One-step nonhydrolytic sol–gel synthesis of mesoporous TiO₂ phosphonate hybrid materials

• Yanhui Wang,
• P. Hubert Mutin and
• Johan G. Alauzun

Beilstein J. Nanotechnol. 2019, 10, 356–362, doi:10.3762/bjnano.10.35

• lack of porosity of this sample likely results from the interdigitation or mixing of the alkyl chains. These mesoporous metal oxide–phosphonate materials can be seen as a low-cost alternative to periodic mesoporous organosilicas (PMOs) and metal–organic frameworks (MOFs) for applications in the field

The nanoscaled metal-organic framework ICR-2 as a carrier of porphyrins for photodynamic therapy

• Jan Hynek,
• Sebastian Jurík,
• Martina Koncošová,
• Jaroslav Zelenka,
• Ivana Křížová,
• Tomáš Ruml,
• Kaplan Kirakci,
• Ivo Jakubec,
• František Kovanda,
• Kamil Lang and
• Jan Demel

Beilstein J. Nanotechnol. 2018, 9, 2960–2967, doi:10.3762/bjnano.9.275

• Technology, Technická 5, 166 28 Prague, Czech Republic 10.3762/bjnano.9.275 Abstract Nanosized porphyrin-containing metal-organic frameworks (MOFs) attract considerable attention as solid-state photosensitizers for biological applications. In this study, we have for the first time synthesised and

• ; Introduction Metal-organic frameworks (MOFs) are a class of crystalline coordination polymers possessing potential voids. Their structures combine inorganic nodes, metal centres forming so-called secondary building units (SBU), with organic linkers. The diversity of possible SBUs coupled with organic linkers

Uniform cobalt nanoparticles embedded in hexagonal mesoporous nanoplates as a magnetically separable, recyclable adsorbent

• Can Zhao,
• Yuexiao Song,
• Tianyu Xiang,
• Wenxiu Qu,
• Shuo Lou,
• Xiaohong Yin and
• Feng Xin

Beilstein J. Nanotechnol. 2018, 9, 1770–1781, doi:10.3762/bjnano.9.168

• metal-organic frameworks (MOFs) with tunable cavities and tailorable chemistry have been demonstrated as precursors to generate TM-MCNs with various morphologies [16][17], it is still a significant challenge to prepare two-dimensional (2D) TM-MCNs derived from MOFs. TM-MCNs with 2D morphology are of

Tailoring the nanoscale morphology of HKUST-1 thin films via codeposition and seeded growth

• Landon J. Brower,
• Lauren K. Gentry,
• Amanda L. Napier and
• Mary E. Anderson

Beilstein J. Nanotechnol. 2017, 8, 2307–2314, doi:10.3762/bjnano.8.230

• -organic frameworks (MOFs), composed of both metal ions and organic ligands, represent a class of extremely porous, crystalline materials with high surface area. Research has investigated their integration as thin films, namely surface-anchored metal-organic frameworks (surMOFs), into a wide variety of

• controllable nanoscale dimensions can be designed and fabricated for integration of MOF systems directly into device architectures and sensor platforms. Keywords: atomic force microscopy; copper(II) 1,3,5-benzenetricarboxylate; ellipsometry; surface-anchored metal-organic frameworks; Introduction Metal

Experimental techniques for the characterization of carbon nanoparticles – a brief overview

• Wojciech Kempiński,
• Szymon Łoś,
• Mateusz Kempiński and
• Damian Markowski

Beilstein J. Nanotechnol. 2014, 5, 1760–1766, doi:10.3762/bjnano.5.186

• to control the charge carrier transport (“tunable electrical conductivity”) was shown in porous metal-organic frameworks (MOFs) with adsorbed guest molecules [9]. It was also shown that by appropriate choice of guest molecules, it is possible to control the charge (spin) transport in the nano

Quasi-1D physics in metal-organic frameworks: MIL-47(V) from first principles

• Danny E. P. Vanpoucke,
• Jan W. Jaeken,
• Stijn De Baerdemacker,
• Kurt Lejaeghere and
• Veronique Van Speybroeck

Beilstein J. Nanotechnol. 2014, 5, 1738–1748, doi:10.3762/bjnano.5.184

• dispersion along the the direction of the VO6 chains, similar as for other quasi-1D materials. Keywords: band structure; density functional theory (DFT); low-dimensional electronics; metal-organic frameworks (MOFs); MIL-47; Introduction Metal-organic frameworks (MOFs) present a class of materials located

Magnesium batteries: Current state of the art, issues and future perspectives

• Rana Mohtadi and
• Fuminori Mizuno

Beilstein J. Nanotechnol. 2014, 5, 1291–1311, doi:10.3762/bjnano.5.143

• study proposed using coordinatively unsaturated metal-organic frameworks (MOFs) as nano media to immobilize magnesium phenolate and/or Mg(TFSI)2/triglyme electrolytes (phenolates were found to be more soluble in triglyme than in tetrahydrofuran) [50]. As the phenolates were strongly interacting with the

Neutral and charged boron-doped fullerenes for CO₂ adsorption

• Suchitra W. de Silva,
• Aijun Du,
• Wijitha Senadeera and
• Yuantong Gu

Beilstein J. Nanotechnol. 2014, 5, 413–418, doi:10.3762/bjnano.5.49

• years metal organic frameworks (MOFs) have emerged as solid CO2 adsorbent materials due to their tuneable chemical and physical properties. Particularly, there is growing interest for metal free carbon-based nanomaterials for gas adsorption. Carbon-based nanomaterials such as fullerene, carbon nanotubes

Site-selective growth of surface-anchored metal-organic frameworks on self-assembled monolayer patterns prepared by AFM nanografting

• Tatjana Ladnorg,
• Alexander Welle,
• Stefan Heißler,
• Christof Wöll and
• Hartmut Gliemann

Beilstein J. Nanotechnol. 2013, 4, 638–648, doi:10.3762/bjnano.4.71

• grown via LPE were investigated and characterized by atomic force microscopy and Fourier-transform infrared microscopy. Keywords: atomic force microscopy (AFM); metal-organic frameworks; nanografting; nanoshaving; SURMOF; Introduction Metal organic frameworks (MOFs) are highly crystalline three

The oriented and patterned growth of fluorescent metal–organic frameworks onto functionalized surfaces

• Jinliang Zhuang,
• Jasmin Friedel and
• Andreas Terfort

Beilstein J. Nanotechnol. 2012, 3, 570–578, doi:10.3762/bjnano.3.66

• -assembled monolayer; surface-attached metal–organic framework; Introduction Metal–organic frameworks (MOFs) are a fascinating class of organic–inorganic hybrid materials with nanometer-sized pores. The size and density of the pores renders these materials with extraordinary large free volumes and inner

Micro- and mesoporous solids: From science to application

• Jörg J. Schneider

Beilstein J. Nanotechnol. 2011, 2, 774–775, doi:10.3762/bjnano.2.85

• , geometry and pore dimensions make these materials outstanding with respect to, e.g., catalytic reaction processes, in the area of sensorics, photonics and gas storage (Figure 1). In the realm of gas storage, mesoporous metal–organic frameworks (MOFs) appeared on the scene a couple of years ago and have

On the reticular construction concept of covalent organic frameworks

• Binit Lukose,
• Agnieszka Kuc,
• Johannes Frenzel and
• Thomas Heine

Beilstein J. Nanotechnol. 2010, 1, 60–70, doi:10.3762/bjnano.1.8

• preservation throughout the assembly process are the key factors that lead to the design and synthesis of reticular structures. One of the first families of materials synthesized using reticular chemistry were the so-called Metal-Organic Frameworks (MOFs) [4]. They are composed of metal-oxide connectors, which