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Beilstein J. Org. Chem. 2024, 20, 1444–1452, doi:10.3762/bjoc.20.127
Graphical Abstract
Figure 1: Examples of cyclic hypervalent halogen reagents.
Figure 2: Common cyclic hypervalent halogen skeletons and transfer groups.
Figure 3: a) Linear dependence between the homolytic BDEs of cyclic hypervalent halogen reagents; b) linear d...
Figure 4: a) Composition and distribution of homolytic BDE dataset; b) graph attention network (GAT) model ar...
Beilstein J. Org. Chem. 2020, 16, 1124–1134, doi:10.3762/bjoc.16.99
Scheme 1: The synthesis of F-1.
Figure 1: View of the crystal structure of F-1 (F-1a phase), with representation of atoms by thermal ellipsoi...
Figure 2: View of the crystal structure of F-1 (F-1a’ phase), with representation of the atoms via thermal el...
Figure 3: SEM image of F-1.
Figure 4: SEM image of F-1 with an F-1a phase.
Figure 5: TGA-DSC analysis of a sample of F-1. The TGA plot is shown in green, the DSC curve is shown in blue...
Scheme 2: Uncrystallized F-1 or F-1 with an F-1a phase promoted the two- and three-phase reactions of styrene...
Scheme 3: CAHOF F-1-promoted reactions of cyclohexene oxide (5) with alcohols and water.
Scheme 4: F-1-promoted Diels–Alder reaction.
Beilstein J. Org. Chem. 2018, 14, 1660–1667, doi:10.3762/bjoc.14.142
Scheme 1: Synthesis of pillar[5]arene mono(oxyalkoxy)benzoic acids 3a–c.
Figure 1: single crystal structure of pillar[5]arene 2a.
Figure 2: Single crystal structure of pillar[5]arene 2f.
Scheme 2: Synthesis of diamido-bridged bis-pillar[5]arenes 5a–d.
Figure 3: The 2D NOSEY spectrum of bis-pillar[5]arene 5d.
Scheme 3: Synthesis of pillar[5]arene di(oxyalkoxy)benzoic acid 8.
Figure 4: Single crystal structure of pillar[5]arene 7.
Scheme 4: Synthesis of diamido-bridged tris-pillar[5]arenes 9a–d.
Figure 5: The 2D NOSEY spectra of tris-pillar[5]arene 9d.