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Search for "solvent" in Full Text gives 653 result(s) in Beilstein Journal of Nanotechnology. Showing first 200.
Structure-dependent thermochromism of PAZO thin films: theory and experiment
Beilstein J. Nanotechnol. 2026, 17, 186–199, doi:10.3762/bjnano.17.12
- ωB97XD/6-31G(d,p) optimized structures in solvent chloroform (used to mimic the polarity of the polymer layer). Simulated (using the vertical excitation energies and oscillator strengths) UV spectra are given in Figure 9. One strong monomer band at 383 nm is predicted. The spectra of the model dimers
- = 1). This finding highlights the influence of solvent polarity, as the diminished dielectric screening characteristic of nonpolar media enhances monomer–monomer association, whereas polar environments preferentially stabilize the monomeric state. Conclusion Understanding the aggregation states and
- based on PAZO polymer. Preparation of thin-film samples All thin films used in this work were fabricated using spin-coating technique. Methanol was used as solvent for all samples, and a magnetic stirrer ensured complete dissolution. The solution was then poured onto the substrate (quartz or glass) and
Functional surface engineering for cultural heritage protection: the role of superhydrophobic and superoleophobic coatings – a comprehensive review
Beilstein J. Nanotechnol. 2026, 17, 63–96, doi:10.3762/bjnano.17.6
- principles. Ethyl lactate acts as the organic solvent, PHB as the gelator, and DFO as a chelating agent for Fe(III), all functioning effectively at a mildly acidic pH (~4.8). The authors prepared several mock-ups of mild steel by chemically inducing corrosion and coating with Paraloid® B72, replicating real
- toxicological or environmental risks. With respect to sustainability, neither study explicitly integrates this parameter as a design or assessment criterion. Although occasional references to environmentally friendly formulations or solvent substitutions are made, a systematic consideration of life-cycle
- suitable for preserving both new and historical wooden structures, also offering a compelling alternative to traditional solvent-based or slower-curing systems, meeting the modern demands of sustainability, efficiency, and long-term durability. Ramos et al. [81] described a sustainable approach for
Reduced graphene oxide paper electrode for lithium-ion cells – towards optimized thermal reduction
Beilstein J. Nanotechnol. 2026, 17, 24–37, doi:10.3762/bjnano.17.3
- easy to scale up and, which is worth emphasizing, eliminates the use of any binder or harmful solvent. In order to obtain rGO paper sheets, the produced paper sheets underwent a mild, three-step thermal procedure described in [34] (i.e., sample M300 mentioned in the current article) with further
Internal 3D temperature mapping in biological systems using ratiometric light-sheet imaging and lipid-coated upconversion nanothermometers
Beilstein J. Nanotechnol. 2025, 16, 2306–2316, doi:10.3762/bjnano.16.159
- 100 µL of UCNPs in a round-bottomed flask. The resulting mixture was then evaporated under a constant flow of N2 gas while stirring in a circular motion for 30 min. After solvent evaporation, 2 mL of Milli-Q water were added to the flask for rehydration overnight at 4 °C. The resulting water
Improving magnetic properties of Mn- and Zn-doped core–shell iron oxide nanoparticles by tuning their size
Beilstein J. Nanotechnol. 2025, 16, 2285–2295, doi:10.3762/bjnano.16.157
- -background sample holder. The latter was installed on a rotating spinner to allow the highest number of grains to be in diffraction position, and the XRD patterns were recorded at room temperature. The nanoparticles were annealed at 300 °C to remove all the traces of the solvent. in an Anton Paar 1200N oven
- plate at 50 °C for 2 h to remove all solvent traces. The chemical compositions of both core and core–shell NPs were investigated by Fourier-transform infrared spectroscopy (FTIR). Both spectra were recorded using a commercial Agilent FTIR 680 spectrometer in attenuated total reflection (ATR) mode. The
Visualizing nanostructures in supramolecular hydrogels: a correlative study using confocal and cryogenic scanning electron microscopy
Beilstein J. Nanotechnol. 2025, 16, 2274–2284, doi:10.3762/bjnano.16.156
- [11]. Cryogenic scanning electron microscopy (cryo-SEM) bypasses many of these resolution limits by preserving the hydrogel through rapid freezing and subsequent fracture, thereby maintaining native-like morphology in the microscope in the form of a xerogel (no solvent) nature [12][13][14]. High
- . The comparison is important because it could reveal an effect of the probe on the morphology of the network of fibres. The gel network itself is formed by the self-assembly of 1,3-bis[(3-octadecyl-1-imidazolium)methyl]benzene dibromide (1·2Br) in a 1:1 water–ethanol solvent system [20][21] and is made
Ultrathin water layers on mannosylated gold nanoparticles
Beilstein J. Nanotechnol. 2025, 16, 2183–2198, doi:10.3762/bjnano.16.151
- scales of the liquid evaporation and the particle movement: The solvent evaporates so slowly that particles move over at least mesoscale distances, thus allowing for aggregation in the ring [33]. In our research, the deposition protocol may have influenced the observed phenomena. The hydrophilic APDMES
- favors NP–surface interactions with subsequent immobilization. This can be based on multiple hydrogen bonds between the NH3+ groups in APDMES and the OH groups in the dimannoside, which immobilize the NPs long before solvent evaporation. Consequently, in this case, we observed no “coffee ring” effect
Quality by design optimization of microemulsions for topical delivery of Passiflora setacea seed oil
Beilstein J. Nanotechnol. 2025, 16, 2116–2131, doi:10.3762/bjnano.16.146
- Discussion Oil extraction and characterization OPS was extracted using the Soxhlet method with n-hexane as the solvent, yielding 30.5 ± 0.8% (w/w) relative to the initial seed mass. After extraction, the oil was dried using a rotary evaporator to remove residual solvent, filtered through a PTFE membrane
- ether to ≈34% with hexane [3][4][5]. Such variations are commonly influenced by parameters including solvent type, moisture content of the seeds, extraction time, and temperature conditions [6]. The chemical profile of OPS was determined after transesterification to fatty acid methyl esters (FAME
- healing [17][18][19]. In addition to its chemical characterization, the thermal stability in inert atmosphere (N2) of OPS was assessed. Thermogravimetric analysis (TGA) revealed an initial mass loss of less than 1% (Tonset = 60 °C), likely associated with the evaporation of residual solvent entrapped in
Stereodiscrimination of guests in chiral organosilica aerogels studied by ESR spectroscopy
Beilstein J. Nanotechnol. 2025, 16, 2034–2054, doi:10.3762/bjnano.16.140
- available material confirmed the method’s reliability. The data underline how crucial the choice of the right solvent is if one wants to reach sufficient selectivity. Together with a series of custom-made organosilica aerogels, it is shown that adjusting solvent and surface properties so that the two
- ) as a spin probe, we observed that the ESR spectra consist of two species, one rotating freely and the other one much more slowly with tumbling dynamics [42]. Because these two species can be correlated to 3CP in the solvent (fast rotation) and 3CP adsorbed at the surfaces (slow dynamics
- ), quantitative evaluation of the spectra allowed for investigating various confinement effects. Our focus was on understanding how a particular functionalization of the surfaces in combination with 3CP and the solvent influences transport properties, and novel ESR imaging techniques were used to determine
Beyond the shell: exploring polymer–lipid interfaces in core–shell nanofibers to carry hyaluronic acid and β-caryophyllene
Beilstein J. Nanotechnol. 2025, 16, 2015–2033, doi:10.3762/bjnano.16.139
- concentration, surface tension, conductivity, and solvent volatility, alongside careful consideration of electrospinning conditions, such as temperature and humidity [18][19]. The polymer selection of nanofibers intended for biomedical applications must prioritize not only mechanical strength, controlled
- number of beads and the formation of fibers with a more dispersed structure, likely reflecting insufficient polymer chain entanglement and Taylor cone instability. This behavior appears to result from interactions between NE-βCp droplets and HA chains, which may disrupt the jet and hinder solvent
- evaporation within the core, as also reported by Ricaurte et al. (2022) [46]. Air relative humidity was additionally found to influence solvent evaporation and the formation of uniform HA fibers. Similar to the observations reported by Yao et al. (2013), a stable process without interruptions was only
Laser ablation in liquids for shape-tailored synthesis of nanomaterials: status and challenges
Beilstein J. Nanotechnol. 2025, 16, 1963–1997, doi:10.3762/bjnano.16.137
- provided in [85][86], giving an insight on the dependences of the resulting morphology on the laser intensity and solvent used. The number of laser pulses determined the length and diameter of nanowires. For testing of the impact of the surrounding liquid, the process was held in ethanol, methanol, and
Phytol-loaded soybean oil nanoemulsion as a promising alternative against Leishmania amazonensis
Beilstein J. Nanotechnol. 2025, 16, 1826–1836, doi:10.3762/bjnano.16.126
- fully confirm the long-term stability and therapeutic reliability of the formulation. Additionally, the presence of glycerin as a co-solvent may have contributed to the reduction in interfacial tension and improved droplet uniformity, factors known to enhance long-term stability [41]. Importantly, the
- -solvent, Tween® 80, and ʟ-α-phosphatidylcholine (PC), as surfactants. For nanoemulsions containing phytol, 10 mg/g of the drug was added to OP. Subsequent to the nanoemulsification step, the nanoemulsions were transferred into hermetically sealed glass vials and stored at room temperature for further
Exploring the potential of polymers: advancements in oral nanocarrier technology
Beilstein J. Nanotechnol. 2025, 16, 1751–1793, doi:10.3762/bjnano.16.122
- , can occur in organic or aqueous continuous phases, with the latter offering a reduction of toxic solvent residues. Miniemulsion and microemulsion methods provide better control over particle size and distribution, although microemulsion polymerization often requires higher concentrations of
- commonly used methods for the preparation of PNs employing preformed polymers. These methods typically begin with the formulation of an emulsifying system, a step common to all techniques, followed by the formation of NPs through a process that varies depending on the method, such as solvent precipitation
- ][42]. These strategies involve dissolving or dispersing pre-existing polymers in appropriate solvents, followed by NP formation through approaches such as nanoprecipitation, solvent diffusion-emulsification, solvent evaporation, ionic gelation, and dialysis. Each technique is intrinsically linked to
Multifunctional anionic nanoemulsion with linseed oil and lecithin: a preliminary approach for dry eye disease
Beilstein J. Nanotechnol. 2025, 16, 1711–1733, doi:10.3762/bjnano.16.120
- the titration of the LO sample (mL), VB is the volume of KOH solution required for blank solvent titration (mL), [KOH] is the concentration of ethanolic KOH solution (0.093 mol·L−1), MA is the mass of the LO sample used (g), and 56.1 g·mol−1 is the molecular weight of KOH. Thermal analysis
Prospects of nanotechnology and natural products for cancer and immunotherapy
Beilstein J. Nanotechnol. 2025, 16, 1644–1667, doi:10.3762/bjnano.16.116
- selective solvent [110]. Ursolic acid exhibits anti-inflammatory, antimicrobial, antiviral, antioxidant, and antiproliferative properties, making it a potential antitumor agent [111]. It inhibits tumor cell proliferation, prevents metastasis and angiogenesis, and induces cell death [112]. The therapeutic
- nanoparticles can be synthesized using methods such as direct polymerization of monomers, nanoprecipitation, solvent evaporation emulsification, dispersion of preformed polymers, or salting-out [27]. For cancer and immunotherapy, polymeric nanoparticles offer advantages such as biocompatibility, stimulation of
Venom-loaded cationic-functionalized poly(lactic acid) nanoparticles for serum production against Tityus serrulatus scorpion
Beilstein J. Nanotechnol. 2025, 16, 1633–1643, doi:10.3762/bjnano.16.115
- -loaded PLA nanoparticles were fabricated by nanoprecipitation methods. In this technique, the PLA nanoparticles (NPs) were produced by low-energy solvent displacement and functionalized with polyethylenimine (cationic polymer) for the T. serrulatus protein adsorption. The NPs showed a mean diameter of
- functionalized cationic PLA nanoparticles adsorbed with negatively charged proteins was successfully developed by low-energy solvent diffusion method, producing effective and stable spherical cationic nanoparticles. The positive surface charge enabled a high protein incorporation into particles. The prolonged
- PVA (1.0% w/v), at an output flux of 3.0 mL⋅min−1. After titrations, the acetone organic solvent evaporation occurred under a 700 rpm of magnetic stirring overnight. After solvent evaporation, colloidal dispersions were centrifuged at 22,000g for 5 minutes. The T. serrulatus venom loading in the
Nanotechnology-based approaches for the removal of microplastics from wastewater: a comprehensive review
Beilstein J. Nanotechnol. 2025, 16, 1607–1632, doi:10.3762/bjnano.16.114
- -precipitation involves solvent displacement method, where acetone, ethanol, hexane are some of the solvents used [75]. In electrospinning, nanofibers are generated [76]. In parallel, green synthesis utilises biological entities such as plant extracts or microorganisms as reducing agents to produce eco-friendly
Dendrimer-modified carbon nanotubes for the removal and recovery of heavy metal ions from water
Beilstein J. Nanotechnol. 2025, 16, 1522–1532, doi:10.3762/bjnano.16.107
- (CNTs) by growing dendrimers on their surface. First, CNTs were pre-functionalized with maleic acid (MA) via Diels–Alder reaction in presence of a deep eutectic solvent under ultrasonication. Subsequently, dendrimers of varying length were grown by the repeated reaction of ethylene diamine and MA. Raman
- involvement of harmful chemicals to pre-functionalize the CNTs with high loading but also provided an effective way to enhance the adsorption of heavy metal ions. Keywords: carbon nanotubes; deep eutectic solvent; dendrimers; Diels–Alder reaction; heavy metal ion adsorption; Introduction The contamination
- reagents or solvent systems [39][40]. DESs are formed through hydrogen bonding between two solid components resulting in eutectic liquids having a melting point lower than those of the individual components [41][42]. They offer advantages such as simple synthesis, low cost, and broad applications in
Laser processing in liquids: insights into nanocolloid generation and thin film integration for energy, photonic, and sensing applications
Beilstein J. Nanotechnol. 2025, 16, 1428–1498, doi:10.3762/bjnano.16.104
- after LFL treatment. By adjusting processing parameters such as solvent choice, the defect emission, including green defect emissions, can be controlled, providing further opportunities for tailoring the optical properties of NPs for various applications. The mechanisms behind nanoparticle formation
- surrounding solvent, owing to the efficient light absorption capability of the NPs and their limited thermal transfer to the solvent. [35][63][72][73][74]. LIL also leads to phase transitions and morphological changes (Figure 7a–d) depending on the laser fluence and irradiation time [42]. Schematic
- illustrations of the pulsed laser heating mechanism are presented in Figure 7f,g. Factors such as laser fluence, irradiation time, and solvent properties, such as dielectric constant and thermal conductivity, must be carefully controlled to optimize nanoparticle formation [49][68][69][75]. Other factors like
Synthesis and antibacterial properties of nanosilver-modified cellulose triacetate membranes for seawater desalination
Beilstein J. Nanotechnol. 2025, 16, 1380–1391, doi:10.3762/bjnano.16.100
- . Bruker AV400 and VARIAN 300 NMR spectrometers were used to collect 13C NMR spectra at 298 K. CDCl3 solvent was used as internal standard in 13C NMR experiment (δ 77.00 ppm). A Scienta ESCA200 apparatus was used to record XPS spectra. The morphology of the membrane was monitored using a field-emission SEM
- water for solvent replacement, a process that lasted for 3 days. During the period, the water was changed once a day. Preparation of dopamine/hydrochloric acid buffer solution The buffer solution was prepared by modifying the reported method [35][36]. Typically, 0.121 g of Tris was dissolved in 100 mL
Ferroptosis induction by engineered liposomes for enhanced tumor therapy
Beilstein J. Nanotechnol. 2025, 16, 1325–1349, doi:10.3762/bjnano.16.97
- efficiency (EE). These techniques can be categorized into conventional approaches such as thin film hydration, reverse phase evaporation, solvent injection, detergent removal, and newer innovations. Also, modern techniques are further developments or adaptations of conventional approaches. These methods
- allow for better control of liposome size, lamellarity, and drug loading. For example, microfluidics, membrane contactors, and pressure-controlled processes can improve EE, reduce organic solvent residues, and improve scalability and reproducibility [111][112][113]. The most commonly used synthesis
Acrocomia aculeata oil-loaded nanoemulsion: development, anti-inflammatory properties, and cytotoxicity evaluation
Beilstein J. Nanotechnol. 2025, 16, 1277–1288, doi:10.3762/bjnano.16.93
- nitrogen for 24 h to obtain the solvent-free oil. Physicochemical characterization of Acrocomia aculeata oil Relative density and refractive index of Acrocomia aculeata oil (AAO) were evaluated according to the American Pharmacopoeia [58]. Iodine value, peroxide value, acid value, and saponification index
- increased to 250 °C at a rate of 5 K/min, maintaining the final temperature for 10 min. Mass spectra were acquired using a mass range of m/z 40–500, an interface temperature of 250 °C, and an ion source temperature of 220 °C. The solvent cutoff time was 3 min, and the event time was 0.20 min. The sweep
- the absorbance of the solvent, and AC is the absorbance of the positive control [61][62]. Cytotoxic activity The cytotoxic activity of AANE was evaluated in murine macrophages of the J774 strain (ATCC USA) according to the technique described by Nakayama and colleagues [64]. Staurosporine (5 μg/mL
Hydrogels and nanogels: effectiveness in dermal applications
Beilstein J. Nanotechnol. 2025, 16, 1216–1233, doi:10.3762/bjnano.16.90
- efficiently encapsulated 5-FU [196]. The 5-FU was encapsulated in the PLGA core using the solvent evaporation technique. Then, the nanoparticle was coated with cationic chitosan, aiming to promote ionic interactions with the anionic cell membrane of the tumor. Finally, eucalyptus oil (1%) was added to the
Investigation of the solubility of protoporphyrin IX in aqueous and hydroalcoholic solvent systems
Beilstein J. Nanotechnol. 2025, 16, 1209–1215, doi:10.3762/bjnano.16.89
- evaluate the solubility of PpIX in distinct solvent systems to support the development of novel pharmaceutical formulations. The shake-flask method was employed, using purified water, 50% ethanol (EtOH50), 77% ethanol (EtOH77), absolute ethanol (EtOHabs), and polymeric systems containing 10% (w/w
- ) poloxamer 407 (P407) in water, in EtOH50 or in EtOH77. Approximately 10 to 25 mg of PpIX was added to 25 mL of the solvent, and the solutions were stirred at 100 rpm, at 37 °C, for up to 96 h. The PpIX concentration was measured by using a validated method (R = 0.9973), with equilibrium reached within 30
- -assembling properties of P407 make it suitable for advanced nanostructures drug delivery platforms, including polymeric microneedles and hydrogels, ensuring enhanced drug retention and permeation [15][17][18]. Therefore, the present study aimed to investigate the best solvent system for PpIX, in order to
Crystalline and amorphous structure selectivity of ignoble high-entropy alloy nanoparticles during laser ablation in organic liquids is set by pulse duration
Beilstein J. Nanotechnol. 2025, 16, 1141–1159, doi:10.3762/bjnano.16.84
- colloids (LSPC) [41][42][43][44] provides nanoparticles dispersed in liquids without the addition of common additives (e.g., citrate [45], tensides [46], polymers [47]) or support material to stabilize the particles with high variability on the used solvent, yielding colloidal nanoparticles with
- shown to be less expensive than wet chemically produced NPs after a break-even-point of 550 mg/h. Thus, it makes the laser system to be of low cost in large-scale processes [61]. Furthermore, procedures for LAL are usually not bound to strict limitations when it comes to pressure and solvent, as for
- . Furthermore, metalloid elements, such as phosphorous, silicon, boron, and carbon were shown to retard crystallization and favor the formation of long-range disordered structures. Organic solvent molecules used in LSPC can serve as a carbon source which strongly affects the stabilization of amorphous
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