Photothermal ablation of murine melanomas by Fe₃O₄ nanoparticle clusters

• Xue Wang,
• Lili Xuan and
• Ying Pan

Beilstein J. Nanotechnol. 2022, 13, 255–264, doi:10.3762/bjnano.13.20

• afterwards due to adverse effects or development of various resistance mechanisms, making the advent of novel strategies imperative for early diagnosis and efficient treatment [2]. Photothermal therapy (PTT) is a recently developed regimen that requires administration of nanomaterials with unique optical

• nanoclusters as PTT agents both in vitro and in vivo, and finally explored the putative molecular mechanisms underlying the observed therapeutic effects. Results and Discussion Properties of Fe3O4 nanoparticle clusters (NPCs) The as-synthesized individual Fe3O4 nanoparticles were evenly dispersed in chloroform

• higher dosage of 5 mg/kg [15]. The extent of tumor volume shrinkage is not different between these two studies. Finally, no abnormalities in general health status, defecation, or urination were seen for all mice (data not shown). To explore the molecular mechanisms underlying PTT, we performed

Relationship between corrosion and nanoscale friction on a metallic glass

• Haoran Ma and
• Roland Bennewitz

Beilstein J. Nanotechnol. 2022, 13, 236–244, doi:10.3762/bjnano.13.18

• surface dissolution at the interface of the two layers. The findings contribute to the understanding of mechanical contacts with metallic glasses under corrosive conditions by exploring the interrelation of microscopic corrosion mechanisms and nanoscale friction. Keywords: atomic force microscopy (AFM

• nanoscale is crucially important. Microscale bearings made of Ni-based MGs lasted four times longer than those machined from sintered alloy [12]. Corrosive degradation, as one of the major failure mechanisms of metals and alloys, is an important issue in engineering applications of MGs. Protective oxide

• surface, and the competition between diffusion of hydrates into solution and their precipitation into a growing outer layer. Understanding the mechanisms of nanoscale friction on metallic glasses is a basis for applications involving mechanical contacts under corrosive conditions. Also, nanotribology

Impact of device design on the electronic and optoelectronic properties of integrated Ru-terpyridine complexes

• Max Mennicken,
• Sophia Katharina Peter,
• Corinna Kaulen,
• Ulrich Simon and
• Silvia Karthäuser

Beilstein J. Nanotechnol. 2022, 13, 219–229, doi:10.3762/bjnano.13.16

• nanometer range determines the accessible conductance values (single-Ru(MPTP)2–AuNP ≫ few-Ru(MPTP)2–AuNP > Ru(TP)2 nanowire) and different conduction mechanisms. While single- and few-Ru(MPTP)2–AuNP devices exhibit sequential tunneling transport, Ru(TP)2-complex wire devices exhibit hopping transport

Engineered titania nanomaterials in advanced clinical applications

• Padmavati Sahare,
• Paulina Govea Alvarez,
• Juan Manual Sanchez Yanez,
• Gabriel Luna-Bárcenas,
• Samik Chakraborty,
• Sujay Paul and
• Miriam Estevez

Beilstein J. Nanotechnol. 2022, 13, 201–218, doi:10.3762/bjnano.13.15

• antibiotics has been observed, and multiple mechanisms of resistance to each type of antimicrobial agent have been discovered. Hence, to counter drug resistance, efficient bactericidal materials are needed, and nps have been identified as a promising solution for the abovementioned issue [75]. TiO2 is

• photocatalytic reaction, as a result of which anatase has been found to have the highest antimicrobial activity among all crystal structures of TiO2 [79]. The mechanisms of titania-induced biocidal activity are mostly by an oxidative attack on the outer/inner cell membrane of the microorganism, as well as

• are external stimuli [103]. The drug release profile of different mechanisms is shown in Figure 4. Another parameter that contributes to drug release is the charge of the drug molecule. Due to the presence of hydroxy groups at the surface of TiO2, it is supposed to be negatively charged. Consequently

Low-energy electron interaction and focused electron beam-induced deposition of molybdenum hexacarbonyl (Mo(CO)₆)

• Po-Yuan Shih,
• Maicol Cipriani,
• Christian Felix Hermanns,
• Jens Oster,
• Klaus Edinger,
• Armin Gölzhäuser and
• Oddur Ingólfsson

Beilstein J. Nanotechnol. 2022, 13, 182–191, doi:10.3762/bjnano.13.13

• deposits composition with carbonyl loss through DEA vs DI. We compare this to previous gas phase, surface science and FEBID experiments on W(CO)6 and discuss these studies in context to the current findings and potential deposition mechanisms. Method Quantum chemical calculations Similar to the approach in

• , promoting reductive ligand elimination and metal–metal bond formation. We anticipate that non-steady-state electron exposure of Mo(CO)6 would reveal similar mechanisms as observed for W(CO)6. Negative ion yield curves from DEA to Mo(CO)6 in the energy range from about 0–12 eV. From top; formation of [Mo(CO

Theoretical understanding of electronic and mechanical properties of 1T′ transition metal dichalcogenide crystals

• Seyedeh Alieh Kazemi,
• Sadegh Imani Yengejeh,
• Vei Wang,
• William Wen and
• Yun Wang

Beilstein J. Nanotechnol. 2022, 13, 160–171, doi:10.3762/bjnano.13.11

• antibonding mechanisms can be characterized based on the negative and positive overlap population, respectively. The bond strengths between Mo/W and S/Se atoms are quantitatively determined by taking the integral of -pCOHP up to the Fermi level (-IpCOHP), which are also listed in Figure 3. In the 1T′ polytype

• the contrary, the 1T′ polytype exhibits metallic characteristics. Figure 5b shows the different -pCOHP of the Mo–S bond of 1T′ and 2H polytypes. Both long and short Mo–S bonds in 1T′ MoS2 are considered. All -pCOHP images show similar features, which suggest similar bonding mechanisms. The

Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• photocatalytic mechanisms, and the polymer photodegradation of the resulting nanocomposite using DFT techniques. The results confirmed that the interaction between NO and PANI is indeed a hydrogen bond and photogenerated holes serve as the primary factor of the photocatalytic NO removal [35]. Moreover, this

• ), Copyright 2018 Springer Nature. This content is not subject to CC BY 4.0. Proposed mechanisms for photocatalytic NO oxidation via interfacial charge migration over BiOBr/SnO2 p–n heterojunctions. Figure 8 was reprinted with permission from [70], Copyright 2020 American Chemical Society. This content is not

Theranostic potential of self-luminescent branched polyethyleneimine-coated superparamagnetic iron oxide nanoparticles

• Rouhollah Khodadust,
• Ozlem Unal and
• Havva Yagci Acar

Beilstein J. Nanotechnol. 2022, 13, 82–95, doi:10.3762/bjnano.13.6

• , possibly due to altered cell internalization mechanisms. Overall, the combination of SPIONs, which are the only FDA approved nanoparticles for imaging, and bPEI, which is the golden standard for non-viral gene transfection with an added advantage of strong luminescence in this unique SPION@bPEI structure

Influence of magnetic domain walls on all-optical magnetic toggle switching in a ferrimagnetic GdFe film

• Rahil Hosseinifar,
• Evangelos Golias,
• Ivar Kumberg,
• Quentin Guillet,
• Karl Frischmuth,
• Sangeeta Thakur,
• Mario Fix,
• Manfred Albrecht,
• Florian Kronast and
• Wolfgang Kuch

Beilstein J. Nanotechnol. 2022, 13, 74–81, doi:10.3762/bjnano.13.5

• above and below the ferrimagnetic magnetization compensation temperature. Besides pulse-to-pulse variations in laser fluence, we identify two main mechanisms that can lead to non-deterministic switching on the nanoscale: (i) domain coarsening, that is, the reduction of domain-wall energy by avoiding

• mechanisms: The first one is related to the shape of the magnetic domains as they are left directly after the all-optical switching and the force on the domain wall resulting from the balance of domain-wall and magnetostatic energy. Sharp domain features that would occur where domain walls are close to the

Nanoscale friction and wear of a polymer coated with graphene

• Robin Vacher and
• Astrid S. de Wijn

Beilstein J. Nanotechnol. 2022, 13, 63–73, doi:10.3762/bjnano.13.4

• different mechanisms at play in such systems. During the last few decades, with the development of the atomic force microscope [8] and increases in computing power, it has become possible to investigate more deeply and develop an understanding of the mechanisms that play a role in the friction of graphene

• 100 Å, we found that the tip moves deeply inside the substrate and the average friction force is above 90 nN, almost an order of magnitude higher than with graphene. This clearly shows that the addition of the graphene layer drastically reduces the friction. To further investigate the mechanisms and

• adhesion or covalent chemical bonds, would behave more like the flat graphene in our simulations and would provide additional protection. The temperature dependence of friction can potentially allow one to probe different relaxation mechanisms in the polymer [33][34]. In our previous work [23], we

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

• extracts to synthesize NPs. Although bio-assisted procedures are very promising, the major problem is the reproducibility of the processes. Besides, the exact mechanisms underlying the NP formation using green plant extracts have not been elucidated yet. Finally, their large-scale use is limited by the

• chapter, we introduce the basic physical mechanisms involved in the sputter deposition of materials and related processes. Low-pressure plasma-based sputter deposition, along with evaporation, cathodic arc, or laser-based deposition, belongs to the family of PVD techniques, which have been originally

• NPs with desired size, shape, and composition [2]. Colloidal synthesis allows one to obtain metal, oxide, halide, chalcogenide, and other types of NPs but the mechanisms of their formation are different, even though all of them include an initial nucleation step followed by a growth step [77]. In this

Biocompatibility and cytotoxicity in vitro of surface-functionalized drug-loaded spinel ferrite nanoparticles

• Sadaf Mushtaq,
• Khuram Shahzad,
• Tariq Saeed,
• Anwar Ul-Hamid,
• Bilal Haider Abbasi,
• Nafees Ahmad,
• Waqas Khalid,
• Muhammad Atif,
• Zulqurnain Ali and
• Rashda Abbasi

Beilstein J. Nanotechnol. 2021, 12, 1339–1364, doi:10.3762/bjnano.12.99

• oxidative stress can be attributed to the presence of xenobiotic detoxification and antioxidant mechanisms [47]. Functionalized MFe2O4 NPs cause cell cycle arrest in cancer cells Evidence of oxidative damage in treated cells may indicate DNA damage and possible effects on cell cycle progression, causing

Identifying diverse metal oxide nanomaterials with lethal effects on embryonic zebrafish using machine learning

• Richard Liam Marchese Robinson,
• Haralambos Sarimveis,
• Philip Doganis,
• Xiaodong Jia,
• Marianna Kotzabasaki,
• Christiana Gousiadou,
• Stacey Lynn Harper and
• Terry Wilkins

Beilstein J. Nanotechnol. 2021, 12, 1297–1325, doi:10.3762/bjnano.12.97

Electrical, electrochemical and structural studies of a chlorine-derived ionic liquid-based polymer gel electrolyte

• Ashish Gupta,
• Amrita Jain,
• Manju Kumari and
• Santosh K. Tripathi

Beilstein J. Nanotechnol. 2021, 12, 1252–1261, doi:10.3762/bjnano.12.92

• observed that the height of the peak decreases by increasing the temperature, which suggests a plurality of relaxation mechanisms. At low frequencies, the values of both real and imaginary moduli decrease to almost zero, indicating a negligible contribution of the electrode polarization phenomenon. The

A review on slip boundary conditions at the nanoscale: recent development and applications

• Ruifei Wang,
• Jin Chai,
• Bobo Luo,
• Xiong Liu,
• Jianting Zhang,
• Min Wu,
• Mingdan Wei and
• Zhuanyue Ma

Beilstein J. Nanotechnol. 2021, 12, 1237–1251, doi:10.3762/bjnano.12.91

• mechanisms is based on the existence of negative slip length and its variation. For example, combining with the negative slip length, Song et al. proposed a single-phase nonlinear seepage model and successfully explained the nonlinear flow characteristics of low permeability reservoirs [127]. Therefore, the

Morphology-driven gas sensing by fabricated fractals: A review

• Vishal Kamathe and
• Rupali Nagar

Beilstein J. Nanotechnol. 2021, 12, 1187–1208, doi:10.3762/bjnano.12.88

• sensitization mechanisms [26]. The mechanisms focusing on a macroscopic perspective deal with adsorption/desorption of surface atomic/molecular species or discuss how the bulk resistance and gas diffusion control mechanisms affect the charge transport [26][87][89]. The changes in electrical resistance of the

• section “Fractal length scales and growth models” described various fab-fracs tested as gas sensors for different analytes. The role of the morphology of fab-fracs in the gas sensing response will now be discussed. Figure 24 explains the common mechanisms of physical adsorption, chemical linkages, gas

Irradiation-driven molecular dynamics simulation of the FEBID process for Pt(PF₃)₄

• Alexey Prosvetov,
• Alexey V. Verkhovtsev,
• Gennady Sushko and
• Andrey V. Solov’yov

Beilstein J. Nanotechnol. 2021, 12, 1151–1172, doi:10.3762/bjnano.12.86

• simulations of irradiation-driven transformations of complex molecular systems by means of the advanced software packages MBN Explorer and MBN Studio. Atomistic simulations performed following the formulated protocol provide valuable insights into the fundamental mechanisms of electron-induced precursor

• thermal decomposition, while dissociation mechanisms in FEBID are predominantly electron-induced reactions. While primary electron (PE) energies during FEBID are typically between 1 and 30 keV, chemical dissociation is most efficient for low-energy (up to several tens of electronvolts) secondary electrons

• fundamental mechanisms of electron-induced precursor fragmentation and the corresponding mechanisms of nanostructure formation and growth using FEBID. Until recently, most computer simulations of FEBID and nanostructure growth have been performed using a Monte Carlo approach and diffusion–reaction theory [2

Self-assembly of amino acids toward functional biomaterials

• Huan Ren,
• Lifang Wu,
• Lina Tan,
• Yanni Bao,
• Yuchen Ma,
• Yong Jin and
• Qianli Zou

Beilstein J. Nanotechnol. 2021, 12, 1140–1150, doi:10.3762/bjnano.12.85

• mechanisms. Scanning electron microscopy and transmission electron microscopy images show that the assembly is layered and has a three-dimensional spherical structure with porous and stacked nanorods (width 50 nm, length 200 nm). During the self-assembly process, tetrakis(4-sulfonatophenyl)porphine and

• conformational changes through various mechanisms, such as protonation, charge inversion, or chemical bond cleavage, promoting tumor-specific cellular uptake or drug release [82]. Sun et al. [83] coupled tryptophan-glycine (WG) to hydrophobic porphyrins (P) by an amidation reaction to obtain pH-responsive

Criteria ruling particle agglomeration

• Dieter Vollath

Beilstein J. Nanotechnol. 2021, 12, 1093–1100, doi:10.3762/bjnano.12.81

• may occur. Agglomeration of nanoparticles may be controlled by different mechanisms. During synthesis one observes agglomeration controlled by the geometry and electrical charges of the particles. Additionally, one may find agglomeration controlled by thermodynamic interaction of the particles in the

• direction of a minimum of the free enthalpy. In this context, one may observe mechanisms leading to a reduction of the surface energy or controlled by the van der Waals interaction. Additionally, the ensemble may arrange in the direction of a maximum of the entropy. Simulations based on Monte Carlo methods

• of these materials, the particle size increases due to agglomeration. This leads to a product of reduced applicability. Therefore, concerning the formation and handling of nanoparticles, agglomeration is the crucial problem. Detailed considerations lead to a few fundamentally different mechanisms

Use of nanosystems to improve the anticancer effects of curcumin

• Andrea M. Araya-Sibaja,
• Norma J. Salazar-López,
• Krissia Wilhelm Romero,
• José R. Vega-Baudrit,
• J. Abraham Domínguez-Avila,
• Carlos A. Velázquez Contreras,
• Ramón E. Robles-Zepeda,
• Mirtha Navarro-Hoyos and
• Gustavo A. González-Aguilar

Beilstein J. Nanotechnol. 2021, 12, 1047–1062, doi:10.3762/bjnano.12.78

• -release delivery mechanisms. This study highlights the versatility of nanoemulsions since their performance can be fine-tuned with the aid of other systems, such as microgels. Nanosystems that respond to external stimuli In addition to their size and other advantages previously discussed, nanosystems can

• studies performed on human subjects. Data generated in vitro and in animals should complement the efficacy of a treatment and can be used to determine its mechanisms of action at cellular and molecular scales. However, there is no substitute for human-derived data. Figure 1 summarizes relevant data

• consider the need to prioritize in vivo over in vitro experimentation, although the latter cannot be ruled out since it is an invaluable tool that allows researchers to elucidate mechanisms and mode of action of CUR in nanosystems. Effects of CUR on cancerous processes observed on clinical trials [28][29

Revealing the formation mechanism and band gap tuning of Sb₂S₃ nanoparticles

• Maximilian Joschko,
• Franck Yvan Fotue Wafo,
• Christina Malsi,
• Danilo Kisić,
• Ivana Validžić and
• Christina Graf

Beilstein J. Nanotechnol. 2021, 12, 1021–1033, doi:10.3762/bjnano.12.76

• mechanisms, and in particular the associated kinetics of Sb2S3 nanoparticles, is therefore still lacking. Nevertheless, it is necessary to understand the nanomaterial formation mechanism to achieve control over the morphological and optical properties of the particles, which is crucial for the further

• the shape, but no individual type I nanoparticles could be identified anymore in TEM at this stage. Also, the type II nanoparticles appeared to have formed superordinate structures (type III). Such multistep hierarchical growth mechanisms have already been observed for different materials, such as

• explained by different preparation conditions [49]. Different formation mechanisms can lead to differences in bond lengths and angles in an amorphous material, and therefore to a different mobility gap [46]. Hence, a decreasing mobility gap suggests that an electronic relaxation process occurs after a

Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries

• Marina Tabuyo-Martínez,
• Bernd Wicklein and
• Pilar Aranda

Beilstein J. Nanotechnol. 2021, 12, 995–1020, doi:10.3762/bjnano.12.75

• capacity of these electrodes depends on two mechanisms, the deposition/stripping of Na and the insertion/extraction of Na+. Metal scaffolds and meshes fabricated from Cu, Ni, Ni@Cu, or Al are other materials onto which Na can be plated. As shown in a recent work, porous Ni structures formed on Cu foil

• alloys. This can be attributed to more effective mitigation mechanisms for the volume expansion [74]. Some intermetallic compounds also show higher capacities. For instance, a Sb anode with 7% of Si can reach a maximum capacity value as high as 663 mAh·g−1 after 140 cycles in a SiB, while the pure Sb

Molecular assemblies on surfaces: towards physical and electronic decoupling of organic molecules

• Sabine Maier and
• Meike Stöhr

Beilstein J. Nanotechnol. 2021, 12, 950–956, doi:10.3762/bjnano.12.71

• molecules, offering unique opportunities for the bottom-up assembly of novel carbon-based materials using on-surface chemistry [48][49]. However, the significantly reduced catalytic activity on non-metallic substrates requires exploring alternative reaction mechanisms beyond thermal activation, for example

The role of deep eutectic solvents and carrageenan in synthesizing biocompatible anisotropic metal nanoparticles

• Nabojit Das,
• Akash Kumar and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2021, 12, 924–938, doi:10.3762/bjnano.12.69

• possible to modulate the viscosity of DESs, especially NADES, by varying the composition ratio of hydrogen bond donor and hydrogen bond acceptor components [29]. Also, the growth mechanisms and nucleation processes of nanoparticles are highly modulated by the components of DESs through modifying reduction

• carrageenan in the synthesis of nanomaterials that are nontoxic. The review begins by discussing widely used wet chemical methods of synthesizing anisotropic plasmonic metal nanomaterials. We also give insight in growth mechanisms during the initiation of anisotropy in the presence of a surfactant. This

In situ transport characterization of magnetic states in Nb/Co superconductor/ferromagnet heterostructures

• Olena M. Kapran,
• Roman Morari,
• Taras Golod,
• Evgenii A. Borodianskyi,
• Vladimir Boian,
• Andrei Prepelita,
• Nikolay Klenov,
• Anatoli S. Sidorenko and
• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2021, 12, 913–923, doi:10.3762/bjnano.12.68

• response, which indicates switching into some specific metastable magnetic states. There are two mechanisms for the appearance of hysteresis in the MLs [34][37]. The major hysteresis is associated with switching in and out from the magnetostatically stable AP state. Multiple smaller ones are associated