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Beilstein J. Org. Chem. 2024, 20, 2108–2113, doi:10.3762/bjoc.20.181
Graphical Abstract
Scheme 1: [3,3]-Rearrangement of aryl sulfoxides.
Scheme 2: The scope of aryl perfluoromethyl sulfoxides and a selenoxide.
Scheme 3: The scope of alkyl nitriles.
Beilstein J. Org. Chem. 2020, 16, 3032–3037, doi:10.3762/bjoc.16.252
Scheme 1: State of the art concerning the direct nucleophilic trifluoromethylselenolation.
Scheme 2: The nucleophilic fluoroalkylselenolation of alkyl bromides. Yields were determined by 19F NMR spect...
Scheme 3: Mechanism proposal.
Beilstein J. Org. Chem. 2020, 16, 2948–2953, doi:10.3762/bjoc.16.244
Figure 1: (a) Cyclic voltammetry onto microelectrode arrays (Ø = 20 µm) in acetonitrile freshly distilled aft...
Figure 2: Variation of the current reduction (i2) of SF6 onto Pt macroelectrode (Ø = 0.76 mm) at −2.3 V vs Fc+...
Figure 3: Single compartment three-electrode experiment. 1: Balloon of SF6, 2: electrochemical cell, 3: refer...
Figure 4: Electrolysis of SF6 at −2.3 V vs Fc+/Fc in acetonitrile freshly distilled after addition of TBAClO4...
Figure 5: 19F NMR evolution of the crude mixture along the time after electrolysis realized at constant poten...