Search results

Search for "excited state" in Full Text gives 241 result(s) in Beilstein Journal of Organic Chemistry. Showing first 200.

Organic thermally activated delayed fluorescence material with strained benzoguanidine donor

  • Alexander C. Brannan,
  • Elvie F. P. Beaumont,
  • Nguyen Le Phuoc,
  • George F. S. Whitehead,
  • Mikko Linnolahti and
  • Alexander S. Romanov

Beilstein J. Org. Chem. 2023, 19, 1289–1298, doi:10.3762/bjoc.19.95

Graphical Abstract
  • aerated MCH solution. The reduction in quantum yield on exposure to oxygen is due to quenching of the triplet excited states indicating a TADF luminescence mechanism. PLQY in Zeonex films is 39% in air, which is lower than the PLQY of 87% reported for 4CzIPN [17]. The two-component excited state lifetime
  • with prompt and delayed fluorescence is characteristic for the TADF-type luminescence [1]. The excited state lifetime of 4BGIPN has a biexponential decay with a prompt fluorescence τp = 13 ns and a delayed fluorescence τd = 1655 ns components in MCH solution. Zeonex films of 4BGIPN exhibit a similar
  • spectra showing both broad and resolved components, thus supporting the assignments of the 3CT and 3LE(donor) excited states. The excited state lifetime of the broad CT component has a multiexponential decay with averaged lifetimes of 0.7 ms in MCH glass and up to 212 ms in Zeonex films, which we assigned
PDF
Album
Supp Info
Full Research Paper
Published 07 Sep 2023

Unravelling a trichloroacetic acid-catalyzed cascade access to benzo[f]chromeno[2,3-h]quinoxalinoporphyrins

  • Chandra Sekhar Tekuri,
  • Pargat Singh and
  • Mahendra Nath

Beilstein J. Org. Chem. 2023, 19, 1216–1224, doi:10.3762/bjoc.19.89

Graphical Abstract
  • incorporated at the porphyrin periphery and different metal ions in the porphyrin core to modulate ground-state and excited-state characteristics of easily accessible meso-tetraarylporphyrins. Some of these π-extended tetrapyrrolic macrocycles have emerged as potential candidates in photodynamic therapy and
PDF
Album
Supp Info
Full Research Paper
Published 11 Aug 2023
Graphical Abstract
  • dioxide [16]. Excited-state PCET, which is of particular interest for interactions between hydrogen atom or hydride-donating sacrificial donors, has recently been reviewed in detail by Dempsey and co-workers [17]. To select an effective sacrificial electron donor, at least four properties need to be
  • and the ground-state redox potentials of the photosensitizer [18][20], or simulated [21][22]. There are actually methods for directly measuring the excited-state redox potentials of a photosensitizer, such as photomodulated voltammetry but they often require a more elaborate experimental setup [23
  • excited state. Hence, Stern–Volmer plots derived from quenching measurements and photosensitizer excited-state lifetimes measured by transient spectroscopy are crucial to understanding and optimizing the system as a whole [18]. Recently, Kientz et al. demonstrated that the dark regeneration of oxidatively
PDF
Album
Supp Info
Review
Published 08 Aug 2023

Exploring the role of halogen bonding in iodonium ylides: insights into unexpected reactivity and reaction control

  • Carlee A. Montgomery and
  • Graham K. Murphy

Beilstein J. Org. Chem. 2023, 19, 1171–1190, doi:10.3762/bjoc.19.86

Graphical Abstract
  • initial halogen-bonded complex 42, whose irradiation with blue light was proposed to produce acyclic excited state 43*, where possible bond rotation could account for the convergence of alkene isomers into a single product (40c). Radical coupling would then lead to the typical iodocyclobutane intermediate
PDF
Album
Review
Published 07 Aug 2023

Photoredox catalysis harvesting multiple photon or electrochemical energies

  • Mattia Lepori,
  • Simon Schmid and
  • Joshua P. Barham

Beilstein J. Org. Chem. 2023, 19, 1055–1145, doi:10.3762/bjoc.19.81

Graphical Abstract
  • UV region, side reactions and selectivity issues arise upon direct excitation of organic molecules. In recent years, two conceptually distinct but mechanistically related strategies have emerged that enable access to excited state catalysts wielding i) higher redox power than standard monophotonic
  • radical anion or radical cation. As a semi-stable, higher energy ground-state entity, this can accumulate in sufficient concentration under the reaction conditions to absorb another photon and thereby generate a super-reducing or super-oxidizing excited state (Figure 2 left). In addition to ‘radical ion
  • generation of super-reductants (*E1/2 > −2.0 V vs SCE) that accumulate the energy of multiple photons. Case studies will now be presented. Hereafter, while we quote the excited state redox potentials from the report in question, it should be noted that these are estimates associated with uncertainties
PDF
Album
Review
Published 28 Jul 2023

The effect of dark states on the intersystem crossing and thermally activated delayed fluorescence of naphthalimide-phenothiazine dyads

  • Liyuan Cao,
  • Xi Liu,
  • Xue Zhang,
  • Jianzhang Zhao,
  • Fabiao Yu and
  • Yan Wan

Beilstein J. Org. Chem. 2023, 19, 1028–1046, doi:10.3762/bjoc.19.79

Graphical Abstract
  • attributed to a localized singlet excited state of 1NI* by comparison with the reported spectra of NI [58]. Within 155 fs, the system evolves to the second spectrum (blue line), for which both a sharp peak centered at 404 nm and a broad band in the range 600–750 nm were observed, which is identified as a
  • Information File 1) and we did not obtain the EADS, CS, CR, and other time constants exactly. In ACN, the first transient species (black line in Figure 7d) can be recognized as a localized singlet excited state of 1NI* by comparison with the spectra reported for the parent NI [58]. Within about 178 fs, the
  • nm) [39], while this positive absorption band is closer to that of NI−•, which was determined at ca. 430 nm [58]. Therefore, this absorption band is assigned to the NI radical anion. The excited state absorption (ESA) band centered at 460 nm is attributed to the 3NI state. Moreover, another positive
PDF
Album
Supp Info
Full Research Paper
Published 19 Jul 2023

Photoredox catalysis enabling decarboxylative radical cyclization of γ,γ-dimethylallyltryptophan (DMAT) derivatives: formal synthesis of 6,7-secoagroclavine

  • Alessio Regni,
  • Francesca Bartoccini and
  • Giovanni Piersanti

Beilstein J. Org. Chem. 2023, 19, 918–927, doi:10.3762/bjoc.19.70

Graphical Abstract
  • visible-light irradiation of the photoredox catalyst [Ir(dF(CF3)ppy)2(dtbpy)]PF6 to access the excited state *[Ir(dF(CF3)ppy)2(dtbpy)]PF6, which can trigger SET oxidation of 8. Rapid decarboxylation leads to α-amino radical V (and the reduced photocatalyst), which is intercepted by the pendant double bond
PDF
Album
Supp Info
Full Research Paper
Published 26 Jun 2023

Synthesis of substituted 8H-benzo[h]pyrano[2,3-f]quinazolin-8-ones via photochemical 6π-electrocyclization of pyrimidines containing an allomaltol fragment

  • Constantine V. Milyutin,
  • Andrey N. Komogortsev,
  • Boris V. Lichitsky,
  • Mikhail E. Minyaev and
  • Valeriya G. Melekhina

Beilstein J. Org. Chem. 2023, 19, 778–788, doi:10.3762/bjoc.19.58

Graphical Abstract
  • proposed. Keywords: allomaltol; dihydrobenzo[h]pyrano[2,3-f]quinazolines; 6π-electrocyclization; photocyclization; pyrimidines; Introduction Photochemical processes involve absorption of UV light leading to the generation of molecules in the excited state and subsequent chemical transformations [1][2
  • pyranone ring leading to the formation of α-hydroxy-1,2-diketones. This phototransformation is initiated by an excited state intramolecular proton transfer (ESIPT) process. In most cases the resulting α-hydroxy-1,2-diketones are unstable and their further reactions open access to various original products
PDF
Album
Supp Info
Full Research Paper
Published 07 Jun 2023

Synthesis, structure, and properties of switchable cross-conjugated 1,4-diaryl-1,3-butadiynes based on 1,8-bis(dimethylamino)naphthalene

  • Semyon V. Tsybulin,
  • Ekaterina A. Filatova,
  • Alexander F. Pozharskii,
  • Valery A. Ozeryanskii and
  • Anna V. Gulevskaya

Beilstein J. Org. Chem. 2023, 19, 674–686, doi:10.3762/bjoc.19.49

Graphical Abstract
  • monomers 6d and 6e are typical rod-like D–π–A systems. In such molecules, a photon absorption induces a shift from a D–π–A ground state to a D+–π–A− excited state. It is obvious that the actual electron transfer depends on all three components of the push–pull molecule. However, the study on the through
PDF
Album
Supp Info
Full Research Paper
Published 15 May 2023

CuAAC-inspired synthesis of 1,2,3-triazole-bridged porphyrin conjugates: an overview

  • Dileep Kumar Singh

Beilstein J. Org. Chem. 2023, 19, 349–379, doi:10.3762/bjoc.19.29

Graphical Abstract
  • protocol in a 42% yield by using CuI and DIPEA in THF at room temperature (Scheme 11). Their photophysical studies revealed that the fluorescence of zinc porphyrin 58 is strongly quenched due to the copper-corrole 59 in the dyad 60. Also, an efficient excited-state interaction was found between zinc
  • metal exchange reaction of porphyrin 90 with excess CoCl2·6H2O in an acetone/THF (1:1) mixture. The results of the photophysical investigations demonstrated that these dyads exhibit adequate electronic interactions between the sensitizer and catalyst in the excited state. In this study, NiO films were
  • recombination dynamics is primarily related to the electronic properties of the conjugates, such as electron affinity, orbital energies, and excited state energies. In another report, Nikolaou et al. [51] described the synthesis of two novel porphyrin dyads 107b and 108b containing terminal carboxylic acid
PDF
Album
Review
Published 22 Mar 2023

Naphthalimide-phenothiazine dyads: effect of conformational flexibility and matching of the energy of the charge-transfer state and the localized triplet excited state on the thermally activated delayed fluorescence

  • Kaiyue Ye,
  • Liyuan Cao,
  • Davita M. E. van Raamsdonk,
  • Zhijia Wang,
  • Jianzhang Zhao,
  • Daniel Escudero and
  • Denis Jacquemin

Beilstein J. Org. Chem. 2022, 18, 1435–1453, doi:10.3762/bjoc.18.149

Graphical Abstract
  • S33a, Supporting Information File 1), sharp excited state absorption (ESA) bands centered at 360 and 470 nm were observed in HEX, and a 63 μs lifetime was determined. For NI-PTZ, positive absorption bands centered at 360, 470, 390, and 520 nm were observed upon pulsed laser in HEX (Figure 8a). This
  • , significantly below the estimated value of 2.88 eV for the CT state (approximated from the CT absorption band, Figure 1). The longer lifetime of NI-PTZ-O infers that for NI-PTZ, CT state sharing similar energy with 3LE may drain the excited state and shorten the triplet state lifetime. The ns-TA spectra of NI
  • excited state potential energy surfaces leads to different scenarios for the studied compounds as shown in Table S2: a 3CT character is found for the lowest triplet excited state (T1) of NI-PTZ and a considerable 3CT character is found for the T1 of NI-N-PTZ and NI-PTZ2. Conversely, for NI-PhMe2-PTZ, NI
PDF
Supp Info
Full Research Paper
Published 11 Oct 2022

Ionic multiresonant thermally activated delayed fluorescence emitters for light emitting electrochemical cells

  • Merve Karaman,
  • Abhishek Kumar Gupta,
  • Subeesh Madayanad Suresh,
  • Tomas Matulaitis,
  • Lorenzo Mardegan,
  • Daniel Tordera,
  • Henk J. Bolink,
  • Sen Wu,
  • Stuart Warriner,
  • Ifor D. Samuel and
  • Eli Zysman-Colman

Beilstein J. Org. Chem. 2022, 18, 1311–1321, doi:10.3762/bjoc.18.136

Graphical Abstract
  • same at 0.27 eV. The nature of S1 and T1 resemble to those of its parent DiKTa and so this compound is likely to behave as a MR-TADF emitter. The nature of the S2 state is n–π* in DiKTa-OMe. The excited state picture of DiKTa-DPA-OMe is different to that of other reported D–A-type systems containing
  • = 3.35 eV, T1 = 3.09 eV) and DMAC-DiKTa (S1 = 3.43 eV, T1 = 3.17 eV) [28]. We also calculated the charge transfer character of each excited state, focussing on the distance of charge transfer (DCT). When considering the S1 excited state, there is an increase in CT character moving from DiKTa, DiKTa-OMe
  • , in line with its decreased oscillator strength (vide supra). According to the calculations (vide supra), the S1 excited state is also SRCT, but with larger long-range charge transfer (LRCT) content. Owing to the relative flexibility around the DPA donor unit, the Stokes shift is larger at 75 nm (2761
PDF
Album
Supp Info
Full Research Paper
Published 22 Sep 2022

Thermally activated delayed fluorescence (TADF) emitters: sensing and boosting spin-flipping by aggregation

  • Ashish Kumar Mazumdar,
  • Gyana Prakash Nanda,
  • Nisha Yadav,
  • Upasana Deori,
  • Upasha Acharyya,
  • Bahadur Sk and
  • Pachaiyappan Rajamalli

Beilstein J. Org. Chem. 2022, 18, 1177–1187, doi:10.3762/bjoc.18.122

Graphical Abstract
  • donor size and strength: the emitter BPy-pTC with tert-butylcarbazole (TC) as the donor and BPy-p3C with bulky tricarbazole (3C) as the donor unit. Both BPy-pTC and BPy-p3C exhibited prominent emission with TADF properties in solution and in the solid phase. The stronger excited-state charge transfer
  • developed mainly by focusing on photophysical processes, such as photoinduced electron transfer (PET), excited-state intramolecular proton transfer (ESIPT), fluorescence resonance energy transfer (FRET), etc. [21][22][24][25]. Several literature reports have also demonstrated the switching of fluorescence
  • molecular design and donor size in tuning ΔEST in an aggregated state and in fluorescence switching by acid–base addition. Results and Discussion Design and synthesis Several BPy derivatives have been reported to lower ΔEST in D–A pairs to promote spin upconversion from the low-lying triplet excited state
PDF
Album
Supp Info
Full Research Paper
Published 08 Sep 2022

Post-synthesis from Lewis acid–base interaction: an alternative way to generate light and harvest triplet excitons

  • Hengjia Liu and
  • Guohua Xie

Beilstein J. Org. Chem. 2022, 18, 825–836, doi:10.3762/bjoc.18.83

Graphical Abstract
  • (C6F5)3 (BCF) to bind to nitrogen atoms at the basic site a of π-conjugated polymer, providing a simple strategy to regulate the optical properties of the A–D–A chromophore with charge transfer excited state properties [28]. In 2019, Wang et al. constructed a novel exciplex system by using the Lewis
PDF
Album
Review
Published 12 Jul 2022

A study of the photochemical behavior of terarylenes containing allomaltol and pyrazole fragments

  • Constantine V. Milyutin,
  • Andrey N. Komogortsev,
  • Boris V. Lichitsky and
  • Valeriya G. Melekhina

Beilstein J. Org. Chem. 2022, 18, 588–596, doi:10.3762/bjoc.18.61

Graphical Abstract
  • of photoreactions can occur under UV irradiation: the classical photocyclization of the 1,3,5-hexatriene system and excited state intramolecular proton transfer (ESIPT) – promoted photoprocesses typical for a 3-hydroxypyran-4-one core. For the ESIPT-induced reactions the general direction is the
  • nonequivalence of corresponding carbon atoms of the aromatic ring is also observed in the 13C NMR spectrum. The plausible route for the formation of α-hydroxy-1,2-diketone 14a is presented in Scheme 4. Based on literature data we suppose that the photoreaction proceeds through an excited state intramolecular
  • proton transfer (ESIPT) [34][35][36]. At first, compound 12a under UV irradiation undergoes rapid proton transfer from the excited state A* resulting in the formation of photoisomer B* followed by the conversion to intermediate C. Further transformation of zwitter-ion C to bicyclic oxirane D and its
PDF
Album
Supp Info
Full Research Paper
Published 27 May 2022

Comparative study of thermally activated delayed fluorescent properties of donor–acceptor and donor–acceptor–donor architectures based on phenoxazine and dibenzo[a,j]phenazine

  • Saika Izumi,
  • Prasannamani Govindharaj,
  • Anna Drewniak,
  • Paola Zimmermann Crocomo,
  • Satoshi Minakata,
  • Leonardo Evaristo de Sousa,
  • Piotr de Silva,
  • Przemyslaw Data and
  • Youhei Takeda

Beilstein J. Org. Chem. 2022, 18, 459–468, doi:10.3762/bjoc.18.48

Graphical Abstract
  • ], is a fundamental photophysical phenomenon that refers to delayed fluorescence radiated from the singlet excited state (S1) as a consequence of a brief detour to a triplet excited state (Tn) [i.e., intersystem crossing (ISC) and reverse intersystem crossing (rISC)]. Since the revisit of TADF in
  • ) occurs in the singlet excited state (1CT). An efficient rISC can be mediated by mixing the 1CT state with a locally excited triplet state on the donor (3LED) or the acceptor (3LEA) through spin–vibronic coupling [14] or non-Condon effects [15][16]. In 2016, we developed a twisted D–A–D compound POZ-DBPHZ
  • (λPL = 502 nm) to toluene (λPL = 608 nm), and no PL was observed in a more polar solvent such as THF and CHCl3 (Figure 2). In addition, the shape of the PL spectrum changed from a vibrationally resolved shape typical of the emission from a locally excited state (1LE) to a Gaussian-type broad one
PDF
Album
Supp Info
Full Research Paper
Published 25 Apr 2022

Tetraphenylethylene-embedded pillar[5]arene-based orthogonal self-assembly for efficient photocatalysis in water

  • Zhihang Bai,
  • Krishnasamy Velmurugan,
  • Xueqi Tian,
  • Minzan Zuo,
  • Kaiya Wang and
  • Xiao-Yu Hu

Beilstein J. Org. Chem. 2022, 18, 429–437, doi:10.3762/bjoc.18.45

Graphical Abstract
  • power factories, containing many manufacturing units called chloroplasts. Briefly, the antenna molecules capture the light energy by using protein–pigment complexes and transfer it to the specialized reaction centers via the FRET process, where the excited state energy is transferred into useable
  • donor absorbs light energy and changes to the excited state (TPEWP5G*) energy level. Through energy transfer from TPEWP5G* to ground state EsY the latter undergoes excitation to the excited state EsY* and is reduced by the Hantzsch ester to generate the radical anion EsY•−. Subsequently, electron
PDF
Album
Supp Info
Full Research Paper
Published 13 Apr 2022

DABCO-promoted photocatalytic C–H functionalization of aldehydes

  • Bruno Maia da Silva Santos,
  • Mariana dos Santos Dupim,
  • Cauê Paula de Souza,
  • Thiago Messias Cardozo and
  • Fernanda Gadini Finelli

Beilstein J. Org. Chem. 2021, 17, 2959–2967, doi:10.3762/bjoc.17.205

Graphical Abstract
  • radical hydrogen abstraction may be possible under similar conditions [31][32]. However, even small amounts of DABCO (Table 1, entry 1) seem to completely shut down this alternative path, probably due to a fast quenching of the excited state photocatalyst, leading to no mechanism competition under the
  • strongly oxidizing complex *Ir[dF(CF3)ppy]2(dtbbpy) (PC*) (E1/2red [*IrIII/IrII] = +1.21 V vs SCE in CH3CN). The *Ir(III) excited state is quenched by DABCO (E1/2ox = +0.69 V vs SCE) producing DABCO radical cation and the reduced Ir(II) complex. Subsequently, DABCO radical cation engage in a HAT event with
PDF
Album
Supp Info
Letter
Published 21 Dec 2021

Effect of a twin-emitter design strategy on a previously reported thermally activated delayed fluorescence organic light-emitting diode

  • Ettore Crovini,
  • Zhen Zhang,
  • Yu Kusakabe,
  • Yongxia Ren,
  • Yoshimasa Wada,
  • Bilal A. Naqvi,
  • Prakhar Sahay,
  • Tomas Matulaitis,
  • Stefan Diesing,
  • Ifor D. W. Samuel,
  • Wolfgang Brütting,
  • Katsuaki Suzuki,
  • Hironori Kaji,
  • Stefan Bräse and
  • Eli Zysman-Colman

Beilstein J. Org. Chem. 2021, 17, 2894–2905, doi:10.3762/bjoc.17.197

Graphical Abstract
  • ). Solvatochromic studies for DICzTRZ show that the PDM of the ground state structure is small and so the absorption spectrum is essentially not affected by changes in polarity, while the excited state shows the characteristic positive solvatochromism associated with an emission from a CT state (λPL going from 462
  • nature of this excited state. The energy of the S1 state varies with the environments (with energies of 2.94 eV, 2.72 eV, and 2.75 eV for toluene solution, CzSi film and PMMA film, respectively for ICzTRZ), characteristic of a CT type state, but the shape of the spectra in all media adopt a structured
  • atoms are omitted for clarity. HOMO, HOMO–1 (H–1), LUMO, and LUMO+1 (L+1) electron density distributions (isovalue: 0.02) and energy levels, excited state energy levels. a) Cyclic voltammetry (CV) and differential pulse voltammetry (DPV) of DICzTRZ in DCM (scan rate = 100 mV/s). b) UV–vis absorption
PDF
Album
Supp Info
Full Research Paper
Published 08 Dec 2021

Iron-catalyzed domino coupling reactions of π-systems

  • Austin Pounder and
  • William Tam

Beilstein J. Org. Chem. 2021, 17, 2848–2893, doi:10.3762/bjoc.17.196

Graphical Abstract
PDF
Album
Review
Published 07 Dec 2021

Photophysical, photostability, and ROS generation properties of new trifluoromethylated quinoline-phenol Schiff bases

  • Inaiá O. Rocha,
  • Yuri G. Kappenberg,
  • Wilian C. Rosa,
  • Clarissa P. Frizzo,
  • Nilo Zanatta,
  • Marcos A. P. Martins,
  • Isadora Tisoco,
  • Bernardo A. Iglesias and
  • Helio G. Bonacorso

Beilstein J. Org. Chem. 2021, 17, 2799–2811, doi:10.3762/bjoc.17.191

Graphical Abstract
  • the 400–550 nm region depending on the solvent polarity (CHCl3, DMSO, and MeOH). Therefore, it is possible to infer that the polarity of the solvents directly influences the electronic transitions in the excited state, with significant changes for the compound in more polar and protic solvents, by
  • = Ph, R1 = 4-NO2) were analyzed, a significant difference was observed compared to the other compounds in the series 3. Thus, we can say that these characteristics exist because there is more stabilization of the excited state in a polar environment (DMSO and MeOH), adding to a possible push–pull
  • effect of the diethylamino group (donor group) [14][28][29]. Moreover, these results should indicate a negative possibility of excited state intramolecular proton transfer (ESIPT) phenomena occurring (in protic MeOH solvent and low values of Stokes shifts), being only a direct influence of the
PDF
Album
Supp Info
Full Research Paper
Published 01 Dec 2021

Visible-light-mediated copper photocatalysis for organic syntheses

  • Yajing Zhang,
  • Qian Wang,
  • Zongsheng Yan,
  • Donglai Ma and
  • Yuguang Zheng

Beilstein J. Org. Chem. 2021, 17, 2520–2542, doi:10.3762/bjoc.17.169

Graphical Abstract
  • ; however, they suffer from relatively poor photostability [14][15][16]. Transition-metal-photoredox catalysts, such as ruthenium and iridium polypyridyl complexes, exhibit high redox potentials, long excited state lifetimes, and strong absorption [17][18][19][20]. However, high cost and their scarcity
  • oxidized RuIII, which subsequently accepts an electron from an external donor (D) to form the ground-state catalyst RuII. This type of reaction mechanism is an oxidative quenching cycle (OQC). Alternatively, the lower energy SOMO of the excited state RuII* can accept an electron from an external donor
  • , which is referred to as a reductive quenching cycle (RQC; Scheme 1). Compared with the photoredox mechanism of ruthenium-based catalysts, copper complexes show unique features [22][28]. Under irradiation, the copper complex CuI is converted to the excited state CuI*, which transfers electrons to an
PDF
Album
Review
Published 12 Oct 2021

A visible-light-induced, metal-free bis-arylation of 2,5-dichlorobenzoquinone

  • Pieterjan Winant and
  • Wim Dehaen

Beilstein J. Org. Chem. 2021, 17, 2315–2320, doi:10.3762/bjoc.17.149

Graphical Abstract
  • through oxidative quenching of the excited substrate. While an excited state of 1 could react in a similar fashion, the absorption maximum of 1 is centered around 280 nm, which is outside the emission spectrum of green LEDs. A recent study by Hashmi et al. [44], however, shed a completely different light
PDF
Album
Supp Info
Full Research Paper
Published 06 Sep 2021

Chemical syntheses and salient features of azulene-containing homo- and copolymers

  • Vijayendra S. Shetti

Beilstein J. Org. Chem. 2021, 17, 2164–2185, doi:10.3762/bjoc.17.139

Graphical Abstract
  • ) resulting in a relatively small electron repulsion energy in the first singlet excited state and thus, a small HOMO–LUMO (S0–S1) gap compared to naphthalene. The large energy gap between its S2 and S1 states (up to 15000 cm−1) makes internal conversion less probable, making azulene emit from the S2 state
PDF
Album
Review
Published 24 Aug 2021

A comprehensive review of flow chemistry techniques tailored to the flavours and fragrances industries

  • Guido Gambacorta,
  • James S. Sharley and
  • Ian R. Baxendale

Beilstein J. Org. Chem. 2021, 17, 1181–1312, doi:10.3762/bjoc.17.90

Graphical Abstract
PDF
Album
Review
Published 18 May 2021
Other Beilstein-Institut Open Science Activities