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Search for "graphene" in Full Text gives 524 result(s) in Beilstein Journal of Nanotechnology. Showing first 200.

Effect of localized helium ion irradiation on the performance of synthetic monolayer MoS2 field-effect transistors

  • Jakub Jadwiszczak,
  • Pierce Maguire,
  • Conor P. Cullen,
  • Georg S. Duesberg and
  • Hongzhou Zhang

Beilstein J. Nanotechnol. 2020, 11, 1329–1335, doi:10.3762/bjnano.11.117

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  • in MoS2 [11], as well as enhanced out-of-plane charge transfer in 2D graphene/WSe2 heterostructures [12]. Energetic light ions are known to preferentially sputter chalcogen atoms from TMDs while retaining an adequate micrometer-scale structural integrity for irradiation doses up to approx. 1016 ions
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Published 04 Sep 2020

Structural and electronic properties of SnO2 doped with non-metal elements

  • Jianyuan Yu,
  • Yingeng Wang,
  • Yan Huang,
  • Xiuwen Wang,
  • Jing Guo,
  • Jingkai Yang and
  • Hongli Zhao

Beilstein J. Nanotechnol. 2020, 11, 1321–1328, doi:10.3762/bjnano.11.116

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  • Jianyuan Yu Yingeng Wang Yan Huang Xiuwen Wang Jing Guo Jingkai Yang Hongli Zhao College of Materials Science and Engineering, Yanshan University, Qinhuangdao 066004, China Department of Environmental and Chemical Engineering, Tangshan University, Tangshan, Hebei 063000, China Graphene Application
  • length and charge of the crystal structure with a non-metal atom replacing an O atom. Binding energy of SnO2 with an O atom substituted by a non-metal element. Acknowledgements The numerical calculations in this paper have been carried out at the computing system of the Graphene Application Technology
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Published 03 Sep 2020

Growth of a self-assembled monolayer decoupled from the substrate: nucleation on-command using buffer layers

  • Robby Reynaerts,
  • Kunal S. Mali and
  • Steven De Feyter

Beilstein J. Nanotechnol. 2020, 11, 1291–1302, doi:10.3762/bjnano.11.113

Graphical Abstract
  • formed at the solution–solid interface, is a more of routine occurrence than an exception. Such structurally diverse monolayers are typically formed on solid substrates such as highly oriented pyrolytic graphite (HOPG), graphene, and metals such as Cu, Ag and Au and have been characterized using scanning
  • . Alkane buffer layers have been employed as efficient electronic decoupling platforms for studying the intrinsic electronic properties of graphene and fullerenes [38]. Apart from alkane derivatives, inorganic systems such as chemisorbed iodine layers [34][35][36][37], and ultrathin layers of KCl [39
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Published 01 Sep 2020

Structure and electrochemical performance of electrospun-ordered porous carbon/graphene composite nanofibers

  • Yi Wang,
  • Yanhua Song,
  • Chengwei Ye and
  • Lan Xu

Beilstein J. Nanotechnol. 2020, 11, 1280–1290, doi:10.3762/bjnano.11.112

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  • Yi Wang Yanhua Song Chengwei Ye Lan Xu National Engineering Laboratory for Modern Silk, College of Textile and Engineering, Soochow University, 199 Ren-ai Road, Suzhou 215123, China 10.3762/bjnano.11.112 Abstract Ordered carbon/graphene composite nanofibers (CGCNFs) with different porous
  • configurations were used as a material to fabricate supercapacitor electrodes. These nanofibers were synthesized by applying a modified parallel electrode to the electrospinning method (MPEM) in order to generate electrospun polyacrylonitrile (PAN) nanofibers containing graphene. After synthesis, these fibers
  • surface area of CGCNFs, thereby significantly increasing their specific capacitance. In addition, the ordering of CGCNFs within the electrode improved the electron transfer efficiency, resulting in a higher specific capacitance. Keywords: carbon/graphene composite nanofibers; carbonization
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Published 27 Aug 2020

Ultrasensitive detection of cadmium ions using a microcantilever-based piezoresistive sensor for groundwater

  • Dinesh Rotake,
  • Anand Darji and
  • Nitin Kale

Beilstein J. Nanotechnol. 2020, 11, 1242–1253, doi:10.3762/bjnano.11.108

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  • graphene oxide (RGO)-based sensor and a microfluidic platform fabricated by [25][26][27] can be used with some surface modification for HMIs, but it is mostly capable of detecting in the micromolar range. A polymer-based microcantilever using an encapsulated piezoresistor has been proposed by Kale et al
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Published 18 Aug 2020

Nonadiabatic superconductivity in a Li-intercalated hexagonal boron nitride bilayer

  • Kamila A. Szewczyk,
  • Izabela A. Domagalska,
  • Artur P. Durajski and
  • Radosław Szczęśniak

Beilstein J. Nanotechnol. 2020, 11, 1178–1189, doi:10.3762/bjnano.11.102

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  • percent. Keywords: critical temperature; electron–phonon interaction; Li-hBN bilayer; Li-intercalated hexagonal boron nitride (Li-hBN); nonadiabatic superconductivity; vertex corrections; Introduction Low-dimensional systems such as graphene [1][2][3][4][5], silicene [6], borophene [7][8], and
  • phosphorene [9][10][11] are mechanically stable only when placed on a substrate [12][13][14]. The substrate should be selected so that it changes the physical properties of the low-dimensional system as little as possible. In the case of graphene, the following substrate materials were used: Co [15], Ni [16
  • ][17][18][19], Ru [20][21], Pt [22][23], SiC [24][25][26], and SiO2 [27][28][29]. Unfortunately, the obtained experimental data showed that the incompatible crystalline structure of the above materials leads to significant suppression of the carrier mobility of graphene [13][30]. It is now assumed that
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Published 07 Aug 2020

Hybridization vs decoupling: influence of an h-BN interlayer on the physical properties of a lander-type molecule on Ni(111)

  • Maximilian Schaal,
  • Takumi Aihara,
  • Marco Gruenewald,
  • Felix Otto,
  • Jari Domke,
  • Roman Forker,
  • Hiroyuki Yoshida and
  • Torsten Fritz

Beilstein J. Nanotechnol. 2020, 11, 1168–1177, doi:10.3762/bjnano.11.101

Graphical Abstract
  • through different ways such as the usage of wide-band-gap insulator thin films (e.g., oxides, alkali halides) [3][4], a molecular spacer layer [5][6], or sp2-hybridized two-dimensional interlayers (e.g., graphene and hexagonal boron nitride (h-BN)) [7][8]. The advantageous properties of an h-BN monolayer
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Published 04 Aug 2020

Scanning tunneling microscopy and spectroscopy of rubrene on clean and graphene-covered metal surfaces

  • Karl Rothe,
  • Alexander Mehler,
  • Nicolas Néel and
  • Jörg Kröger

Beilstein J. Nanotechnol. 2020, 11, 1157–1167, doi:10.3762/bjnano.11.100

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  • Karl Rothe Alexander Mehler Nicolas Neel Jorg Kroger Institut für Physik, Technische Universität Ilmenau, D-98693 Ilmenau, Germany 10.3762/bjnano.11.100 Abstract Rubrene (C42H28) was adsorbed with submonolayer coverage on Pt(111), Au(111), and graphene-covered Pt(111). Adsorption phases and
  • vibronic properties of C42H28 consistently reflect the progressive reduction of the molecule–substrate hybridization. Separate C42H28 clusters are observed on Pt(111) as well as broad molecular resonances. On Au(111) and graphene-covered Pt(111) compact molecular islands with similar unit cells of the
  • superstructure characterize the adsorption phase. The highest occupied molecular orbital of C42H28 on Au(111) exhibits weak vibronic progression while unoccupied molecular resonances appear with a broad line shape. In contrast, vibronic subbands are present for both frontier orbitals of C42H28 on graphene. They
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Published 03 Aug 2020

Photothermally active nanoparticles as a promising tool for eliminating bacteria and biofilms

  • Mykola Borzenkov,
  • Piersandro Pallavicini,
  • Angelo Taglietti,
  • Laura D’Alfonso,
  • Maddalena Collini and
  • Giuseppe Chirico

Beilstein J. Nanotechnol. 2020, 11, 1134–1146, doi:10.3762/bjnano.11.98

Graphical Abstract
  • . In 2018, an interesting approach demonstrated that a paper surface functionalized with gold nanoparticles conjugated with graphene oxide showed NIR laser-triggered photothermal ablation of pathogenic bacteria [64]. Upon NIR light exposure, the fabricated paper generated a temperature increase of over
  • nanohole arrays with reduced graphene oxide nanosheets in a unique and flexible polyimide film for laser-gated pathogen inactivation. For the in vivo experiments, the patch was irradiated for 5 min with an LED array (940 nm, 10 W) and the patch surface temperature increased to 52 °C. These tests indicated
  • in 77% planktonic P. aeruginosa cell death. In addition, polyurethane nanocomposites containing the same hybrid nanomaterials were also able to eliminate all the surface-grafted P. aeruginosa cells under NIR light irradiation. Reduced graphene oxide, which is characterized by a broad absorption
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Published 31 Jul 2020

Applications of superparamagnetic iron oxide nanoparticles in drug and therapeutic delivery, and biotechnological advancements

  • Maria Suciu,
  • Corina M. Ionescu,
  • Alexandra Ciorita,
  • Septimiu C. Tripon,
  • Dragos Nica,
  • Hani Al-Salami and
  • Lucian Barbu-Tudoran

Beilstein J. Nanotechnol. 2020, 11, 1092–1109, doi:10.3762/bjnano.11.94

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  • PEG and adsorbed on reduced graphene oxide sheets, which enhanced the thermal effect of hyperthermia and reduced the viability of breast cancer cells to less than 25% by reaching 43 °C [152]. Also, Zuvin et al. used 4–5 nm SPIONs conjugated with poly(acrylic acid) and anti-HER2 antibody against breast
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Published 27 Jul 2020

Monolayers of MoS2 on Ag(111) as decoupling layers for organic molecules: resolution of electronic and vibronic states of TCNQ

  • Asieh Yousofnejad,
  • Gaël Reecht,
  • Nils Krane,
  • Christian Lotze and
  • Katharina J. Franke

Beilstein J. Nanotechnol. 2020, 11, 1062–1071, doi:10.3762/bjnano.11.91

Graphical Abstract
  • decouple such flat-lying molecules from a metal, thin insulating layers have been engineered, ranging from ionic salts [15][16], over oxides [17][18][19], nitrides [20], and molecular layers [21][22] to 2D materials, such as graphene [23][24], and hexagonal boron nitride [25]. The most recent development
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Published 20 Jul 2020

A few-layer graphene/chlorin e6 hybrid nanomaterial and its application in photodynamic therapy against Candida albicans

  • Selene Acosta,
  • Carlos Moreno-Aguilar,
  • Dania Hernández-Sánchez,
  • Beatriz Morales-Cruzado,
  • Erick Sarmiento-Gomez,
  • Carla Bittencourt,
  • Luis Octavio Sánchez-Vargas and
  • Mildred Quintana

Beilstein J. Nanotechnol. 2020, 11, 1054–1061, doi:10.3762/bjnano.11.90

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  • the global health care sector. There is an urgent need to develop noninvasive, nontoxic, and new antinosocomial approaches that work more effectively and faster than current antibiotics. In this work, we report on a biocompatible hybrid nanomaterial composed of few-layer graphene and chlorin e6 (FLG
  • ; few-layer graphene (FLG); hybrid nanomaterial; photodynamic therapy (PDT); photosensitizer; Introduction The frequency of fungal infections has notably increased in the last decades; for instance, Candida albicans is now reported as the fourth cause of nosocomial septicemia in the United States [1
  • biological applications, such as biosensors, protein detection, bioimaging and drug delivery [17][18]. In recent years, graphene nanoparticles have been used in many different applications ranging from enhanced spectroscopy techniques, coatings, polymeric composites, sensors, drug delivery systems and others
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Published 17 Jul 2020

A new photodetector structure based on graphene nanomeshes: an ab initio study

  • Babak Sakkaki,
  • Hassan Rasooli Saghai,
  • Ghafar Darvish and
  • Mehdi Khatir

Beilstein J. Nanotechnol. 2020, 11, 1036–1044, doi:10.3762/bjnano.11.88

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  • Abstract Recent experiments suggest graphene-based materials as candidates in future electronic and optoelectronic devices. In this paper, we propose to investigate new photodetectors based on graphene nanomeshes (GNMs). Density functional theory (DFT) calculations are performed to gain insight into
  • GNMs have both metallic and semiconducting properties depending on the arrangements of perforations. Also, absorption spectrum analysis indicates attractive infrared peaks for GNMs with semiconducting characteristics, making them better photodetectors than graphene nanoribbon (GNR)-based alternatives
  • . The results suggest that GNMs can be potentially used in mid-infrared detectors with specific detectivity values that are 100-fold that of graphene-based devices and 1000-fold that of GNR-based devices. Hence, the special properties of graphene combined with the quantum feathers of the perforation
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Published 15 Jul 2020

Microwave-induced electric discharges on metal particles for the synthesis of inorganic nanomaterials under solvent-free conditions

  • Vijay Tripathi,
  • Harit Kumar,
  • Anubhav Agarwal and
  • Leela S. Panchakarla

Beilstein J. Nanotechnol. 2020, 11, 1019–1025, doi:10.3762/bjnano.11.86

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  • nanoparticles of Cu and Ni and one-dimensional nanorods of CuS, ZnF2, and NiF2 protected with fluorinated amorphous carbon. We have also synthesized reduced graphene oxide and partially rolled graphene by this method. Keywords: electric discharges; microwave synthesis; nanomaterials; transmission electron
  • graphene oxide and graphene without using any solvents or additional surfactants. Results and Discussion Smooth surfaces on commercially available metal particles do not create arcs under microwave irradiation. Instead, they heat up or reflects the microwaves. Thus, activating metal surfaces by acid
  • . However, the choice of graphite or g-C3N4 has shown little to no difference in the synthesis of nanoparticles. We have also studied exfoliation of graphite and graphite oxide (GO) under microwave irradiation in the presence of Zn metal. We have observed exfoliation of graphite into few-layered graphene
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Published 13 Jul 2020

Electrochemical nanostructuring of (111) oriented GaAs crystals: from porous structures to nanowires

  • Elena I. Monaico,
  • Eduard V. Monaico,
  • Veaceslav V. Ursaki,
  • Shashank Honnali,
  • Vitalie Postolache,
  • Karin Leistner,
  • Kornelius Nielsch and
  • Ion M. Tiginyanu

Beilstein J. Nanotechnol. 2020, 11, 966–975, doi:10.3762/bjnano.11.81

Graphical Abstract
  • decreasing diameter, but to a lesser extent. The obtained values of responsivity and detectivity are comparable with those previously reported for a graphene/GaAs NW photodetector with a Schottky junction working at 532 nm radiation [33]. The detectivity of our photodetector is better than that reported for
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Published 29 Jun 2020

Measurement of electrostatic tip–sample interactions by time-domain Kelvin probe force microscopy

  • Christian Ritz,
  • Tino Wagner and
  • Andreas Stemmer

Beilstein J. Nanotechnol. 2020, 11, 911–921, doi:10.3762/bjnano.11.76

Graphical Abstract
  • was obtained above a single-layer graphene flake. The figure shows the influence of the three sample properties on the shape of the parabola and gives an overview of the different components of the frequency shift Δf. Traditional closed-loop controllers for KFM use lock-in techniques to measure the
  • were steady, both switches were closed. Note that the topography setpoint should be adjusted before closing S1 because Δftopo ≥ Δfmean as illustrated in Figure 1. Results and Discussion The performance of the TD-KFM controller is demonstrated on multilayer graphene samples. The samples were obtained by
  • the electrostatic potential above the graphene flake and the SiO2 substrate. The patterns observable on the graphene flake are most likely caused by water droplets, which have formed due to the ambient conditions [34][35]. Small changes in the patterns were observed between two different scans
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Published 15 Jun 2020

Templating effect of single-layer graphene supported by an insulating substrate on the molecular orientation of lead phthalocyanine

  • K. Priya Madhuri,
  • Abhay A. Sagade,
  • Pralay K. Santra and
  • Neena S. John

Beilstein J. Nanotechnol. 2020, 11, 814–820, doi:10.3762/bjnano.11.66

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  • Technology, Kattankulathur 603 203, Tamil Nadu, India 10.3762/bjnano.11.66 Abstract The influence of single-layer graphene on top of a SiO2/Si surface on the orientation of nonplanar lead phthalocyanine (PbPc) molecules is studied using two-dimensional grazing incidence X-ray diffraction. The studies
  • indicate the formation of a mixture of polymorphs, i.e., monoclinic and triclinic forms of PbPc with face-on (lying down) and edge-on (standing up) PbPc orientations, respectively. The formation of monoclinic fractions is attributed to the presence of the graphene layer directing the π interactions between
  • the highly delocalized macrocycles. The competing interfacial van der Waals forces and molecule–molecule interactions lead to the formation of a small fraction of triclinic moieties. The nanoscale electrical characterization of the thin PbPc layer on graphene by means of conducting atomic force
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Published 19 May 2020

Light–matter interactions in two-dimensional layered WSe2 for gauging evolution of phonon dynamics

  • Avra S. Bandyopadhyay,
  • Chandan Biswas and
  • Anupama B. Kaul

Beilstein J. Nanotechnol. 2020, 11, 782–797, doi:10.3762/bjnano.11.63

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  • electronic, optoelectronic and thermoelectric devices in the future. Keywords: phonon concentration; phonon lifetime; Raman spectroscopy; thermal coefficients; Tungsten diselenide; two-dimensional material; Introduction Since the discovery of graphene, atomically thin two-dimensional layered materials have
  • drawn intense attention due to their unique physical properties [1][2]. Two-dimensional (2D) layered materials beyond graphene, such as transitional metal dichalcogenides (TMDCs) [3], black phosphorus (BP) [4], and other families of layered materials [5], can be mechanically exfoliated or, in some cases
  • , grown from bottom-up processes akin to graphene. While graphene is comprised of a single element on the periodic table, i.e., carbon, TMDCs are binary compounds which makes their lattice dynamics more complex compared to multilayer (ML) graphene [6]. The symmetry, force constants, and frequency
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Published 12 May 2020

Nickel nanoparticles supported on a covalent triazine framework as electrocatalyst for oxygen evolution reaction and oxygen reduction reactions

  • Secil Öztürk,
  • Yu-Xuan Xiao,
  • Dennis Dietrich,
  • Beatriz Giesen,
  • Juri Barthel,
  • Jie Ying,
  • Xiao-Yu Yang and
  • Christoph Janiak

Beilstein J. Nanotechnol. 2020, 11, 770–781, doi:10.3762/bjnano.11.62

Graphical Abstract
  • ][11][12][13]. The performance of the nickel catalysts could be further enhanced via modifications, such as the usage of carbon supports including N-doped graphene [14], active carbon [15], graphene oxide [16][17], carbon nanotubes [12][18] and covalent triazine frameworks (CTFs) [19][20]. CTFs are
  • layers (25.2 wt %), Ni encapsulated within single-layer graphene (32.8 wt %), but higher than that of nickel nanoparticles encapsulated in N-doped carbon nanotubes (14.5 wt %), and much lower than those of with N-doped carbon shells coated face-centered cubic (fcc) or hexagonal closed packed (hcp) nickel
  • than N-doped carbon sheets requiring 0.41 V vs RHE [58] and better performance than nitrogen-doped graphene/carbon nanotube hybrids requiring an overpotential of 0.4 V vs RHE at 10 mA/cm2 [59]. In comparison with the literature, CTF-1-600 and Ni/CTF-1-600-22 appear to be highly active OER
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Published 11 May 2020

Hexagonal boron nitride: a review of the emerging material platform for single-photon sources and the spin–photon interface

  • Stefania Castelletto,
  • Faraz A. Inam,
  • Shin-ichiro Sato and
  • Alberto Boretti

Beilstein J. Nanotechnol. 2020, 11, 740–769, doi:10.3762/bjnano.11.61

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  • heterojunctions of armchair graphene and boron nitride nanoribbons, exhibiting negative differential resistance is proposed. Low-bandgap armchair graphene nanoribbons and high-bandgap armchair boron nitride nanoribbons are used to design the well and the barrier region, respectively. The effect of all possible
  • substitutional defects (including BC, NC, CB, and CN) at the interface of graphene and boron nitride nanoribbons on the negative differential resistance behavior of the proposed resonant tunneling diode is investigated. Transport simulations are carried out in the framework of tight-binding Hamiltonians and non
  • -equilibrium Green’s functions. The results show that a single substitutional defect at the interface of armchair graphene and boron nitride nanoribbons can dramatically affect the negative differential resistance behavior depending on its type and location in the structure. Keywords: AGNR/ABNNR
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Published 24 Apr 2020

Exfoliation in a low boiling point solvent and electrochemical applications of MoO3

  • Matangi Sricharan,
  • Bikesh Gupta,
  • Sreejesh Moolayadukkam and
  • H. S. S. Ramakrishna Matte

Beilstein J. Nanotechnol. 2020, 11, 662–670, doi:10.3762/bjnano.11.52

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  • mV·s−1. Keywords: 2-butanone; liquid-phase exfoliation; low-boiling point solvent; molybdenum trioxide (MoO3); supercapacitors; Introduction The advent of graphene has opened a new area of research in the field of two-dimensional materials [1]. The extraordinary properties of graphene have led
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Published 17 Apr 2020

Preparation, characterization and photocatalytic performance of heterostructured CuO–ZnO-loaded composite nanofiber membranes

  • Wei Fang,
  • Liang Yu and
  • Lan Xu

Beilstein J. Nanotechnol. 2020, 11, 631–650, doi:10.3762/bjnano.11.50

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  • characteristics, such as high surface area, good thermal stability, and excellent mechanical properties [32][33]. CNFs loaded with metal oxide nanoparticles have attracted a great deal of attention regarding the photocatalytic purification of water. He et al. [34] fabricated porous graphene/TiO2 CNFs by
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Published 15 Apr 2020

Adsorptive removal of bulky dye molecules from water with mesoporous polyaniline-derived carbon

  • Hyung Jun An,
  • Jong Min Park,
  • Nazmul Abedin Khan and
  • Sung Hwa Jhung

Beilstein J. Nanotechnol. 2020, 11, 597–605, doi:10.3762/bjnano.11.47

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  • because of functional carbon materials (graphene [16] or porous carbon [17]), mesoporous materials [18] and MOFs [19][20][21][22]. For example, MOFs [23][24][25], carbonaceous materials (such as carbon nanotubes, graphene, biochar and activated carbon) [26] and clay [27] have been applied in adsorptive
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Published 08 Apr 2020

Multilayer capsules made of weak polyelectrolytes: a review on the preparation, functionalization and applications in drug delivery

  • Varsha Sharma and
  • Anandhakumar Sundaramurthy

Beilstein J. Nanotechnol. 2020, 11, 508–532, doi:10.3762/bjnano.11.41

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  • CNTs ruptured upon laser light irradiation [115]. The introduction of graphene oxide (GO) nanosheets with PDDA as multilayers caused the migration and rearrangement of chains compared to PDDA/PAA multilayers [116]. The PDDA/GO multilayers showed improved resistance to damage and maintained a defect
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Published 27 Mar 2020
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