Beilstein J. Nanotechnol.2025,16, 128–140, doi:10.3762/bjnano.16.12
hydrolysis medium.
Keywords: 2D zeolite; hierarchicalporosity; mordenite; TEOT; TiO2; titanium tetraethoxide; Introduction
Zeolites are important heterogeneous catalysts in various industrial processes. More and more functional materials based on zeolites are being searched for, including zeolites with
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Figure 1:
(a) Small-angle powder patterns for the parent compound MOR-L and the samples after TEOT hydrolysis...
Beilstein J. Nanotechnol.2020,11, 240–251, doi:10.3762/bjnano.11.18
sample is characterized by a combination of type–IV and type–I isotherms, indicating the presence of micro- and mesopores with monolayer–multilayer adsorption. Furthermore, two distinct pore distribution curves are observed in the inset of Figure 5c revealing a hierarchicalporosity: micro/mesopores
smaller than 5 nm and meso/macropores with diameters of 20–60 nm. As shown in Table 1, the NiMoO4@Co3O4/CA sample has the largest SBET of 334.47 m2/g and Vtotal of 0.8 cm3/g, much higher than that of CA (87.7 m2/g, 0.3 cm3/g) and NiMoO4/CA (94.9 m2/g, 0.4 cm3/g). The hierarchicalporosity and large
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Figure 1:
Schematic illustration of the preparation of the uniform hierarchical NiMoO4@Co3O4/CA sample.