Beilstein J. Org. Chem.2008,4, No. 24, doi:10.3762/bjoc.4.24
self-assembly of nano-sized arjuna-bromolactone are reported.
Keywords: arjunolic acid; nanochemistry; renewable; self-assembly; triterpene; Introduction
Triterpenes are an important class of plant secondary metabolites derived from C30 precursors [1][2]. More than 100 triterpenoids with different
networks [17][18]. We propose that the procedure outlined here to obtain the renewable nanosized triterpenic acids in pure form and the self-assembled fibrillar networks obtained in the aromatic solvents will find applications in various facets of supramolecular chemistry and nanoscience [19][20
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Graphical Abstract
Scheme 1:
(a) (i) Br2/AcOH, (ii) CH2N2, (iii) separation by crystallization, (b) Zn/AcOH/RT (c) LiBr/DMF. The...