Effect of additives on the synthesis efficiency of nanoparticles by laser-induced reduction

• Rikuto Kuroda,
• Takahiro Nakamura,
• Hideki Ina and
• Shuhei Shibata

Beilstein J. Nanotechnol. 2025, 16, 464–472, doi:10.3762/bjnano.16.35

• solution without IPA. On the other hand, when 10 vol % IPA was added (red line in Figure 1), an increase in absorbance was immediately seen after the start of laser irradiation, and the absorbance levelled off after 5 min of laser irradiation. Figure 2 shows the transmission electron microscopy (TEM

• alloy nanoparticles by LRL with the addition of IPA as a radical scavenger to a solution containing multiple metal ions, and the structure of the synthesized nanoparticles was evaluated by scanning transmission electron microscopy-energy dispersive spectroscopy (STEM-EDS). In this case, we selected an

• solution during laser irradiation with a wavelength range from 300 to 800 nm was measured every 5 s using a fiber multi-channel spectrometer (FRAME-T, Ocean Optics Inc.). The nanoparticles synthesized by laser irradiation were observed using a transmission electron microscope (TEM, JEM-2100Plus, JEOL Ltd

Quantification of lead through rod-shaped silver-doped zinc oxide nanoparticles using an electrochemical approach

• Ravinder Lamba,
• Gaurav Bhanjana,
• Neeraj Dilbaghi,
• Vivek Gupta and
• Sandeep Kumar

Beilstein J. Nanotechnol. 2025, 16, 422–434, doi:10.3762/bjnano.16.33

• chemical substances [7][8]. Target detection in real time is a strong suit for electrochemical devices. Electron mediators are typically used to modify the working electrodes in electrochemical sensor fabrication. These days, due to their unique electrical and optical characteristics, nanomaterials are

• employed as effective electron mediators [9]. Zinc oxide nanoparticles have gained a lot of attention due to their unique features, such as wide bandgap (approximately 3.37 eV), excellent electron transportation, piezoelectric behavior, semiconductor nature, low toxicity, and enhanced electrochemical

• the effects of transition metal ions, such as silver, copper, nickel, and manganese on the chemical and physical properties of ZnO nanoparticles. These metal dopants utilize their partially occupied d-electron shells, leading to the presence of unpaired electrons. Out of these metals, silver is

Size control of nanoparticles synthesized by pulsed laser ablation in liquids using donut-shaped beams

• Abdel Rahman Altakroury,
• Oleksandr Gatsa,
• Farbod Riahi,
• Zongwen Fu,
• Miroslava Flimelová,
• Andrei Samokhvalov,
• Stephan Barcikowski,
• Carlos Doñate-Buendía,
• Alexander V. Bulgakov and
• Bilal Gökce

Beilstein J. Nanotechnol. 2025, 16, 407–417, doi:10.3762/bjnano.16.31

• the morphology and size of the NPs synthesized by PLAL, the colloidal samples were drop-cast on a silicon wafer and dried for microscopic analysis. All NPs were characterized using scanning electron microscopy (SEM, Quanta 400 FEG, FEI Company, USA and TESCAN MIRA3 LMH, Brno, Czech Republic). The

ReactorAFM/STM – dynamic reactions on surfaces at elevated temperature and atmospheric pressure

• Tycho Roorda,
• Hamed Achour,
• Matthijs A. van Spronsen,
• Marta E. Cañas-Ventura,
• Sander B. Roobol,
• Willem Onderwaater,
• Mirthe Bergman,
• Peter van der Tuijn,
• Gertjan van Baarle,
• Johan W. Bakker,
• Joost W. M. Frenken and
• Irene M. N. Groot

Beilstein J. Nanotechnol. 2025, 16, 397–406, doi:10.3762/bjnano.16.30

• setup by means of a load lock and transferred throughout the chambers with a transfer stick. The preparation chamber accommodates standard surface preparation techniques including an ion sputter gun, an e-beam evaporator, a quadrupole mass spectrometer, as well as a combined low-energy electron

• diffraction/Auger electron spectroscopy system to verify the cleanliness, structure, and composition of the surface. The UHV system is supported by four pneumatic air legs resting on a concrete slab, which is separated from the foundation of the building, and isolated from the main floor in an ultramicroscopy

• damping for vibration isolation. The sample holder (highlighted in blue in Figure 2a is inserted by locking the spring mechanism with the locking bellow and then fixed to the microscope by inflating the “reactor” bellow. The substrate can be heated from behind by electron bombardment using a tungsten

Engineered PEG–PCL nanoparticles enable sensitive and selective detection of sodium dodecyl sulfate: a qualitative and quantitative analysis

• Soni Prajapati and
• Ranjana Singh

Beilstein J. Nanotechnol. 2025, 16, 385–396, doi:10.3762/bjnano.16.29

• . Polystyrene latex absorption coefficient and refractive index were used to measure synthesized nanoparticles, prefilled in the software with values of 0.01 and 1.59, respectively. All measurements were performed at 25 °C. The surface morphology of PEG–PCL nanoparticles was analyzed using scanning electron

• performed using SEM (FEI Quanta 250, Netherlands). Transmission electron microscopy (TEM) was also performed to measure nanoparticle mean size and their distribution. The sample was diluted 1000-fold from the stock solution, and 5 µL of the sample was placed onto a carbon-coated copper grid with 200 mesh

• delivery and biosensing. Further insights into the size and morphology of the PEG–PCL NPs were obtained through electron microscopy. Scanning electron microscopy was used to examine the surface structure and to conduct a quantitative size distribution analysis. The SEM images (Figure 2c) revealed that the

Development of a mucoadhesive drug delivery system and its interaction with gastric cells

• Ahmet Baki Sahin,
• Serdar Karakurt and
• Deniz Sezlev Bilecen

Beilstein J. Nanotechnol. 2025, 16, 371–384, doi:10.3762/bjnano.16.28

• nanoparticles Morphology of nanoparticles The morphological characterization of nanoparticles was done via scanning electron microscopy (SEM, Zeiss, GeminiSEM500) and scanning transmission electron microscopy (STEM, Ziess, GeminiSEM500). For SEM analysis, nanoparticles were air-dried on SEM stabs and coated

Pulsed laser in liquid grafting of gold nanoparticle–carbon support composites

• Madeleine K. Wilsey,
• Teona Taseska,
• Qishen Lyu,
• Connor P. Cox and
• Astrid M. Müller

Beilstein J. Nanotechnol. 2025, 16, 349–361, doi:10.3762/bjnano.16.26

• , rapid, scalable, acid-free process to make carbon fiber paper hydrophilic without destroying the carbon network, as other carbon fiber paper oxidation methods do [22], evident from scanning electron microscopy (SEM) imaging (Figure 2A). Hydrophilicity was achieved by graphitic edge carbon oxygenation

• custom-made Teflon tub, in 2.0 mL of commercially available aqueous colloid of citrate-capped gold nanoparticles (100 nm, nanoComposix), followed by drying under a heat lamp at 60 °C for 20 min. Physical characterization Scanning electron microscopy (SEM) images were obtained at UR-Nano. A Zeiss Auriga

• scanning electron microscope with a Schottky field-emission emitter was operated at 20.00 kV with a working distance of 4.9 mm. Energy-dispersive X-ray (EDX) spectroscopy data were collected using an SEM-integrated EDAX Octane elect plus spectrometer with a with silicon drift detector. Double sided carbon

Tailoring of physical properties of RF-sputtered ZnTe films: role of substrate temperature

• Kafi Devi,
• Usha Rani,
• Arun Kumar,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 333–348, doi:10.3762/bjnano.16.25

• II–VI semiconductor with a direct bandgap of 2.26 eV, which lies in the visible range of the electromagnetic spectrum. ZnTe is a p-type semiconductor because of zinc vacancies and has a low electron affinity of 3.53 eV at room temperature [5]. It exists in both zincblende and wurtzite structures

• than 5.78 eV, that is, the sum of CdTe electron affinity (4.28 eV) and bandgap (1.5 eV), would be required. Such a material is not available; therefore, the formation of a Schottky barrier is unavoidable. Because of the small 0.1 eV valance band offset at the CdTe/ZnTe interface, which is best for

• physical and chemical methods such as molecular beam epitaxy [8], electron-beam evaporation [9], thermal evaporation [10], pulsed laser deposition (PLD) [11], and RF sputtering [12]. RF sputtering is a versatile technique because various process parameters such as RF power, deposition time, substrate

Graphene oxide–chloroquine conjugate induces DNA damage in A549 lung cancer cells through autophagy modulation

• Braham Dutt Arya,
• Sandeep Mittal,
• Prachi Joshi,
• Alok Kumar Pandey,
• Jaime E. Ramirez-Vick,
• Govind Gupta and
• Surinder P. Singh

Beilstein J. Nanotechnol. 2025, 16, 316–332, doi:10.3762/bjnano.16.24

• -resolution transmission electron microscope (Technai G2 F30 STWIN, Japan), field emission scanning electron microscope (FEI, Quanta FEG 450, USA), and atomic force microscope (Nanoscope, Veeco V, USA) [28][29][30]. Cell culture A549 cells from the American Type Culture Collection (ATCC, Manassas, VA, USA

• the specific experiment. Each group contained four technical replicates and three biological replicates for each experiment. In each assay cells without nanoconjugates were used as a control. Transmission electron microscopy analysis The A549 cells (2 × 105 cells/mL/well in 6-well plates) were exposed

• nanoconjugates. The observed data with relative % are shown in Supporting Information File 1, Table S1. The morphological analysis of GO was carried out using field-emission scanning electron microscopy (FESEM) and high-resolution transmission electron microscopy (HRTEM). In Supporting Information File 1, Figure

Fabrication and evaluation of BerNPs regarding the growth and development of Streptococcus mutans

• Tuyen Huu Nguyen,
• Hong Thanh Pham,
• Kieu Kim Thanh Nguyen,
• Loan Hong Ngo,
• Anh Ngoc Tuan Mai,
• Thu Hoang Anh Lam,
• Ngan Thi Kim Phan,
• Dung Tien Pham,
• Duong Thuy Hoang,
• Thuc Dong Nguyen and
• Lien Thi Xuan Truong

Beilstein J. Nanotechnol. 2025, 16, 308–315, doi:10.3762/bjnano.16.23

• prepared using a wet-milling method with zirconium balls to enhance bioavailability and expand potential applications. The particle size and physicochemical properties of the BerNPs were analyzed using field-emission scanning electron microscopy (FE-SEM), UV–vis spectroscopy, X-ray diffraction, and Fourier

• from the wells in the MIC assay were dripped on the TSA plate and incubated at 37 °C for 24 h. The MBC value was determined as the lowest concentration at which no visible bacterial colonies were observed. Evaluation of the effect of BerNPs on S. mutans cells Filed-emission scanning electron microscopy

Enhancing mechanical properties of chitosan/PVA electrospun nanofibers: a comprehensive review

• Nur Areisman Mohd Salleh,
• Amalina Muhammad Afifi,
• Fathiah Mohamed Zuki and
• Hanna Sofia SalehHudin

Beilstein J. Nanotechnol. 2025, 16, 286–307, doi:10.3762/bjnano.16.22

• not impossible. This was demonstrated by Olvera Bernal et al. [58] who employed differentially interferential contrasting to accentuate the color contrast for the fiber diameter measurements of electrospun chitosan/PVA. Imaging techniques based on the principles of electron beams such as scanning

• electron microscopy (SEM) and field-emission scanning electron microscopy (FESEM) are more commonly used to analyze the fiber diameter, distribution, and overall surface morphology [144]. Microscopic images obtained from these techniques help to identify defects such as beading or non-uniformity in fibers

• , which can adversely affect mechanical performance. Besides SEM and FESEM, transmission electron microscopy (TEM) has the additional ability to visualize fiber cross sections and can be employed to examine core–shell, encapsulated, and particle-incorporated fiber structures [112][145][146]. Atomic force

Emerging strategies in the sustainable removal of antibiotics using semiconductor-based photocatalysts

• Yunus Ahmed,
• Keya Rani Dutta,
• Parul Akhtar,
• Md. Arif Hossen,
• Md. Jahangir Alam,
• Obaid A. Alharbi,
• Hamad AlMohamadi and
• Abdul Wahab Mohammad

Beilstein J. Nanotechnol. 2025, 16, 264–285, doi:10.3762/bjnano.16.21

• hydrogen electrode (NHE)). In this reductive pathway, the photoexcited electrons have the ability to interact with electron acceptors, like O2, which can be found on the catalyst surface or dissolved in water. This reaction reduces O2, forming a superoxide radical anion (O2•−) (O2 + e− → O2•−) [35][55

• (antibiotics + HO• and/or O2•− → CO2 + H2O). Mechanisms of metal, nonmetal, or co-doped photocatalysts The large bandgap and high electron–hole recombination rate of traditional and single semiconductor photocatalysts limit their effectiveness under visible light, which hinders their practical application. To

• nonmetal atoms. This method has attracted considerable interest because of its synergistic effect on improving the absorption of visible light and minimizing electron–hole recombination [62][63][64]. However, these synthesized materials not only remove antibiotic pollutants but also impact the formation of

Preferential enrichment and extraction of laser-synthesized nanoparticles in organic phases

• Theo Fromme,
• Maximilian L. Spiekermann,
• Florian Lehmann,
• Stephan Barcikowski,
• Thomas Seidensticker and
• Sven Reichenberger

Beilstein J. Nanotechnol. 2025, 16, 254–263, doi:10.3762/bjnano.16.20

• detectible. Extinction values for the Cu and Fe colloids can be found in Supporting Information File 1, Table S1 and Table S2, and the fractions of colloidal NPs in the propylene carbonate phase are found in Supporting Information File 1, Table S3. High-resolution transmission electron microscopy (HRTEM

Radiosensitizing properties of dual-functionalized carbon nanostructures loaded with temozolomide

• Radmila Milenkovska,
• Nikola Geskovski,
• Dushko Shalabalija,
• Ljubica Mihailova,
• Petre Makreski,
• Dushko Lukarski,
• Igor Stojkovski,
• Maja Simonoska Crcarevska and
• Kristina Mladenovska

Beilstein J. Nanotechnol. 2025, 16, 229–251, doi:10.3762/bjnano.16.18

Synthesis and the impact of hydroxyapatite nanoparticles on the viability and activity of rhizobacteria

• Bedah Rupaedah,
• Indrika Novella,
• Atiek Rostika Noviyanti,
• Diana Rakhmawaty Eddy,
• Anna Safarrida,
• Abdul Hapid,
• Zhafira Amila Haqqa,
• Suryana Suryana,
• Irwan Kurnia and
• Fathiyah Inayatirrahmi

Beilstein J. Nanotechnol. 2025, 16, 216–228, doi:10.3762/bjnano.16.17

• used as a carrier for two rhizobacteria strains (Pd and Tb). The structural and morphological properties of nHA were examined through XRD and scanning electron microscopy analyses. Rhizobacteria were encapsulated within the carrier material, and their viability was evaluated using the total plate count

• . The morphology of the analyzed sample, observed through scanning electron microscopy (SEM) at magnifications of 15,000× and 50,000× are depicted in Figure 3. Figure 3 provides a clear view of the sample demonstrating spherical shapes with a consistent particle size distribution. The SEM analysis

• Novella and coworkers [26]. Nanohydroxyapatite characterization Structural assessment of the synthesized nHA was conducted using X-ray diffraction (XRD) with the PANalytical AERIS system and OriginLab 8.5.1 software. Further examination of the sample’s morphology was carried out using a scanning electron

Recent advances in photothermal nanomaterials for ophthalmic applications

• Jiayuan Zhuang,
• Linhui Jia,
• Chenghao Li,
• Rui Yang,
• Jiapeng Wang,
• Wen-an Wang,
• Heng Zhou and
• Xiangxia Luo

Beilstein J. Nanotechnol. 2025, 16, 195–215, doi:10.3762/bjnano.16.16

• photons aligns with the intramolecular electron orbital transition (π→π*) [55], resulting in electrons being excited from their ground state to higher energy orbitals [56]. As these excited electrons relax back to their ground state, they induce vibrations in the molecular lattice, which in turn release

• their bandgap energy (incident wavelength from approximately 310 to 1240 nm) [73], leading to the generation of electron–hole pairs that possess energy equivalent to the bandgap [74]. Once these excited electrons are transferred to impurities, defects, or surface dangling bonds [75], they release energy

A review of metal-organic frameworks and polymers in mixed matrix membranes for CO₂ capture

• Charlotte Skjold Qvist Christensen,
• Nicholas Hansen,
• Mahboubeh Motadayen,
• Nina Lock,
• Martin Lahn Henriksen and
• Jonathan Quinson

Beilstein J. Nanotechnol. 2025, 16, 155–186, doi:10.3762/bjnano.16.14

• synthesizing amine-functionalized MOFs. The uncoordinated and electron-rich nitrogen atoms in amines are ‘CO2-philic’ [33][35] and provide active adsorption sites for CO2 through Lewis acid–base interaction between CO2 and amines [67]. As illustrated in Figure 2d, adsorptive selectivity can also result from

•  7d. For instance, in a study by Carja et al. [128], PIM-1 was functionalized with amidoxime groups to induce superior adhesion to UiO-66 in flat sheet MMMs, drastically reducing defect formation as predicted by molecular simulations and confirmed by field-emission scanning electron microscopy and

• high-resolution transmission electron microscopy (HRTEM). Utilizing smaller MOF filler sizes is a straightforward approach to improve filler dispersion. The contact area with the polymer matrix increases when the size of MOF particles is decreased, promoting adhesion, and reducing interfacial defects

Clays enhanced with niobium: potential in wastewater treatment and reuse as pigment with antibacterial activity

• Silvia Jaerger,
• Patricia Appelt,
• Mario Antônio Alves da Cunha,
• Fabián Ccahuana Ayma,
• Ricardo Schneider,
• Carla Bittencourt and
• Fauze Jacó Anaissi

Beilstein J. Nanotechnol. 2025, 16, 141–154, doi:10.3762/bjnano.16.13

• comparison obtained regarding the percentage of removal from adsorption and heterogeneous photocatalysis tests. The photocatalysis mechanism can be explained as follows: a semiconductor such as the BEPh and BEOx samples absorbs a photon, promoting an electron from the valence band (VB) to the conduction band

• modified clays BEOx and BEPh, which exhibit a strong affinity with the positively charged structure of the MB dye. On the other hand, the BEOx and BEPh samples demonstrated significant efficacy in MB removal, with removal rates of 94.5% and 99.81%, respectively. The preferential electron–hole (hBV

TiO₂ immobilized on 2D mordenite: effect of hydrolysis conditions on structural, textural, and optical characteristics of the nanocomposites

• Marina G. Shelyapina,
• Rosario Isidro Yocupicio-Gaxiola,
• Gleb A. Valkovsky and
• Vitalii Petranovskii

Beilstein J. Nanotechnol. 2025, 16, 128–140, doi:10.3762/bjnano.16.12

• studied composites. The scanning electron microscopy (SEM) image of the initial lamellar mordenite sample MOR-L is also shown for comparison. As can be seen, MOR-L exhibits elongated plates up to 1 μm long and 0.1 μm wide, combined into stacks. After introduction of TEOT followed by hydrolysis and

• diffuse reflectance spectra. In this method, it is assumed that the energy-dependent absorption coefficient α can be written as where h is the Planck constant, hν is the photon energy, and B is a constant. The factor n depends on the nature of the electron transition, that is, n = 1/2 for direct and n = 2

Comparison of organic and inorganic hole transport layers in double perovskite material-based solar cell

• Deepika K and
• Arjun Singh

Beilstein J. Nanotechnol. 2025, 16, 119–127, doi:10.3762/bjnano.16.11

• performance. Keywords: double perovskite solar cell (DPSC); electron transport layer (ETL); hole transport layer (HTL); SCAPS-1D; simulation; Introduction The rapid growth of the world population has increased the global need for energy, which has become undoubtedly quite strong. To date, the energy

• 2009 to 26.1% in 2023 [5][6]. PSCs consist of an absorber layer sandwiched between charge transport layers (CTLs), that is, the hole transport layer (HTL) and the electron transport layer (ETL). Light generates excitons, which further dissociate into electrons and holes. The electrons and holes are

• equation is as follows [20]: where e is the electronic charge, ϕ is the electric potential, ε0 is the vacuum permittivity, εr is the relative permittivity, p(x) and n(x) are, respectively, hole and electron position dependence, ND is the shallow donor density, NA is the acceptor donor density, and ρp and

Modeling and simulation of carbon-nanocomposite-based gas sensors

• Roopa Hegde,
• Punya Prabha V,
• Shipra Upadhyay and
• Krishna S B

Beilstein J. Nanotechnol. 2025, 16, 90–96, doi:10.3762/bjnano.16.9

• showed high sensitivity towards strong electron-withdrawing molecules for NO2 gas detection [10]. To simulate gas adsorption in COMSOL Multiphysics for a gas sensor, several adsorption models can be employed depending on the physical and chemical behavior of the sensor. Commonly used models include the

Characterization of ZnO nanoparticles synthesized using probiotic Lactiplantibacillus plantarum GP258

• Prashantkumar Siddappa Chakra,
• Aishwarya Banakar,
• Shriram Narayan Puranik,
• Vishwas Kaveeshwar,
• C. R. Ravikumar and
• Devaraja Gayathri

Beilstein J. Nanotechnol. 2025, 16, 78–89, doi:10.3762/bjnano.16.8

• characterization using UV–vis spectroscopy, Fourier-transform infrared spectroscopy, X-ray diffraction measurements, energy-dispersive X-ray spectroscopy, scanning and transmission electron microscopy, photocatalytic studies, electrochemical analysis, and determination of antibacterial and anticancer activity. The

• reduction currents and increased peak oxidation, indicating rapid electron transport at the contacts between the electrolyte and electrode. Pseudo-capacitive behavior was observed in both electrolytes, where ionic conductivity influenced capacitance [17][18]. The addition of dextrose increased the redox

• frequency (ω), Y, and n. The obtained results suggest robust electron transfer and enhanced electrocatalytic efficiency in dextrose oxidation [19][20][21] (Figure 5). Antibacterial activity of ZnO NPs The biogenic ZnO NPs presented a good dispersion and exhibited antibacterial activity against both Gram

Instance maps as an organising concept for complex experimental workflows as demonstrated for (nano)material safety research

• Benjamin Punz,
• Maja Brajnik,
• Joh Dokler,
• Jaleesia D. Amos,
• Litty Johnson,
• Katie Reilly,
• Anastasios G. Papadiamantis,
• Amaia Green Etxabe,
• Lee Walker,
• Diego S. T. Martinez,
• Steffi Friedrichs,
• Klaus M. Weltring,
• Nazende Günday-Türeli,
• Claus Svendsen,
• Christine Ogilvie Hendren,
• Mark R. Wiesner,
• Martin Himly,
• Iseult Lynch and
• Thomas E. Exner

Beilstein J. Nanotechnol. 2025, 16, 57–77, doi:10.3762/bjnano.16.7

• focused on silica (SiO2) nanomaterials in the size range of 50–100 nm (depending on the method used, i.e., transmission electron microscopy, nanoparticle tracking analysis, or dynamic light scattering (intensity or number distribution)) with different surface modifications, which are reported to be

Precursor sticking coefficient determination from indented deposits fabricated by electron beam induced deposition

• Alexander Kuprava and
• Michael Huth

Beilstein J. Nanotechnol. 2025, 16, 35–43, doi:10.3762/bjnano.16.4

• Alexander Kuprava Michael Huth Physics Institute, Goethe University Frankfurt, Max-von-Laue-Str. 1, 60438 Frankfurt am Main, Germany 10.3762/bjnano.16.4 Abstract A fast simulation approach for focused electron beam induced deposition (FEBID) numerically solves the diffusion–reaction equation

• (continuum model) of the precursor surface on the growing nanostructure in conjunction with a Monte Carlo simulation for electron transport in the growing deposit. An important requirement in this regard is to have access to a methodology that can be used to systematically determine the values for the set of

• the center region of an intentionally defocused electron beam. We employ the method to determine the precursor sticking coefficient for bis(benzene)chromium, Cr(C6H6)2, and trimethyl(methylcyclopentadienyl)platinum(IV), Me3CpPtMe, and find a value of about 10−2 for both precursors, which is

A nanocarrier containing carboxylic and histamine groups with dual action: acetylcholine hydrolysis and antidote atropine delivery

• Elina E. Mansurova,
• Andrey A. Maslennikov,
• Anna P. Lyubina,
• Alexandra D. Voloshina,
• Irek R. Nizameev,
• Marsil K. Kadirov,
• Anzhela A. Mikhailova,
• Polina V. Mikshina,
• Albina Y. Ziganshina and
• Igor S. Antipin

Beilstein J. Nanotechnol. 2025, 16, 11–24, doi:10.3762/bjnano.16.2

• electron microscopy (TEM) images were taken with a Libra 120 EFTEM (A Carl Zeiss SMT AG Company, Oberkochen, Carl Zeiss, Germany) at 100 kV. Samples were spread on a 300 mesh copper grid with a carbon/formvar support film. 1H and 13C NMR spectra were obtained using a Bruker Avance 600 spectrometer with an