Anion-dependent ion-pairing assemblies of triazatriangulenium cation that interferes with stacking structures

• Yohei Haketa,
• Takuma Matsuda and
• Hiromitsu Maeda

Beilstein J. Org. Chem. 2024, 20, 2567–2576, doi:10.3762/bjoc.20.215

• . Moreover, the N-aryl-substituted TATA+ cations have been used as the building units of porous organic polymers for capturing CO2 [27]. Cations with characteristic electron-deficient planar triangular geometries were used as scaffolds for various supramolecular cage structures [28][29]. Although

Green and sustainable approaches for the Friedel–Crafts reaction between aldehydes and indoles

• Periklis X. Kolagkis,
• Eirini M. Galathri and
• Christoforos G. Kokotos

Beilstein J. Org. Chem. 2024, 20, 379–426, doi:10.3762/bjoc.20.36

Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors

• Sven Grätz,
• Sebastian Zink,
• Hanna Kraffczyk,
• Marcus Rose and
• Lars Borchardt

Beilstein J. Org. Chem. 2019, 15, 1154–1161, doi:10.3762/bjoc.15.112

• POPs (porous organic polymers) [4] are currently in the focus of research. The modular bottom-up building concept of these organic materials allows for tailoring of materials properties towards desired applications. POPs synthesis can be achieved by a huge variety of reactions ranging from Friedel

Novel approach to hydroxy-group-containing porous organic polymers from bisphenol A

• Tao Wang,
• Yan-Chao Zhao,
• Li-Min Zhang,
• Yi Cui,
• Chang-Shan Zhang and
• Bao-Hang Han

Beilstein J. Org. Chem. 2017, 13, 2131–2137, doi:10.3762/bjoc.13.211

• of Science and Technology, Nanjing 210094, China 10.3762/bjoc.13.211 Abstract We successfully employed bisphenol A and several different formyl-containing monomers as useful building blocks to construct a series of hydroxy-group-containing porous organic polymers in a sealed tube at high temperature

• . Fourier transform infrared and solid-state 13C CP/MAS NMR spectroscopy are utilized to characterize the possible structure of the obtained polymers. The highest Brunauer–Emmet–Teller specific surface area of the phenolic-resin porous organic polymers (PPOPs) is estimated to be 920 m2 g–1. The PPOPs

• : bisphenol A; carbon dioxide uptake; hydrogen storage; OH-containing; porous organic polymers; Introduction Porous organic polymers standing out from kinds of porous materials such as zeolite, activated carbon, metal-organic frameworks [1][2], and covalent organic frameworks [3][4], with their prominent

Sugar-based micro/mesoporous hypercross-linked polymers with in situ embedded silver nanoparticles for catalytic reduction

• Qing Yin,
• Qi Chen,
• Li-Can Lu and
• Bao-Hang Han

Beilstein J. Org. Chem. 2017, 13, 1212–1221, doi:10.3762/bjoc.13.120

• [32][33][34]. In the catalytic process, porous organic polymers with a high SSA, low framework density and permanent porosity represent a new type of catalyst support [35][36][37]. The porosity of the matrix can particularly improve the efficiency of the catalyst due to the promotion of the reactant

• molecules into the holes with the catalyst active sites [38][39]. Therefore, it is of great interest to improve the catalytic efficiency by encapsulating the nanocatalyst in a porous organic polymer. Keeping these issues in mind, three novel sugar-based porous organic polymers SugPOP-1–3 were designed and

• temperature. Results and Discussion All the sugar-based porous organic polymers (SugPOP-1–3) were synthesized by Friedel–Crafts reaction using FDA as an external cross-linker in a similar way. The preparation routes are shown in Scheme 1. Using benzylated monosaccharides as monomers and FDA as the cross