Heat-induced transformation of nickel-coated polycrystalline diamond film studied in situ by XPS and NEXAFS

• Olga V. Sedelnikova,
• Yuliya V. Fedoseeva,
• Dmitriy V. Gorodetskiy,
• Yuri N. Palyanov,
• Elena V. Shlyakhova,
• Eugene A. Maksimovskiy,
• Anna A. Makarova,
• Lyubov G. Bulusheva and
• Aleksandr V. Okotrub

Beilstein J. Nanotechnol. 2025, 16, 887–898, doi:10.3762/bjnano.16.67

• structure (NEXAFS) methods are noncontact and nondestructive methods to investigate the chemical state of the elements on the surface and in the bulk of solids. The signals collected over a large surface area provide overall insight into the surface state. Moreover, the polarization-dependence of NEXAFS

• oriented perpendicular to this plane [53]. The difference in the polarization of π- and σ-electrons explains the dependence of NEXAFS spectra of graphitic materials on the angle of incidence of the radiation. Thus, it can be concluded that the orientation of graphitic layers is predominantly vertical

• Russian–German dipole beamline (RGBL dipole) of the Berliner Elektronenspeicherring für Synchrotronstrahlung (BESSY II) operated by the Helmholtz-Zentrum Berlin für Materialien und Energie (Berlin, Germany) [55]. Light polarization at the RGBL dipole is linearly horizontal. The samples were fixed in pairs

Insights into the electronic and atomic structures of cerium oxide-based ultrathin films and nanostructures using high-brilliance light sources

• Paola Luches and
• Federico Boscherini

Beilstein J. Nanotechnol. 2025, 16, 860–871, doi:10.3762/bjnano.16.65

• density of empty states of the investigated sample. In contrast, the extended energy range X-ray absorption fine structure (EXAFS), up to a few hundred electronvolts above the absorption edge, is sensitive to the local atomic structure around the absorbers. A polarization-dependent Ce L3-edge EXAFS study

Facile one-step radio frequency magnetron sputtering of Ni/NiO on stainless steel for an efficient electrode for hydrogen evolution reaction

• Ha Huu Do,
• Khac Binh Nguyen,
• Phuong N. Nguyen and
• Hoai Phuong Pham

Beilstein J. Nanotechnol. 2025, 16, 837–846, doi:10.3762/bjnano.16.63

• mapping of the Ni/NiO/SS-10 sample. (a) Survey XPS spectrum of Ni/NiO/SS-10. High-resolution XPS spectra of (b) Ni 2p3/2 and (c) O 1s. (a) Polarization curves of SS, Ni/NiO/SS-5, Ni/NiO/SS-10, Ni/NiO/SS-15, and Ni/NiO/SS-20 electrodes. (b) Corresponding Tafel slopes of electrodes. (c) Nyquist plots of

• /NiO/SS-20 electrodes at an overpotential of 200 mV. (c) Potential–time response of the Ni/NiO/SS-10 electrode measured over a period of 12 h. Inset: Polarization curves recorded initially and after 2000 CV cycles of the Ni/NiO/SS-10 electrode. (d) Chronoamperometric curve of Ni/NiO/SS-10 electrode

Changes of structural, magnetic and spectroscopic properties of microencapsulated iron sucrose nanoparticles in saline

• Sabina Lewińska,
• Pavlo Aleshkevych,
• Roman Minikayev,
• Anna Bajorek,
• Mateusz Dulski,
• Krystian Prusik,
• Tomasz Wojciechowski and
• Anna Ślawska-Waniewska

Beilstein J. Nanotechnol. 2025, 16, 762–784, doi:10.3762/bjnano.16.59

Nanoscale capacitance spectroscopy based on multifrequency electrostatic force microscopy

• Pascal N. Rohrbeck,
• Lukas D. Cavar,
• Franjo Weber,
• Peter G. Reichel,
• Mara Niebling and
• Stefan A. L. Weber

Beilstein J. Nanotechnol. 2025, 16, 637–651, doi:10.3762/bjnano.16.49

• way for the design of materials with tailored functionalities [1][2][3][4][5][6]. Dielectric properties are fundamental for understanding the behavior and performance of various material systems, as they directly influence charge storage, polarization, and energy dissipation mechanisms. For instance

• variations influence key properties such as charge transport, polarization dynamics, and defect distributions, directly impacting the performance of microelectronic and energy systems [14][15]. Understanding these effects requires correlating nanoscale dielectric properties with structural and morphological

Retrieval of B1 phase from high-pressure B2 phase for CdO nanoparticles by electronic excitations in Cd_xZn_1−xO composite thin films

• Arkaprava Das,
• Marcin Zając and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2025, 16, 551–560, doi:10.3762/bjnano.16.43

• any polarization effects of the incident laser light. The optically active phonon modes at the center of the Brillouin zone have the following point symmetries: In this equation, the A1 and E1 modes correspond to Raman and infrared (IR) active branches, characterized by polar symmetries that further

N₂⁺-implantation-induced tailoring of structural, morphological, optical, and electrical characteristics of sputtered molybdenum thin films

• Usha Rani,
• Kafi Devi,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 495–509, doi:10.3762/bjnano.16.38

• two parameters ψ and Δ characterize a change in polarization state. ψ denotes the amplitude ratio between p-polarized (parallel to the plane of incidence) and s-polarized (perpendicular to the plane of incidence) light components after interaction with the sample. Δ denotes the phase difference

Size control of nanoparticles synthesized by pulsed laser ablation in liquids using donut-shaped beams

• Abdel Rahman Altakroury,
• Oleksandr Gatsa,
• Farbod Riahi,
• Zongwen Fu,
• Miroslava Flimelová,
• Andrei Samokhvalov,
• Stephan Barcikowski,
• Carlos Doñate-Buendía,
• Alexander V. Bulgakov and
• Bilal Gökce

Beilstein J. Nanotechnol. 2025, 16, 407–417, doi:10.3762/bjnano.16.31

• beams of controlled polarization was performed to produce nanoparticles from metal (gold), oxide (yttrium oxide, Y2O3), and alloy (high-entropy alloy (HEA)) targets. The selected materials are typical representatives of their classes, whose NPs are widely used in applications such as biology and

• was added in front of the S-waveplate to control the polarization state of the donut-shaped pulses between radial and azimuthal. The shapes of the beams were monitored on a temporarily reflected beam branch using a profiler (typical shapes of the Gaussian and donut-shaped beams are shown in Figure 1b

• and Figure 1c, respectively). To monitor the polarization of the donut-shaped beam, an additional Glan–Taylor polarizer was placed in front of the profiler. The spot diameters, 2wo, of the Gaussian beams (where wo is the beam waist) at the sample surface were measured with a silicon target using the

Vortex lattices of layered HTSCs at different vortex–vortex interaction potentials

• Valerii P. Lenkov,
• Anastasia N. Maksimova,
• Anna N. Moroz and
• Vladimir A. Kashurnikov

Beilstein J. Nanotechnol. 2025, 16, 362–370, doi:10.3762/bjnano.16.27

• . A potential different from the classical one is observed for intervortex interaction and in the so-called ferromagnetic superconductors [22]. The polarization of the magnetic moments of the crystal lattice induced by vortices leads to an interaction potential that has a minimum and a maximum (at

Nanocarriers and macrophage interaction: from a potential hurdle to an alternative therapeutic strategy

• Naths Grazia Sukubo,
• Paolo Bigini and
• Annalisa Morelli

Beilstein J. Nanotechnol. 2025, 16, 97–118, doi:10.3762/bjnano.16.10

• innovative strategies to exploit macrophage interactions for therapeutic advantage. Recent advancements in treating liver and lung diseases, particularly focusing on macrophage polarization and RNA-based therapies, have highlighted the potential developments in macrophage–NC interaction. Furthermore, we will

• delve into the intriguing potential of nanomedicine in neurology and traumatology, associated with macrophage interaction, and the exciting possibilities it holds for the future. Keywords: drug delivery; macrophages; nanomedicine; polarization; RNA-based therapies; Review 1 Introduction In the vast

• following degradation in lysosomes using hydrolytic enzymes and reactive oxygen species (ROS). Additionally, macrophages present antigen fragments through major histocompatibility complex (MHC) molecules, activating adaptive immune responses [16]. 2.2 Macrophage polarization Macrophages are involved in

Theoretical study of the electronic and optical properties of a composite formed by the zeolite NaA and a magnetite cluster

• Joel Antúnez-García,
• Roberto Núñez-González,
• Vitalii Petranovskii,
• H’Linh Hmok,
• Armando Reyes-Serrato,
• Fabian N. Murrieta-Rico,
• Mufei Xiao and
• Jonathan Zamora

Beilstein J. Nanotechnol. 2025, 16, 44–53, doi:10.3762/bjnano.16.5

• properties. For the energy convergence criterion, we consider a value of 1 × 10−4 Ry. For a valid comparison, the same values were used to calculate the electronic and optical properties of the isolated magnetite cluster. Finally, spin polarization was considered for both calculations (zeolite-cluster and

• transition from spin up to spin down. Figure 4c displays the TDOS for the magnetite cluster. Notably, it reveals the presence of both spin polarizations at the Fermi level, with the spin-down polarization being the dominant one. This observation is indicative of a ferromagnetic behavior, aligning with the

Orientation-dependent photonic bandgaps in gold-dust weevil scales and their titania bioreplicates

• Norma Salvadores Farran,
• Limin Wang,
• Primoz Pirih and
• Bodo D. Wilts

Beilstein J. Nanotechnol. 2025, 16, 1–10, doi:10.3762/bjnano.16.1

• }-oriented domains exhibits polarization conversion, rotating the angle of linearly polarized light. The overall coloration, resulting from the reflections from many scales, is close to uniformly diffuse because of the random orientation of the domains. Using titania sol–gel chemistry, we produced negative

• customizable photonic bandgaps that might be used in novel optical materials. Keywords: animal coloration; photonic crystal; polarization conversion; sol–gel replication; weevil; Introduction Animal coloration is produced by means of absorption, scattering, luminescence, and interference. The latter is

• . The domains in lattice orientation {100} exhibited polarization conversion. The structure inferred from optical measurements was confirmed using conventional and focused ion beam scanning electron microscopy (FIB-SEM). By averaging the reciprocal space images obtained from different lattice

Fabrication of hafnium-based nanoparticles and nanostructures using picosecond laser ablation

• Abhishek Das,
• Mangababu Akkanaboina,
• Jagannath Rathod,
• R. Sai Prasad Goud,
• Kanaka Ravi Kumar,
• Raghu C. Reddy,
• Ratheesh Ravendran,
• Katia Vutova,
• S. V. S. Nageswara Rao and
• Venugopal Rao Soma

Beilstein J. Nanotechnol. 2024, 15, 1639–1653, doi:10.3762/bjnano.15.129

• properties make Hf metal suitable for laser patterning of sub-wavelength-size structures, and the choice of the liquid for LAL enables the variation of feature size. We have used linearly polarised light in the present study. The orientation of the LIPSS depends on the polarization and rotates with the input

• polarization. The available literature on LIPSS suggests that there will be no changes in the spacing or other morphological features except the orientation of the LIPSS with respect to the polarisation. Combined with the picosecond laser’s high precision processing and industrial scalability, Hf is a

Lithium niobate on insulator: an emerging nanophotonic crystal for optimized light control

• Midhun Murali,
• Amit Banerjee and
• Tanmoy Basu

Beilstein J. Nanotechnol. 2024, 15, 1415–1426, doi:10.3762/bjnano.15.114

• modulation capabilities of lithium niobate coupled with transparency and high refractive index of titanium dioxide, offer a versatile platform for designing devices with controlled polarization, tunable modulation, and well-defined photonic bandgaps [9][13][24]. The complementary nonlinear optical properties

A biomimetic approach towards a universal slippery liquid infused surface coating

• Ryan A. Faase,
• Madeleine H. Hummel,
• AnneMarie V. Hasbrook,
• Andrew P. Carpenter and
• Joe E. Baio

Beilstein J. Nanotechnol. 2024, 15, 1376–1389, doi:10.3762/bjnano.15.111

• –4000 cm−1). Each beam was overlapped in space and time to produce SFG photons at a spot size of approximately 1 mm. Spectra were collected and offset with a 4 cm−1 step size at 200 acquisitions per step. Spectra were collected in an ssp, ppp, and sps polarization combinations (SFG, visible, IR) in a

• in the bulk. A final mode was assigned to the CF3 asymmetric stretching at 1370 cm−1 [46]. Observed changes across the SFG spectra collected with different polarization combinations provide information about the orientation of molecular bonds at the interface [26][27]. Here, by collecting SFG spectra

• 1800 cm−1 from a COC substrate coated with PDA–FDT. The top spectra were collected in ppp, the middle spectra in ssp, and the bottom spectra in sps polarization combinations. FXIIa concentration after 1 h incubation with HMWK and PK on surfaces. Error bars indicate standard deviation, n = 18. COC, PDA

Out-of-plane polarization induces a picosecond photoresponse in rhombohedral stacked bilayer WSe₂

• Guixian Liu,
• Yufan Wang,
• Zhoujuan Xu,
• Zhouxiaosong Zeng,
• Lanyu Huang,
• Cuihuan Ge and
• Xiao Wang

Beilstein J. Nanotechnol. 2024, 15, 1362–1368, doi:10.3762/bjnano.15.109

• .15.109 Abstract Constructing van der Waals materials with spontaneous out-of-plane polarization through interlayer engineering expands the family of two-dimensional ferroelectrics and provides an excellent platform for enhancing the photoelectric conversion efficiency. Here, we reveal the effect of

• spontaneous polarization on ultrafast carrier dynamics in rhombohedral stacked bilayer WSe2. Using precise stacking techniques, a 3R WSe2-based vertical heterojunction was successfully constructed and confirmed by polarization-resolved second harmonic generation measurements. Through output characteristics

• and the scanning photocurrent map under zero bias, we reveal a non-zero short-circuit current in the graphene/3R WSe2/graphene heterojunction region, demonstrating the bulk photovoltaic effect. Furthermore, the out-of-plane polarization enables the 3R WSe2 heterojunction region to achieve an ultrafast

The role of a tantalum interlayer in enhancing the properties of Fe₃O₄ thin films

• Hai Dang Ngo,
• Vo Doan Thanh Truong,
• Van Qui Le,
• Hoai Phuong Pham and
• Thi Kim Hang Pham

Beilstein J. Nanotechnol. 2024, 15, 1253–1259, doi:10.3762/bjnano.15.101

• NTT Hi-Tech Institute, Nguyen Tat Thanh University, 298-300A Nguyen Tat Thanh Street, Ward 13, District 4, Ho Chi Minh City 700000, Vietnam 10.3762/bjnano.15.101 Abstract High spin polarization and low resistivity of Fe3O4 at room temperature have been an appealing topic in spintronics with various

• K [1], as well as its high spin polarization with only one spin at the Fermi level, even at room temperature [2][3][4][5][6]. Fe3O4 thin films are an issue of interest and have extensive applications in Li-ion batteries, spin Seebeck devices, supercapacitors, spin Hall magnetoresistance, and the

AI-assisted models to predict chemotherapy drugs modified with C₆₀ fullerene derivatives

• Jonathan-Siu-Loong Robles-Hernández,
• Dora Iliana Medina,
• Katerin Aguirre-Hurtado,
• Marlene Bosquez,
• Roberto Salcedo and
• Alan Miralrio

Beilstein J. Nanotechnol. 2024, 15, 1170–1188, doi:10.3762/bjnano.15.95

• . Gemcitabine includes an active pyrimidinone fragment as a very reactive zone. The frontier molecular orbitals and the ESP map are shown Supporting Information File 1, Figure S2. Again, there is a strong polarization, which can induce a route for reaction. The ring nitrogen atom in alpha position concerning

Quantum-to-classical modeling of monolayer Ge₂Se₂ and its application in photovoltaic devices

• Anup Shrivastava,
• Shivani Saini,
• Dolly Kumari,
• Sanjai Singh and
• Jost Adam

Beilstein J. Nanotechnol. 2024, 15, 1153–1169, doi:10.3762/bjnano.15.94

• , we can calculate the refractive index and extinction coefficient as Here, and are the conduction and valence band Bloch states with energies and , respectively, r is the position of the electron, and u is the polarization of light. e is the electronic charge, and Ω is the volume. Via the well

Interface properties of nanostructured carbon-coated biological implants: an overview

• Mattia Bartoli,
• Francesca Cardano,
• Erik Piatti,
• Stefania Lettieri,
• Andrea Fin and
• Alberto Tagliaferro

Beilstein J. Nanotechnol. 2024, 15, 1041–1053, doi:10.3762/bjnano.15.85

• roughness, inducing macrophage polarization to the pro-inflammatory state without producing a great excess of pro-inflammatory factors. Furthermore, GO-coated implants showed a reduction of the expression of the fibrosis-related protein α-SMA and collagen deposition in the presence of both fibroblasts and

Entry of nanoparticles into cells and tissues: status and challenges

• Kirsten Sandvig,
• Tore Geir Iversen and
• Tore Skotland

Beilstein J. Nanotechnol. 2024, 15, 1017–1029, doi:10.3762/bjnano.15.83

• another breast cancer xenograft model and found a strong reduction in immunosuppressive function of macrophages [94]. An influence of NPs on macrophage recruitment, differentiation, and polarization has also been reported by others [95][96]. Thus, a combined effect on the tumor cells and the tumor

Ca_n neutral clusters: a two-step G₀W₀ and DFT benchmark

• Sunila Bakhsh,
• Sameen Aslam,
• Muhammad Khalid,
• Muhammad Sohail,
• Sundas Zafar,
• Sumayya Abdul Wadood,
• Kareem Morsy and
• Muhammad Aamir Iqbal

Beilstein J. Nanotechnol. 2024, 15, 1010–1016, doi:10.3762/bjnano.15.82

• ONCV-type multi-projector pseudopotentials for the description of the core ions, which is used in our calculation as provided by the SG15 library [23]. We have therefore set the energy cutoff as 100 Ry for better accuracy. The double-ζ plus polarization (DZP) basis set was used in ABACUS calculations

• , which was tested against the triple-ζ plus double polarization (TZDP) to obtain the total energies of Ca6, Ca7, and Ca8. The convergence plot can be found in Supporting Information File 1, Figure S1. It is worth mentioning that our motivation for the selection of DZP is based on our previously reported

Effect of repeating hydrothermal growth processes and rapid thermal annealing on CuO thin film properties

• Monika Ozga,
• Eunika Zielony,
• Aleksandra Wierzbicka,
• Anna Wolska,
• Marcin Klepka,
• Marek Godlewski,
• Bogdan J. Kowalski and
• Bartłomiej S. Witkowski

Beilstein J. Nanotechnol. 2024, 15, 743–754, doi:10.3762/bjnano.15.62

• × magnification. The spectral resolution was of the order of 0.5 cm−1. A 532 nm semiconductor laser was used to illuminate the samples. The measurements were performed without detection of polarization of the scattered light. A liquid nitrogen-cooled multichannel silicon CCD camera was used as a detector. Results

Cholesterol nanoarchaeosomes for alendronate targeted delivery as an anti-endothelial dysfunction agent

• Horacio Emanuel Jerez,
• Yamila Roxana Simioni,
• Kajal Ghosal,
• Maria Jose Morilla and
• Eder Lilia Romero

Beilstein J. Nanotechnol. 2024, 15, 517–534, doi:10.3762/bjnano.15.46

• (Flowing Software, Finland). Plasma membrane order Effects of nanovesicle uptake on THP-1 macrophages and HUVEC plasma membrane order were determined by measuring the Laurdan generalized polarization (GP) [83]. Briefly, THP-1 macrophages and HUVECs grown at a density of 1–1.5 × 104 cells/cm2 on 96-well

Classification and application of metal-based nanoantioxidants in medicine and healthcare

• Nguyen Nhat Nam,
• Nguyen Khoi Song Tran,
• Tan Tai Nguyen,
• Nguyen Ngoc Trai,
• Nguyen Phuong Thuy,
• Hoang Dang Khoa Do,
• Nhu Hoa Thi Tran and
• Kieu The Loan Trinh

Beilstein J. Nanotechnol. 2024, 15, 396–415, doi:10.3762/bjnano.15.36

• -inflammatory and antioxidant effects, a study by Chen et al. explored the use of Zn NPs to modulate macrophage polarization within atherosclerotic plaques, proving the potential for metal-based materials to actively influence the underlying inflammatory processes [175]. Clinical applications of metal-based