Green fabrication of lanthanide-doped hydroxide-based phosphors: Y(OH)₃:Eu³⁺ nanoparticles for white light generation

• Tugrul Guner,
• Anilcan Kus,
• Mehmet Ozcan,
• Aziz Genc,
• Hasan Sahin and
• Mustafa M. Demir

Beilstein J. Nanotechnol. 2019, 10, 1200–1210, doi:10.3762/bjnano.10.119

• as quantum dots [22], perovskites [23], organic dyes [24], etc. In the case of phosphors, combining a red phosphor with YAG:Ce3+ over a blue LED is the simplest way of increasing the CRI while reducing the CCT. Phosphors mostly consist of thermally and chemically stable inorganic hosts such as YAG

CuInSe₂ quantum dots grown by molecular beam epitaxy on amorphous SiO₂ surfaces

• Henrique Limborço,
• Pedro M.P. Salomé,
• Rodrigo Ribeiro-Andrade,
• Jennifer P. Teixeira,
• Nicoleta Nicoara,
• Kamal Abderrafi,
• Joaquim P. Leitão,
• Juan C. Gonzalez and
• Sascha Sadewasser

Beilstein J. Nanotechnol. 2019, 10, 1103–1111, doi:10.3762/bjnano.10.110

• with the average size of the nanodots. Keywords: copper indium gallium selenide (CuInSe2); quantum dots; Introduction The chalcopyrite compound Cu(In,Ga)Se2 (CIGS) is used as the light absorber layer in thin film solar cells that typically consist of a glass substrate, a Mo back contact, the CIGS

• defects are important sources of radiative and non-radiative recombination affecting the optoelectronic properties of CIS quantum dots (QDs), such as photo-generated carrier lifetime and photoluminescence [15]. We ascribe the increase in the photoluminescence related to the nanodots to the passivation of

Correlation of surface-enhanced Raman scattering (SERS) with the surface density of gold nanoparticles: evaluation of the critical number of SERS tags for a detectable signal

• Vincenzo Amendola

Beilstein J. Nanotechnol. 2019, 10, 1016–1023, doi:10.3762/bjnano.10.102

• to the use of Raman tags, mostly related to the intensity and narrow bandwidth of their Raman peaks. SERS labels can be even brighter than semiconductor quantum dots; for example, the high intensity allows for detection using only a single nanotag with an ordinary Raman spectrometer [27][28]. The

Deposition of metal particles onto semiconductor nanorods using an ionic liquid

• Michael D. Ballentine,
• Elizabeth G. Embry,
• Marco A. Garcia and
• Lawrence J. Hill

Beilstein J. Nanotechnol. 2019, 10, 718–724, doi:10.3762/bjnano.10.71

• without the need for additional surfactants or reducing agents. Results and Discussion CdSe quantum dots and CdSe@CdS nanorods were synthesized using cadmium oxide, octadecylphosphonic acid, hexylphosphonic acid, trioctylphosphine, and trioctylphosphine oxide based on methods reported by Manna et al. and

• expanded upon by Pyun et al. [27][28]. Our CdSe quantum dots had an average diameter of 2.4 nm as determined using the correlation of particle diameter with the wavelength of the low energy absorbance peak (λmax = 509 nm) [29]. The CdSe@CdS nanorods had an average length of 50 ± 10 nm and an average

Coexisting spin and Rabi oscillations at intermediate time regimes in electron transport through a photon cavity

• Vidar Gudmundsson,
• Hallmann Gestsson,
• Nzar Rauf Abdullah,
• Chi-Shung Tang,
• Andrei Manolescu and
• Valeriu Moldoveanu

Beilstein J. Nanotechnol. 2019, 10, 606–616, doi:10.3762/bjnano.10.61

• ]. The formation of very slow Rabi-like spin-flip transitions promoted by the interplay of tunneling and spin orbit interactions in a system of double quantum dots has been studied by Khomitsky et al. [14]. In earlier publications we have shown how a Rabi oscillation can be detected in the transport of

• , but only in this regime dominated by strong nonequilibrium processes. In the earlier calculations the central system was a short quantum wire with parallel quantum dots of the same shape. The anisotropy of the system makes the first excitation of the even parity one-electron ground state to be an odd

• parity state with respect to the axis of the quantum dots, the y-axis. Subsequently, y-polarized cavity photons couple the two states strongly through the paramagnetic electron–photon interaction, but only weakly through the diamagnetic interaction. On the other hand, x-polarized photons can only couple

Reduced graphene oxide supported C₃N₄ nanoflakes and quantum dots as metal-free catalysts for visible light assisted CO₂ reduction

• Md Rakibuddin and
• Haekyoung Kim

Beilstein J. Nanotechnol. 2019, 10, 448–458, doi:10.3762/bjnano.10.44

• promising for CO2 photoreduction because of their excellent activity and environmental sustainability. Keywords: CO2 reduction; metal-free hybrid; nanoflakes; photocatalyst; quantum dots; Introduction The solar-light-assisted photocatalytic reduction of CO2 into useful chemicals, such as HCOOH, HCHO, CH4

• electronic modification of the g-C3N4 material with rGO, another interesting strategy is to increase the number of catalytic active sites (pyridinic N, graphitic N, and edge amine groups) in g-C3N4 [19]. This can be achieved by generating zero-dimensional (0D) quantum dots (QDs) and nanoflakes (NFs) of g

• hydrothermal heating, it undergoes many structural changes (breaking of aromatic planes along (002) directions) internally. Thus, the size of the nanosheet is drastically decreased when it transforms into quantum dots. Consequently, the intensity of the planes is expected to largely decrease. In the GCN hybrid

Sub-wavelength waveguide properties of 1D and surface-functionalized SnO₂ nanostructures of various morphologies

• Venkataramana Bonu,
• Binaya Kumar Sahu,
• Arindam Das,
• Sankarakumar Amirthapandian,
• Sandip Dhara and
• Harish C. Barshilia

Beilstein J. Nanotechnol. 2019, 10, 379–388, doi:10.3762/bjnano.10.37

• understanding of the surface defects and role of morphology in 1D SnO2 nanowires can help to better utilize these nanostructures more efficiently. For this purpose, three different nanowires (NWs), namely belts, cylindrical- and square-shaped structures were grown using SnO2 quantum dots as a precursor material

• tapered Ag NW waveguides showed that plasmon polaritons are slowed near the tip and subsequent accumulation of energy and giant local fields appear at the tip [9][10]. A NW waveguide was reported for use as a single photon emitter [4][6][7][11]. In particular, InAsP quantum dots embedded on the axis of an

• , we focus on the growth of elongated SnO2 NWs with different cross sections such as circular, square, and rectangular (belt) using SnO2 quantum dots (QDs) as a precursor material. The waveguide behavior in square- and cylindrical-shaped NWs, uniform-sized nanobelts (NBs), tapered NBs and surface

Transport signatures of an Andreev molecule in a quantum dot–superconductor–quantum dot setup

• Zoltán Scherübl,
• András Pályi and
• Szabolcs Csonka

Beilstein J. Nanotechnol. 2019, 10, 363–378, doi:10.3762/bjnano.10.36

• Group, Budapest University of Technology and Economics, 1111 Budapest, Hungary 10.3762/bjnano.10.36 Abstract Hybrid devices combining quantum dots with superconductors are important building blocks of conventional and topological quantum-information experiments. A requirement for the success of such

• experiments is to understand the various tunneling-induced non-local interaction mechanisms that are present in the devices, namely crossed Andreev reflection, elastic co-tunneling, and direct interdot tunneling. Here, we provide a theoretical study of a simple device that consists of two quantum dots and a

• ][14], Majorana states in graphene [15][16][17] and devices with even more exotic non-Abelian excitations, such as parafermions [18][19][20]. CAR was studied experimentally in metallic nanostructures [21][22][23][24] and later in so-called Cooper-pair splitter devices, where two quantum dots (QDs) are

Surface plasmon resonance enhancement of photoluminescence intensity and bioimaging application of gold nanorod@CdSe/ZnS quantum dots

• Siyi Hu,
• Yu Ren,
• Yue Wang,
• Jinhua Li,
• Junle Qu,
• Liwei Liu,
• Hanbin Ma and
• Yuguo Tang

Beilstein J. Nanotechnol. 2019, 10, 22–31, doi:10.3762/bjnano.10.3

• Technology, Changchun 130022, P. R. China College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, P. R. China 10.3762/bjnano.10.3 Abstract Biological applications of core/shell near-infrared quantum dots (QDs) have attracted broad interest due to their unique optical and chemical

• as an optical process for MCF-7 breast cancer cells. Keywords: bioimaging; gold nanorods; photoluminescence enhancement; quantum dots; Introduction In the past decades, quantum dots (QDs) have proven to be increasingly useful for their unique features [1][2][3][4][5]. The light emission from QDs

Charged particle single nanometre manufacturing

• Philip D. Prewett,
• Cornelis W. Hagen,
• Claudia Lenk,
• Steve Lenk,
• Marcus Kaestner,
• Tzvetan Ivanov,
• Ahmad Ahmad,
• Ivo W. Rangelow,
• Xiaoqing Shi,
• Stuart A. Boden,
• Alex P. G. Robinson,
• Dongxu Yang,
• Sangeetha Hari,
• Marijke Scotuzzi and
• Ejaz Huq

Beilstein J. Nanotechnol. 2018, 9, 2855–2882, doi:10.3762/bjnano.9.266

• combined with CVD. As another example, 5 nm GaN quantum dots were deposited by Crozier [86] by EBID from a specially tailored precursor resulting in high-quality uniform deposits on a thin film of Si/SiO2. Shimojo [87] demonstrated the deposition of self-standing nanorods, 10 nm in diameter, by electrons

Variation of the photoluminescence spectrum of InAs/GaAs heterostructures grown by ion-beam deposition

• Alexander S. Pashchenko,
• Leonid S. Lunin,
• Eleonora M. Danilina and
• Sergei N. Chebotarev

Beilstein J. Nanotechnol. 2018, 9, 2794–2801, doi:10.3762/bjnano.9.261

• Electronics, Platov South-Russian State Polytechnic University (NPI), 346428, 132, Prosveshchenia str., Novocherkassk, Russia 10.3762/bjnano.9.261 Abstract This work reports on an experimental investigation of the influence of vertical stacking of quantum dots, the thickness of GaAs potential barriers, and

• their isovalent doping with bismuth on the photoluminescence properties of InAs/GaAs heterostructures. The experimental samples were grown by ion-beam deposition. We showed that using three vertically stacked layers of InAs quantum dots separated by thin GaAs barrier layers was accompanied by a red

• heterostructures was investigated. It was found that the Bi content up to 4.96 atom % in GaAs decreases the density of InAs quantum dots from 1.53 × 1010 to 0.93 × 1010 cm−2. In addition, the average lateral size of the InAs quantum dots increased from 14 to 20 nm, due to an increase in the surface diffusion of In

Silencing the second harmonic generation from plasmonic nanodimers: A comprehensive discussion

• Jérémy Butet,
• Gabriel D. Bernasconi and
• Olivier J. F. Martin

Beilstein J. Nanotechnol. 2018, 9, 2674–2683, doi:10.3762/bjnano.9.250

• gap of a few nanometers [6]. Several methods have been developed for the fabrication of these nanoantennas, including both top-down and bottom-up approaches [7]. The challenge of loading the interstice between the two arms with different materials, including single molecules [8], quantum dots [9], and

Polarization-dependent strong coupling between silver nanorods and photochromic molecules

• Gwénaëlle Lamri,
• Alessandro Veltri,
• Jean Aubard,
• Pierre-Michel Adam,
• Nordin Felidj and
• Anne-Laure Baudrion

Beilstein J. Nanotechnol. 2018, 9, 2657–2664, doi:10.3762/bjnano.9.247

• light emitted by quantum dots or molecules [2][3], and to kill cancer cells [4]. This resonance is directly linked to the intrinsic properties of the metallic nanoparticles (depending on the geometry or the nature of the metal), which makes it difficult to easily control its spectral position. Many

Interaction-induced zero-energy pinning and quantum dot formation in Majorana nanowires

• Samuel D. Escribano,
• Alfredo Levy Yeyati and
• Elsa Prada

Beilstein J. Nanotechnol. 2018, 9, 2171–2180, doi:10.3762/bjnano.9.203

• features are observed in recent experiments on the detection of Majoranas and could thus help to properly characterize them. Keywords: hybrid superconductor–semiconductor nanowires; interactions; Majorana bound states; quantum dots; Introduction Semiconducting nanowires with strong spin–orbit interaction

• unexplored before is the creation of deep potential wells at the ends of the wire close to the bulk metallic electrodes. These wells, obtained explicitly here through the self-consistent calculation, are similar to the confinement potentials typical of quantum dots. Localized quantum dot-like energy levels

Electrospun one-dimensional nanostructures: a new horizon for gas sensing materials

• Muhammad Imran,
• Nunzio Motta and
• Mahnaz Shafiei

Beilstein J. Nanotechnol. 2018, 9, 2128–2170, doi:10.3762/bjnano.9.202

• the NPs in the fibers. Based on the type of NP (0D – dots, 1D – wires, 2D – plates), the nanofibers can be classified as: 0D NPs–electrospun fibers containing quantum dots or zero-dimensional particles, 1D NPs–electrospun fibers containing wires or similar elongated morphologies, 2D NPs–electrospun

A scanning probe microscopy study of nanostructured TiO₂/poly(3-hexylthiophene) hybrid heterojunctions for photovoltaic applications

• Laurie Letertre,
• Roland Roche,
• Olivier Douhéret,
• Hailu G. Kassa,
• Denis Mariolle,
• Nicolas Chevalier,
• Łukasz Borowik,
• Philippe Dumas,
• Benjamin Grévin,
• Roberto Lazzaroni and
• Philippe Leclère

Beilstein J. Nanotechnol. 2018, 9, 2087–2096, doi:10.3762/bjnano.9.197

• other hand. Hybrid PV devices include various technologies such as perovskite cells, dye sensitized solar cells (DSSC), with power efficiencies up to 13% [5] and hybrid bulk heterojunctions (HBHJ), which combine an organic matrix and inorganic semiconducting nanostructures such as quantum dots. Among

Electromigrated electrical optical antennas for transducing electrons and photons at the nanoscale

• Arindam Dasgupta,
• Mickaël Buret,
• Nicolas Cazier,
• Marie-Maxime Mennemanteuil,
• Reinaldo Chacon,
• Kamal Hammani,
• Jean-Claude Weeber,
• Juan Arocas,
• Laurent Markey,
• Gérard Colas des Francs,
• Alexander Uskov,
• Igor Smetanin and
• Alexandre Bouhelier

Beilstein J. Nanotechnol. 2018, 9, 1964–1976, doi:10.3762/bjnano.9.187

• versatile and low-cost integrated light sources, and optical tunneling gap antennas may provide an alternative technology to solid-state light emitting diodes or quantum dots. Coupling of such a junction have been recently demonstrated in plasmonic strips [27][59] and we extend the concept to dielectric

A zero-dimensional topologically nontrivial state in a superconducting quantum dot

• Pasquale Marra,
• Alessandro Braggio and
• Roberta Citro

Beilstein J. Nanotechnol. 2018, 9, 1705–1714, doi:10.3762/bjnano.9.162

• temperatures. Keywords: Josephson effect; Josephson junctions; quantum dots; superconducting quantum dots; topological states; topological superconductors; Introduction Since the discovery of the quantum Hall effect [1][2] and the theoretical prediction of Majorana bound states in triplet superconductors [3

• discontinuities and ground-state parity crossings [55][56][57][58][59][60][61] have been recognized as precursors of Majorana modes in the long-wire limit [27][50], and of Floquet–Majorana modes realized in driven quantum dots [62][63]. We will analytically derive and discuss the spectrum and the Josephson

Photoluminescence of CdSe/ZnS quantum dots in nematic liquid crystals in electric fields

• Margarita A. Kurochkina,
• Elena A. Konshina and
• Daria Khmelevskaia

Beilstein J. Nanotechnol. 2018, 9, 1544–1549, doi:10.3762/bjnano.9.145

• , Russia 10.3762/bjnano.9.145 Abstract We have experimentally investigated the effect of the reorientation of a nematic liquid crystal (LC) in an electric field on the photoluminescence (PL) of CdSe/ZnS semiconductor quantum dots (QDs). To the LC with positive dielectric anisotropy, 1 wt % QDs with a core

• obtained results are interesting for controlling the PL intensity of semiconductor QDs in liquid crystals by the application of electric fields. Keywords: aggregation; decay time; liquid crystal; luminescence intensity; orientation; Introduction Colloidal quantum dots (QDs) are a special kind of

• nanocrystals. These nanoparticles (NPs) of spherical shape are unique luminophores due to the dimensional dependence of the optical properties. The small dimensions of QDs (of the order of 1–10 nm) make it possible to integrate QDs relatively easily into hybrid structures and composite materials. Quantum dots

Spatial Rabi oscillations between Majorana bound states and quantum dots

• Jun-Hui Zheng,
• Dao-Xin Yao and
• Zhi Wang

Beilstein J. Nanotechnol. 2018, 9, 1527–1535, doi:10.3762/bjnano.9.143

• states. Quantum dot has been proved to be a good probe to study the Majorana bound states [27][3][28][29][30][31][32][33][34][35][36][7][37][38]. The quantum dots are zero-dimensional systems that have controllable discrete energy levels. The Rabi oscillation, a fundamental quantum phenomenon in two

• -level quantum systems, may occur between the states of the quantum dot when the quantum dot is periodically modulated. In particular, the spatial Rabi oscillation between two quantum dots has been proven to be useful for single-electron pumping. An attractive idea is to exploit the spatial Rabi

• oscillation between the quantum dots and the Majorana bound states [29] and to investigate the self-conjugateness and exponential protection of Majorana bound states. In recent experiments, a hybrid structure of a quantum dot and a one-dimensional topological superconductor nanowire has been realized [36

Absence of free carriers in silicon nanocrystals grown from phosphorus- and boron-doped silicon-rich oxide and oxynitride

• Daniel Hiller,
• Julian López-Vidrier,
• Keita Nomoto,
• Michael Wahl,
• Wolfgang Bock,
• Tomáš Chlouba,
• František Trojánek,
• Sebastian Gutsch,
• Margit Zacharias,
• Dirk König,
• Petr Malý and
• Michael Kopnarski

Beilstein J. Nanotechnol. 2018, 9, 1501–1511, doi:10.3762/bjnano.9.141

• the effects described above will appear. Si NCs of a few nanometres in diameter (i.e., quantum dots) represent a good model system to study doping at the nanoscale. They can be fabricated by various methods [7][8][9] and doped either during growth [7] or post-growth [10]. A recent review provides a

Cathodoluminescence as a probe of the optical properties of resonant apertures in a metallic film

• Kalpana Singh,
• Evgeniy Panchenko,
• Babak Nasr,
• Amelia Liu,
• Lukas Wesemann,
• Timothy J. Davis and
• Ann Roberts

Beilstein J. Nanotechnol. 2018, 9, 1491–1500, doi:10.3762/bjnano.9.140

• ] and enhanced coupling to plasmonic cavities by emitters such as quantum dots [36]. One way to enhance the signal-to-noise ratio of transmission measurements is to study the collective optical properties of an array of apertures, choosing the periodicity to minimize both the effects of diffraction and

• demonstrated [50]. The spectral properties of core–shell CdSe/CdS quantum dots have also been studied using CL in a transmission electron microscope [51]. The same technique has been used to generate single photons and to characterize quantum states and the nature of the emitted beam with subwavelength

• these two different modes within this structure raises the prospect of designing aperture structures where the transverse geometry could be tailored to facilitate coupling between cavity and plasmonic resonances. This could underpin novel approaches to controlling the emission of molecules and quantum

Colorimetric detection of Cu²⁺ based on the formation of peptide–copper complexes on silver nanoparticle surfaces

• Gajanan Sampatrao Ghodake,
• Surendra Krishna Shinde,
• Rijuta Ganesh Saratale,
• Avinash Ashok Kadam,
• Ganesh Dattatraya Saratale,
• Asad Syed,
• Fuad Ameen and
• Dae-Young Kim

Beilstein J. Nanotechnol. 2018, 9, 1414–1422, doi:10.3762/bjnano.9.134

• traditional organic probes [8][9][10], but the preparation of such functionalized quantum dots is a time-consuming process. Similarly, colorimetric methods based on Cu2+-dependent click chemistry are well-known for high selectivity and tolerance to interference caused by other metal ions. Nonetheless, these

Interplay between pairing and correlations in spin-polarized bound states

• Szczepan Głodzik,
• Aksel Kobiałka,
• Anna Gorczyca-Goraj,
• Andrzej Ptok,
• Grzegorz Górski,
• Maciej M. Maśka and
• Tadeusz Domański

Beilstein J. Nanotechnol. 2018, 9, 1370–1380, doi:10.3762/bjnano.9.129

• between the opposite spin electrons can bring additional important effects. In the proximitized quantum dots it can lead to a parity change (quantum phase transition) with further influence on the subgap Kondo effect (driven by effective spin-exchange coupling with mobile electrons). Furthermore, such

• co-authors [49]. Inspired by this achievement, extensive studies have been carried out regarding the YSR states coalescencing into the zero-energy Majorana states in side-coupled quantum dots driven by electrostatic or magnetic fields [50][51][52]. This issue would be particularly important when

• , we analyzed leakage of the polarized Majorana modes on the multi-site quantum dots, revealing their partial delocalization (Figure 6). Majorana vs Kondo effect In previous section we have discussed the polarized Majorana modes leaking into side-attached objects, such as single impurities or segments

Computational exploration of two-dimensional silicon diarsenide and germanium arsenide for photovoltaic applications

• Sri Kasi Matta,
• Chunmei Zhang,
• Yalong Jiao,
• Anthony O'Mullane and
• Aijun Du

Beilstein J. Nanotechnol. 2018, 9, 1247–1253, doi:10.3762/bjnano.9.116

• . Additionally, the exciton binding energies are quite low and are comparable to quantum dot semiconductors. It might be possible that these semiconductors could be synthesized as quantum dots and studied in further detail. Band gap tuning appears also possible and could be used to tailor the compounds for