Layered double hydroxide/sepiolite hybrid nanoarchitectures for the controlled release of herbicides

• Ediana Paula Rebitski,
• Margarita Darder and
• Pilar Aranda

Beilstein J. Nanotechnol. 2019, 10, 1679–1690, doi:10.3762/bjnano.10.163

• nanofiller in Nafion membranes for fuel-cell applications [35]. With these premises, the current aim is to ascertain if it is possible to develop organic–inorganic hybrid materials using LDH-sepiolite nanoarchitectonic materials, as the presence of an organic counterpart could be of interest for introducing

Magnetic segregation effect in liquid crystals doped with carbon nanotubes

• Danil A. Petrov,
• Pavel K. Skokov,
• Alexander N. Zakhlevnykh and
• Dmitriy V. Makarov

Beilstein J. Nanotechnol. 2019, 10, 1464–1474, doi:10.3762/bjnano.10.145

• modifies many properties of liquid crystals and leads to the possibility of obtaining new hybrid materials with unique electro- and magneto-optical properties, which opens prospects for new practical applications in optoelectronics, photonics, and display technology [11]. From a physical perspective, these

Multicomponent bionanocomposites based on clay nanoarchitectures for electrochemical devices

• Giulia Lo Dico,
• Bernd Wicklein,
• Lorenzo Lisuzzo,
• Giuseppe Lazzara,
• Pilar Aranda and
• Eduardo Ruiz-Hitzky

Beilstein J. Nanotechnol. 2019, 10, 1303–1315, doi:10.3762/bjnano.10.129

• stability of these multicomponent hybrid materials in water showing a mass loss of only 3.2 wt % over the course of two months. This excellent stability, together with the good electrical and mechanical properties, suggest that the prepared multicomponent bionanocomposite can be suitable as electrode

Tailoring the magnetic properties of cobalt ferrite nanoparticles using the polyol process

• Malek Bibani,
• Romain Breitwieser,
• Alex Aubert,
• Vincent Loyau,
• Silvana Mercone,
• Souad Ammar and
• Fayna Mammeri

Beilstein J. Nanotechnol. 2019, 10, 1166–1176, doi:10.3762/bjnano.10.116

• be significantly smaller. This discrepancy is mainly due to the difficulties in producing hybrid materials with large and perfect interfaces [5]. The use of nanomaterials exhibiting large surface-to-volume ratios instead of bulk materials can help to overcome this limitation. To the best of our

• -stoichiometric, appropriate for the use as ferromagnetic building blocks in nanostructured magnetoelectric materials, particularly polymer-based hybrid materials. We hope this work is providing some insight into the ability to design efficient magnetic and magnetostrictive particles that can be further

Renewable energy conversion using nano- and microstructured materials

• Harry Mönig and
• Martina Schmid

Beilstein J. Nanotechnol. 2019, 10, 771–773, doi:10.3762/bjnano.10.76

• cases in which organic or hybrid materials are involved [20]. For example protection against device degradation by advanced encapsulation techniques can help to further develop such technologies [21]. As it is the case for conventional materials, interface engineering is also a major factor for device

Towards rare-earth-free white light-emitting diode devices based on the combination of dicyanomethylene and pyranine as organic dyes supported on zinc single-layered hydroxide

• Jeff L. Nyalosaso,
• Rachod Boonsin,
• Pierre Vialat,
• Damien Boyer,
• Geneviève Chadeyron,
• Rachid Mahiou and
• Fabrice Leroux

Beilstein J. Nanotechnol. 2019, 10, 760–770, doi:10.3762/bjnano.10.75

• large part of the visible spectrum. The concept developed in our work consisted in keeping SLH in its wet form to ensure a good dispersion of the fluorescent dyes prior to immobilizing the hybrid materials in a silicone polymer to achieve luminescent composite films. We demonstrate that these coatings

• . For all these reasons, we have studied the development of a rare-earth-free LED device by considering the use of stabilized synthetic organic dyes in an inorganic solid matrix to form a luminescent hybrid material. Some of these hybrid materials consist of a layered inorganic matrix, the role of which

• . The optical properties of the luminescent wet hybrid materials and films were recorded. Finally, a down-conversion pseudo-white LED was designed by simply associating, in remote-phosphor configuration, silicone/SLH-dye composite film and a GaN LED emitting at 450 nm. Composite films with a single dye

On the transformation of “zincone”-like into porous ZnO thin films from sub-saturated plasma enhanced atomic layer deposition

• Alberto Perrotta,
• Julian Pilz,
• Stefan Pachmajer,
• Antonella Milella and
• Anna Maria Coclite

Beilstein J. Nanotechnol. 2019, 10, 746–759, doi:10.3762/bjnano.10.74

• crystal growth occurred, giving insights in the manufacturing of nanoporous ZnO from Zn-based hybrid materials. Keywords: calcination; PE-ALD; porosity; thin films; ZnO; Introduction Atomic layer deposition (ALD) and molecular layer deposition (MLD) are sequential self-limiting vapor-phase deposition

• layers were grown with sub-saturated PE-ALD using the sequential exposure of oxygen plasma and DEZ. By adopting different times of exposure to O2 plasma, the chemical composition of the resulting hybrid materials was varied, yielding zincone-like thin films with different amount of organic fractions. The

Outstanding chain-extension effect and high UV resistance of polybutylene succinate containing amino-acid-modified layered double hydroxides

• Adam A. Marek,
• Vincent Verney,
• Christine Taviot-Gueho,
• Grazia Totaro,
• Laura Sisti,
• Annamaria Celli and
• Fabrice Leroux

Beilstein J. Nanotechnol. 2019, 10, 684–695, doi:10.3762/bjnano.10.68

• melt compounding process. The Mg2Al-based PBS nanocomposites, dispersed with inorganic–organic hybrid materials (layered double hydroxides, LDHs), were functionalized with the amino acids L-histidine (HIS) and L-phenylalanine (PHE). The rheological and anti-ultraviolet (anti-UV) properties were

• LDH hybrid materials, and in particular, their application as a polymer chain extender and UV stabilizer for PBS, which can likely be extended to other biodegradable polymers. Keywords: amino acid; layered double hydroxide; phenylalanine; polybutylene succinate; Introduction Polymer nanocomposite

• Molder, obtaining small-sized bars (33 × 8 × 2 mm). Such samples were scanned from −150 °C to 80 °C (heating rate 3 °C min−1, frequency 3 Hz, strain 0.01%). Results and Discussion Layered double hydroxide filler characterization The organo-modified Mg2Al LDH hybrid materials containing the levorotary

Topochemical engineering of composite hybrid fibers using layered double hydroxides and abietic acid

• Liji Sobhana,
• Lokesh Kesavan,
• Jan Gustafsson and
• Pedro Fardim

Beilstein J. Nanotechnol. 2019, 10, 589–605, doi:10.3762/bjnano.10.60

• Turku, Vatselankatu 2, FI-20014 Turku, Finland Department of Chemical Engineering, KU Leuven, Celestijnenlaan 200F b,us 2424, B-3001 Leuven, Belgium 10.3762/bjnano.10.60 Abstract Topochemical engineering of hybrid materials is an efficient way of synthesizing hydrophobic and highly tensile fiber

Hydrophilicity and carbon chain length effects on the gas sensing properties of chemoresistive, self-assembled monolayer carbon nanotube sensors

• Juan Casanova-Cháfer,
• Carla Bittencourt and
• Eduard Llobet

Beilstein J. Nanotechnol. 2019, 10, 565–577, doi:10.3762/bjnano.10.58

• based on the interaction between the carboxylic acid functional groups in MWCNTs and nitrogen dioxide. In contrast, the response to nitrogen dioxide is clearly enhanced (up to an 8-fold increase) when hybrid materials formed by thiol SAMs on Au-MWCNTs are used. Since it was found that Au nanoparticles

Widening of the electroactivity potential range by composite formation – capacitive properties of TiO₂/BiVO₄/PEDOT:PSS electrodes in contact with an aqueous electrolyte

• Konrad Trzciński,
• Mariusz Szkoda,
• Andrzej P. Nowak,
• Marcin Łapiński and
• Anna Lisowska-Oleksiak

Beilstein J. Nanotechnol. 2019, 10, 483–493, doi:10.3762/bjnano.10.49

• materials characterized by a developed surface area [9], graphene-based [10] and diamond-based materials [11], conductive polymers (CPs) and hybrid materials [12][13], and numerous types of composite materials [14][15]. For many years, conjugated polymers, also known as conductive polymers, e.g., poly(3,4

Reduced graphene oxide supported C₃N₄ nanoflakes and quantum dots as metal-free catalysts for visible light assisted CO₂ reduction

• Md Rakibuddin and
• Haekyoung Kim

Beilstein J. Nanotechnol. 2019, 10, 448–458, doi:10.3762/bjnano.10.44

• , we report the synthesis of novel reduced graphene oxide (rGO)-supported C3N4 nanoflake (NF) and quantum dot (QD) hybrid materials (GCN) for visible light induced reduction of CO2. The C3N4 NFs and QDs are prepared by acid treatment of C3N4 nanosheets followed by ultrasonication and hydrothermal

• heating at 130–190 °C for 5−20 h. It is observed that hydrothermal exposure of acid-treated graphitic carbon nitride (g-C3N4) nanosheets at low temperature generated larger NFs, whereas QDs are formed at higher temperatures. The formation of GCN hybrid materials was confirmed by powder X-ray diffraction

• distributed on the rGO surface within the GCN hybrid material. Among the as-prepared GCN hybrid materials, GCN-5 QDs exhibit excellent CO2 reductive activity for the generation of formaldehyde, HCHO (10.3 mmol h−1 g−1). Therefore, utilization of metal-free carbon-based GCN hybrid materials could be very

Biocompatible organic–inorganic hybrid materials based on nucleobases and titanium developed by molecular layer deposition

• Leva Momtazi,
• Henrik H. Sønsteby and
• Ola Nilsen

Beilstein J. Nanotechnol. 2019, 10, 399–411, doi:10.3762/bjnano.10.39

• refraction. Keywords: ALD; bioactive materials; hybrid materials; MLD; nucleobases; Introduction There is an ever-increasing interest in organometallic compounds in the field of medicinal chemistry. Organometallic complexes are now being developed as anticancer agents, radiopharmaceuticals for diagnosis

• tetra-isopropoxide (TTIP) with thymine, uracil, and adenine (Figure 1). We have recently reported a significant increase in the proliferation rate of rat conjunctival goblet cells cultured on substrates coated with these hybrid materials based on amino acids, and also the currently presented nucleobases

• uncoated cover slips [23]. Conclusion Thin films of organic–inorganic hybrid materials were successfully deposited using thymine, uracil, or adenine along with TTIP. The films are hydrophilic, however, the nucleobases do leach when the films are immersed in water. The films are amorphous as-deposited

One-step nonhydrolytic sol–gel synthesis of mesoporous TiO₂ phosphonate hybrid materials

• Yanhui Wang,
• P. Hubert Mutin and
• Johan G. Alauzun

Beilstein J. Nanotechnol. 2019, 10, 356–362, doi:10.3762/bjnano.10.35

• Yanhui Wang P. Hubert Mutin Johan G. Alauzun Institut Charles Gerhardt Montpellier, UMR 5253, Université de Montpellier, CC 1701, Place Eugène Bataillon, 34095 Montpellier Cedex 5, France 10.3762/bjnano.10.35 Abstract Mesoporous TiO2–octylphosphonate hybrid materials were prepared in one step by

• infrared spectroscopy, Raman spectroscopy, X-ray diffraction, and nitrogen physisorption. For P/Ti ratios up to 0.1, the hybrid materials can be described as aggregated, roughly spherical, crystalline anatase nanoparticles grafted by octylphosphonate groups via Ti–O–P bonds. The crystallite size decreases

• ][2][3]. Combining inorganic and organic moieties at the nanoscale allows the design of tailor-made functional materials with enhanced or new properties, adapted to a wide range of advanced applications [4][5][6][7]. In Class I hybrid materials, the inorganic and organic parts are linked through weak

Removal of toxic heavy metals from river water samples using a porous silica surface modified with a new β-ketoenolic host

• Said Tighadouini,
• Smaail Radi,
• Abderrahman Elidrissi,
• Khadija Haboubi,
• Maryse Bacquet,
• Stéphanie Degoutin,
• Mustapha Zaghrioui and
• Yann Garcia

Beilstein J. Nanotechnol. 2019, 10, 262–273, doi:10.3762/bjnano.10.25

• cycles of adsorption/desorption. Compared to literature results, this material can be considered a high-performing remediation adsorbent for the extraction of Zn(II) from natural real water solution. Keywords: heavy metals; hybrid materials; β-ketoenol–pyridine–furan ligands; polluted media; porous

pH-mediated control over the mesostructure of ordered mesoporous materials templated by polyion complex micelles

• Emilie Molina,
• Mélody Mathonnat,
• Jason Richard,
• Patrick Lacroix-Desmazes,
• Martin In,
• Philippe Dieudonné,
• Thomas Cacciaguerra,
• Corine Gérardin and
• Nathalie Marcotte

Beilstein J. Nanotechnol. 2019, 10, 144–156, doi:10.3762/bjnano.10.14

• long as no competing interactions involving silicic species exist. In a previous study, we had shown that when the strength of the organic–inorganic interaction is kept constant (by synthesizing hybrid materials at a fixed pH), the material mesostructure can be controlled by varying parameters that

• obtained. The variations of the mesostructures and the chemical composition of the corresponding hybrid materials as a function of pH are reported and discussed. Experimental Materials Poly(ethylene oxide)-b-poly(acrylic acid) (PEO-b-PAA, MPEO = 5000 g·mol−1, MPAA = 1420 g·mol−1) was synthesized by atom

• additional hours at 30 °C. The precipitate was then recovered by centrifugation and air-dried at 40 °C for 48 hours. For characterization purposes, the as-synthesized hybrid materials were calcined under air flow from room temperature to 550 °C at a heating rate of 2 °C·min−1 and then maintained at 550 °C

New micro/mesoporous nanocomposite material from low-cost sources for the efficient removal of aromatic and pathogenic pollutants from water

• Emmanuel I. Unuabonah,
• Robert Nöske,
• Jens Weber,
• Christina Günter and
• Andreas Taubert

Beilstein J. Nanotechnol. 2019, 10, 119–131, doi:10.3762/bjnano.10.11

• ; micro/mesoporous; nanocomposite; water remediation; Introduction Porous carbon-based materials and carbon/inorganic hybrid materials have extensively been used for the adsorption of pollutants, such as heavy metals or aromatic hydrocarbons, from water in developing countries [1][2][3][4]. The removal

Co-intercalated layered double hydroxides as thermal and photo-oxidation stabilizers for polypropylene

• Qian Zhang,
• Qiyu Gu,
• Fabrice Leroux,
• Pinggui Tang,
• Dianqing Li and
• Yongjun Feng

Beilstein J. Nanotechnol. 2018, 9, 2980–2988, doi:10.3762/bjnano.9.277

• various techniques. The results show that the powdered HnMn′-Ca2Al-LDHs hybrid materials have a much higher thermal stability than MP-Ca and HALS before intercalation. In addition, the HnMn′-Ca2Al/PP composites exhibit a higher overall resistance against thermal degradation and photo-oxidation compared to

Ternary nanocomposites of reduced graphene oxide, polyaniline and hexaniobate: hierarchical architecture and high polaron formation

• Claudio H. B. Silva,
• Maria Iliut,
• Christopher Muryn,
• Christian Berger,
• Zachary Coldrick,
• Vera R. L. Constantino,
• Marcia L. A. Temperini and
• Aravind Vijayaraghavan

Beilstein J. Nanotechnol. 2018, 9, 2936–2946, doi:10.3762/bjnano.9.272

• emeraldine salt form (doped polymer) for all samples. However, comparing the spectra of the nanocomposites with the neat polymer (PANI), the bands at ca. 1336 and ca. 1600 cm−1 for the hybrid materials present higher relative intensities. These results can be attributed to the contribution of rGO bands [35

Size-selected Fe₃O₄–Au hybrid nanoparticles for improved magnetism-based theranostics

• Maria V. Efremova,
• Yulia A. Nalench,
• Eirini Myrovali,
• Anastasiia S. Garanina,
• Ivan S. Grebennikov,
• Polina K. Gifer,
• Maxim A. Abakumov,
• Marina Spasova,
• Makis Angelakeris,
• Alexander G. Savchenko,
• Michael Farle,
• Natalia L. Klyachko,
• Alexander G. Majouga and
• Ulf Wiedwald

Beilstein J. Nanotechnol. 2018, 9, 2684–2699, doi:10.3762/bjnano.9.251

• MS values) is not reached, an additional stabilization by agarose seems to play a decisive role for significantly enhanced r2 values [57]. This means that the effectiveness of the hybrid materials as contrast agents increases under in vitro and in vivo operational conditions. Magnetic hyperthermia

• as compared to the hybrids in water or agarose in line with previous cell culture experiments [85]. Here, we focus on the hyperthermia function of the hybrid materials in the same cell line. For this purpose, polymer-coated MNP-25 NPs were dispersed in RPMI medium at 3.6 mg·mL−1 Fe concentration

Nanocellulose: Recent advances and its prospects in environmental remediation

• Katrina Pui Yee Shak,
• Yean Ling Pang and
• Shee Keat Mah

Beilstein J. Nanotechnol. 2018, 9, 2479–2498, doi:10.3762/bjnano.9.232

• nanostructures in the form of thin film, membrane, fibre and hybrid materials under UV and visible light irradiation. Nanocellulose–metal oxide (TiO2, ZnO, graphene oxide, and Fe2O3) composites have been used as photocatalysts to improve the degradation rate of organic pollutants as compared to individual

Electrospun one-dimensional nanostructures: a new horizon for gas sensing materials

• Muhammad Imran,
• Nunzio Motta and
• Mahnaz Shafiei

Beilstein J. Nanotechnol. 2018, 9, 2128–2170, doi:10.3762/bjnano.9.202

Facile phase transfer of gold nanorods and nanospheres stabilized with block copolymers

• Yaroslav I. Derikov,
• Georgiy A. Shandryuk,
• Raisa V. Talroze,
• Alexander A. Ezhov and
• Yaroslav V. Kudryavtsev

Beilstein J. Nanotechnol. 2018, 9, 616–627, doi:10.3762/bjnano.9.58

• copolymers doped with noble metal nanoparticles are considered as promising hybrid materials that combine the plasmonic, catalytic or other functionality of nanoparticles, their periodic spatial arrangement in the microphase separated copolymer domains and the general processability of polymer matrices [3][4

Liquid-crystalline nanoarchitectures for tissue engineering

• Baeckkyoung Sung and
• Min-Ho Kim

Beilstein J. Nanotechnol. 2018, 9, 205–215, doi:10.3762/bjnano.9.22

• local alignments, which resulted in directed and oriented growth of human mesenchymal stem cells and their osteogenic differentiation [105]. Additionally, biomineralization-mimicking hybrid materials, using chitin nanowhisker gel matrices in a nematic phase as templates for CaCO3 crystallization, have

Bombyx mori silk/titania/gold hybrid materials for photocatalytic water splitting: combining renewable raw materials with clean fuels

• Stefanie Krüger,
• Michael Schwarze,
• Otto Baumann,
• Christina Günter,
• Michael Bruns,
• Christian Kübel,
• Dorothée Vinga Szabó,
• Rafael Meinusch,
• Verónica de Zea Bermudez and
• Andreas Taubert

Beilstein J. Nanotechnol. 2018, 9, 187–204, doi:10.3762/bjnano.9.21

• Giessen, Germany Department of Chemistry and CQ-VR, University of Trás-os-Montes e Alto Douro, Pt-5001-801 Vila Real, Portugal 10.3762/bjnano.9.21 Abstract The synthesis, structure, and photocatalytic water splitting performance of two new titania (TiO2)/gold(Au)/Bombyx mori silk hybrid materials are

• resulting slightly yellow solid was purified via solvent exchange with EtOH/H2O (1:1 v/v), EtOH/H2O (3:7 v/v) each for at least 8 h at 60 °C, and finally with water for 24 h. Step 5: When a modification with AuNP was desired, the as-prepared wet silk/TiO2 hybrid materials obtained in step 4 were stored in

• washed three times with 50 mL of water at room temperature. Characterization Samples for all transmission electron microscopy (TEM) investigations were prepared as follows: small pieces (ca. 2 mm2) of the wet hybrid materials were immersed in a 3% glutaraldehyde solution in 0.1 M phosphate buffer (pH 7