TiO2 particles were collected before thermal treatment at 350 °C for 60 min. TiO2@MWCNTs nanocomposite First, 1.0

In search of cytotoxic selectivity on cancer cells with biogenically synthesized Ag/AgCl nanoparticles

• Mitzi J. Ramírez-Hernández,
• Mario Valera-Zaragoza,
• Omar Viñas-Bravo,
• Ariana A. Huerta-Heredia,
• Miguel A. Peña-Rico,
• Erick A. Juarez-Arellano,
• David Paniagua-Vega,
• Eduardo Ramírez-Vargas and
• Saúl Sánchez-Valdes

Beilstein J. Nanotechnol. 2022, 13, 1505–1519, doi:10.3762/bjnano.13.124

• sizes. In the micrographs in Figure 6, it can be seen that the nanoparticles are embedded in a disordered system, with very low electron density. This system could be made of organic molecules that act as capping materials for nanoparticles, as described in the literature [24][40]. Thermal behavior The

• Figure 7, it is remarkable that the reaction products have a higher thermal stability than that of the pineapple peel extract. This behavior can be attributed to two complementary situations. The first is a change in the chemical structure of the organic compounds used in the formation and capping of Ag

• /AgCl nanoparticles as observed by FTIR spectroscopy (Figure 5). The reducing species are oxidized and as a consequence have greater thermal stability. Hence, the higher temperature-shifted TGA curves show the thermal behavior of the modified metabolites during chemical reaction. The results are also

Hydroxyapatite–bioglass nanocomposites: Structural, mechanical, and biological aspects

• Olga Shikimaka,
• Mihaela Bivol,
• Bogdan A. Sava,
• Marius Dumitru,
• Christu Tardei,
• Beatrice G. Sbarcea,
• Daria Grabco,
• Constantin Pyrtsac,
• Daria Topal,
• Andrian Prisacaru,
• Vitalie Cobzac and
• Viorel Nacu

Beilstein J. Nanotechnol. 2022, 13, 1490–1504, doi:10.3762/bjnano.13.123

• HA inhibits the thermal decomposition of HA and significantly enhances bending strength and fracture toughness [30]. It was shown as well that B2O3 in the phosphate glass composition increases its hardness and fracture toughness [31]. The doping of bioglasses with Zn and Ce has two effects. On the

• glass preparation comprised the following steps: (i) Preparation of raw materials, that is, the reagents were introduced in H3PO4 solution under continuous stirring. (ii) Drying of the mixture on an electrical heating plate at 130–140 °C. (iii) Thermal treatment of mixture, that is, the dried mixture

• (Figure 3 f), due to the non-uniform thermal expansion during the sintering at higher temperature. Vickers microhardness and deformation peculiarities Figure 5 shows the microhardness (H) as function of the load (P) applied to the Vickers indenter for HAP- and HAG-based composites. The obtained results

Structural studies and selected physical investigations of LiCoO₂ obtained by combustion synthesis

• Monika Michalska,
• Paweł Ławniczak,
• Tomasz Strachowski,
• Adam Ostrowski and
• Waldemar Bednarski

Beilstein J. Nanotechnol. 2022, 13, 1473–1482, doi:10.3762/bjnano.13.121

• [42], thermal decomposition [43], or microwave synthesis [44][45][46][47] have been used. Wet chemical synthesis allows for molecular-level mixing of the starting components, resulting in a very homogeneous product comprising fine particles and a large surface area. The stoichiometry of the product

• analysis, (ii) morphology (size and distribution of grains) by using SEM, (iii) specific surface area (SSA) by carrying out Brunauer–Emmett–Teller (BET) measurements, (iv) oxidation states of metals by measuring electron paramagnetic resonance (EPR), and (v) electrical parameters (thermal dependencies of

• increasing temperature as the size of the crystallites increases. Electrical studies showed that conductivity strongly depends on the synthesis temperature. The samples obtained at the highest temperature had lower (more than one magnitude) conductivity. Strong thermal hysteresis is observed in all samples

Facile preparation of Au- and BODIPY-grafted lipid nanoparticles for synergized photothermal therapy

• Yuran Wang,
• Xudong Li,
• Haijun Chen and
• Yu Gao

Beilstein J. Nanotechnol. 2022, 13, 1432–1444, doi:10.3762/bjnano.13.118

• changes of water, BDP, Au-LNPs, and AB-LNPs with a BDP concentration of 100 μM and a Au concentration of 100 μM with laser irradiation (680 nm, 0.5 W/cm2) were also recorded for 10 min. The temperature of the samples for photothermal conversion measurements was recorded by an infrared thermal camera

• ) were consistent in each cycle, indicating the excellent photothermal stability of AB-LNPs. Thermal images of water, BDP, Au-LNPs, and AB-LNPs under laser irradiation (680 nm, 0.5 W/cm2) were shown in Figure 2e, which also demonstrated the best photothermal effects of AB-LNPs. The results proved that

• platform to deliver both AuNPs and BODIPY dye for synergized PTT. To our knowledge, this is the first report about using LNPs as carriers for the co-delivery of gold nanoclusters and BODIPY, the first investigation of the synergistic thermal effects of gold nanoclusters and BODIPY, and the first

Recent trends in Bi-based nanomaterials: challenges, fabrication, enhancement techniques, and environmental applications

• Vishal Dutta,
• Ankush Chauhan,
• Ritesh Verma,
• C. Gopalkrishnan and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 1316–1336, doi:10.3762/bjnano.13.109

• also reported. The Fenelon group successfully fabricated SnO2 and Bi2S3–Bi25 composites via a facile hydrothermal technique followed by thermal breakdown [27]. The photocatalytic performance of the fabricated ternary composite photocatalyst was 2.75 times higher than that of pristine Bi2S3 for the

Enhanced electronic transport properties of Te roll-like nanostructures

• E. R. Viana,
• N. Cifuentes and
• J. C. González

Beilstein J. Nanotechnol. 2022, 13, 1284–1291, doi:10.3762/bjnano.13.106

• cm2/Vs at 5 K. The thermal ionization of shallow acceptors, with small ionization energy between 2 and 4 meV, leads to free-hole conduction at high temperatures. The free-hole mobility follows a negative power-law temperature behavior, with an exponent between −1.28 and −1.42, indicating strong phonon

Studies of probe tip materials by atomic force microscopy: a review

• Ke Xu and
• Yuzhe Liu

Beilstein J. Nanotechnol. 2022, 13, 1256–1267, doi:10.3762/bjnano.13.104

• the thermal noise method when prepared in the chamber, after which FC is obtained on the substrate to measure the deflection sensitivity, and the position of the loading point is measured by optical microscopy when the sphere is attached. The process of calibrating the kTL into the manifold is shown

Role of titanium and organic precursors in molecular layer deposition of “titanicone” hybrid materials

• Arbresha Muriqi and
• Michael Nolan

Beilstein J. Nanotechnol. 2022, 13, 1240–1255, doi:10.3762/bjnano.13.103

• thermal stability for GL-based titanicones as well [30]. Ti(DMA)4 is another Ti-based inorganic precursor that was investigated as an alternative to TiCl4 as the titanium precursor. Ti(DMA)4 was combined with EG and GL to deposit titanicone films in a temperature range from 80 °C to 160 °C on an Si

• substrate with 100 nm thermal oxide. In situ ellipsometry revealed for EG-based titanicones that the growth initiates but terminates after only 5 to 10 cycles, while for GL-based titanicones the growth proceeds and films have a GPC of 0.9 Å/cycle to 0.2 Å/cycle as the temperature increases. This is due to

• widely used in ALD for the deposition of TiO2 and TiN films by thermal and plasma-enhanced processes [35][36]. As described above, TiCl4 and Ti(DMA)4 were successfully employed in MLD of titanicone films [30][33]. While TiCl4 is a small halide molecule that has Ti–Cl bonds, Ti(DMA)4 is a bulkier molecule

Rapid fabrication of MgO@g-C₃N₄ heterojunctions for photocatalytic nitric oxide removal

• Minh-Thuan Pham,
• Duyen P. H. Tran,
• Xuan-Thanh Bui and
• Sheng-Jie You

Beilstein J. Nanotechnol. 2022, 13, 1141–1154, doi:10.3762/bjnano.13.96

• are different approaches to mitigate NO pollution, including catalyst/non-catalyst [4], oxidation [5], bioprocesses [6], adsorption [7], absorption [8], and non-thermal plasma technologies [9]. Photocatalytic oxidation is considered a promising approach due to its ability to degrade various air

A cantilever-based, ultrahigh-vacuum, low-temperature scanning probe instrument for multidimensional scanning force microscopy

• Hao Liu,
• Zuned Ahmed,
• Sasa Vranjkovic,
• Manfred Parschau,
• Andrada-Oana Mandru and
• Hans J. Hug

Beilstein J. Nanotechnol. 2022, 13, 1120–1140, doi:10.3762/bjnano.13.95

• nitrogen (LN2) container and an additional heat shield, which is passively cooled by the evaporating He gases of the LHe tank (Figure 2a). The microscope is surrounded by two shields (a Au-plated oxygen-free high thermal conductivity (OFHC) copper LHe shield and an Al LN2 shield) of which there is an inner

• minimized and the design has to be kept as symmetrical as possible to reduce thermal drift; third, the design must allow for a precise adjustment of the pressure of the sliders towards the sapphire rails for the xy-directions. All these conditions can be fulfilled with a concentric design, where the shear

• stacks and sliders with temperature are at least partially compensated by those of the scan piezo. Together with the highly symmetric design along the x and y axes, this further reduces the thermal drift. Moreover, any mechanical excitation of the instrument, for example, from floor or acoustic

Green synthesis of zinc oxide nanoparticles toward highly efficient photocatalysis and antibacterial application

• Vo Thi Thu Nhu,
• Nguyen Duy Dat,
• Le-Minh Tam and
• Nguyen Hoang Phuong

Beilstein J. Nanotechnol. 2022, 13, 1108–1119, doi:10.3762/bjnano.13.94

• microscopy (HR-TEM) on a JEOL JEM-2100. The thermal decomposition of zinc resinate to form ZnO NPs were studied by thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) curves using thermal gravimetric analysis (DSC131, LABSYS TG/DSC1600, TMv), by heating up to 1000 °C at a heating rate

Recent advances in green carbon dots (2015–2022): synthesis, metal ion sensing, and biological applications

• Aisha Kanwal,
• Naheed Bibi,
• Sajjad Hyder,
• Arif Muhammad,
• Hao Ren,
• Jiangtao Liu and
• Zhongli Lei

Beilstein J. Nanotechnol. 2022, 13, 1068–1107, doi:10.3762/bjnano.13.93

• emitting CDs [48]. A new type of fluorescent CDs from the flowers of Borassus flabellifer (male tree) through a green thermal pyrolysis method without adding any chemicals was synthesized [59]. A high QY of up to 13.97% was obtained at an optimized temperature of 300 °C. Hoan et al. used lemon juice to

Spindle-like MIL101(Fe) decorated with Bi₂O₃ nanoparticles for enhanced degradation of chlortetracycline under visible-light irradiation

• Chen-chen Hao,
• Fang-yan Chen,
• Kun Bian,
• Yu-bin Tang and
• Wei-long Shi

Beilstein J. Nanotechnol. 2022, 13, 1038–1050, doi:10.3762/bjnano.13.91

• cavities, and excellent thermal stability [20][21]. These advantages make it appalling to adsorption [22], gaseous capture/separation [23], sensing [24], and drug release applications [25]. Moreover, some MOFs can be excited under UV or visible light and exhibit light harvesting properties due to ligand

Analytical and numerical design of a hybrid Fabry–Perot plano-concave microcavity for hexagonal boron nitride

• Felipe Ortiz-Huerta and
• Karina Garay-Palmett

Beilstein J. Nanotechnol. 2022, 13, 1030–1037, doi:10.3762/bjnano.13.90

• . Afterwards an 80 nm silver layer could be added, by thermal evaporative deposition, on top of the concave shape polymer to ensure a high reflectivity inside our microcavity. When designing the concave shape polymer a small rectangular aperture at its edge must be taken into account in the fabrication step

Numerical study on all-optical modulation characteristics of quantum cascade lasers

• Biao Wei,
• Haijun Zhou,
• Guangxiang Li and
• Bin Tang

Beilstein J. Nanotechnol. 2022, 13, 1011–1019, doi:10.3762/bjnano.13.88

• have been reported, including thermal [8], electrical [9], acousto-optic [10], Faraday rotation effect spectroscopy [11], and all-optical methods [12]. The unipolar characteristics of QCLs provide them with unique advantages for all-optical modulation. All-optical modulation can avoid parasitic effects

Influence of water contamination on the sputtering of silicon with low-energy argon ions investigated by molecular dynamics simulations

• Grégoire R. N. Defoort-Levkov,
• Alan Bahm and
• Patrick Philipp

Beilstein J. Nanotechnol. 2022, 13, 986–1003, doi:10.3762/bjnano.13.86

• potential well in the order of a few meV, which makes it rather difficult for the fit to precisely match the well. However, this is not problematic as the potential well is in the order of magnitude of thermal vibrations and its impact on the outcome of the simulations is small. The fits match the repulsive

• for more details). The 0.94 < µ < 1 interval describes a region where no defects are present. Changes in µ are due to variations in bond length coming from thermal vibrations around the equilibrium bond length. This region is crystalline. The 0.89 < µ < 0.94 interval describes regions that contain

Design of a biomimetic, small-scale artificial leaf surface for the study of environmental interactions

• Miriam Anna Huth,
• Axel Huth,
• Lukas Schreiber and
• Kerstin Koch

Beilstein J. Nanotechnol. 2022, 13, 944–957, doi:10.3762/bjnano.13.83

• composition play significant roles. Here, the ability of self-assembly of wax after isolation from the leaves was used to develop a small-scale wax-coated artificial leaf surface with the chemical composition and wettability of wheat (Triticum aestivum) leaves. By thermal evaporation of extracted plant waxes

• prerequisite for the applicability of the artificial surface as bio-inspired leaf surface, it was defined that the artificial surface needs to have a homogeneous coating and uniform wettability. Previous recrystallization studies have shown that a homogeneous coating can be produced by thermal evaporation [40

• comparison of the native wax with the wax recrystallized after thermal evaporation, we could show that the wax still had the same chemical composition as the wax on the native leaves. In the wax precipitate on glass, the same substances were detected in the same amounts as in the wax that was vaporized

Comparing the performance of single and multifrequency Kelvin probe force microscopy techniques in air and water

• Jason I. Kilpatrick,
• Emrullah Kargin and
• Brian J. Rodriguez

Beilstein J. Nanotechnol. 2022, 13, 922–943, doi:10.3762/bjnano.13.82

• forces in KPFM is generally expressed as the minimum detectable CPD [53], and is directly limited by the geometry of the interaction, thermal noise of the cantilever, and the detection noise limits of the AFM [36][54]. Cantilevers have a number of eigenmodes, ωn, where there is a mechanical enhancement

• cantilever. Under small amplitude conditions the tip can be positioned very close to the surface and as such there is an advantage in increasing the spatial resolution. The trade-off here is that the SNR will be small as the mechanical amplitude approaches the thermal noise limits of the cantilever. In

Bioselectivity of silk protein-based materials and their bio-inspired applications

• Hendrik Bargel,
• Vanessa T. Trossmann,
• Christoph Sommer and
• Thomas Scheibel

Beilstein J. Nanotechnol. 2022, 13, 902–921, doi:10.3762/bjnano.13.81

• coatings through fluorous media-assisted thermal treatment of stable, hydrophilic protein films [75]. One prominent natural route to prevent the colonization and infection with microbes on cells, tissues, and material surfaces is to block adhesion of bacteria and inhibit attachment to host cells. Microbial