A comparative study of the nanoscale and macroscale tribological attributes of alumina and stainless steel surfaces immersed in aqueous suspensions of positively or negatively charged nanodiamonds

• Colin K. Curtis,
• Antonin Marek,
• Alex I. Smirnov and
• Jacqueline Krim

Beilstein J. Nanotechnol. 2017, 8, 2045–2059, doi:10.3762/bjnano.8.205

• dominate the tribological performance. The surface charges on ND are also expected to affect the interfacial solid–fluid slip lengths attributes, and therefore the apparent fluid viscosity, via electroviscous and/or steric mechanisms [18][19][20]. Fundamental studies at the nanoscale are clearly essential

• of the liquid under no-slip boundary conditions are given by [35]: where ρq = 2.648 g/cm3 is the density and µq = 2.947 × 1011 g/cm/s2 is the shear modulus of quartz. Immersion of one side of a 5 MHz resonant frequency QCM in water at room temperature (ρ3 = 1 g/cm3, η3 = 0.01 poise) results in a δf

• is manifested as an increase in the series resonant resistance Rm of the QCM resonator that can be measured electrically. For a QCM electrode exposed to a fluid from one side under non-slip conditions [36][37]: where K2 = 7.74 × 10−3 is the electromechanical coupling factor for the AT cut quartz (AT

Stick–slip boundary friction mode as a second-order phase transition with an inhomogeneous distribution of elastic stress in the contact area

• Iakov A. Lyashenko,
• Vadym N. Borysiuk and
• Valentin L. Popov

Beilstein J. Nanotechnol. 2017, 8, 1889–1896, doi:10.3762/bjnano.8.189

• the stick–slip mode of boundary friction. An analytical description and numerical simulation with radial distributions of the order parameter, stress and strain were performed to investigate the spatial inhomogeneity. It is shown that in the case when the driving device is connected to the upper part

• of the friction block through an elastic spring, the frequency of the melting/solidification phase transitions increases with time. Keywords: boundary friction; dimensionality reduction; numerical simulation; shear stress and strain; stick–slip motion; tribology; Introduction The boundary friction

• structure states which may lead to the stick–slip motion with non-monotonic time dependence of the friction force [1][2][4][5]. Stick–slip motion is known to cause fast destruction of the contact parts of microscopic devices, which is why it receives significant attention from the scientists and engineers

The effect of the electrical double layer on hydrodynamic lubrication: a non-monotonic trend with increasing zeta potential

• Dalei Jing,
• Yunlu Pan and
• Xiaoming Wang

Beilstein J. Nanotechnol. 2017, 8, 1515–1522, doi:10.3762/bjnano.8.152

• and have the same zeta potential, ζ. The lubricant film thickness is much larger than the Debye length, thus, the two EDLs are non-overlapped. The no slip condition of the velocity is considered. The lubricant is an incompressible Newtonian fluid in the steady laminar state. Inertial force is

Liquid permeation and chemical stability of anodic alumina membranes

• Dmitrii I. Petukhov,
• Dmitrii A. Buldakov,
• Alexey A. Tishkin,
• Alexey V. Lukashin and
• Andrei A. Eliseev

Beilstein J. Nanotechnol. 2017, 8, 561–570, doi:10.3762/bjnano.8.60

• carbon coating (Figure 8). A slight decrease of the ethanol permeance from 49.4 ± 2.1 to 41.9 ± 0.5 L/(m2·bar·h) was observed for the composite membrane. In comparison with earlier published studies [26][27], we have not observed any improvement of the membrane performance due to slip flow. This can

Studying friction while playing the violin: exploring the stick–slip phenomenon

• Santiago Casado

Beilstein J. Nanotechnol. 2017, 8, 159–166, doi:10.3762/bjnano.8.16

• Santiago Casado Madrid Institute for Advanced Studies in Nanoscience (IMDEA Nanoscience), Faraday 9, Ciudad Universitaria de Cantoblanco, 28049 Madrid, Spain 10.3762/bjnano.8.16 Abstract Controlling the stick–slip friction phenomenon is of major importance for many familiar situations. This

• the case of a musical bow-stringed instrument, stick–slip is controlled in order to provide well-tuned notes at different intensities. A trained ear is able to distinguish slight sound variations caused by small friction differences. Hence, a violin can be regarded as a perfect benchmark to explore

• the stick–slip effect at the mesoscale. Two violin bow hairs were studied, a natural horse tail used in a professional philharmonic orchestra, and a synthetic one used with a violin for beginners. Atomic force microscopy characterization revealed clear differences when comparing the surfaces of both

Structural and tribometric characterization of biomimetically inspired synthetic "insect adhesives"

• Matthias W. Speidel,
• Malte Kleemeier,
• Andreas Hartwig,
• Klaus Rischka,
• Angelika Ellermann,
• Rolf Daniels and
• Oliver Betz

Beilstein J. Nanotechnol. 2017, 8, 45–63, doi:10.3762/bjnano.8.6

• (grease-like) consistency of the adhesive emulsion with increased viscosity, in accordance with the properties of a Bingham fluid. Such a property would consolidate several functional principles and properties that are essential for effective locomotion: (1) improving slip resistance, (2) facilitating

• speed in VG50, VP50 and WP20, the opposite was the case in WG20 (Figure 4a, Supporting Information File 1, Tables S2 and S11). In addition, the friction curves of emulsion VG50 showed a stick and slip pattern (not shown), especially at 50 µm s−1; this was caused by the short-term sticking of the

• property would consolidate several functions in the context of effective locomotion (and possibly technical applications) such as Bingham-like slip resistance, tarsal releasability, desiccation resistance, mechanical compliance and protection from abrasive damage. Tarsal releasability might be brought by

When the going gets rough – studying the effect of surface roughness on the adhesive abilities of tree frogs

• Niall Crawford,
• Thomas Endlein,
• Jonathan T. Pham,
• Mathis Riehle and
• W. Jon P. Barnes

Beilstein J. Nanotechnol. 2016, 7, 2116–2131, doi:10.3762/bjnano.7.201

• = −5.7368, p < 0.0001). As the roughness of the surfaces increased, this resulted in a decrease in the angle of slip. Slipping occurred before vertical (mean of 89.4°) on the 30 µm surface, significantly lower than on the smooth surface (z = 3.6554, p < 0.0001). On the largest roughnesses, frogs performed

• and fell were recorded, which relate to their frictional and adhesive abilities, respectively. Results for this experiment are shown in Figure 7. The angles of slip and fall on the dry smooth surface (97.6 ± 6.2° for slip and 121.2 ± 6.1° for fall) were broadly similar to the results described

• previously (in the free climbing tree frog section). Likewise, the frogs also attached poorly to the dry rough surfaces (slip angle: 73.4 ± 4.98°, fall angle: 82.8 ± 3.7°). However, when water was introduced to the smooth surface, it caused a loss of friction in the frogs’ pads. This lead to the frogs

“Sticky invasion” – the physical properties of Plantago lanceolata L. seed mucilage

• Agnieszka Kreitschitz,
• Alexander Kovalev and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2016, 7, 1918–1927, doi:10.3762/bjnano.7.183

• the following equation: where the first sum minimizes the deviation of the estimated slip angle from the measured slip angle and the second sum is a regulatory term smoothing the curves of μ and Fad. D2 is an operator of the second derivative of time, λ is a regulatory parameter, c is a weighing

A new approach to grain boundary engineering for nanocrystalline materials

• Shigeaki Kobayashi,
• Sadahiro Tsurekawa and
• Tadao Watanabe

Beilstein J. Nanotechnol. 2016, 7, 1829–1849, doi:10.3762/bjnano.7.176

• probably deformed by shear stress as in the case of a single crystal, because the persistent slip bands (PSBs) can continuously transfer across the low-angle boundaries [97]. The fatigue cracks preferentially nucleated along random boundaries whose boundary plane may almost correspond to the direction of

Biomechanics of selected arborescent and shrubby monocotyledons

• Tom Masselter,
• Tobias Haushahn,
• Samuel Fink and
• Thomas Speck

Beilstein J. Nanotechnol. 2016, 7, 1602–1619, doi:10.3762/bjnano.7.154

• clamping jaws was carefully adjusted to prevent radial crushing of the sample but at the same time to prevent any axial slip during testing. Details on the individual testing procedures per plant are provided in Supporting Information File 2. For the determination of the Young’s modulus (MoE) an ordinary

Deformation-driven catalysis of nanocrystallization in amorphous Al alloys

• Rainer J. Hebert,
• John H. Perepezko,
• Harald Rösner and
• Gerhard Wilde

Beilstein J. Nanotechnol. 2016, 7, 1428–1433, doi:10.3762/bjnano.7.134

• spikes with shear band formation [43], but models were also developed that demonstrated stick–slip of shear bands and “cold” temperatures in the shear bands [44]. The findings on temperature behavior in shear bands of metallic glasses over the last years were summarized by Greer, Cheng, and Ma [45]. One

Reasons and remedies for the agglomeration of multilayered graphene and carbon nanotubes in polymers

• Rasheed Atif and
• Fawad Inam

Beilstein J. Nanotechnol. 2016, 7, 1174–1196, doi:10.3762/bjnano.7.109

The hydraulic mechanism in the hind wing veins of Cybister japonicus Sharp (order: Coleoptera)

• Jiyu Sun,
• Wei Wu,
• Mingze Ling,
• Bharat Bhushan and
• Jin Tong

Beilstein J. Nanotechnol. 2016, 7, 904–913, doi:10.3762/bjnano.7.82

• shown in Figure 2. At 0.036 s, the opening of the elytra appears; at 0.054 s, the hind wings slip from the elytra that are gradually rotating and ascending to a certain height; at 0.651 s, the hind wings start flapping but are still folded; until 0.741 s, the elytra keep rotating outward and lifting

Characterization of spherical domains at the polystyrene thin film–water interface

• Khurshid Ahmad,
• Xuezeng Zhao,
• Yunlu Pan and
• Danish Hussain

Beilstein J. Nanotechnol. 2016, 7, 581–590, doi:10.3762/bjnano.7.51

• example, to study boundary slip and micro-/nanobubble formation [15][16][17][18][19]. Nanobubbles are gaseous domains that may be found at a solid–liquid interface. Over the past few decades, dedicated research has been carried out on nanobubbles at the solid–liquid interface. AFM has been proven to be a

Nanoscale rippling on polymer surfaces induced by AFM manipulation

• Mario D’Acunto,
• Franco Dinelli and
• Pasqualantonio Pingue

Beilstein J. Nanotechnol. 2015, 6, 2278–2289, doi:10.3762/bjnano.6.234

• of an AFM tip on polymer films are basically three: Schallamach waves [28], stick–slip behavior [52][53], and fracture-based descriptions [15][48]. On the macroscale, Schallamach waves are a reversible phenomenon that occurs at the surface of an elastomer when it slides past a stiff surface under

• contact area. Or, it is better to say that the possible formation of Schallamach waves within the contact area cannot be observed. Therefore the formation of nanoripples is a phenomenon that occurs at the front edge of the contact. In particular, it has been suggested to be due to a stick–slip motion of

• the tip during the stage movement. A hole forms where the tip resides and a mound forms in front of the tip hindering the sliding motion [20]. The tip can slip over when the cantilever exerts a lateral force larger than the tip–sample adhesive interaction. Then the tip forms a new pair of hole and

Electroviscous effect on fluid drag in a microchannel with large zeta potential

• Dalei Jing and
• Bharat Bhushan

Beilstein J. Nanotechnol. 2015, 6, 2207–2216, doi:10.3762/bjnano.6.226

• . Nevertheless, the study on the combined effect of EDL with large zeta potential up to several hundred millivolts and surface charge depenedent-slip on the micro/nano flow is still needed. In this paper, the nonlinear Poisson–Boltzmann equation for electrical potential and ion distribution in non-overlapping

• EDL is first analytically solved. Then, the modified Navier–Stokes equation for the flow considering the effect of surface charge on the electrical conductivity of the electrolyte and slip length is analytically solved. This analysis is used to study the effect of non-overlapping EDL with large zeta

• potential on the pressure-driven flow in a microchannel with no-slip and charge-dependent slip conditions. The results show that the EDL leads to an increase in the fluid drag, but that slip can reduce the fluid drag. When the zeta potential is large enough, the electroviscous effect disappears for flow in

Tattoo ink nanoparticles in skin tissue and fibroblasts

• Colin A. Grant,
• Peter C. Twigg,
• Richard Baker and
• Desmond J. Tobin

Beilstein J. Nanotechnol. 2015, 6, 1183–1191, doi:10.3762/bjnano.6.120

• gently washed before mounting with a glass cover slip. Skin tissue collection for isolation and culture of dermal fibroblasts Normal human tissue (female, 35 years of age) was sourced from elective plastic surgery (facelift) and placed immediately in transport media. After arrival at the laboratory the

Automatic morphological characterization of nanobubbles with a novel image segmentation method and its application in the study of nanobubble coalescence

• Yuliang Wang,
• Huimin Wang,
• Shusheng Bi and
• Bin Guo

Beilstein J. Nanotechnol. 2015, 6, 952–963, doi:10.3762/bjnano.6.98

• -range attractive hydrophobic forces [19][20]. The coalescence of NBs on hydrophobic surfaces is believed to form a gas bridge and leads to long-range attractive forces [19][21]. They are also believed to be the reason for the breakdown of the no-slip boundary condition at the solid–liquid interface on

Stiffness of sphere–plate contacts at MHz frequencies: dependence on normal load, oscillation amplitude, and ambient medium

• Jana Vlachová,
• Rebekka König and
• Diethelm Johannsmann

Beilstein J. Nanotechnol. 2015, 6, 845–856, doi:10.3762/bjnano.6.87

• tentatively explained by the rocking motion of the spheres, which couples to a squeeze flow of the water close to the contact. The loss tangent of the contact stiffness is on the order of 0.1, where the energy losses are associated with interfacial processes. At high amplitudes partial slip was found to occur

• can be explained by nanoroughness. In other words, contact splitting (i.e., a transport of shear stress across many small contacts, rather than a few large ones) can be exploited to reduce partial slip. Keywords: contact mechanics; contact splitting; contact stiffness; partial slip; quartz crystal

• microbalance; Introduction Partial slip is a widespread and multifacetted phenomenon. When a contact experiences partial slip, parts of a contact stick to each other under a tangential stress, while others slide. Partial slip is found in many tribological situations of practical relevance. This includes

Stick–slip behaviour on Au(111) with adsorption of copper and sulfate

• Nikolay Podgaynyy,
• Sabine Wezisla,
• Christoph Molls,
• Shahid Iqbal and
• Helmut Baltruschat

Beilstein J. Nanotechnol. 2015, 6, 820–830, doi:10.3762/bjnano.6.85

• found on Au(111) in sulfuric acid electrolyte containing Cu ions when a monolayer (or submonolayer) of Cu is adsorbed. At the corresponding normal loads, a transition to double or multiple slips in stick–slip friction is observed. The stick length in this case corresponds to multiples of the lattice

• distance of the adsorbed sulfate, which is adsorbed in a √3 × √7 superstructure on the copper monolayer. Stick–slip behaviour for the copper monolayer as well as for 2/3 coverage can be observed at FN ≥ 15 nN. At this normal load, a change from a small to a large friction coefficient occurs. This leads to

• the interpretation that the tip penetrates the electrochemical double layer at this point. At the potential (or point) of zero charge (pzc), stick–slip resolution persists at all normal forces investigated. Keywords: AFM; friction; friction force microscopy; nanotribology; underpotential deposition

Data-adaptive image-denoising for detecting and quantifying nanoparticle entry in mucosal tissues through intravital 2-photon microscopy

• Torsten Bölke,
• Lisa Krapf,
• Regina Orzekowsky-Schroeder,
• Tobias Vossmeyer,
• Jelena Dimitrijevic,
• Horst Weller,
• Anna Schüth,
• Antje Klinger,
• Gereon Hüttmann and
• Andreas Gebert

Beilstein J. Nanotechnol. 2014, 5, 2016–2025, doi:10.3762/bjnano.5.210

• slip to dampen movement artefacts (Figure 9). The gut segment was constantly moisturized with pre-warmed saline, and the body core temperature was maintained at 37 °C by using a homeothermic table. The mucosa was steadily perfused, as seen by an erythrocyte movement phenomenon, and the tissue remained

Precise quantification of silica and ceria nanoparticle uptake revealed by 3D fluorescence microscopy

• Adriano A. Torrano and
• Christoph Bräuchle

Beilstein J. Nanotechnol. 2014, 5, 1616–1624, doi:10.3762/bjnano.5.173

• instead of having cells incubated with nanoparticles, the particles were deposited and spread on a cover slip and, in order to maintain the same environmental conditions, cell medium was added to the particles. The acquired images were evaluated with the subroutine ‘Calibration’ of our macro and the mean

Physical principles of fluid-mediated insect attachment - Shouldn’t insects slip?

• Jan-Henning Dirks

Beilstein J. Nanotechnol. 2014, 5, 1160–1166, doi:10.3762/bjnano.5.127

Dry friction of microstructured polymer surfaces inspired by snake skin

• Martina J. Baum,
• Lars Heepe,
• Elena Fadeeva and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2014, 5, 1091–1103, doi:10.3762/bjnano.5.122

• , frictional behaviour in respect to stick–slip behaviour is strongly influenced by the dimension of surface microstructures even when no mechanical interlocking occurs. One possible explanation for this phenomenon is that the microornamentation causes a critical stiction length, which leads to a periodical

The study of surface wetting, nanobubbles and boundary slip with an applied voltage: A review

• Yunlu Pan,
• Bharat Bhushan and
• Xuezeng Zhao

Beilstein J. Nanotechnol. 2014, 5, 1042–1065, doi:10.3762/bjnano.5.117

• The drag of fluid flow at the solid–liquid interface in the micro/nanoscale is an important issue in micro/nanofluidic systems. Drag depends on the surface wetting, nanobubbles, surface charge and boundary slip. Some researchers have focused on the relationship between these interface properties. In

• this review, the influence of an applied voltage on the surface wettability, nanobubbles, surface charge density and slip length are discussed. The contact angle (CA) and contact angle hysteresis (CAH) of a droplet of deionized (DI) water on a hydrophobic polystyrene (PS) surface were measured with

• applied direct current (DC) and alternating current (AC) voltages. The nanobubbles in DI water and three kinds of saline solution on a PS surface were imaged when a voltage was applied. The influence of the surface charge density on the nanobubbles was analyzed. Then the slip length and the electrostatic