Wet chemistry route for the decoration of carbon nanotubes with iron oxide nanoparticles for gas sensing

• Hussam M. Elnabawy,
• Juan Casanova-Chafer,
• Badawi Anis,
• Mostafa Fedawy,
• Mattia Scardamaglia,
• Carla Bittencourt,
• Ahmed S. G. Khalil,
• Eduard Llobet and
• Xavier Vilanova

Beilstein J. Nanotechnol. 2019, 10, 105–118, doi:10.3762/bjnano.10.10

• layer were connected to a printed circuit board (PCB) using platinum wires. Those wires were attached to the heaters and CNT layers using silver paste that was cured in an oven at 120 °C for 30 minutes. To connect the Pt wires to the PCB we used tin wire and a soldering iron. Wire bonded sensors ready

Zn/F-doped tin oxide nanoparticles synthesized by laser pyrolysis: structural and optical properties

• Florian Dumitrache,
• Iuliana P. Morjan,
• Elena Dutu,
• Ion Morjan,
• Claudiu Teodor Fleaca,
• Monica Scarisoreanu,
• Alina Ilie,
• Marius Dumitru,
• Cristian Mihailescu,
• Adriana Smarandache and
• Gabriel Prodan

Beilstein J. Nanotechnol. 2019, 10, 9–21, doi:10.3762/bjnano.10.2

• dopant concentration). Keywords: laser pyrolysis; nanoparticles; optical bandgap; Zn/F-doped SnO2; Introduction Recently, there has been growing interest in the field of transparent conducting oxides and wide bandgap oxide nanocrystalline materials such as tin oxide (SnO2). It is generally agreed that

• reduced bandgap of tin oxide nanoparticles by introduction of defects to the crystal lattice is ≈0.7 eV [4]. Generally, the doping of these semiconducting oxides with specific cations or anions is performed in order to increase their electrical conductivity while maintaining a high optical transparency in

• the visible range [5][6]. For the case of tin oxide, a comparative study using halogen anions (F, Cl, Br, I) as dopants shows that the fluorine anion induces the formation of thin films and exhibits the best performance in terms of transparency and conductivity [7]. Today, the most used material for

Colloidal chemistry with patchy silica nanoparticles

• Pierre-Etienne Rouet,
• Cyril Chomette,
• Laurent Adumeau,
• Etienne Duguet and
• Serge Ravaine

Beilstein J. Nanotechnol. 2018, 9, 2989–2998, doi:10.3762/bjnano.9.278

• water, SDS), tin tetrachloride (SnCl4, Sigma-Aldrich, >99%), hydrochloric acid (37%, Sigma-Aldrich), ethylenediamine (Fluka, 99.5%), gold(III) chloride trihydrate (HAuCl4·3H2O, Sigma-Aldrich), trisodium citrate dihydrate (NaCit) (Na3C6H5O7·2H2O, Sigma-Aldrich, 99%), O-[2-(3-mercaptopropionylamino)ethyl

Graphene-enhanced metal oxide gas sensors at room temperature: a review

• Dongjin Sun,
• Yifan Luo,
• Marc Debliquy and
• Chao Zhang

Beilstein J. Nanotechnol. 2018, 9, 2832–2844, doi:10.3762/bjnano.9.264

• achieved at all [19][20]. Metal-oxide semiconductors (MOS), including tin oxide (SnO2), titanium dioxide (TiO2), zinc oxide (ZnO), copper oxide (CuO), tungsten oxide (WO3), indium oxide (In2O3), ferric oxide (Fe2O3) and cobalt oxide (Co3O4) are important materials for gas sensors [21][22][23][24][25][26

Oriented zinc oxide nanorods: A novel saturable absorber for lasers in the near-infrared

• Pavel Loiko,
• Tanujjal Bora,
• Josep Maria Serres,
• Haohai Yu,
• Magdalena Aguiló,
• Francesc Díaz,
• Uwe Griebner,
• Valentin Petrov,
• Xavier Mateos and
• Joydeep Dutta

Beilstein J. Nanotechnol. 2018, 9, 2730–2740, doi:10.3762/bjnano.9.255

• compact laser designs (e.g., microchip or waveguide lasers) [22]. ZnO NRs have not been explored as saturable absorbers, yet. Singh et al. studied Mn2+-doped ZnO NRs grown from an aqueous solution on indium tin oxide (ITO) substrates which exhibited saturable absorption (optical bleaching) at 0.532 µm

Optimization of Mo/Cr bilayer back contacts for thin-film solar cells

• Nima Khoshsirat,
• Fawad Ali,
• Vincent Tiing Tiong,
• Mojtaba Amjadipour,
• Hongxia Wang,
• Mahnaz Shafiei and
• Nunzio Motta

Beilstein J. Nanotechnol. 2018, 9, 2700–2707, doi:10.3762/bjnano.9.252

• chromium (Cr) adhesion layer is used as the back contact for a copper zinc tin sulfide (CZTS) thin-film solar cell on a SLG substrate. DC magnetron sputtering is used for deposition of Mo and Cr films. The conductivity of Mo/Cr bilayer films, their microstructure and surface morphology are studied at

Silicene, germanene and other group IV 2D materials

• Patrick Vogt

Beilstein J. Nanotechnol. 2018, 9, 2665–2667, doi:10.3762/bjnano.9.248

• methods. The synthesis of germanene (2D germanium) was reported in 2014 [4] and the synthesis of stanene (2D tin) in 2016 [5]. Except for their 2D character, these materials are substantially different from prototypical graphene. First of all, these materials do not exist in nature, nor do their 3D

Thickness-dependent photoelectrochemical properties of a semitransparent Co₃O₄ photocathode

• Malkeshkumar Patel and
• Joondong Kim

Beilstein J. Nanotechnol. 2018, 9, 2432–2442, doi:10.3762/bjnano.9.228

• heterojunctions. Experimental Sample fabrication: The photocathode was composed of Co3O4/fluorine-doped tin oxide (FTO)/glass. The general synthesis of Kirkendall diffusion grown Co3O4 film was analogue to our previous study [20]. In brief, a commercial fluorine-doped tin oxide (FTO)-coated glass (735167, Sigma

Hydrothermal-derived carbon as a stabilizing matrix for improved cycling performance of silicon-based anodes for lithium-ion full cells

• Mirco Ruttert,
• Florian Holtstiege,
• Jessica Hüsker,
• Markus Börner,
• Martin Winter and
• Tobias Placke

Beilstein J. Nanotechnol. 2018, 9, 2381–2395, doi:10.3762/bjnano.9.223

• anode materials, such as silicon (Si) and tin (Sn), have aroused great interest in the last decade with the aim to replace graphite, as these materials offer considerably higher theoretical, specific capacities of 3,579 mAh g−1 and 990 mAh g−1, respectively, compared to that of graphite [9][10][11][12

Directional light beams by design from electrically driven elliptical slit antennas

• Shuiyan Cao,
• Eric Le Moal,
• Quanbo Jiang,
• Aurélien Drezet,
• Serge Huant,
• Jean-Paul Hugonin,
• Gérald Dujardin and
• Elizabeth Boer-Duchemin

Beilstein J. Nanotechnol. 2018, 9, 2361–2371, doi:10.3762/bjnano.9.221

• , conducting indium tin oxide (ITO) layer (purchased from SOLEMS, Palaiseau, France). ITO is used to electrically connect the inner gold area delineated by the elliptical slit to the rest of the gold film as is required for applying the tip–sample bias voltage for the STM measurements. The elliptical slits are

Performance analysis of rigorous coupled-wave analysis and its integration in a coupled modeling approach for optical simulation of complete heterojunction silicon solar cells

• Ziga Lokar,
• Benjamin Lipovsek,
• Marko Topic and
• Janez Krc

Beilstein J. Nanotechnol. 2018, 9, 2315–2329, doi:10.3762/bjnano.9.216

• (EVA) encapsulation (Figure 3). The front of the basic solar cell structure consists of transparent conductive oxide (e.g., indium tin oxide (ITO)), a thin p-doped and intrinsic amorphous silicon (a-Si:H) layer for electrical passivation, a slightly n-doped crystalline Si (c-Si) wafer (absorber), and

Surface energy of nanoparticles – influence of particle size and structure

• Dieter Vollath,
• Franz Dieter Fischer and
• David Holec

Beilstein J. Nanotechnol. 2018, 9, 2265–2276, doi:10.3762/bjnano.9.211

• phases occurs. Also these results predict (for certain particle sizes) the existence of a layer with reduced order, possibly a premelted liquid layer at the surface of a crystallized particle. From the experimental data on the melting of gold [11][39] and tin [40][41] particles, Vollath and Fischer [24

• . Excerpt with permission from [26], copyright 2006 by the American Physical Society. Landau’s order parameter M for tin particles of different particle diameters as function of the radius at a temperature of 440 K. The term “radius” represents the radial distance to the particle center [35]. Difference of

• the surface energy between the solid and the liquid state at the melting temperature of the particles as function of the particle diameter for gold and tin [24]. Radial profiles of the density for a fcc metal cluster consisting of 3302 atoms versus the particle radius [43]. One observes the formation

Lead-free hybrid perovskites for photovoltaics

• Oleksandr Stroyuk

Beilstein J. Nanotechnol. 2018, 9, 2209–2235, doi:10.3762/bjnano.9.207

• -charged cations, such as Sn2+, Mn2+, or Ge2+, where the tin-based materials have gained the most attention and progress [10][16][18][29][30][38][44][54][59][60][61][62][63][64][65]. The Sn-based HPs (CsSnX3, MASnX3) show a high charge carrier mobility and diffusion length, comparable to the Pb-based

• to 1.24 eV for x = 0.4 and then increasing to ≈1.3 eV for the FASnI3 perovskite [93]. The “bowing” of the Eg(x) dependence may originate from a transition from cubic to orthorhombic lattice symmetry upon increasing tin content [93]. A similar anomalous variation of the bandgap, as well as the CB/VB

• inactive with this HTL material. A higher efficiency of mixed Sn,Pb-HPs stems largely from a broader absorption range extending to λe = 1060 nm as compared to only 800 nm for MAPI (Figure 3a). A partial substitution of the lead with tin was found to affect the VB position of the HP much stronger than the

Electrospun one-dimensional nanostructures: a new horizon for gas sensing materials

• Muhammad Imran,
• Nunzio Motta and
• Mahnaz Shafiei

Beilstein J. Nanotechnol. 2018, 9, 2128–2170, doi:10.3762/bjnano.9.202

• ], Co3O4 [113][114], iron oxide (Fe2O3) [115][116], tin dioxide (SnO2) [76][117][118][119][120][121][122][123], zinc oxide (ZnO) [124][125][126][127][128][129][130], and indium oxide (In2O3) [78][80][131][132][133][134][135][136][137][138]. Table S2 in Supporting Information File 1 summarizes the sensing

Improving the catalytic activity for hydrogen evolution of monolayered SnSe_2(1−x)S_2x by mechanical strain

• Sha Dong and
• Zhiguo Wang

Beilstein J. Nanotechnol. 2018, 9, 1820–1827, doi:10.3762/bjnano.9.173

• . Recently, tin dichalcogenides SnX2 (X = S, Se) have also received considerable attention in a variety of fields because of their low cost, use of earth-abundant resources and environmental friendliness [18][20][21][22][23]. Monolayer SnX2 has a X–Sn–X sandwich-like structure, which can be easily

Know your full potential: Quantitative Kelvin probe force microscopy on nanoscale electrical devices

• Amelie Axt,
• Ilka M. Hermes,
• Victor W. Bergmann,
• Niklas Tausendpfund and
• Stefan A. L. Weber

Beilstein J. Nanotechnol. 2018, 9, 1809–1819, doi:10.3762/bjnano.9.172

• , visualized by the red and blue line, respectively. The cell consisted of a fluorine-doped tin oxide (FTO) electrode, a compact TiO2 electron extraction layer and a mesoscopic TiO2 layer (meso) filled with the perovskite light-absorber methylammonium lead iodide (MAPI). The mesoscopic layer was followed by a

Toward the use of CVD-grown MoS₂ nanosheets as field-emission source

• Geetanjali Deokar,
• Nitul S. Rajput,
• Junjie Li,
• Francis Leonard Deepak,
• Wei Ou-Yang,
• Nicolas Reckinger,
• Carla Bittencourt,
• Jean-Francois Colomer and
• Mustapha Jouiad

Beilstein J. Nanotechnol. 2018, 9, 1686–1694, doi:10.3762/bjnano.9.160

• on the NSs transferred onto a conducting fluorine-tin-oxide (FTO) substrate. Experimental Sample preparation The NSs were grown on SiO2/Si substrates via double sulfurization of a sputter-deposited 50 nm Mo film using an ambient-pressure CVD technique. Flushing of the quartz tube using Ar gas stream

Photoluminescence of CdSe/ZnS quantum dots in nematic liquid crystals in electric fields

• Margarita A. Kurochkina,
• Elena A. Konshina and
• Daria Khmelevskaia

Beilstein J. Nanotechnol. 2018, 9, 1544–1549, doi:10.3762/bjnano.9.145

• of two quartz substrates with a fixed gap of about 33 μm. Both substrates were coated by cathode sputtering with transparent conductive electrodes based on indium tin oxide. Orienting layers of rubbed polyimide and chromolane were used to obtain a planar or vertical orientation of the LC molecules

Formation and development of nanometer-sized cybotactic clusters in bent-core nematic liquid crystalline compounds

• Yuri P. Panarin,
• Sithara P. Sreenilayam,
• Jagdish K. Vij,
• Anne Lehmann and
• Carsten Tschierske

Beilstein J. Nanotechnol. 2018, 9, 1288–1296, doi:10.3762/bjnano.9.121

• GmbH, Germany). The sample cells for dielectric measurements are constructed from glass substrates coated with indium tin oxide (ITO) with low sheet resistance (20 Ω/ ). This shifts the parasitic dielectric peak to a higher frequency due to the capacitance of the cell in series with the finite

A novel copper precursor for electron beam induced deposition

• Caspar Haverkamp,
• George Sarau,
• Mikhail N. Polyakov,
• Ivo Utke,
• Marcos V. Puydinger dos Santos,
• Silke Christiansen and
• Katja Höflich

Beilstein J. Nanotechnol. 2018, 9, 1220–1227, doi:10.3762/bjnano.9.113

• pieces with a native oxide layer and glass cover slips with an optically characterized layer of 50 nm indium tin oxide (ITO) were used. EDX measurements were carried out in a Tescan LYRA 3 dual beam microscope equipped with an EDX Quantax system of Bruker. Spectra were taking in spot mode at an

Electrodeposition of reduced graphene oxide with chitosan based on the coordination deposition method

• Mingyang Liu,
• Yanjun Chen,
• Chaoran Qin,
• Zheng Zhang,
• Shuai Ma,
• Xiuru Cai,
• Xueqian Li and
• Yifeng Wang

Beilstein J. Nanotechnol. 2018, 9, 1200–1210, doi:10.3762/bjnano.9.111

• indium tin oxide (ITO) electrode through the codeposition of rGO and chitosan [21]. The main limitation of this method is that graphene disperses poorly and has poor colloidal stability in most common solvents [22][23]. In our previous experiments, it was found that the unmodified rGO was very difficult

Thermoelectric current in topological insulator nanowires with impurities

• Sigurdur I. Erlingsson,
• Jens H. Bardarson and
• Andrei Manolescu

Beilstein J. Nanotechnol. 2018, 9, 1156–1161, doi:10.3762/bjnano.9.107

• properties is not always straightforward [3]. Even though few experimental studies exist on thermoelectric properties in topological insulator nanowires (TIN), many studies have reported magnetoresistance oscillations, both in longitudinal and transversal fields for TINs [4][5][6][7][8][9][10]. In its

• experimental reach. Also, since the transport is over long systems, it is much simpler to maintain a large temperature difference of tens of kelvins, compared to the case of quantum dots. In this paper we extend our previous work on thermoelectric currents in TIN [11], by including the effects of impurities

Effect of annealing treatments on CeO₂ grown on TiN and Si substrates by atomic layer deposition

• Silvia Vangelista,
• Rossella Piagge,
• Satu Ek and
• Alessio Lamperti

Beilstein J. Nanotechnol. 2018, 9, 890–899, doi:10.3762/bjnano.9.83

• this work, we investigate the effect of thermal treatment on CeO2 films fabricated by using atomic layer deposition (ALD) on titanium nitride (TiN) or on silicon (Si) substrates. In particular, we report on the structural, chemical and morphological properties of 25 nm thick ceria oxide with particular

• crystallization. When ceria is deposited on TiN, the temperature has to be limited to 600 °C due to the thermal instability of the underlying TiN substrate with a broadening of the interface, while there are no changes detected inside the CeO2 films. As-deposited CeO2 films show a cubic fluorite polycrystalline

• intriguing and could be considered as a valuable approach for fine-tuning the properties of ceria. Extending the results of our recent study on as-deposited CeO2 films on Si and on TiN substrates [8], this work aims to show the structural and chemical properties of CeO2 films deposited on the same substrates

Mechanistic insights into plasmonic photocatalysts in utilizing visible light

• Kah Hon Leong,
• Azrina Abd Aziz,
• Lan Ching Sim,
• Pichiah Saravanan,
• Min Jang and
• Detlef Bahnemann

Beilstein J. Nanotechnol. 2018, 9, 628–648, doi:10.3762/bjnano.9.59

• spatial charge separation of photoinduced carriers by creating an alternate permutation of band edges at the interface [146]. Some researchers found that both titanium nitride (TiN) and zirconium nitride (ZrN) displayed similar optical properties as Au and can replace Au NPs for vis–NIR light absorption

Design of polar self-assembling lactic acid derivatives possessing submicrometre helical pitch

• Alexej Bubnov,
• Cyril Vacek,
• Michał Czerwiński,
• Terezia Vojtylová,
• Wiktor Piecek and
• Věra Hamplová

Beilstein J. Nanotechnol. 2018, 9, 333–341, doi:10.3762/bjnano.9.33

• filled into glass cells (Military University of Technology, cell gap of 12 μm, homogeneous alignment) with indium tin oxide transparent electrodes and polyimide layers rubbed unidirectional, which ensured a planar geometry supporting an induction of bookshelf-like smectic structures. The alignment was