Gold nanomakura: nanoarchitectonics and their photothermal response in association with carrageenan hydrogels

• Nabojit Das,
• Vikas,
• Akash Kumar,
• Sanjeev Soni and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2024, 15, 678–693, doi:10.3762/bjnano.15.56

• scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM/EDX) of the powdered form of AuNM, as shown in Supporting Information File 1, Figure S4. Growth mechanism in AuNMs during seed-mediated synthesis Seed-mediated synthesis approach has been adopted in the present work which is quite

• well known to generate anisotropic nanomaterials. The mechanism mainly involves the arrangement of surfactant micelles which dictates anisotropy in nanoparticle during synthesis. A seed is a tiny crystal of ≈2–3 nm that initiates growth of a nanoparticle when introduced in a proper growth solution. The

• DTAB-AuNM, respectively. Growth mechanism of gold nanomakura particles (AuNM). (a) AuNM surrounded by surfactant micelles; (b) growth facet of AuNM; and (c) stepwise growth mechanism during AuNM formation. (a) Seed-mediated synthesis of CTAB-capped AuNR. (b) Seedless synthesis of DTAB-capped AuNR. (c

Laser synthesis of nanoparticles in organic solvents – products, reactions, and perspectives

• Theo Fromme,
• Sven Reichenberger,
• Katharine M. Tibbetts and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2024, 15, 638–663, doi:10.3762/bjnano.15.54

• with the [AuCl4]− reduction rate through a two-step autocatalytic nanoparticle growth mechanism [71]. The autocatalytic growth step is driven by H2O2 and can be slowed down by adding hydroxyl radical scavengers resulting in smaller nanoparticles (Figure 4) [48]. Hence, the water decomposition leads to

• proposed a mechanism of electron transfer from the solvent, which produced acetone as a by-product. Since this transfer is not possible in water and only plasma reactions are available, Ag could not nucleate during LRL in water because of the oxidizing activity of hydroxyl radicals [121]. Overall, LSPC in

• termination reaction with hydrogen, different end-capping groups such as CN or CH3 can be added [118][132][140][141][142][143]. While this mechanism for polyyne formation is widely accepted for ns-LAL, the synthesis of polyynes by fs-LAL is proposed to undergo different reactions. In contrast to ns-LAL, where

Comparative analysis of the ultrastructure and adhesive secretion pathways of different smooth attachment pads of the stick insect Medauroidea extradentata (Phasmatodea)

• Julian Thomas,
• Stanislav N. Gorb and
• Thies H. Büscher

Beilstein J. Nanotechnol. 2024, 15, 612–630, doi:10.3762/bjnano.15.52

• Julian Thomas Stanislav N. Gorb Thies H. Buscher Functional Morphology and Biomechanics, Institute of Zoology, Kiel University, Am Botanischen Garten 9, 24118 Kiel, Germany 10.3762/bjnano.15.52 Abstract The mechanism by which insects achieve attachment and locomotion across diverse substrates has

• roughness and thereby increase the contact area [14][16][17][18][19]. It can aid in the enhancement of viscous and capillary forces further increasing the attachment strength [9][14][20][21][22][23][24]. The adhesive secretion can be essential for the self-cleaning mechanism by binding smaller contamination

• structural mechanism for product release (e.g., a duct), and the presence of a dedicated storage area for their respective products (e.g., the adhesive secretion reservoir). Collectively, these distinctive features categorize the exocrine cells as exocrine cells type I [62]. Despite their morphological

Radiofrequency enhances drug release from responsive nanoflowers for hepatocellular carcinoma therapy

• Yanyan Wen,
• Ningning Song,
• Yueyou Peng,
• Weiwei Wu,
• Qixiong Lin,
• Minjie Cui,
• Rongrong Li,
• Qiufeng Yu,
• Sixue Wu,
• Yongkang Liang,
• Wei Tian and
• Yanfeng Meng

Beilstein J. Nanotechnol. 2024, 15, 569–579, doi:10.3762/bjnano.15.49

• model has the highest degree of fitting with the release of NFs in different simulated environments within 72 h, which indicates conformity with the Fick diffusion mechanism. Meanwhile, we found that RF heating does not affect the release kinetics model. Ritger–Peppas is a semiempirical model, and n is

• an indicator of the drug release mechanism, where n ≤ 0.45 represents the Fick diffusion. The n values calculated in this study are all less than 0.45, indicating that the CUR release from NFs is in accordance with the Fick diffusion. Similarly, the Higuchi model has the highest degree of fitting

Cholesterol nanoarchaeosomes for alendronate targeted delivery as an anti-endothelial dysfunction agent

• Horacio Emanuel Jerez,
• Yamila Roxana Simioni,
• Kajal Ghosal,
• Maria Jose Morilla and
• Eder Lilia Romero

Beilstein J. Nanotechnol. 2024, 15, 517–534, doi:10.3762/bjnano.15.46

• due to the lower ALN internalization, resulting from the lower ALN/lipid ratio and lower endocytosis of the formulation. In either case, the mechanism of reduction of IL-6/IL-8 of ALN-loaded nanoarchaeosomes would differ from that mediated by the corticosteroid receptor since the corticosteroid

• dexamethasone did not affect HUVECs. The nanovesicles are internalized by endocytosis, a mechanism independent of their concentration and dose. Nanoarchaeosomes from H. tebenquichense are massively endocytosed, total or partly via SRA1, the receptor responsible for massive, high-rate internalization of

Photocatalytic degradation of methylene blue under visible light by cobalt ferrite nanoparticles/graphene quantum dots

• Vo Chau Ngoc Anh,
• Le Thi Thanh Nhi,
• Le Thi Kim Dung,
• Dang Thi Ngoc Hoa,
• Nguyen Truong Son,
• Nguyen Thi Thao Uyen,
• Nguyen Ngoc Uyen Thu,
• Le Van Thanh Son,
• Le Trung Hieu,
• Tran Ngoc Tuyen and
• Dinh Quang Khieu

Beilstein J. Nanotechnol. 2024, 15, 475–489, doi:10.3762/bjnano.15.43

• /GQDs nanoparticles. Magnetic properties, morphology, structure, and fluorescence of the nanocomposites were studied, and the photocatalytic degradation of methylene blue as a dye model and the mechanism of methylene degradation were also addressed. Experimental Materials Cobalt(II) nitrate hexahydrate

• provides the value of k1. The values of k1, along with others from the literature, are presented in Table 3. However, because the reactions were conducted under different conditions, the comparison is arbitrary. To clarify the mechanism of MB photocatalytic degradation, 10 mM isopropyl (IPA), potassium

• photocorrosion and exhibits excellent reusability for the degradation process. The mechanism of MB degradation over the CF/GQDs catalyst is illustrated in Scheme 2. Under visible light irradiation, photogenerated holes (h+) are created in the valence bands via the transfer of photogenerated electrons (e−) from

Heat-induced morphological changes in silver nanowires deposited on a patterned silicon substrate

• Elyad Damerchi,
• Sven Oras,
• Edgars Butanovs,
• Allar Liivlaid,
• Mikk Antsov,
• Boris Polyakov,
• Annamarija Trausa,
• Veronika Zadin,
• Andreas Kyritsakis,
• Loïc Vidal,
• Karine Mougin,
• Siim Pikker and
• Sergei Vlassov

Beilstein J. Nanotechnol. 2024, 15, 435–446, doi:10.3762/bjnano.15.39

• leading to heat-induced fragmentation of Ag NWs as the mechanism of stress release, and could potentially involve recrystallization into single crystals. To test this hypothesis, we repeated experiments on TEM grids with subsequent observation of the crystal structure via TEM. It was found that the

• a driving force for the redistribution of Ag atoms and splitting of the adhered part of a NW into shorter fragments as a mechanism for stress mitigation. For the suspended parts, the thermal expansion should result in deformation. To estimate the extent and distribution of the heat-induced

• occur in the real system as a mechanism of stress mitigation. The model is completely elastic, and the simulated processes are fully reversible. Therefore, the results of FEM simulations should only be treated as a simplified qualitative illustration of the thermomechanical processes that may occur in

Classification and application of metal-based nanoantioxidants in medicine and healthcare

• Nguyen Nhat Nam,
• Nguyen Khoi Song Tran,
• Tan Tai Nguyen,
• Nguyen Ngoc Trai,
• Nguyen Phuong Thuy,
• Hoang Dang Khoa Do,
• Nhu Hoa Thi Tran and
• Kieu The Loan Trinh

Beilstein J. Nanotechnol. 2024, 15, 396–415, doi:10.3762/bjnano.15.36

• metal-based nanoantioxidants of each type are described focusing on the mechanism of action, antioxidant activities, and individual properties. Second, the application of metal-based nanoantioxidants in medicine and healthcare is carefully discussed in order to demonstrate the potential of

• antioxidant appearing in low-density lipoprotein and human blood plasma contributing to the decrease of oxidative stress. Its mechanism of action relies on the ability to transfer the phenolic H atom to a peroxyl radical (ROO•) much more rapidly than the propagation reactions [50][51][52][53]. Despite the

• stability during long-term storage [54][55][56]. Relying on the mechanism of chain-breaking antioxidants, nanomaterials can be synthesized to directly react with ROS after the oxidative reaction begins. Chain-breaking antioxidant nanomaterials are materials or chemical substances having a size between 0–100

Insect attachment on waxy plant surfaces: the effect of pad contamination by different waxes

• Elena V. Gorb and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2024, 15, 385–395, doi:10.3762/bjnano.15.35

• previously reported findings in many plant and insect species [4][5][6]. The contaminating ability of plant waxes has been previously shown for many plants [8][28][29][30][31][32][33][34]. Our study clearly revealed the effect of pad contamination by plant wax material as an important mechanism of insect

On the mechanism of piezoresistance in nanocrystalline graphite

• Sandeep Kumar,
• Simone Dehm and
• Ralph Krupke

Beilstein J. Nanotechnol. 2024, 15, 376–384, doi:10.3762/bjnano.15.34

• applied strain on NCG placed on polyethylene terephthalate (PET) substrates provide intriguing insights into the underlying mechanism. Raman measurements, in conjunction with strain applied to NCG grown on flexible glass, indicate that the strain is concentrated at the grain boundaries for smaller strain

• properties, a mechanism for piezoresistance in NCG is proposed. The work included here is a part of the PhD thesis completed by the first author S. Kumar [23]. Results and Discussion The two-point bending fixture, which was constructed to impart external strain and simultaneously perform sheet resistance

• observed the plateau-like region as reported here, where the gauge factor is similar to the gauge factor at very low strain [24][33]. A plateau-like region has neither been observed in nanocrystalline graphite [33], amorphous carbon films [34], nor in metallic films [35]. The mechanism that leads to an

Investigating ripple pattern formation and damage profiles in Si and Ge induced by 100 keV Ar⁺ ion beam: a comparative study

• Indra Sulania,
• Harpreet Sondhi,
• Tanuj Kumar,
• Sunil Ojha,
• G R Umapathy,
• Ambuj Mishra,
• Ambuj Tripathi,
• Richa Krishna,
• Devesh Kumar Avasthi and
• Yogendra Kumar Mishra

Beilstein J. Nanotechnol. 2024, 15, 367–375, doi:10.3762/bjnano.15.33

• to induce that type of energy deposition in the Ge lattice. This way, the defects can be produced and the substrate can be amorphized. The roughness and growth exponents have been deduced from the RMS surface roughness and power spectral density data to understand the mechanism of ripple formation on

• slope is obtained as 0.23 ± 0.07 and 0.19 ± 0.09 for Si and Ge, respectively. The roughness parameter α and the growth parameter β give information about the mechanism responsible for creating these surface structures due to the interplay between roughness induced by sputtering and smoothening due to

Exploring the relationships between physiochemical properties of nanoparticles and cell damage to combat cancer growth using simple periodic table-based descriptors

• Joyita Roy and
• Kunal Roy

Beilstein J. Nanotechnol. 2024, 15, 297–309, doi:10.3762/bjnano.15.27

• . To date, few studies have reported on the mechanism of apoptosis of cancerous cells after metal oxide treatment, which still remains unclear. Traditional approaches are very costly, time-consuming, involve a lot of resources and lead to ethical implications; also, they are inadequate in addressing

• interpretability [21][22][23][24][25]. This type of descriptors can indicate relevant features and mend the mechanism interpretation. Some properties (size, zeta potential, molecular weight, mass percentage of metal elements, and cation charge) are investigated to have a better understanding of the structure of

• intensity of oxidative stress. This happens because longer exposure times enhance the toxicity mechanism of NPs. In contrast, short-term exposure does not affect significantly the cells. NPs can induce oxidative stress by impairing antioxidant defenses in humans when they are chronically exposed to NPs

Ultrasensitive and ultrastretchable metal crack strain sensor based on helical polydimethylsiloxane

• Shangbi Chen,
• Dewen Liu,
• Weiwei Chen,
• Huajiang Chen,
• Jiawei Li and
• Jinfang Wang

Beilstein J. Nanotechnol. 2024, 15, 270–278, doi:10.3762/bjnano.15.25

• formation under stretching. The sensors with helix indices C1, C2, and C3 exhibited distinct turning points at 250%, 550%, and 850% strain, respectively. The dominance of strain in the sensing mechanism can be attributed to the tunneling effect [37]. As the Au film is stretched, it gradually separates

Vinorelbine-loaded multifunctional magnetic nanoparticles as anticancer drug delivery systems: synthesis, characterization, and in vitro release study

• Zeynep Özcan and
• Afife Binnaz Hazar Yoruç

Beilstein J. Nanotechnol. 2024, 15, 256–269, doi:10.3762/bjnano.15.24

• tumor microenvironment triggers the controlled release of VNB. When combined with laser-induced photothermal therapy, this results in effective tumor elimination without recurrence. This mechanism holds immense promise for precise and targeted drug delivery. Moreover, VNB/PDA/Fe3O4 NPs exhibit

Design, fabrication, and characterization of kinetic-inductive force sensors for scanning probe applications

• August K. Roos,
• Ermes Scarano,
• Elisabet K. Arvidsson,
• Erik Holmgren and
• David B. Haviland

Beilstein J. Nanotechnol. 2024, 15, 242–255, doi:10.3762/bjnano.15.23

• verify that kinetic inductive mechano-electric coupling (KIMEC) is a useful, albeit not entirely understood, physical effect. Further investigation of alternative designs will help to shed light on the underlying physical mechanism behind KIMEC. We hope that this study motivates future work in this

Multiscale modelling of biomolecular corona formation on metallic surfaces

• Parinaz Mosaddeghi Amini,
• Ian Rouse,
• Julia Subbotina and
• Vladimir Lobaskin

Beilstein J. Nanotechnol. 2024, 15, 215–229, doi:10.3762/bjnano.15.21

• engage in a complex interplay of dynamic physicochemical interactions, kinetics, and thermodynamic exchanges that can lead to undesirable outcomes [1][8][9][10]. In a more general context, the importance in understanding the mechanism of bionano interactions arises from the increasing awareness and

Ion beam processing of DNA origami nanostructures

• Leo Sala,
• Agnes Zerolová,
• Violaine Vizcaino,
• Alain Mery,
• Alicja Domaracka,
• Hermann Rothard,
• Philippe Boduch,
• Dominik Pinkas and
• Jaroslav Kocišek

Beilstein J. Nanotechnol. 2024, 15, 207–214, doi:10.3762/bjnano.15.20

• the generation of plasma from air affecting the nanostructures and DNA–substrate interactions. Despite the underlying mechanism, which is worth of further exploration, this behavior should be emphasized in the present content. Random irradiation of the origami-deposited nanostructures results in a

• install in large infrastructures. Nonetheless, it is possible that the most probable mechanism of the height variation could be the radical attack from the environment when the irradiation is done in air. A similar behavior was observed also upon chemical modification of the nanostructures [38]. DNA

Exploring disorder correlations in superconducting systems: spectroscopic insights and matrix element effects

• Vyacheslav D. Neverov,
• Alexander E. Lukyanov,
• Andrey V. Krasavin,
• Alexei Vagov,
• Boris G. Lvov and
• Mihail D. Croitoru

Beilstein J. Nanotechnol. 2024, 15, 199–206, doi:10.3762/bjnano.15.19

• this mechanism, which controls superconductivity in strongly disordered materials, is modified when the disorder becomes correlated. Model Superconductivity characteristics of a disordered superconductor are investigated using an attractive Hubbard lattice Hamiltonian with point interaction, introduced

Graphene removal by water-assisted focused electron-beam-induced etching – unveiling the dose and dwell time impact on the etch profile and topographical changes in SiO₂ substrates

• Aleksandra Szkudlarek,
• Jan M. Michalik,
• Inés Serrano-Esparza,
• Zdeněk Nováček,
• Veronika Novotná,
• Piotr Ozga,
• Czesław Kapusta and
• José María De Teresa

Beilstein J. Nanotechnol. 2024, 15, 190–198, doi:10.3762/bjnano.15.18

• changes upon stationary exposure were investigated in the work of Stevens Kalceff et al. [24], where the authors observed an increase/decrease in volume of crystalline and amorphous SiO2, respectively. However, the explicit mechanism responsible for the process that considers possible reactions paths with

• already been studied by several groups [32][33][34][35]. However, the direct mechanism has not yet been fully elucidated up to now [36]. In the studies of etching of thermally grown SiO2, reported in 1995 by Bakker and Hess [32], the authors claim that chemical reactions between Si atoms and OH− groups

• lead to the formation of the volatile Si(OH)4 compound. A similar mechanism is proposed by Rosamila et al. [33] for O2-promoted water etching of Si surface, established on the observation that the etching rate is proportional to the concentration of OH− groups. Those hydroxyl groups are also electron

Development and characterization of potential larvicidal nanoemulsions against Aedes aegypti

• Jonatas L. Duarte,
• Leonardo Delello Di Filippo,
• Anna Eliza Maciel de Faria Mota Oliveira,
• Rafael Miguel Sábio,
• Gabriel Davi Marena,
• Tais Maria Bauab,
• Cristiane Duque,
• Vincent Corbel and
• Marlus Chorilli

Beilstein J. Nanotechnol. 2024, 15, 104–114, doi:10.3762/bjnano.15.10

• maturation, a very important mechanism when it comes to the instability of NEs. It is related to the difference between the droplet sizes in the formulation, with the smaller droplets having greater chemical potential and, thus, diffusing to the larger ones [26]. Formulations with HLB values of 14 and 15

• a transport exponent value (n) of 0.3, indicating a release mechanism primarily driven by Fickian diffusion [44]. The free terpenes exhibited a value of 0.6, suggesting an anomalous transport mechanism for drug release. This mechanism involves a combination of diffusion and dissolution processes for

Berberine-loaded polylactic acid nanofiber scaffold as a drug delivery system: The relationship between chemical characteristics, drug-release behavior, and antibacterial efficiency

• Le Thi Le,
• Hue Thi Nguyen,
• Liem Thanh Nguyen,
• Huy Quang Tran and
• Thuy Thi Thu Nguyen

Beilstein J. Nanotechnol. 2024, 15, 71–82, doi:10.3762/bjnano.15.7

• good antibacterial activity for wound dressing [28][30]. In order to study the mechanism of BBR release from BBR/PLA and BBR NPs/PLA nanofiber scaffolds, the release data were fitted to several kinetic models, including zero-order, first-order, Higuchi, and Ritger–Peppas models. The regression

• compared to that of other models. In addition, the release exponent (n) of the equation was 0.1703, indicating that the BBR release from the BBR/PLA nanofiber scaffold followed the Fickian diffusion. In this mechanism, the release of BBR was governed by a diffusion process, where the diffusion rate was

• higher than the polymer relaxation [43]. Based on the R2 values shown in Table 1, the release data of the BBR NPs/PLA nanofiber scaffold was simultaneously well described by the Higuchi and Ritger–Peppas models, suggesting that BBR NPs release was mainly controlled by a diffusion mechanism. However, the

Influence of conductive carbon and MnCo₂O₄ on morphological and electrical properties of hydrogels for electrochemical energy conversion

• Sylwia Pawłowska,
• Karolina Cysewska,
• Yasamin Ziai,
• Jakub Karczewski,
• Piotr Jasiński and
• Sebastian Molin

Beilstein J. Nanotechnol. 2024, 15, 57–70, doi:10.3762/bjnano.15.6

• mechanism (two or three electron transfer processes), with a strong influence of two electron transfers. Comparing the value of the Tafel slope of the hydrogel composite containing MCO and cCB particles with the Tafel slope of pure hydrogel (141 mV·dec−1), it is visible that the addition of the catalyst

• (Figure 5a). This is related to the increase of the electrode double-layer capacitance with the increase in the amount of cCB (Figure 5b). This confirms the comparable rate and mechanism of the OER reaction of the Hgel-MCO-cCB electrode. Comparing our Tafel slope with the values obtained for the PPy

Josephson dynamics and Shapiro steps at high transmissions: current bias regime

• Artem V. Galaktionov and
• Andrei D. Zaikin

Beilstein J. Nanotechnol. 2024, 15, 51–56, doi:10.3762/bjnano.15.5

• T → 0 can flow across the junction. The situation becomes entirely different provided one goes beyond the tunneling limit and considers highly transparent superconducting weak links in which case the charge transfer is essentially controlled by the mechanism of multiple Andreev reflection [2]. This

• mechanism causes intrinsic dissipation at subgap energies. Recently, we demonstrated [3] that such intrinsic dissipation has a dominating sub-Ohmic component in the subgap regime. This observation implies, for example, substantial modifications of the I–V curve at bias currents I just slightly exceeding the

Curcumin-loaded nanostructured systems for treatment of leishmaniasis: a review

• Douglas Dourado,
• Thayse Silva Medeiros,
• Éverton do Nascimento Alencar,
• Edijane Matos Sales and
• Fábio Rocha Formiga

Beilstein J. Nanotechnol. 2024, 15, 37–50, doi:10.3762/bjnano.15.4

• Leishmania spp. Although its mechanism of action has not yet been fully elucidated, its leishmanicidal potential may be associated with its antioxidant and anti-inflammatory properties. However, it has limitations that compromise its clinical use. Conversely, nanotechnology has been used as a tool for

Nanotechnological approaches in the treatment of schistosomiasis: an overview

• Lucas Carvalho,
• Michelle Sarcinelli and
• Beatriz Patrício

Beilstein J. Nanotechnol. 2024, 15, 13–25, doi:10.3762/bjnano.15.2

• mechanism by which the nanoemulsion could reduce the worm burden is its antimicrobial activity, connecting changes in microbiota with the response to parasites. However, the mechanism of action of carvacrol remains unknown [67]. Repositioned drugs Works utilizing compounds repositioned from other diseases