Tailoring of physical properties of RF-sputtered ZnTe films: role of substrate temperature

• Kafi Devi,
• Usha Rani,
• Arun Kumar,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 333–348, doi:10.3762/bjnano.16.25

• SCSA parametric analyser. For this, equally spaced ohmic contacts were made on the surface of the films using silver paste. The characteristics were recorded in the voltage range from −1 V to 1 V. The I–V characteristics are nearly linear and regular in both positive and negative voltage regions. This

Graphene oxide–chloroquine conjugate induces DNA damage in A549 lung cancer cells through autophagy modulation

• Braham Dutt Arya,
• Sandeep Mittal,
• Prachi Joshi,
• Alok Kumar Pandey,
• Jaime E. Ramirez-Vick,
• Govind Gupta and
• Surinder P. Singh

Beilstein J. Nanotechnol. 2025, 16, 316–332, doi:10.3762/bjnano.16.24

• exposure to starch-capped silver nanoparticles (AgNPs) [11]. Gemcitabine-encapsulated poly(lactic-co-glycolic acid) (PLGA) nanoparticles have been shown to enhance cell death in chemoresistant PANC1 cells, human pancreatic epithelial carcinoma cells [12]. Also, TiO2 nanoparticles can sensitize A549 cells

Preferential enrichment and extraction of laser-synthesized nanoparticles in organic phases

• Theo Fromme,
• Maximilian L. Spiekermann,
• Florian Lehmann,
• Stephan Barcikowski,
• Thomas Seidensticker and
• Sven Reichenberger

Beilstein J. Nanotechnol. 2025, 16, 254–263, doi:10.3762/bjnano.16.20

• ) to determine the preferred phase (1-nonanol or propylene carbonate) of the colloidal nanoparticles (Figure 1a,b). For gold and silver, the nanoparticles remained in the propylene carbonate phase, which is the more polar phase, while the nanoparticles made by LAL of aluminum and titanium were found to

• noble metals accumulating in the propylene carbonate phase, while base metals gather in the alcohol phase. The origin of this behavior is likely linked to the chemical composition of the nanoparticle surface. In earlier studies, nanoparticles of the more noble metals (gold, silver, and copper) formed by

• formation is to be expected during the ablation of copper compared to gold and silver, which leads to a decreased polarity of the formed nanoparticles and potentially a higher affinity to less polar solvents. However, the base metals (iron, aluminum, and titanium) show a different behavior during LAL in

Radiosensitizing properties of dual-functionalized carbon nanostructures loaded with temozolomide

• Radmila Milenkovska,
• Nikola Geskovski,
• Dushko Shalabalija,
• Ljubica Mihailova,
• Petre Makreski,
• Dushko Lukarski,
• Igor Stojkovski,
• Maja Simonoska Crcarevska and
• Kristina Mladenovska

Beilstein J. Nanotechnol. 2025, 16, 229–251, doi:10.3762/bjnano.16.18

• chemical modifications and/or coupling with hydrophilic polymers. TMZ was successfully incorporated in magnetic NPs [36], mesoporous silica NPs [37], and NPs made of silver [38], zinc oxide [39], and gold [40], all of them showing high accumulation in tumor cells and cytotoxic activity in vitro and in vivo

Nanocarriers and macrophage interaction: from a potential hurdle to an alternative therapeutic strategy

• Naths Grazia Sukubo,
• Paolo Bigini and
• Annalisa Morelli

Beilstein J. Nanotechnol. 2025, 16, 97–118, doi:10.3762/bjnano.16.10

• ]. In RA, the predominance of M1 macrophages in inflamed joints drives synovitis and cartilage destruction. Yang and colleagues developed folic acid-modified silver nanoparticles (FA-AgNPs) to target M1 macrophages via folate receptor-mediated endocytosis. Once internalized, these NPs scavenged ROS

Instance maps as an organising concept for complex experimental workflows as demonstrated for (nano)material safety research

• Benjamin Punz,
• Maja Brajnik,
• Joh Dokler,
• Jaleesia D. Amos,
• Litty Johnson,
• Katie Reilly,
• Anastasios G. Papadiamantis,
• Amaia Green Etxabe,
• Lee Walker,
• Diego S. T. Martinez,
• Steffi Friedrichs,
• Klaus M. Weltring,
• Nazende Günday-Türeli,
• Claus Svendsen,
• Christine Ogilvie Hendren,
• Mark R. Wiesner,
• Martin Himly,
• Iseult Lynch and
• Thomas E. Exner

Beilstein J. Nanotechnol. 2025, 16, 57–77, doi:10.3762/bjnano.16.7

• based on differences in the particles’ sulfidation levels [35]. We note that the same reasons underpinned its selection for the discussion of instance maps in [28]. The instance map in Figure 3 delineates all steps of the synthesis of sulfidised silver nanoparticles (AgNPs). AgNPs are synthesised with a

• polyvinylpyrrolidone (PVP) surface by reduction of silver nitrate in ethylene glycol with 10k PVP. The PVP-AgNPs are characterised regarding some of their physical attributes such as the particles’ shape, size, and crystalline phase. The particles are then sulfidised using different specified concentrations of the PVP

Facile synthesis of size-tunable L-carnosine-capped silver nanoparticles and their role in metal ion sensing and catalytic degradation of p-nitrophenol

• Akash Kumar,
• Ridhima Chadha,
• Abhishek Das,
• Nandita Maiti and
• Rayavarapu Raja Gopal

Beilstein J. Nanotechnol. 2024, 15, 1576–1592, doi:10.3762/bjnano.15.124

• ʟ-carnosine in synthesizing tunable plasmonic silver nanoparticles (ʟ-car-AgNPs). The formation of ʟ-car-AgNPs was confirmed via UV–vis optical absorption spectroscopy, showing single and double plasmonic peaks, depending on the synthesis conditions. Physicochemical characterization using TEM, FTIR

• with various contaminants. Keywords: catalysis; heavy metals; ʟ-carnosine; p-nitrophenol; silver nanoparticles; Introduction The persistent rise in environmental pollution, notably from heavy metal ions and organic pollutants, has propelled the development of innovative and efficient environmental

• sustainability and public health. Silver nanoparticles (AgNPs) have attracted the interest of researchers worldwide in recent years because of their promising use in environmental chemistry. The unique optochemical properties of AgNPs, including high surface area to volume ratio, optical absorbance, excellent

Green synthesis of silver nanoparticles derived from algae and their larvicidal properties to control Aedes aegypti

• Matheus Alves Siqueira de Assunção,
• Douglas Dourado,
• Daiane Rodrigues dos Santos,
• Gabriel Bezerra Faierstein,
• Mara Elga Medeiros Braga,
• Severino Alves Junior,
• Rosângela Maria Rodrigues Barbosa,
• Herminio José Cipriano de Sousa and
• Fábio Rocha Formiga

Beilstein J. Nanotechnol. 2024, 15, 1566–1575, doi:10.3762/bjnano.15.123

• for ways to control these insects, avoiding the use of conventional chemical insecticides that are proven to be toxic to nature. In the last years, there has been growing evidence for the potential of silver nanoparticles (AgNPs) to be ecologically benign alternatives to the commercially available

• chemical reduction of metal ions through biological compounds can be used to synthesize non-toxic and environmentally safe “green” insecticide alternatives in the form of metal-based nanoparticles [15]. A promising option are silver nanoparticles (AgNPs) obtained through synthesis from natural extracts

• containing secondary metabolites that act as reducing and stabilizing agents. Among these metabolites, alkanes, aromatics, phenols, ethers, amines, and amides stand out for their role in the reduction, stabilization, and capping of silver nanoparticles [11][16][17][18][19]. Compounds of natural origin are

Integrating high-performance computing, machine learning, data management workflows, and infrastructures for multiscale simulations and nanomaterials technologies

• Fabio Le Piane,
• Mario Vozza,
• Matteo Baldoni and
• Francesco Mercuri

Beilstein J. Nanotechnol. 2024, 15, 1498–1521, doi:10.3762/bjnano.15.119

• predictive analysis [71]. Moreover, it is tailored to the safe-by-design paradigm, making it an essential tool for future researches [72]. ASCOT (an acronym derived from Ag-Silver, Copper Oxide, Titanium Oxide) is a tool for the automated construction and optimization of molecular structures for, as the name

• suggests, silver, copper oxide, and titanium oxide [73]. ASCOT assists in the generation of high-quality digital twins of materials and the computation of relevant molecular descriptors. Nanotube Modeler is a software tool designed to create three-dimensional coordinates for various nanoscale carbon

Hymenoptera and biomimetic surfaces: insights and innovations

• Vinicius Marques Lopez,
• Carlo Polidori and
• Rhainer Guillermo Ferreira

Beilstein J. Nanotechnol. 2024, 15, 1333–1352, doi:10.3762/bjnano.15.107

• mechanisms and, consequently, longer life time. Special hairs that may be useful to create surfaces optimized for protection from overheating are those responsible for the silver appearance of the Saharan silver ant Cataglyphis bombycine [51] (Figure 1A). These hairs have a particular, rarely found

• mechanics continues to unlock new possibilities for technological innovation, underscoring the profound impact of nature-inspired designs. Diversity of hymenopteran species showcasing a range of shapes and life strategies. (A) Saharan silver ant (Cataglyphis bombycine) (© 2017 Manuel García-Viñó Sánchez

Nanoarchitectonics with cetrimonium bromide on metal nanoparticles for linker-free detection of toxic metal ions and catalytic degradation of 4-nitrophenol

• Akash Kumar and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2024, 15, 1312–1332, doi:10.3762/bjnano.15.106

• metals and efficient degradation of 4-NP. For enabling linker-free/ligand-free detection of heavy metal ions and catalytic degradation of 4-NP, CTAB was engineered as a versatile capping agent on gold and silver nanoparticles. Various factors, including nanoparticle characteristics such as shape, size

• degrading 94.37% of 4-NP within 1 min. In contrast, silver nanospheres effectively detected Hg2+, Cu2+, and Fe3+ at concentrations as low as 1 ppm and degraded 90.78% of 4-NP within 30 min. Moreover, anisotropic gold nanorods (CTAB-AuNR1 and CTAB-AuNR2) showed promising sensing capabilities towards Cu2

• and silver) nanoprobes are emerging as versatile colorimetric and spectrophotometric nanosensors for rapid detection/degradation of heavy metal ions and toxic pollutants that pose a serious challenge to environment and human health. Globally, acceleration of industrial growth and urbanization led to

Dual-functionalized architecture enables stable and tumor cell-specific SiO₂NPs in complex biological fluids

• Iris Renata Sousa Ribeiro,
• Raquel Frenedoso da Silva,
• Romênia Ramos Domingues,
• Adriana Franco Paes Leme and
• Mateus Borba Cardoso

Beilstein J. Nanotechnol. 2024, 15, 1238–1252, doi:10.3762/bjnano.15.100

• 200 V for 1 h and then the gel was stained with silver nitrate to visualize the bands. PageRuler™ Prestained Protein Ladder (Thermo Scientific) was used as a standard. The DMEM culture medium used for SiO2NP incubation was also added to the gel for comparison purposes. To determine the total protein

Realizing active targeting in cancer nanomedicine with ultrasmall nanoparticles

• André F. Lima,
• Giselle Z. Justo and
• Alioscka A. Sousa

Beilstein J. Nanotechnol. 2024, 15, 1208–1226, doi:10.3762/bjnano.15.98

• modalities of actively targeted usNPs and their current applications in cancer diagnosis and treatment. 2 Inorganic ultrasmall NPs in cancer nanomedicine Important classes of inorganic usNPs under investigation for cancer nanomedicine include metallic usNPs (gold, silver), oxide and sulfide usNPs (silica

Quantum-to-classical modeling of monolayer Ge₂Se₂ and its application in photovoltaic devices

• Anup Shrivastava,
• Shivani Saini,
• Dolly Kumari,
• Sanjai Singh and
• Jost Adam

Beilstein J. Nanotechnol. 2024, 15, 1153–1169, doi:10.3762/bjnano.15.94

• offset and ease of synthesis. The front and back contacts are supposed to be ohmic and are made of silver (Ag) to maintain proper band alignment and reduce the band offset. It has been reported that tuning the CBM and VBM positions to keep a low band offset leads to superior device performance. Figure 6b

Photocatalytic methane oxidation over a TiO₂/SiNWs p–n junction catalyst at room temperature

• Qui Thanh Hoai Ta,
• Luan Minh Nguyen,
• Ngoc Hoi Nguyen,
• Phan Khanh Thinh Nguyen and
• Dai Hai Nguyen

Beilstein J. Nanotechnol. 2024, 15, 1132–1141, doi:10.3762/bjnano.15.92

• . Experimental Chemicals and materials Commercial p-type Si 3-inch wafers (⟨100⟩ orientation, boron-doped, resistivity = 0.01–1 Ω·cm) were purchased from Silicon Mitus Corporation, South Korea. Silver nitrate (AgNO3, 0.1 M), hydrofluoric acid HF (50 wt %), nitric acid (HNO3, 63%), acetone, and ethanol were

Direct electron beam writing of silver using a β-diketonate precursor: first insights

• Katja Höflich,
• Krzysztof Maćkosz,
• Chinmai S. Jureddy,
• Aleksei Tsarapkin and
• Ivo Utke

Beilstein J. Nanotechnol. 2024, 15, 1117–1124, doi:10.3762/bjnano.15.90

• without the need for a resist or development step. Here, we employ for the first time a silver β-diketonate precursor for focused electron beam-induced deposition (FEBID). The used compound (hfac)AgPMe3 operates at an evaporation temperature of 70–80 °C and is compatible with commercially available gas

• injection systems used in any standard scanning electron microscope. Growth of smooth 3D geometries could be demonstrated for tightly focused electron beams, albeit with low silver content in the deposit volume. The electron beam-induced deposition proved sensitive to the irradiation conditions, leading to

• varying compositions of the deposit and internal inhomogeneities such as the formation of a layered structure consisting of a pure silver layer at the interface to the substrate covered by a deposit layer with low silver content. Imaging after the deposition process revealed morphological changes such as

Unveiling the potential of alginate-based nanomaterials in sensing technology and smart delivery applications

• Shakhzodjon Uzokboev,
• Khojimukhammad Akhmadbekov,
• Ra’no Nuritdinova,
• Salah M. Tawfik and
• Yong-Ill Lee

Beilstein J. Nanotechnol. 2024, 15, 1077–1104, doi:10.3762/bjnano.15.88

• organic compounds sensing: Metal sensing has become a crucial area of research because of the detrimental effects of heavy metal ions on living organisms and ecosystems [104][105]. Metal ions, such as silver, are commonly found in water systems because of industrial activities. In recent years, the use of

• ]. This property allows the alginate-based nanoparticles to effectively bind and detect heavy metal ions present in water systems. The synthesis of alginate-based nanoparticles for metal sensing involves the incorporation of metallic nanoparticles, such as silver nanoparticles or zinc oxide nanoparticles

• environmental monitoring. Accurate detection and measurement of H2O2 levels is vital for understanding its role in biological processes, diagnosing diseases, and monitoring environmental pollutants [114]. Alginate-based nanoparticles have depicted great potential in hydrogen peroxide sensing. A silver/poly(3

Effect of wavelength and liquid on formation of Ag, Au, Ag/Au nanoparticles via picosecond laser ablation and SERS-based detection of DMMP

• Sree Satya Bharati Moram,
• Chandu Byram and
• Venugopal Rao Soma

Beilstein J. Nanotechnol. 2024, 15, 1054–1069, doi:10.3762/bjnano.15.86

• Abstract The present study investigates the effects of input wavelength (1064, 532, and 355 nm) and surrounding liquid environment (distilled water and aqueous NaCl solution) on the picosecond laser ablation on silver (Ag), gold (Au), and Ag/Au alloy targets. The efficacy of the laser ablation technique

• investigated the impact of 355, 532, and 1064 nm wavelengths on picosecond laser ablation of silver, gold, and silver/gold alloy samples within two distinct liquid media: distilled water (DW) and aqueous NaCl solution. Significant variations in the productivity and size of NPs were observed across different

• were of analytic grade and used for cleaning and diluting the samples. The laser ablation samples were 99% pure and had a thickness of 1 mm. Synthesis of nanoparticles by laser ablation in liquid Initially, silver, gold, and silver/gold (Ag50Au50) alloy targets (99%) were obtained from a local market

Atomistic insights into the morphological dynamics of gold and platinum nanoparticles: MD simulations in vacuum and aqueous media

• Evangelos Voyiatzis,
• Eugenia Valsami-Jones and
• Antreas Afantitis

Beilstein J. Nanotechnol. 2024, 15, 995–1009, doi:10.3762/bjnano.15.81

• shape was looked into by Holec et al. [48], while Martin et al. considered silver NPs [49]. A comparative study of surface disorder in Au and Ag NPs upon cooling was carried out by Agudelo-Giraldo et al. [50]. Chushak and Bartell considered the structural modifications upon freezing of several molten Au

A review on the structural characterization of nanomaterials for nano-QSAR models

• Salvador Moncho,
• Eva Serrano-Candelas,
• Jesús Vicente de Julián-Ortiz and
• Rafael Gozalbes

Beilstein J. Nanotechnol. 2024, 15, 854–866, doi:10.3762/bjnano.15.71

• of metal and oxygen atoms as descriptors in metal oxide models [15][16]. It is also common to find single-element descriptors based on the physicochemical properties of pure elements. The use of single-element descriptors is trivial in single-metal nanoforms, such as silver or gold nanoparticles [17

• substituents or modifiers on the surface of a NM is essential to identify and describe the nanoform as they may influence its properties. The characterization of these substituents or modifiers becomes even more relevant when the core composition among different NMs is the same (e.g., silver), but the

• descriptor of the category “a” or “b” in our classification). Kudrinskiy et al. also modelled silver nanoparticles with different coatings without introducing directly the capping agent in the model, but only by observing the differences in size, reactivity, and electric behavior of the nanoforms with

Synthesis of silver–palladium Janus nanoparticles using co-sputtering of independent sources: experimental and theorical study

• Maria J. Martínez-Carreón,
• Francisco Solís-Pomar,
• Abel Fundora,
• Claudio D. Gutiérrez-Lazos,
• Sergio Mejía-Rosales,
• Hector N. Fernández-Escamilla,
• Jonathan Guerrero-Sánchez,
• Manuel F. Meléndrez and
• Eduardo Pérez-Tijerina

Beilstein J. Nanotechnol. 2024, 15, 808–816, doi:10.3762/bjnano.15.67

• functionalities in a single particle, making them extremely versatile and valuable in various scientific, technological, and industrial applications. In this work, bimetallic silver–palladium Janus nanoparticles were obtained for the first time using the inert gas condensation technique. In order to achieve this

• particle. A density functional theory structural aims to understand the atomic arrangement at the interface of the Janus particle. Keywords: bimetallic nanoparticles; inert gas condensation; Janus nanoparticles; silver–palladium nanoparticles; Introduction Janus-type nanoparticles are specific structures

• offered by the same two metals in the bulk, such as Au and Ni [4]. Alloying immiscible elements is feasible in the nanoscale regime because the enthalpy of the mixture decreases as the size of the nanoparticles decreases, and it generally becomes negative below a certain particle size [5]. Silver

Electrospun polysuccinimide scaffolds containing different salts as potential wound dressing material

• Veronika Pálos,
• Krisztina S. Nagy,
• Rita Pázmány,
• Krisztina Juriga-Tóth,
• Bálint Budavári,
• Judit Domokos,
• Dóra Szabó,
• Ákos Zsembery and
• Angela Jedlovszky-Hajdu

Beilstein J. Nanotechnol. 2024, 15, 781–796, doi:10.3762/bjnano.15.65

• polymeric scaffold containing polysuccinimide (PSI) and antibacterial salts. Antibacterial agents for therapeutical purposes mostly contain silver ions which are associated with high environmental impact and, in some cases, may cause undesired immune reactions. In our work, we prepared nanofibrous systems

• to apply silver ions, which are frequently used in clinical practice. However, they can cause a large environmental burden [26][27] and, in some cases, allergies [28]. Since urgent actions are needed to stop AMR and avoid the negative environmental impact, developing other agents and treatment

• strategies to fight bacterial pathogens with similar effects to antibiotics and silver is essential. In our study, inorganic salts, namely Zn(O2CCH3)2 and Sr(NO3)2, were added to the polymer fibers. These salts possess antibacterial properties and stimulate cell proliferation as well as tissue regeneration

Gold nanomakura: nanoarchitectonics and their photothermal response in association with carrageenan hydrogels

• Nabojit Das,
• Vikas,
• Akash Kumar,
• Sanjeev Soni and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2024, 15, 678–693, doi:10.3762/bjnano.15.56

• their true potential application. Experimental Materials All the following chemicals were used as received: hexadecyltrimethylammonium bromide (Fluka), myristyltrimethylammonium bromide (Fluka), dodecyltrimethylammonium bromide (TCI Chemicals), chloroauric acid (HAuCl4·3H2O, Finar Chemicals), silver

Laser synthesis of nanoparticles in organic solvents – products, reactions, and perspectives

• Theo Fromme,
• Sven Reichenberger,
• Katharine M. Tibbetts and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2024, 15, 638–663, doi:10.3762/bjnano.15.54

• structures on top of surfactant-free gold, silver, and copper nanoparticles after adding polyynes, while Zhang et al. performed ablation of silver in acetone with long-term storage, which resulted in shape alteration, size separation, and changes in the carbon shells. As such, molecular hydrocarbons with

• nanoparticles by picosecond LAL [166], indicating that solid carbon products can form independently from solvent decomposition during LAL. Femtosecond LRL of copper and silver acetylacetonate in alcohol solvent was found to produce Cu and Cu–Ag alloy nanoparticles with carbon shells composed of disordered

Fabrication of nanocrystal forms of ᴅ-cycloserine and their application for transdermal and enteric drug delivery systems

• Hsuan-Ang Tsai,
• Tsai-Miao Shih,
• Theodore Tsai,
• Jhe-Wei Hu,
• Yi-An Lai,
• Jui-Fu Hsiao and
• Guochuan Emil Tsai

Beilstein J. Nanotechnol. 2024, 15, 465–474, doi:10.3762/bjnano.15.42

• absorber [20]. In addition, silver (Ag) nanoparticles were synthesized from cotton fabrics and exhibited strong inhibition activity against some bacteria [21]. Recently, pure active pharmaceutical ingredient (API) composed of nanocrystals was investigated, as opposed to drug nanocarrier platforms [22