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Search for "nucleation" in Full Text gives 349 result(s) in Beilstein Journal of Nanotechnology. Showing first 200.
Pulsed laser in liquid grafting of gold nanoparticle–carbon support composites
Beilstein J. Nanotechnol. 2025, 16, 349–361, doi:10.3762/bjnano.16.26
- composites as cathodes in electrocatalytic aqueous bicarbonate reduction and compared their performance and electrical impedance to analogous electrodes that were conventionally prepared by electrostatically attaching commercial nucleation grown and citrate-capped gold nanoparticles to carbon fiber paper
- ns, 532 nm, and 87 mJ·cm−2 pulses. We employed 532 nm pulses because gold nanoparticle generation works well at that wavelength, as nanoparticle nucleation and growth take advantage of this laser wavelength being resonant with the surface plasmon resonance in gold nanoparticles [25]. For 532 nm
- that our laser fluence did not enable carbon sublimation. Stable gold colloids have been produced by reactive nanosecond laser irradiation of aqueous [AuCl4]– solutions [29][30]. Colloidal gold nanoparticle formation occurred by nucleation of reduced (metallic) gold atoms [25][31][32]. As in pulsed
Tailoring of physical properties of RF-sputtered ZnTe films: role of substrate temperature
Beilstein J. Nanotechnol. 2025, 16, 333–348, doi:10.3762/bjnano.16.25
- steps, namely, condensation, nucleation, and crystallization on the substrate surface. The mobility of atoms on the substrate surface is very much affected by the substrate temperature. At low substrate temperatures, because of the low diffusion rate and low mobility of atoms, columnar microstructures
Radiosensitizing properties of dual-functionalized carbon nanostructures loaded with temozolomide
Beilstein J. Nanotechnol. 2025, 16, 229–251, doi:10.3762/bjnano.16.18
- the ectopic (acentrosomal) microtubule nucleation was observed, with disassembly of the centrosome and a cytoskeletal reorganization that trigger the generation of ineffective biomechanical forces, which leads to migration defects, and ultimately to spindle-assembly checkpoint blockage and apoptosis
A review of metal-organic frameworks and polymers in mixed matrix membranes for CO2 capture
Beilstein J. Nanotechnol. 2025, 16, 155–186, doi:10.3762/bjnano.16.14
- another polymer solution with 2-methylimidazole. Nucleation and MOF growth occurred in situ within the polymer matrix upon combining the two precursor solutions. This approach resulted in nearly perfect MOF–polymer interfaces in an 8 wt % ZIF-8 MMM. For evaluating the gas separation performance, the
Bioinspired nanofilament coatings for scale reduction on steel
Beilstein J. Nanotechnol. 2025, 16, 25–34, doi:10.3762/bjnano.16.3
- . This reduction is attributed to altered flow dynamics near the super-hydrophobic surface, inhibiting nucleation and growth of scale. Our findings highlight the potential of bioinspired SNF coatings to enhance the performance and longevity of steel surfaces in industrial environments. Keywords
- in the bulk solution or heterogeneously on material surface [25]. Once nucleation occurs, calcium carbonate crystals start to grow. The growth process involves the continuous deposition of Ca2+ and CO32− ions onto the surface-bound nuclei. Over time, these crystals increase in size and adhere more
- interfaces, the flow velocity is assumed to be zero when modeling viscous drag, on super-hydrophobic surfaces the shear is reduced, leading to slip of the liquid across the surfaces and a non-zero flow velocity [26]. Flow at the material interface can hinder or prevent settling, nucleation, and growth of
Fabrication of hafnium-based nanoparticles and nanostructures using picosecond laser ablation
Beilstein J. Nanotechnol. 2024, 15, 1639–1653, doi:10.3762/bjnano.15.129
- is due to the suppression of nucleation [43][49]. Thus, a mix of amorphous and polycrystalline structures in NPs obtained in DW is seen. The formation of these HfO2 NPs and nanofibres is responsible for the turbid white colour observed after ablation in DW. Earlier reports on Hf ablation in toluene
Heterogeneous reactions in a HFCVD reactor: simulation using a 2D model
Beilstein J. Nanotechnol. 2024, 15, 1627–1638, doi:10.3762/bjnano.15.128
- regarding the filaments (2300 K), compared with other CVD reactors like low-pressure CVD (800 K). Hence, diffusion is expected to dominate the reactions for the formation of the precursor species. The growth of SiOx films is controlled by nucleation effects. According to results for high temperatures over
- 700 K, the supersaturation is high and the nucleation is homogeneous in the process, leading to the precipitation of solid particles on the substrate and powder formation [23]. SiOx powders are obtained in the HFCVD reactor when the distance between the filaments and the source is less than 6 mm
- . According to what was discussed above, the distance decreases the temperature, increases the size of the clusters, and decreases the diffusion of the species, resulting in powder formation. Heterogeneous nucleation on the substrate promotes the growth of SiOx films. The distance between the filaments and
Effect of radiation-induced vacancy saturation on the first-order phase transformation in nanoparticles: insights from a model
Beilstein J. Nanotechnol. 2024, 15, 1453–1472, doi:10.3762/bjnano.15.117
- incorporate nucleation through the appearance and growth of the nucleus of a new phase, resulting in the formation of a two-phase α+β system, and we highlight the importance of accounting for nucleation. Our model study reveals that very small α-phase particles are unstable (while very small β-phase particles
- cannot occur regardless of irradiation because of bulk driving forces; initially, α-phase particles are stable, whereas the β-phase particles are unstable. In some cases, nucleation requires a large additional energy change, resulting in a low probability of phase change fluctuations. This behavior is
- materials. Keywords: α-phase; β-phase; chemical rate theory; Fe; nanoparticle; nucleation; phase stability diagram; polymorphic phase transision; radiation stability; thermodynamics; vacancy saturation; Introduction Solid metal or ceramic nanoparticles with a diameter in the range of 1–100 nm, when placed
Nanoarchitectonics with cetrimonium bromide on metal nanoparticles for linker-free detection of toxic metal ions and catalytic degradation of 4-nitrophenol
Beilstein J. Nanotechnol. 2024, 15, 1312–1332, doi:10.3762/bjnano.15.106
- synthesized using wet chemical reduction, as shown in Figure 1a. A unique feature of CTAB is its robust and selective binding to certain crystal facets of metal surfaces that define the growth and nucleation of nanoparticles. CTAB on metal surfaces plays a key role in nanoparticle stabilization but hinders
Mn-doped ZnO nanopowders prepared by sol–gel and microwave-assisted sol–gel methods and their photocatalytic properties
Beilstein J. Nanotechnol. 2024, 15, 1283–1296, doi:10.3762/bjnano.15.104
- nucleation in a supersaturated solution) can be experimentally identified [18] and correlated with specific parameters of the systems exposed to microwaves [18][19][20]. For instance, the use of microwaves in nanoparticle production may increase the reaction rate, also contributing to a narrow particle size
Enhanced catalytic reduction through in situ synthesized gold nanoparticles embedded in glucosamine/alginate nanocomposites
Beilstein J. Nanotechnol. 2024, 15, 1227–1237, doi:10.3762/bjnano.15.99
- particular, have demonstrated significant control over the nucleation and growth of metallic nanoparticles. Utilizing polysaccharide-mediated procedures for AuNP synthesis offers several advantages over conventional methods, including cost-effectiveness, energy efficiency, low toxicity, and eco-friendliness
Effect of wavelength and liquid on formation of Ag, Au, Ag/Au nanoparticles via picosecond laser ablation and SERS-based detection of DMMP
Beilstein J. Nanotechnol. 2024, 15, 1054–1069, doi:10.3762/bjnano.15.86
- with water. The expanding metal/water mixture promotes rapid nucleation and growth of small metal NPs and contributes to forming a cavitation bubble. The hot metal layer also breaks into larger droplets due to instabilities, creating NPs of different sizes within a few nanoseconds of laser exposure [6
- solution than in those fabricated in DW. The size reduction effect observed during ablation in aqueous NaCl solution can be attributed to Cl− ions [55][57]. When a laser ablation process is conducted in the presence of NaCl, the ions in the solution can strongly influence nucleation processes and growth in
Atomistic insights into the morphological dynamics of gold and platinum nanoparticles: MD simulations in vacuum and aqueous media
Beilstein J. Nanotechnol. 2024, 15, 995–1009, doi:10.3762/bjnano.15.81
- scattering [23], and optical microscopy [24], have provided accurate estimates of nucleation rates and critical nucleation sizes, but little data have been produced for the sub-micrometer size regime regarding crystal facet formation and the mechanism of crystal growth. Moreover, a fundamental prerequisite
- adapting theories suitable for bulk materials to NPs; examples include the classical nucleation theory [33], phenomenological models [34][35][36], as well as molecular simulations [37][38][39][40]. A molecular dynamics (MD) study of shape transformation and melting of tetrahexahedral Pt NPs has been
- clusters consisting of 1157 atoms [51]. Some light on the microscopic origin of the anisotropic growth of gold NPs has been cast via molecular dynamics simulations [52]. In a similar way, Lümmen and Kraska investigated the homogeneous nucleation and cluster growth of Pt clusters from supersaturated vapour
Synthesis of silver–palladium Janus nanoparticles using co-sputtering of independent sources: experimental and theorical study
Beilstein J. Nanotechnol. 2024, 15, 808–816, doi:10.3762/bjnano.15.67
- addition, Pd–Ag alloys form during the Pd nucleation in an environment with Ag atoms. Therefore, other Janus nanoparticles can be composed of Ag/AgPd or Ag/AgPd/Pd, where the AgPd alloy could be on one side of the particle (labeled as Ag/AgPd) or between Ag and Pd (labeled as Ag/AgPd/Pd). Considering such
Effect of repeating hydrothermal growth processes and rapid thermal annealing on CuO thin film properties
Beilstein J. Nanotechnol. 2024, 15, 743–754, doi:10.3762/bjnano.15.62
- silicon (100) substrates (Siegert Wafer). These substrates were covered with a nucleation layer in the form of gold nanoislands sputtered using a turbomolecular-pumped coater Quorum Q150T ES. CuO films were obtained according to the following procedure. First, an aqueous solution of copper(II) acetate
- procedure are denoted as “1×”, “2×”, and “3×”, depending on the number of HT+RTA cycles. It is worth highlighting that re-executing the hydrothermal processes does not necessitate any supplementary preparation of samples, for example, surface re-nucleation. Measurement equipment CuO thin films were
Laser synthesis of nanoparticles in organic solvents – products, reactions, and perspectives
Beilstein J. Nanotechnol. 2024, 15, 638–663, doi:10.3762/bjnano.15.54
- % for gold [68][69] to a completely oxidized bulk volume, for example, for nickel [70]. In contrast, laser reduction in water leads to the reduction of metal salts and, thus, to the nucleation of metallic nanoparticles [36][71]. Hence, water acts as an oxidizing agent in the context of LAL, LFL, and LML
- enhanced by the Au nanoparticles resulting from LRL, producing the previously mentioned C1–C5 products. In addition to this, the authors found a difference regarding the nucleation of Ag nanoparticles depending on the used solvent. For the formation of Ag nanoparticles during LRL in isopropyl alcohol, they
Directed growth of quinacridone chains on the vicinal Ag(35 1 1) surface
Beilstein J. Nanotechnol. 2024, 15, 556–568, doi:10.3762/bjnano.15.48
- with the (100) surface. At 300 K, the chains grow across the Ag steps, which do not break the azimuthal chain orientations. In contrast, during the deposition at sample temperatures of 400 and 500 K, the nucleation of the chains takes place at the Ag step edges. Hence, these have a strong influence on
- structures after deposition at 300 K is the absence of the orientations B and D, which confirms above LEED results. This symmetry break can only be explained by the step edges and is a strong indication that, at 400 K, the nucleation of the chains proceeds now from the Ag step edges. The molecules in chains
TEM sample preparation of lithographically patterned permalloy nanostructures on silicon nitride membranes
Beilstein J. Nanotechnol. 2024, 15, 1–12, doi:10.3762/bjnano.15.1
- (nucleation field), the bright spot appears near the edge of the disks. The same observation was made as we applied the opposite field direction until saturation and started decreasing it. The saturation field is larger than the nucleation field, which agrees with other works [7][8][33]. Off-axis electron
- objective-lens field. The vortex state started with counterclockwise helicity and moved perpendicular to the applied field. The magnetization before and after saturation was not similar under an external field of 335 Oe since nucleation started after the external field decreased to around 300 Oe. The
Sulfur nanocomposites with insecticidal effect for the control of Bactericera cockerelli
Beilstein J. Nanotechnol. 2023, 14, 1106–1115, doi:10.3762/bjnano.14.91
- larger and smaller clusters, whose diameters can be estimated from the density function in Figure 3b. The formation process appears to be influenced by two key steps, namely nucleation and growth. They are crucial in the formation of nanoparticles and control various properties of the final product, such
- processes that involve classical nucleation, aggregation, and/or Ostwald ripening [38]. Figure 6 shows a STEM micrograph of the nanomicellar structure of a rosemary NCMP composed of two immiscible phases, that is, (a) the aqueous phase formed by the sulfur nanoparticles and (b) the oily phase formed by
Density functional theory study of Au-fcc/Ge and Au-hcp/Ge interfaces
Beilstein J. Nanotechnol. 2023, 14, 1093–1105, doi:10.3762/bjnano.14.90
- structure; hexagonal gold; interface energy; Introduction Heterophase interfaces are responsible for unique properties of many advanced devices designed for electronics and other applications [1]. Understanding the formation and energetics of interfaces is highly important for the nucleation of new
Upscaling the urea method synthesis of CoAl layered double hydroxides
Beilstein J. Nanotechnol. 2023, 14, 927–938, doi:10.3762/bjnano.14.76
- alkalinization rates and, concomitantly, the precipitation, even under recrystallization at high temperatures. In contrast, for the tenfold mass scale-up, similar morphological features were observed and assigned to changes in nucleation and growth. However, at higher concentrations, simonkolleite-like Co-based
- alkalinization rate, which (mainly) controls the nucleation and growth processes, and therefore particle size, morphology, and crystallinity [33][36][37]. Attempts to upscale the production of LDHs included incrementing the concentration of the reactants [38][39], the use of large-scale reactors [40][41], byway
- differences in the nucleation and growth processes because of increased concentration and ionic strength of the reagents, modifying the whole precipitation process [33]. However, the differences are surprising in the case of the volumetric scale-up approach where the initial concentrations were kept constant
Two-dimensional molecular networks at the solid/liquid interface and the role of alkyl chains in their building blocks
Beilstein J. Nanotechnol. 2023, 14, 872–892, doi:10.3762/bjnano.14.72
- proposed to act as precursors for nucleation on the surface, resulting in the induction of handedness in the 2D network. Chiral network formation was also demonstrated by installing chiral alkyl chains in the DBA [148][149][150][151] and 5-(benzyloxy)isophthalic acid cores [152]. 7 Other effects 7.1
Control of morphology and crystallinity of CNTs in flame synthesis with one-dimensional reaction zone
Beilstein J. Nanotechnol. 2023, 14, 741–750, doi:10.3762/bjnano.14.61
- graphene sheets on the surface [18][19]. In flame synthesis, the rapid heating rate causes catalytic activation and nucleation to occur almost instantaneously by the arrangement of carbon atoms on the surface of catalyst nanoparticles, leading to cap formation and liftoff. Figure 2b and Figure 2d show
ZnO-decorated SiC@C hybrids with strong electromagnetic absorption
Beilstein J. Nanotechnol. 2023, 14, 565–573, doi:10.3762/bjnano.14.47
- amorphous state (Figure 2e). The carbon shell may have a positive effect on the nucleation of ZnO particles. This is because oxygen-containing functional groups (such as carboxyl and hydroxy groups) and structural defects are generated on the SiC@C surface during the in situ carbonization [24], which both
- hybrids can be adjusted by changing the dosage of ZnNO3·6H2O. The amorphous carbon shell has a significant effect on the nucleation of crystalline ZnO particles, possibly due to oxygen-containing functional groups (such as carboxyl and hydroxy groups) and defects on the SiC@C surface, which both provide
Plasmonic nanotechnology for photothermal applications – an evaluation
Beilstein J. Nanotechnol. 2023, 14, 380–419, doi:10.3762/bjnano.14.33
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