Prediction of cytotoxicity of heavy metals adsorbed on nano-TiO₂ with periodic table descriptors using machine learning approaches

• Joyita Roy,
• Souvik Pore and
• Kunal Roy

Beilstein J. Nanotechnol. 2023, 14, 939–950, doi:10.3762/bjnano.14.77

• attention due to their widespread applications in different areas, and they are continually designed to yield certain desired properties [1]. With the uninterrupted development of new NPs, engineered nanoparticles in the form of metal oxide nanoparticles are becoming a new area of research. Metal oxides

• have been used in different industries, and the market is developing rapidly [2]. According to a recent analysis, approximately 1300 consumer products containing NPs were marketed in 2012. As a common metal oxide nanoparticle material, nanoscale titanium dioxide (nano-TiO2) has been evaluated for

• time-effectively and cost-effectively. The previously used descriptors by Kar et al. [23] are the metal electronegativity (χ), the sum of metal electronegativity for an individual metal oxide (∑χ), the sum of metal electronegativity for an individual metal oxide divided by the number of oxygen atoms

Carboxylic acids and light interact to affect nanoceria stability and dissolution in acidic aqueous environments

• Matthew L. Hancock,
• Eric A. Grulke and
• Robert A. Yokel

Beilstein J. Nanotechnol. 2023, 14, 762–780, doi:10.3762/bjnano.14.63

• structures. The authors thank Marsha Ensor for her contribution. This report is based on the following: Hancock, M. L. The Fabrication and Characterization of Metal Oxide Nanoparticles Employed in Environmental Toxicity and Polymeric Nanocomposite Applications. Doctoral Dissertation, University of Kentucky

Humidity-dependent electrical performance of CuO nanowire networks studied by electrochemical impedance spectroscopy

• Jelena Kosmaca,
• Juris Katkevics,
• Jana Andzane,
• Raitis Sondors,
• Liga Jasulaneca,
• Raimonds Meija,
• Kiryl Niherysh,
• Yelyzaveta Rublova and
• Donats Erts

Beilstein J. Nanotechnol. 2023, 14, 683–691, doi:10.3762/bjnano.14.54

• ; electrochemical impedance spectroscopy; humidity; nanowire; sensor; Introduction Semiconductor metal oxide nanomaterials have demonstrated a great potential for integration in a variety of devices, such as gas and humidity sensors, nanoelectronics, and low-power thermoelectrical generators [1][2][3][4][5][6

Metal-organic framework-based nanomaterials as opto-electrochemical sensors for the detection of antibiotics and hormones: A review

• Akeem Adeyemi Oladipo,
• Saba Derakhshan Oskouei and
• Mustafa Gazi

Beilstein J. Nanotechnol. 2023, 14, 631–673, doi:10.3762/bjnano.14.52

• of their exceptionally high thermal and electrical conductivities, effective catalytic properties, high chemical stability, rapid rate of electron transfer, adequate surface area, and favourable piezoelectric, electronic and gravimetric properties, metal and metal oxide materials with sizes less than

• of a distinct linker, and the creation of MOF composites with other conducting materials (carbon-based, metal, and mixed metal oxide nanoparticles) are just a few experimental strategies that have been suggested to further improve the electronic properties of MOFs. Luminescence properties: The fact

Plasmonic nanotechnology for photothermal applications – an evaluation

• A. R. Indhu,
• L. Keerthana and
• Gnanaprakash Dharmalingam

Beilstein J. Nanotechnol. 2023, 14, 380–419, doi:10.3762/bjnano.14.33

• theory, Gans theory, generic simulations on common plasmonic material morphologies, and the evaluation processes of PT performance. Further, a variety of nanomaterials and material classes that have potential for PPT conversion are elucidated, such as plasmonic metals, bimetals, and metal–metal oxide

• semiconductor metal oxide nanoparticles exhibit the spill-over effect, which alters the plasmonic absorption and spectral width of the plasmonic nanoparticles integrated in dielectric matrices. This spill-over effect, however, decreases with a decrease in electron density. For nanoparticles with low electron

Bismuth-based nanostructured photocatalysts for the remediation of antibiotics and organic dyes

• Akeem Adeyemi Oladipo and
• Faisal Suleiman Mustafa

Beilstein J. Nanotechnol. 2023, 14, 291–321, doi:10.3762/bjnano.14.26

• of the bismuth-based photocatalysts with some of the typical metal oxide-based photocatalysts. Some of these important variables and values have been extracted from articles that have been published [27][28][29][30][31][32][33][34][35][36][37][38]. As an alternative to TiO2 for photocatalysis

High–low Kelvin probe force spectroscopy for measuring the interface state density

• Ryo Izumi,
• Masato Miyazaki,
• Yan Jun Li and
• Yasuhiro Sugawara

Beilstein J. Nanotechnol. 2023, 14, 175–189, doi:10.3762/bjnano.14.18

• metal-oxide semiconductor capacitors on Si(100) substrates, the lifetimes τn and τp as functions of the sum of the surface potential and the Fermi potential with respect to the midgap have been experimentally investigated [24]. As a result, for Si semiconductors with a low carrier density (small Fermi

Double-layer symmetric gratings with bound states in the continuum for dual-band high-Q optical sensing

• Chaoying Shi,
• Jinhua Hu,
• Xiuhong Liu,
• Junfang Liang,
• Jijun Zhao,
• Haiyan Han and
• Qiaofen Zhu

Beilstein J. Nanotechnol. 2022, 13, 1408–1417, doi:10.3762/bjnano.13.116

• complementary metal oxide semiconductor (CMOS) processes [13][14]. It has been shown that the HCG system can support the optical bound states in the continuum (BICs) [15][16][17][18]. BIC plays an important role in determining the characteristics of the radiative high-Q resonance [17]. However, there are fewer

Application of nanoarchitectonics in moist-electric generation

• Jia-Cheng Feng and
• Hong Xia

Beilstein J. Nanotechnol. 2022, 13, 1185–1200, doi:10.3762/bjnano.13.99

• contributed significantly to the development of the principle exploration of MEG. Future research work should be inspired by these proof-of-principle studies to develop innovative advances. 2.2 Metal compounds Metal oxide and transition metal chalcogenide materials perform similarly in MEGs. These materials

Rapid fabrication of MgO@g-C₃N₄ heterojunctions for photocatalytic nitric oxide removal

• Minh-Thuan Pham,
• Duyen P. H. Tran,
• Xuan-Thanh Bui and
• Sheng-Jie You

Beilstein J. Nanotechnol. 2022, 13, 1141–1154, doi:10.3762/bjnano.13.96

• (+1.75 eV) is more negative than that of H2O/•OH (+2.40 eV), reducing the photocatalytic efficiency [16][17]. A well-known approach for overcoming this problem in order to achieve increased photocatalytic performance is to couple two semiconductors with optimal band alignment. MgO is an alkaline metal

• oxide with wide bandgap (3.5–5 eV), high availability, non-toxicity, low cost, and native structural defects [18][19]. The large bandgap energy is the limitation of MgO, reducing the photocatalytic performance and applicability of MgO [20]. Various efforts have been made to enhance the absorption in the

Spindle-like MIL101(Fe) decorated with Bi₂O₃ nanoparticles for enhanced degradation of chlortetracycline under visible-light irradiation

• Chen-chen Hao,
• Fang-yan Chen,
• Kun Bian,
• Yu-bin Tang and
• Wei-long Shi

Beilstein J. Nanotechnol. 2022, 13, 1038–1050, doi:10.3762/bjnano.13.91

• be improved by combining it with other suitable semiconductor materials to construct Z-scheme heterojunctions. Bismuth trioxide (Bi2O3), a metal oxide semiconductor with a bandgap of 2.8 eV, can be excited by visible light [43][44]. However, pure Bi2O3 exhibits poor photocatalytic activity due to the

Theoretical investigations of oxygen vacancy effects in nickel-doped zirconia from ab initio XANES spectroscopy at the oxygen K-edge

• Dick Hartmann Douma,
• Lodvert Tchibota Poaty,
• Alessio Lamperti,
• Stéphane Kenmoe,
• Abdulrafiu Tunde Raji,
• Alberto Debernardi and
• Bernard M’Passi-Mabiala

Beilstein J. Nanotechnol. 2022, 13, 975–985, doi:10.3762/bjnano.13.85

• absorption near-edge structure (XANES) spectroscopy becomes relevant since its signature can indirectly reveal the presence of O vacancies in a metal oxide matrix. It is therefore a technique useful to understand the microscopic origin of magnetism in DMO. XANES spectroscopy concerns the part of the X-ray

Comparative molecular dynamics simulations of thermal conductivities of aqueous and hydrocarbon nanofluids

• Adil Loya,
• Antash Najib,
• Fahad Aziz,
• Asif Khan,
• Guogang Ren and
• Kun Luo

Beilstein J. Nanotechnol. 2022, 13, 620–628, doi:10.3762/bjnano.13.54

• , Karachi, Pakistan University of Hertfordshire, School of Engineering and Technology, Hatfield, UK Changzhou University, School of Materials Science and Engineering, Changzhou Science Town, Changzhou, P. R. China 10.3762/bjnano.13.54 Abstract The addition of metal oxide nanoparticles to fluids has been

• ., alkane) the thermal conductivity was increased three times (from 0.1 to 0.4 W·m−1·K−1). This approach to determine the thermal conductivity of metal oxide nanoparticles in aqueous and nonaqueous fluids using visual molecular dynamics and interactive autocorrelations demonstrate a great tool to quantify

• nanoparticles with the hydrocarbon-based fluid took less time to stabilise (i.e., about 10 picoseconds). This is because in the aqueous medium, intermolecular collisions and dynamics of metal oxide atoms form metal ionic bonding, thereby taking more time for equilibration. Moreover, the velocity of the CuO

Relationship between corrosion and nanoscale friction on a metallic glass

• Haoran Ma and
• Roland Bennewitz

Beilstein J. Nanotechnol. 2022, 13, 236–244, doi:10.3762/bjnano.13.18

• are susceptible to corrosion when exposed to environmental conditions, the role of surface chemistry for friction must be investigated. At the macroscale, the existence of metal oxide surface films on MGs enhanced the wear resistance in corrosive solutions and the fluid lubricating films formed by

Thermal oxidation process on Si(113)-(3 × 2) investigated using high-temperature scanning tunneling microscopy

• Hiroya Tanaka,
• Shinya Ohno,
• Kazushi Miki and
• Masatoshi Tanaka

Beilstein J. Nanotechnol. 2022, 13, 172–181, doi:10.3762/bjnano.13.12

• three-dimensional metal oxide semiconductor field-effect transistors (MOSFETs) [1]. Here, formation processes of ultrathin SiO2 at the interface are considered to be quite important in determining its dielectric properties. To study procedures to fabricate gate dielectrics, it will be necessary to

Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• introducing defects in metal oxide semiconductors opens up the possibility of their use in the visible spectrum [77]. Recently, Xie et al. reported using SnO2/graphene quantum dot (GQD) composites. They showed that the absorption edge of as-prepared SnO2 (Figure 13a black line) is around 340 nm, equaling to a

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

• NPs with desired size, shape, and composition [2]. Colloidal synthesis allows one to obtain metal, oxide, halide, chalcogenide, and other types of NPs but the mechanisms of their formation are different, even though all of them include an initial nucleation step followed by a growth step [77]. In this

Identifying diverse metal oxide nanomaterials with lethal effects on embryonic zebrafish using machine learning

• Richard Liam Marchese Robinson,
• Haralambos Sarimveis,
• Philip Doganis,
• Xiaodong Jia,
• Marianna Kotzabasaki,
• Christiana Gousiadou,
• Stacey Lynn Harper and
• Terry Wilkins

Beilstein J. Nanotechnol. 2021, 12, 1297–1325, doi:10.3762/bjnano.12.97

• , embryonic zebrafish (Danio Rerio) are recognised as a key human safety relevant in vivo test system. Hence, machine learning models were developed for identifying metal oxide nanomaterials causing lethality to embryonic zebrafish up to 24 hours post-fertilisation, or excess lethality in the period of 24–120

• -based magnetic resonance imaging (MRI) contrast agent (Feridex) was withdrawn from the market, following concerns regarding its observed side effects [2][7]. In spite of concerns around safety [7][8][9] and other challenges [10], there remains interest in developing novel metal oxide nanomaterials for

• various biomedical applications [10][11][12], as well as applications in other areas, such as in agriculture [13]. Nonetheless, the possibility that novel metal oxide ENMs developed for applications, such as biomedical applications, could be harmful to human health [8][9], means that there is a real need

Plasmon-enhanced photoluminescence from TiO₂ and TeO₂ thin films doped by Eu³⁺ for optoelectronic applications

• Marcin Łapiński,
• Jakub Czubek,
• Katarzyna Drozdowska,
• Anna Synak,
• Wojciech Sadowski and
• Barbara Kościelska

Beilstein J. Nanotechnol. 2021, 12, 1271–1278, doi:10.3762/bjnano.12.94

• . Interestingly, no transition caused by the electric dipole (615 nm, typical for Eu3+ ions) was observed in the emission spectrum for both kinds of metal oxide matrix. The main emission peak corresponds to the transition occurring via magnetic dipole, which is independent of the host matrix. Such a phenomenon

Morphology-driven gas sensing by fabricated fractals: A review

• Vishal Kamathe and
• Rupali Nagar

Beilstein J. Nanotechnol. 2021, 12, 1187–1208, doi:10.3762/bjnano.12.88

• metal oxide (SMO) sensors are most popular due to their low cost, simplicity, easy fabrication, and wide range of gas detection capabilities [9]. Thin films and nanostructures exhibit better sensing characteristics. Various researchers have reported structures with morphologies such as nanowires (NWs

pH-driven enhancement of anti-tubercular drug loading on iron oxide nanoparticles for drug delivery in macrophages

• Karishma Berta Cotta,
• Sarika Mehra and
• Rajdip Bandyopadhyaya

Beilstein J. Nanotechnol. 2021, 12, 1127–1139, doi:10.3762/bjnano.12.84

• ]. Furthermore, their interaction with IONPs may be via carboxylate groups, amine groups or by neither [27]. pH variations thus can play a key role in promoting interactions between amino acids and metal oxide surfaces [29]. NOR has also been reported to form stable complexes with Fe2+/3+ [22]. It was also

Assessment of the optical and electrical properties of light-emitting diodes containing carbon-based nanostructures and plasmonic nanoparticles: a review

• Keshav Nagpal,
• Erwan Rauwel,
• Frédérique Ducroquet and
• Protima Rauwel

Beilstein J. Nanotechnol. 2021, 12, 1078–1092, doi:10.3762/bjnano.12.80

• , the device with 2–3% Ag-doped ZnO EIL shows maximum luminance of 10982 cd/m2, maximum current efficiency of 41.0 cd/A, and EQE of 15.2%. The addition of AgNP to PBD-based ETL enhances the green emission [75]. Kandulna et al. have addressed the effect of plasmonic NP on hybrid metal oxide–polymer

• enhanced through the SPR effect of AgNP, which in turn could counteract the high external luminance. Thus, the low brightness and short operation lifetime of blue QLED could be improved by using CNT–polymer or CNT–metal oxide nanocomposites as ETL and incorporating AgNP in this layer. Further strategies to

• , and maximum luminance of various LED with carbon nanostructures, plasmonic, and metal oxide NP in the device layers. Funding This research has been supported by the European Regional Development Fund project EQUiTANT TK134 (F180175TIBT) and EMÜ bridge funding P200030TIBT.

Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries

• Marina Tabuyo-Martínez,
• Bernd Wicklein and
• Pilar Aranda

Beilstein J. Nanotechnol. 2021, 12, 995–1020, doi:10.3762/bjnano.12.75

• 10 A·g−1) [49]. Metallic and metal oxide compounds have also attracted much interest due to their electronic conductivity and their high polarity, which leads to strong chemical interaction with polysulfides. For instance, Yan et al. [50] reported an electrode with an excellent performance that is

Molecular assemblies on surfaces: towards physical and electronic decoupling of organic molecules

• Sabine Maier and
• Meike Stöhr

Beilstein J. Nanotechnol. 2021, 12, 950–956, doi:10.3762/bjnano.12.71

• the substituents of the pyrenes derivatives [87]. Metal oxide thin films on top of metal substrates are another interesting class of ultrathin interfacial layers to decouple organic molecules and to enable the study of their electronic properties without the contribution of the underlying metal

• molecular conformation by planarizing the carbon backbone as well as the self-assembly. Hurdax et al. [89] suggested that work function measurements before and after the adsorption of molecules should give insight into the electronic and physical decoupling. It should be noted that metal oxide thin films

The role of deep eutectic solvents and carrageenan in synthesizing biocompatible anisotropic metal nanoparticles

• Nabojit Das,
• Akash Kumar and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2021, 12, 924–938, doi:10.3762/bjnano.12.69

• the principles of green chemistry. Despite extensive studies for more than a decade, DESs as solvents for nanomaterial synthesis yet awaits exploration regarding biological applications. In an interesting recently published work, a natural deep eutectic solvent (NADES) has been used to extract metal

• oxide nanoparticles [28]. Numerous indispensable parameters including surface tension, polarity, viscosity, and hydrogen bonding have an important influence on the reactivity of species. Also, the formation of nanostructures is governed by the mass transport properties of the DES components. It is also