Imaging the surface potential at the steps on the rutile TiO₂(110) surface by Kelvin probe force microscopy

• Masato Miyazaki,
• Huan Fei Wen,
• Quanzhen Zhang,
• Yuuki Adachi,
• Jan Brndiar,
• Ivan Štich,
• Yan Jun Li and
• Yasuhiro Sugawara

Beilstein J. Nanotechnol. 2019, 10, 1228–1236, doi:10.3762/bjnano.10.122

• function between the tip and the sample, on the basis of atomic force microscopy (AFM) [39][40]. Since the CPD strongly depends on the charge distribution on the surface, KPFM allows us to investigate the electrostatic properties of surfaces [41][42][43]. In this study, we measured the CPD around the steps

• out with a custom-built ultrahigh-vacuum noncontact atomic force microscopy (NC-AFM) system operated at a temperature of 78 K with a base pressure below 4 × 10−11 mbar. The NC-AFM system was operated in the frequency-modulation mode [44] with a constant cantilever oscillation amplitude (5 Å). The

Tailoring the stability/aggregation of one-dimensional TiO₂(B)/titanate nanowires using surfactants

• Atiđa Selmani,
• Johannes Lützenkirchen,
• Kristina Kučanda,
• Dario Dabić,
• Engelbert Redel,
• Ida Delač Marion,
• Damir Kralj,
• Darija Domazet Jurašin and
• Maja Dutour Sikirić

Beilstein J. Nanotechnol. 2019, 10, 1024–1037, doi:10.3762/bjnano.10.103

• ) micrographs revealed that the synthesized TNWs have a distinct, straight, wire-like morphology (Figure 1a). The analysis of the micrographs showed that the length of the TNWs is in the range from 900 to 2000 nm, while the measured diameter ranged from 25 to 250 nm. Atomic force microscopy (AFM) revealed the

• TNW surface and 12-2-12 due to the two positively charged polar heads of 12-2-12. Micrographs of synthesized TNWs taken by a) high-resolution scanning electron microscopy and b) atomic force microscopy. Variation of zeta potential (ζ) with pH of TNWs in 10−3 mol dm−3 NaBr aqueous solution. γ(TNW) = 1

Direct growth of few-layer graphene on AlN-based resonators for high-sensitivity gravimetric biosensors

• Jimena Olivares,
• Teona Mirea,
• Lorena Gordillo-Dagallier,
• Bruno Marco,
• José Miguel Escolano,
• Marta Clement and
• Enrique Iborra

Beilstein J. Nanotechnol. 2019, 10, 975–984, doi:10.3762/bjnano.10.98

• surface of the Ni film suffered from restructuration during the CVD process that strongly depended on the heating rate. In order to assess the surface of the films after the growth of graphene, the samples were analysed by atomic force microscopy (AFM) using a Molecular Imaging Pico LE apparatus operated

In situ AFM visualization of Li–O₂ battery discharge products during redox cycling in an atmospherically controlled sample cell

• Kumar Virwani,
• Younes Ansari,
• Khanh Nguyen,
• Francisco José Alía Moreno-Ortiz,
• Jangwoo Kim,
• Maxwell J. Giammona,
• Ho-Cheol Kim and
• Young-Hye La

Beilstein J. Nanotechnol. 2019, 10, 930–940, doi:10.3762/bjnano.10.94

• /bjnano.10.94 Abstract The in situ observation of electrochemical reactions is challenging due to a constantly changing electrode surface under highly sensitive conditions. This study reports the development of an in situ atomic force microscopy (AFM) technique for electrochemical systems, including the

• these redox materials at the micrometer and nanometer scales. Gewirth et al. [2] reviewed the use of scanning tunneling microscopy (STM) and atomic force microscopy (AFM) investigations of phenomena such as reconstructions, restructuring and adsorption of ions. Phenomena such as under-potential

Nanoscale optical and structural characterisation of silk

• Meguya Ryu,
• Reo Honda,
• Adrian Cernescu,
• Arturas Vailionis,
• Armandas Balčytis,
• Jitraporn Vongsvivut,
• Jing-Liang Li,
• Denver P. Linklater,
• Elena P. Ivanova,
• Vygantas Mizeikis,
• Mark J. Tobin,
• Junko Morikawa and
• Saulius Juodkazis

Beilstein J. Nanotechnol. 2019, 10, 922–929, doi:10.3762/bjnano.10.93

• different methods, i.e., (i) a table-top Fourier-transform infrared (FTIR) transmission spectrometer, (ii) a synchrotron-based attenuated total reflection (ATR) FTIR spectrometer, and (iii) an atomic force microscopy (AFM) tip responding to the absorbed IR light (nano-IR [9]), produced comparable spectral

• diffractometer using a Cu Kα microfocus X-ray source with λ = 1.5418 Å (Figure 2a). IR spectral measurements The sub-diffraction scattering scanning near-field optical microscope (s-SNOM, neaspec GmbH) uses a metalized atomic force microscopy (AFM) tip. The tip maps the surface relief (topography) by its basic

Comparing a porphyrin- and a coumarin-based dye adsorbed on NiO(001)

• Sara Freund,
• Antoine Hinaut,
• Nathalie Marinakis,
• Edwin C. Constable,
• Ernst Meyer,
• Catherine E. Housecroft and
• Thilo Glatzel

Beilstein J. Nanotechnol. 2019, 10, 874–881, doi:10.3762/bjnano.10.88

• -layered islands on a NiO(001) single crystal surface have been studied by means of non-contact atomic force microscopy at room temperature. Comparison of both island types reveals different adsorption and packing of each dye, as well as an opposite charge-transfer direction, which has been quantified by

• Kelvin probe force microscopy measurements. Keywords: coumarin; Kelvin probe force microscopy; metal oxide; molecular resolution; nickel oxide (NiO); non-contact atomic force microscopy; porphyrin; Introduction With regard to its use in dye-sensitized solar cells (DSSCs), the wide-bandgap n-type

• -carboxyphenyl)porphyrin (Cu-TCPP) has been studied for the fabrication of n-type DSSCs [21][22]. In contrast, Coumarin 343 (C343) is an electron acceptor and is used for the design of p-type devices [23][24]. Both molecules structures are shown in Figure 1b. In this paper, non-contact atomic force microscopy

Novel reversibly switchable wettability of superhydrophobic–superhydrophilic surfaces induced by charge injection and heating

• Xiangdong Ye,
• Junwen Hou and
• Dongbao Cai

Beilstein J. Nanotechnol. 2019, 10, 840–847, doi:10.3762/bjnano.10.84

• surface-potential characterization. Atomic force microscopy (AFM) was used to characterize the physical morphology (Bruker Dimension Icon, Brook). The water contact angle (CA) of all surfaces was measured using a JC2000C1 contact angle measurements system (Shanghai Zhongchen Digital equipment). At room

Self-assembly and wetting properties of gold nanorod–CTAB molecules on HOPG

• Imtiaz Ahmad,
• Floor Derkink,
• Tim Boulogne,
• Pantelis Bampoulis,
• Harold J. W. Zandvliet,
• Hidayat Ullah Khan,
• Rahim Jan and
• E. Stefan Kooij

Beilstein J. Nanotechnol. 2019, 10, 696–705, doi:10.3762/bjnano.10.69

• drying on a nonwetting highly ordered pyrolytic graphite (HOPG) surface have been investigated using scanning electron microscopy (SEM) and atomic force microscopy (AFM). Although SEM did not reveal coverage of CTAB layers, AFM showed not only CTAB assembly, but also the dynamics of the process on the

• superstructures on HOPG substrates using atomic force microscopy (AFM). The assembly of CTAB molecules was investigated at various positions on the substrate. Also, the role of CTAB molecules that changes the wettability of the HOPG terraces is discussed in relation to the previous work [51]. The application of

Ultrathin hydrophobic films based on the metal organic framework UiO-66-COOH(Zr)

• Miguel A. Andrés,
• Clemence Sicard,
• Christian Serre,
• Olivier Roubeau and
• Ignacio Gascón

Beilstein J. Nanotechnol. 2019, 10, 654–665, doi:10.3762/bjnano.10.65

• substrates such as mica or glass up to 120°. These films were characterized by scanning electron microscopy, grazing incidence X-ray diffraction, Fourier transform infrared spectroscopy and atomic force microscopy, revealing the formation of a continuous film where ODP molecules adopt an almost vertical

• OPD/MOF ultrathin films have been fabricated onto glass, calcium fluoride, quartz crystal microbalance (QCM), Si(100) substrates and mica and characterized using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), atomic force microscopy (AFM

• substrates using an optical tensiometer (Theta Lite) purchased from Attension. Average values and error are calculated from four measurements performed at different positions of each sample. Atomic force microscopy (AFM) imaging was conducted on a NTEGRA Aura microscope from NT-MDT under ambient conditions

Review of time-resolved non-contact electrostatic force microscopy techniques with applications to ionic transport measurements

• Aaron Mascaro,
• Yoichi Miyahara,
• Tyler Enright,
• Omur E. Dagdeviren and
• Peter Grütter

Beilstein J. Nanotechnol. 2019, 10, 617–633, doi:10.3762/bjnano.10.62

• atomic force microscopy. Here, we review in detail several time-resolved EFM techniques based on non-contact atomic force microscopy, elaborating on their specific limitations and challenges. We also introduce a new experimental technique that can resolve time-varying signals well below the oscillation

• period of the cantilever and compare and contrast it with those previously established. Keywords: atomic force microscopy; electrostatic force microscopy; ionic transport; lithium ion batteries; nanotechnology; Introduction Since the inception of the atomic force microscope (AFM) a variety of

Direct observation of the CVD growth of monolayer MoS₂ using in situ optical spectroscopy

• Claudia Beatriz López-Posadas,
• Yaxu Wei,
• Wanfu Shen,
• Daniel Kahr,
• Michael Hohage and
• Lidong Sun

Beilstein J. Nanotechnol. 2019, 10, 557–564, doi:10.3762/bjnano.10.57

• of the sapphire substrate. This conclusion is based on a thorough ex situ characterization after CVD growth using differential reflectance spectroscopy (DRS), Raman spectroscopy, photoluminescent spectroscopy (PL), optical microscopy (OM), and atomic force microscopy (AFM). Actually, from the first

• situ using atomic force microscopy (Veeco Dimensions S3100) in tapping mode. A soft cantilever (TipsNano) was employed. The Raman and PL spectra spectra of the MoS2 thin films were collected using a JY Horiba LabRAM Aramis VIS microscope with an excitation wavelength of 532 nm. Measurements were

Mechanical and thermodynamic properties of Aβ₄₂, Aβ₄₀, and α-synuclein fibrils: a coarse-grained method to complement experimental studies

• Adolfo B. Poma,
• Horacio V. Guzman,
• Mai Suan Li and
• Panagiotis E. Theodorakis

Beilstein J. Nanotechnol. 2019, 10, 500–513, doi:10.3762/bjnano.10.51

• experimental observations. Keywords: β-amyloid; atomic force microscopy, mechanical deformation; molecular simulation; proteins; α-synuclein; Introduction All-atom molecular dynamics (MD) simulations have been employed to study the physical and chemical behaviour of the fundamental biomolecules of life (e.g

• mechanism of deformation that gives rise to the linear response can be characterized in the CG simulations. From the experimental point of view, there is a long-standing discussion in the atomic force microscopy (AFM) community whether Hertzian mechanics is applicable to all soft-matter samples explored

Temperature-dependent Raman spectroscopy and sensor applications of PtSe₂ nanosheets synthesized by wet chemistry

• Mahendra S. Pawar and
• Dattatray J. Late

Beilstein J. Nanotechnol. 2019, 10, 467–474, doi:10.3762/bjnano.10.46

• low intensity at 52.9 eV which corresponds to Pt 5d3/2 [24]. The thickness of the as-prepared PtSe2 nanosheets was calculated using atomic force microscopy (AFM). Figure 5a shows the AFM image which clearly shows that the lateral dimensions of the nanosheets are ≈700 nm. Figure 5b represents the

Advanced scanning probe lithography using anatase-to-rutile transition to create localized TiO₂ nanorods

• Julian Kalb,
• Vanessa Knittel and
• Lukas Schmidt-Mende

Beilstein J. Nanotechnol. 2019, 10, 412–418, doi:10.3762/bjnano.10.40

• probe lithography method in which a silicon tip, commonly used for atomic force microscopy, was pulled across an anatase TiO2 film. This process scratches the film causing tiny anatase TiO2 nanoparticles to form on the surface. According to previous reports, these anatase particles convert into rutile

Biocompatible organic–inorganic hybrid materials based on nucleobases and titanium developed by molecular layer deposition

• Leva Momtazi,
• Henrik H. Sønsteby and
• Ola Nilsen

Beilstein J. Nanotechnol. 2019, 10, 399–411, doi:10.3762/bjnano.10.39

• for 15 minutes was measured by atomic force microscopy (AFM) (Figure 8). All as-deposited films exhibit high surface roughness; however, the roughness of the Ti-adenine film is caused by small islands appearing on an otherwise almost flat surface. After water treatment, the surface roughness decreases

• purging system. An uncoated Si(100) substrate was used to collect the background. Atomic force microscopy (AFM) measurements were performed in contact mode using a Park XE70 device. The data were analyzed using the Gwyddion 2.44 SPM visualization tool. The contact angle measurements were performed using a

Nitrous oxide as an effective AFM tip functionalization: a comparative study

• Taras Chutora,
• Bruno de la Torre,
• Pingo Mutombo,
• Jack Hellerstedt,
• Jaromír Kopeček,
• Pavel Jelínek and
• Martin Švec

Beilstein J. Nanotechnol. 2019, 10, 315–321, doi:10.3762/bjnano.10.30

• characterize the adsorption of the N2O species on Au(111) by means of atomic force microscopy with CO-functionalized tips and density functional theory (DFT) simulations. Subsequently we devise a method of attaching a single N2O to a metal tip apex and benchmark its high-resolution imaging and spectroscopic

• apexes. Keywords: atomic force microscopy; Au(111); carbon monoxide; functionalization; high resolution; nitrous oxide; submolecular resolution; Introduction Frequency-modulated atomic force microscopy (AFM) has become the tool of choice for the characterization of molecules on the atomic scale

Scanning probe microscopy for energy-related materials

• Rüdiger Berger,
• Benjamin Grévin,
• Philippe Leclère and
• Yi Zhang

Beilstein J. Nanotechnol. 2019, 10, 132–134, doi:10.3762/bjnano.10.12

• significant role for the in-operando characterization. SPM methods offer a plethora of operation modes beyond topography imaging, which is well reflected in the articles of this thematic issue. The majority of contributions stem from research on photovoltaic materials. Here, electrical conductive atomic force

• microscopy (cAFM) and Kelvin probe force microscopy (KPFM) are the major methods that enable the study of the movement of charge carriers and their pathways [1]. We note that the KPFM method is rapidly becoming a tool capable of time-resolved studies. In this context, Yann Almadori and co-workers discuss the

Pull-off and friction forces of micropatterned elastomers on soft substrates: the effects of pattern length scale and stiffness

• Peter van Assenbergh,
• Marike Fokker,
• Julian Langowski,
• Jan van Esch,
• Marleen Kamperman and
• Dimitra Dodou

Beilstein J. Nanotechnol. 2019, 10, 79–94, doi:10.3762/bjnano.10.8

• samples from sub-microscale particles were characterized with atomic force microscopy (AFM), optical microscopy, and scanning electron microscopy (SEM). Monolayers and samples from microscale particles were characterized with optical microscopy and SEM. The elastic modulus of the fabricated micropatterns

Threshold voltage decrease in a thermotropic nematic liquid crystal doped with graphene oxide flakes

• Mateusz Mrukiewicz,
• Krystian Kowiorski,
• Paweł Perkowski,
• Rafał Mazur and
• Małgorzata Djas

Beilstein J. Nanotechnol. 2019, 10, 71–78, doi:10.3762/bjnano.10.7

• , electric anisotropy, splay elastic constant, switch-on time, and switch-off time. The shape and dimensions of the GO flakes were studied using atomic force microscopy (AFM) and scanning electron microscopy (SEM). The influence of the GO concentration on the physical properties and switching process in the

Surface plasmon resonance enhancement of photoluminescence intensity and bioimaging application of gold nanorod@CdSe/ZnS quantum dots

• Siyi Hu,
• Yu Ren,
• Yue Wang,
• Jinhua Li,
• Junle Qu,
• Liwei Liu,
• Hanbin Ma and
• Yuguo Tang

Beilstein J. Nanotechnol. 2019, 10, 22–31, doi:10.3762/bjnano.10.3

• particle per 1 × 1 μm area. The experimental microspectroscopy equipment was used to collect the integrated, white light, dark-field scattering, as well as the PL spectra and the atomic force microscopy techniques. We measured the scattering and the PL emission signal from a single particle. The

Characterization and influence of hydroxyapatite nanopowders on living cells

• Przemyslaw Oberbek,
• Tomasz Bolek,
• Adrian Chlanda,
• Seishiro Hirano,
• Sylwia Kusnieruk,
• Julia Rogowska-Tylman,
• Ganna Nechyporenko,
• Viktor Zinchenko,
• Wojciech Swieszkowski and
• Tomasz Puzyn

Beilstein J. Nanotechnol. 2018, 9, 3079–3094, doi:10.3762/bjnano.9.286

• done taking into account at least 15 different agglomerates for each sample. Atomic force microscopy Atomic force microscope (AFM) was used for topography imaging, surface evaluation at the nanoscale and evaluation of the particle shapes [35]. The sample preparation protocol was as follows: A water

• distribution of all tested HAps (Table 2). Obtained SEM data were further verified using atomic force microscopy. It is worth to note that AFM has proven to be a powerful visualization technique for a wide range of nanomaterials and nanoscale changes in the materials [51][52][53], including qualitative and

Electrostatic force microscopy for the accurate characterization of interphases in nanocomposites

• Diana El Khoury,
• Richard Arinero,
• Jean-Charles Laurentie,
• Mikhaël Bechelany,
• Michel Ramonda and
• Jérôme Castellon

Beilstein J. Nanotechnol. 2018, 9, 2999–3012, doi:10.3762/bjnano.9.279

• deduced by comparison of experimental data and numerical simulations, as well as the interface state of silicone dioxide layers. Keywords: atomic force microscopy; building-block materials; dielectric permittivity; electrostatic force microscopy; finite element simulation; interphases; nanocomposites

• conditions are fulfilled by electrostatic force microscopy (EFM) [18][19]. EFM is an atomic force microscopy (AFM)-based electrostatic method in which a conductive tip and a metallic sample holder are used. The probe-to-stage system is electrically polarized for the detection of electrostatic forces or force

Investigation of CVD graphene as-grown on Cu foil using simultaneous scanning tunneling/atomic force microscopy

• Majid Fazeli Jadidi,
• Umut Kamber,
• Oğuzhan Gürlü and
• H. Özgür Özer

Beilstein J. Nanotechnol. 2018, 9, 2953–2959, doi:10.3762/bjnano.9.274

• Majid Fazeli Jadidi Umut Kamber Oguzhan Gurlu H. Ozgur Ozer Department of Physics Engineering, İstanbul Technical University, 34469, İstanbul, Turkey 10.3762/bjnano.9.274 Abstract Scanning tunneling microscopy (STM) and atomic force microscopy (AFM) images of graphene reveal either a triangular

• array with maxima located in between the two carbon atoms was acquired in STM topography. Keywords: atomic force microscopy; CVD graphene; scanning tunneling microscopy; simultaneous operation; small amplitude; Introduction Graphene has been widely studied because of its potential use in future

• scanning tunneling microscopy (STM) and atomic force microscopy (AFM) by various groups [3]. The interaction of graphene with its substrate affects the STM measurements and that casts doubts on its electronic structure. Having the possibility to make simultaneous STM and AFM measurements, on the same area

Ternary nanocomposites of reduced graphene oxide, polyaniline and hexaniobate: hierarchical architecture and high polaron formation

• Claudio H. B. Silva,
• Maria Iliut,
• Christopher Muryn,
• Christian Berger,
• Zachary Coldrick,
• Vera R. L. Constantino,
• Marcia L. A. Temperini and
• Aravind Vijayaraghavan

Beilstein J. Nanotechnol. 2018, 9, 2936–2946, doi:10.3762/bjnano.9.272

• nanocomposite composed of polyaniline (PANI), reduced graphene oxide (rGO) and hexaniobate (hexNb) nanoscrolls. Atomic force microscopy images show an interesting architecture of rGO flakes coated with PANI and decorated by hexNb. Such features are attributed to the high stability of the rGO flakes prepared at

• that the nanocomposites may exhibit low compositional heterogeneity and possibly strong interactions (such as electrostatic and π–π interactions) between their components. The morphological characterisation of rGO-25, rGO/PANI and rGO/PANI/hexNb samples was carried out by atomic force microscopy, as

In situ characterization of nanoscale contaminations adsorbed in air using atomic force microscopy

• Jesús S. Lacasa,
• Lisa Almonte and
• Jaime Colchero

Beilstein J. Nanotechnol. 2018, 9, 2925–2935, doi:10.3762/bjnano.9.271

• model system for investigating a variety of nanoscale phenomena. In the present work we use atomic force microscopy to directly image nanoscale contamination on surfaces, and to characterize this contamination by using multidimensional spectroscopy techniques. By acquisition of spectroscopy data as a

• to access the state of contamination of real surfaces under ambient conditions using advanced atomic force microscopy techniques. Keywords: atomic force microscopy; cantilever; contact potential; electrostatic forces; force spectroscopy; Hamaker constant; Kelvin probe microscopy; surface

• of clean and well-prepared surfaces. Accordingly, a wealth of experimental techniques have been developed to control and characterize their contamination state [8]. In the present work we propose atomic force microscopy (AFM) [9][10] as a valuable tool to visualize nanoscale surface contamination and