Preferential enrichment and extraction of laser-synthesized nanoparticles in organic phases

• Theo Fromme,
• Maximilian L. Spiekermann,
• Florian Lehmann,
• Stephan Barcikowski,
• Thomas Seidensticker and
• Sven Reichenberger

Beilstein J. Nanotechnol. 2025, 16, 254–263, doi:10.3762/bjnano.16.20

• decreasing polarity were chosen for this study. For each metal, LAL was performed at elevated temperatures (85 °C) where the PC/A mixture forms a single phase. Upon cooling, the phases separated and the amount of colloidal nanoparticles in the alcohol and propylene carbonate phase was analyzed for each metal

• ) to determine the preferred phase (1-nonanol or propylene carbonate) of the colloidal nanoparticles (Figure 1a,b). For gold and silver, the nanoparticles remained in the propylene carbonate phase, which is the more polar phase, while the nanoparticles made by LAL of aluminum and titanium were found to

• cycling, the distribution of colloidal copper and iron nanoparticles over the PC and alcohol phase was quantified via UV–vis extinction measurements afterward (Figure 4). Figure 4 shows the mass fraction of colloidal nanoparticles in the propylene carbonate phase (bottom phase of the TMS) for the

Laser synthesis of nanoparticles in organic solvents – products, reactions, and perspectives

• Theo Fromme,
• Sven Reichenberger,
• Katharine M. Tibbetts and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2024, 15, 638–663, doi:10.3762/bjnano.15.54

• generation of products that differ from the initial target’s composition [28][29][30][31][32]. Besides LAL, LFL, and LML, where a solid bulk or particulate material is laser-excited, another method to synthesize colloidal nanoparticles is the laser reduction in liquid (LRL), where the liquid contains

• stabilizing the nanoparticles’ glass structure [65]. While these reviews consider at least in part the chemical reactions occurring in organic liquids, they focus on specific topics. Thus, this perspective article aims to survey the current state of knowledge on the laser-based synthesis of colloidal

• nanoparticles in organic solvents as well as the underlying chemical reactions and their influence on particulate properties. Additionally, the knowledge base on the role of volatile and non-volatile molecular products forming during LSPC will be addressed. Review LSPC in aqueous liquids Laser-based

Silver-based SERS substrates fabricated using a 3D printed microfluidic device

• Phommachith Sonexai,
• Minh Van Nguyen,
• Bui The Huy and
• Yong-Ill Lee

Beilstein J. Nanotechnol. 2023, 14, 793–803, doi:10.3762/bjnano.14.65

• fields in industry and laboratories, such as chemical synthesis and microreactors [11][12], drug screening [13], and clinical trials [14]. They can create homogeneous reaction environments with controllable parameters for synthesizing homogeneous colloidal nanoparticles with a narrow size distribution

Biocatalytic synthesis and ordered self-assembly of silica nanoparticles via a silica-binding peptide

• Mustafa Gungormus

Beilstein J. Nanotechnol. 2023, 14, 280–290, doi:10.3762/bjnano.14.25

• . Capping agents are not only used to regulate growth and size of colloidal nanoparticles, but also to control the physicochemical or biological characteristics. As will be demonstrated below, in addition to the size of the particles, the SiBP also changes the surface charge of the particles, resulting in

Surfactant-free syntheses and pair distribution function analysis of osmium nanoparticles

• Mikkel Juelsholt,
• Jonathan Quinson,
• Emil T. S. Kjær,
• Baiyu Wang,
• Rebecca Pittkowski,
• Susan R. Cooper,
• Tiffany L. Kinnibrugh,
• Søren B. Simonsen,
• Luise Theil Kuhn,
• María Escudero-Escribano and
• Kirsten M. Ø. Jensen

Beilstein J. Nanotechnol. 2022, 13, 230–235, doi:10.3762/bjnano.13.17

• medical properties [10][11][12][13][14][15][16][17] in experimental and theoretical work [18]. Common wet chemical syntheses require surfactants, viscous solvents, or shape-directing agents [5][17][19][20][21] that act as ligands to stabilize colloidal nanoparticles (NPs). These additives can bring

Uniform arrays of gold nanoelectrodes with tuneable recess depth

• Elena O. Gordeeva,
• Ilya V. Roslyakov,
• Alexey P. Leontiev,
• Alexey A. Klimenko and
• Kirill S. Napolskii

Beilstein J. Nanotechnol. 2021, 12, 957–964, doi:10.3762/bjnano.12.72

• alternative approach includes bulk electrode structuring by deposition or etching techniques using self-assembled arrays of colloidal nanoparticles [15], liquid crystals [16], or track-etched membranes [17][18][19] as template or mask, respectively. Among porous templates, anodic aluminium oxide (AAO) allows

On the stability of microwave-fabricated SERS substrates – chemical and morphological considerations

• Limin Wang,
• Aisha Adebola Womiloju,
• Christiane Höppener,
• Ulrich S. Schubert and
• Stephanie Hoeppener

Beilstein J. Nanotechnol. 2021, 12, 541–551, doi:10.3762/bjnano.12.44

• gaps which can particularly enhance the Raman intensities. Consequently, a lot of research and development efforts have been devoted to the fabrication of high-performance substrates following a wide range of different design concepts. These include, for example, the assembly of colloidal nanoparticles

Influence of the magnetic nanoparticle coating on the magnetic relaxation time

• Mihaela Osaci and
• Matteo Cacciola

Beilstein J. Nanotechnol. 2020, 11, 1207–1216, doi:10.3762/bjnano.11.105

• fill in this gap, this study presents a numerical simulation model that elucidates how the nanoparticle coating affects the nanoparticle agglomeration tendency as well as the effective magnetic relaxation time of the system. To simulate the self-organization of the colloidal nanoparticles, a stochastic

• thickness of the surfactant coating layer and the density of the polymer surface layer influence both the Néel relaxation time and the effective magnetic relaxation time in a system consisting of magnetic nanoparticles suspended in a liquid matrix. To simulate the self-organization of the colloidal

• nanoparticles we used a stochastic method called the Langevin dynamics, which is based on an effective Verlet-type algorithm. To simulate the Néel relaxation time we used the Coffey solution in an oblique magnetic field, adapted to the local magnetic field on a nanoparticle (Equation 1). The effective magnetic

Photothermally active nanoparticles as a promising tool for eliminating bacteria and biofilms

• Mykola Borzenkov,
• Piersandro Pallavicini,
• Angelo Taglietti,
• Laura D’Alfonso,
• Maddalena Collini and
• Giuseppe Chirico

Beilstein J. Nanotechnol. 2020, 11, 1134–1146, doi:10.3762/bjnano.11.98

• as the FDA-approved Prussian blue nanoparticles, should be explored more systematically. Secondly, given the imposed restrictions on the use of colloidal nanoparticles due to long-term stability and reusability issues, alternative approaches such as nanocomposite materials (e.g., gels, thin films

The role of Ag⁺, Ca²⁺, Pb²⁺ and Al³⁺ adions in the SERS turn-on effect of anionic analytes

• Stefania D. Iancu,
• Andrei Stefancu,
• Vlad Moisoiu,
• Loredana F. Leopold and
• Nicolae Leopold

Beilstein J. Nanotechnol. 2019, 10, 2338–2345, doi:10.3762/bjnano.10.224

• − showing a high affinity for the silver surface. The colloidal nanoparticles used here are surrounded by citrate anions in an electrostatic interaction with the silver surface, which confer the nanoparticles a negative zeta potential and thus electrostatically stabilize the AgNPs and prevent aggregation

Enhancement of X-ray emission from nanocolloidal gold suspensions under double-pulse excitation

• Wei-Hung Hsu,
• Frances Camille P. Masim,
• Armandas Balčytis,
• Hsin-Hui Huang,
• Tetsu Yonezawa,
• Aleksandr A. Kuchmizhak,
• Saulius Juodkazis and
• Koji Hatanaka

Beilstein J. Nanotechnol. 2018, 9, 2609–2617, doi:10.3762/bjnano.9.242

• for bulk gold [39] as well as the fragmentation thresholds for gold colloidal nanoparticles in water [40][41]. It should be stressed out that the increase of the effective size of the laser spot due to filamentation can significantly reduce the incident fluence [3][4]. However, it is reasonable to

SERS active Ag–SiO₂ nanoparticles obtained by laser ablation of silver in colloidal silica

• Cristina Gellini,
• Francesco Muniz-Miranda,
• Alfonso Pedone and
• Maurizio Muniz-Miranda

Beilstein J. Nanotechnol. 2018, 9, 2396–2404, doi:10.3762/bjnano.9.224

• silver, but that can undergo SERS enhancement thanks to the vicinal presence of silver nanoparticles. The Ag–SiO2 colloidal nanoparticles also show an efficient SERS response for organic ligands such as 2,2'-bipyridine at a laser excitation wavelength of 1064 nm. The possibility to observe FT-SERS

• calculations, can also explain the SERS effect obtained by NIR excitation, even if the excitation radiation does not match the plasmonic band of the silver nanoparticles. In conclusion, a simple method is proposed to obtain Ag-doping of silica colloidal nanoparticles, avoiding complicated procedures and

• ) and Ag-doped silica suspension before (B) and after addition of bpy (C). TEM micrographs of silica colloidal nanoparticles after laser ablation of silver. SERS spectra of bpy in Ag-doped silica colloid by excitation with the 514 nm (B) and 1064 nm (C) laser lines. The Raman spectrum of silica (514 nm

The role of adatoms in chloride-activated colloidal silver nanoparticles for surface-enhanced Raman scattering enhancement

• Nicolae Leopold,
• Andrei Stefancu,
• Krisztian Herman,
• István Sz. Tódor,
• Stefania D. Iancu,
• Vlad Moisoiu and
• Loredana F. Leopold

Beilstein J. Nanotechnol. 2018, 9, 2236–2247, doi:10.3762/bjnano.9.208

• spectroscopy. When the SERS effect is explained in terms of the electromagnetic mechanism, an aggregating effect of the colloidal nanoparticles is attributed to the chloride ions [6], whereas in the chemical mechanism, a so-called activation effect is attributed to the chloride ions [7]. The electromagnetic

Dumbbell gold nanoparticle dimer antennas with advanced optical properties

• Janning F. Herrmann and
• Christiane Höppener

Beilstein J. Nanotechnol. 2018, 9, 2188–2197, doi:10.3762/bjnano.9.205

• box of nanoparticles made of different materials, shapes and sizes. In addition, the crystallinity of these structures leads to the formation of facets, edges and corners. Using colloidal nanoparticles, their chemical assembly demands for certain properties of the specific linker molecules [46]. In

Interaction-tailored organization of large-area colloidal assemblies

• Silvia Rizzato,
• Elisabetta Primiceri,
• Anna Grazia Monteduro,
• Adriano Colombelli,
• Angelo Leo,
• Maria Grazia Manera,
• Roberto Rella and
• Giuseppe Maruccio

Beilstein J. Nanotechnol. 2018, 9, 1582–1593, doi:10.3762/bjnano.9.150

• distances and indicates the achievement of a long-range order. Once the parameters required for the assembly of colloidal nanoparticles in regular 2D arrays were identified, their functional role as masks for the realization of metal nanostructure arrays on planar substrates was investigated, in view of

Room-temperature single-photon emitters in titanium dioxide optical defects

• Kelvin Chung,
• Yu H. Leung,
• Chap H. To,
• Aleksandra B. Djurišić and
• Snjezana Tomljenovic-Hanic

Beilstein J. Nanotechnol. 2018, 9, 1085–1094, doi:10.3762/bjnano.9.100

• found on films. It is typical for the sub-bandgap excitation at 532 nm wavelength used here. Previous work by Mathew et al. [61] on TiO2 anatase colloidal nanoparticles has shown fluorescence spectra with distinct emission peaks in the visible spectrum between 400 and 600 nm. Mathew et al. also

Tuning adhesion forces between functionalized gold colloidal nanoparticles and silicon AFM tips: role of ligands and capillary forces

• Sven Oras,
• Sergei Vlassov,
• Marta Berholts,
• Rünno Lõhmus and
• Karine Mougin

Beilstein J. Nanotechnol. 2018, 9, 660–670, doi:10.3762/bjnano.9.61

• , France Department of Physics and Astronomy, University of Turku, FIN-20014 Turku, Finland 10.3762/bjnano.9.61 Abstract Adhesion forces between functionalized gold colloidal nanoparticles (Au NPs) and scanning probe microscope silicon tips were experimentally investigated by atomic force microscopy (AFM

• have strong influence on the intermolecular interactions between the silicon tip and the Au NPs. Adhesion of Au colloidal nanoparticles Freshly prepared NPs were drop-casted onto a silicon wafer and dried as described in the experimental section. Topography and adhesion of the NPs were measured by AFM

Substrate and Mg doping effects in GaAs nanowires

• Perumal Kannappan,
• Nabiha Ben Sedrine,
• Jennifer P. Teixeira,
• Maria R. Soares,
• Bruno P. Falcão,
• Maria R. Correia,
• Nestor Cifuentes,
• Emilson R. Viana,
• Marcus V. B. Moreira,
• Geraldo M. Ribeiro,
• Alfredo G. de Oliveira,
• Juan C. González and
• Joaquim P. Leitão

Beilstein J. Nanotechnol. 2017, 8, 2126–2138, doi:10.3762/bjnano.8.212

• growth mechanism by drop-coating the substrate with Au colloidal nanoparticles with average diameter of 5.0 ± 0.5 nm. The growth was performed at 615 °C for 90 min, under an As4 beam equivalent pressure (BEP) of 3.8 × 10−5 torr and Ga BEP of 7.2 × 10−7 torr. The Mg doping of the nanowires was achieved by

Nanotopographical control of surfaces using chemical vapor deposition processes

• Meike Koenig and
• Joerg Lahann

Beilstein J. Nanotechnol. 2017, 8, 1250–1256, doi:10.3762/bjnano.8.126

• feed. Trujillo et al. produced polymeric nanostructures using colloidal lithography [12]. In this technique, two-dimensional self-assembled monolayer (SAM) arrays of colloidal nanoparticles serve as lithographic templates for “nanobowl” patterns in an initiated chemical vapor deposition (iCVD) process

Streptavidin-coated gold nanoparticles: critical role of oligonucleotides on stability and fractal aggregation

• Roberta D'Agata,
• Pasquale Palladino and
• Giuseppe Spoto

Beilstein J. Nanotechnol. 2017, 8, 1–11, doi:10.3762/bjnano.8.1

• in contact with free biotin is caused by the displaced BiotinDNA and is not dependent on the high concentration of free biotin (up to 1.28 mM). Displaced BiotinDNA brings negatively charged oligonucleotide strands in solution thus altering the electrostatic environment around colloidal nanoparticles

Chemiresistive/SERS dual sensor based on densely packed gold nanoparticles

• Sanda Boca,
• Cosmin Leordean,
• Simion Astilean and
• Cosmin Farcau

Beilstein J. Nanotechnol. 2015, 6, 2498–2503, doi:10.3762/bjnano.6.259

• demonstrated by the detection of a biologically relevant model analyte, 4-mercaptophenyl boronic acid. Keywords: colloidal nanoparticles; convective self-assembly; interparticle gaps; surface enhanced Raman scattering; chemiresistor; Introduction The development of optical sensors is still following an

• : for FA-capped nanoparticles (21 nm) the obtained hydrodynamic diameter was larger than for bare colloidal nanoparticles (18 nm) (Figure S2, Supporting Information File 1). Zeta potential measurements of the concentrated suspension show an average value of ζ = −32 mV, which prove a good electrostatic

• HAuCl4·3H2O was boiled. A solution of 38.8·10−3 M sodium citrate (10 mL) was added under stirring. After the color changed from yellow to burgundy-red, the heat was stopped, and stirring continued until the colloid reached room temperature. Folic acid was mixed with the colloidal nanoparticles and

Selective porous gates made from colloidal silica nanoparticles

• Roberto Nisticò,
• Paola Avetta,
• Paola Calza,
• Debora Fabbri,
• Giuliana Magnacca and
• Dominique Scalarone

Beilstein J. Nanotechnol. 2015, 6, 2105–2112, doi:10.3762/bjnano.6.215

• were obtained, suggesting possible applications of these nanoporous films as selective gates for controlled transport of chemical species in solution. Keywords: block copolymers; coatings; colloidal nanoparticles; silica; sol–gel synthesis; Introduction The development of smart nanoporous devices for

• proved to generate a variety of well-ordered materials by self-assembling processes [31][32][33][34][35]. Here, we describe the synthesis, deposition and physicochemical characterization of silica coatings, obtained by spin-coating deposition of soft-templated silica colloidal nanoparticles onto

Characterization of nanostructured ZnO thin films deposited through vacuum evaporation

• Jose Alberto Alvarado,
• Arturo Maldonado,
• Héctor Juarez,
• Mauricio Pacio and
• Rene Perez

Beilstein J. Nanotechnol. 2015, 6, 971–975, doi:10.3762/bjnano.6.100

• , Benemérita Universidad Autónoma de Puebla, Ciudad Universitaria Avenida San Claudio y 14 Sur, 72570, Puebla, México 10.3762/bjnano.6.100 Abstract This work presents a novel technique to deposit ZnO thin films through a metal vacuum evaporation technique using colloidal nanoparticles (average size of 30 nm

• was chosen because is easy to handle and only the deposition time is considered a control parameter. Another reason is the use of colloidal nanoparticles with well-controlled size, which were synthesized at the laboratory of the authors [13]. Experimental The proposed thin film deposition is a novel

• The authors successfully deposited worm-shaped nanostructured thin films by vacuum evaporation using colloidal nanoparticles as the source. The transmittance for annealed thin film is up to 80%, and this result is directly correlated with the annealing. The obtained thin films have a thickness between

SERS and DFT study of copper surfaces coated with corrosion inhibitor

• Maurizio Muniz-Miranda,
• Francesco Muniz-Miranda and
• Stefano Caporali

Beilstein J. Nanotechnol. 2014, 5, 2489–2497, doi:10.3762/bjnano.5.258

• SERS activation was ensured by the deposition of silver colloidal nanoparticles on the copper substrate where the organic molecules were already stable and present due to chemisorption [9][10][11]. Regardless, it must be taken into account that the deposited silver particles, in addition to promoting

Biopolymer colloids for controlling and templating inorganic synthesis

• Laura C. Preiss,
• Katharina Landfester and
• Rafael Muñoz-Espí

Beilstein J. Nanotechnol. 2014, 5, 2129–2138, doi:10.3762/bjnano.5.222

• nanoparticles [7]. In a different approach, biopolymers can also be applied to modify surfaces and induce the deposition of nanoparticles. For instance, Nochomovitz et al. [8] described the deposition and patterning of gold colloidal nanoparticles and carbon nanotubes on surfaces previously modified with