TiO₂ immobilized on 2D mordenite: effect of hydrolysis conditions on structural, textural, and optical characteristics of the nanocomposites

• Marina G. Shelyapina,
• Rosario Isidro Yocupicio-Gaxiola,
• Gleb A. Valkovsky and
• Vitalii Petranovskii

Beilstein J. Nanotechnol. 2025, 16, 128–140, doi:10.3762/bjnano.16.12

• accuracy of the experiment). Therefore, this step is immediately followed by condensation: The final composition of the hydrolysis products of alkoxides of titanium roughly corresponds to TiO1.5(OR)·yROH, where y = 0.15–1.00 depending on the nature of the alcohol. The residual carbon during thermal

• treatment in air is eliminated in the process of crystallization at 400–550 °C; thus, titanium dioxide nanoparticles are obtained [29]. In this study we investigate in detail the influence of the hydrolysis medium and the duration of the hydrolytic process on composition, local structure, morphology

• /hydrophobic properties than the samples hydrolyzed in pure water. It is known that the hydrophilicity of TiO2 depends on the crystalline phase and surface composition, but not on the size [43]. Moreover, it was found that introduction of TiO2 into an amorphous siliceous matrix increases the hydrophilicity of

Characterization of ZnO nanoparticles synthesized using probiotic Lactiplantibacillus plantarum GP258

• Prashantkumar Siddappa Chakra,
• Aishwarya Banakar,
• Shriram Narayan Puranik,
• Vishwas Kaveeshwar,
• C. R. Ravikumar and
• Devaraja Gayathri

Beilstein J. Nanotechnol. 2025, 16, 78–89, doi:10.3762/bjnano.16.8

• measurements were employed to analyze the morphology, dimensions, and elemental composition of the generated nanoparticles. The experimental outcomes confirmed the presence of hexagonal wurtzite-structured ZnO NPs with an average size of 10 nm. The colloidal system demonstrated excellent stability with a zeta

• wrinkled pattern, and it was found that the NPs average size was 72 nm. The presence of ZnO NPs on the surface was confirmed through EDX, which showed characteristic elemental peaks validating the composition (Figure 4a–d). Zeta potential The ZnO NPs synthesized using GP258 showed good stability as

• ) EDX spectroscopy for elemental composition. (e) Zeta potential measurement. (f) DLS results showing the size distribution of ZnO NPs. (a, b) Cyclic voltammetry response of the ZnO electrode in 0.1 M KCl solution at varying scan rates, showing redox behavior and electron transfer characteristics. (c

Theoretical study of the electronic and optical properties of a composite formed by the zeolite NaA and a magnetite cluster

• Joel Antúnez-García,
• Roberto Núñez-González,
• Vitalii Petranovskii,
• H’Linh Hmok,
• Armando Reyes-Serrato,
• Fabian N. Murrieta-Rico,
• Mufei Xiao and
• Jonathan Zamora

Beilstein J. Nanotechnol. 2025, 16, 44–53, doi:10.3762/bjnano.16.5

• characteristics of zeolites depend largely on the chemical composition of the framework, specifically the Si/Al ratio [1][2]. These characteristics make zeolites highly appealing for a wide range of applications, including the production of fine chemicals [3][4], gas separation [5][6][7], ion exchange [8][9][10

• response are intricately linked to factors such as the chemical composition, particle size, structure, and geometry of these materials [18][19][20]. Hence, it is generally undesirable for nanoscale materials to undergo structural alterations because of environmental exposure or to change their properties

Bioinspired nanofilament coatings for scale reduction on steel

• Siad Dahir Ali,
• Mette Heidemann Rasmussen,
• Jacopo Catalano,
• Christian Husum Frederiksen and
• Tobias Weidner

Beilstein J. Nanotechnol. 2025, 16, 25–34, doi:10.3762/bjnano.16.3

• expected for SNF coating are clearly visible from a coated steel surface. Figure 3B and Figure 3C show the images of the measured angle of the coated and uncoated steel surfaces. The related atomic composition of the coating was analyzed by energy-dispersive X-ray spectroscopy (EDX) for both coated steel

• surfaces. The elemental composition in Figure 4B shows the silicon emission expected for the SNF film, which is not present on the bare steel surface. Oxygen and carbon, additional components of the SNF coating, are also detected for the SNFs. At the same time, these elements are also observed on the bare

• steel substrate and the elemental composition of the SNFs is difficult to disentangle. The contact angle of the uncoated surfaces was 71°. The contact angle of the SNF-coated surfaces is more difficult to measure as the droplet will not attach itself to the surface seen for Figure 3B and Figure 5D, in

Orientation-dependent photonic bandgaps in gold-dust weevil scales and their titania bioreplicates

• Norma Salvadores Farran,
• Limin Wang,
• Primoz Pirih and
• Bodo D. Wilts

Beilstein J. Nanotechnol. 2025, 16, 1–10, doi:10.3762/bjnano.16.1

• elemental composition of the original scales and the replicas (Supporting Information File 1, Table S1) shows that nitrogen is absent in the replicas, indicating that the cleaning procedure, despite its relatively low maximal temperature (130 °C) satisfactorily removed the template’s original material from

• our knowledge never conclusively for photonic crystals (for a review, see [21]). The iridescence effect was reversed when we turned the animal to the side (not shown); hence, the effect is likely not due to the material composition or lattice periodicity differences between the scales at the top and

Mechanistic insights into endosomal escape by sodium oleate-modified liposomes

• Ebrahim Sadaqa,
• Satrialdi,
• Fransiska Kurniawan and
• Diky Mudhakir

Beilstein J. Nanotechnol. 2024, 15, 1667–1685, doi:10.3762/bjnano.15.131

• engineered three distinct liposomal formulations to investigate mechanisms of endosomal escape, namely, unmodified-Lipo, SO-Lipo, and AUR-Lipo. The base composition for the unmodified liposomes consisted of DMPC and cholesterol, mixed in a molar ratio of 9:1, yielding a total lipid concentration of 2.7 mM

Attempts to preserve and visualize protein corona on the surface of biological nanoparticles in blood serum using photomodification

• Julia E. Poletaeva,
• Anastasiya V. Tupitsyna,
• Alina E. Grigor’eva,
• Ilya S. Dovydenko and
• Elena I. Ryabchikova

Beilstein J. Nanotechnol. 2024, 15, 1654–1666, doi:10.3762/bjnano.15.130

• efforts of many researchers are aimed at finding approaches and methods for “managing” the composition of the protein corona, which, in particular, can provide the possibility of targeted delivery of drugs [1][2][3]. The protein corona is formed by two layers on any NP, called the hard and soft coronas

• . The former is tightly linked the surface of the NPs and is stable when isolating the NPs, which allows for determining its protein composition [4][5][6][7]. In contrast, the components of the soft corona are weakly bonded to the underlying hard one and are easily separated by the slightest force. The

• vacated space is quickly occupied by neighboring components of the medium, as a result of which the composition of the soft corona is constantly changing, even when a NP suspension is stirred [8][9]. As data accumulate on the role of the protein corona in the implementation of nanomedicine, researchers

Fabrication of hafnium-based nanoparticles and nanostructures using picosecond laser ablation

• Abhishek Das,
• Mangababu Akkanaboina,
• Jagannath Rathod,
• R. Sai Prasad Goud,
• Kanaka Ravi Kumar,
• Raghu C. Reddy,
• Ratheesh Ravendran,
• Katia Vutova,
• S. V. S. Nageswara Rao and
• Venugopal Rao Soma

Beilstein J. Nanotechnol. 2024, 15, 1639–1653, doi:10.3762/bjnano.15.129

• size and morphology [1]. Recently, interest has risen regarding synthesis and study of Hf-based NPs. Depending on the morphology, chemical composition, and quantum confinement effects, NPs can exhibit novel properties, making them applicable for large-spectrum usage [12][13]. Thus, synthesizing the

• target, from a single pure medium to a mixture of liquid media, with a range of target types such as powder, pellets, and well-defined structures and shapes [16][20]. The choice of the liquid medium can significantly affect morphology and chemical composition of the obtained NPs. The high energy of the

• . These Hf sponges, cut and polished to 10 mm × 10 mm × 2 mm, were used as ablation targets. The pristine target had the crystal structure of hexagonal HfO0.25, as confirmed by X-ray diffraction (XRD) data (see Figure 1a). The elemental composition (Hf: 73.68%, O: 26.32%) was determined by energy

Heterogeneous reactions in a HFCVD reactor: simulation using a 2D model

• Xochitl Aleyda Morán Martínez,
• José Alberto Luna López,
• Zaira Jocelyn Hernández Simón,
• Gabriel Omar Mendoza Conde,
• José Álvaro David Hernández de Luz and
• Godofredo García Salgado

Beilstein J. Nanotechnol. 2024, 15, 1627–1638, doi:10.3762/bjnano.15.128

• increases with the flux of H2. This effect was already studied experimentally, and the most significant results were the analysis of how the hydrogen flow influences the composition SiOx films by X-ray photoelectron spectroscopy; as the hydrogen flow increases, the concentration of Si also increases in

Natural nanofibers embedded in the seed mucilage envelope: composite hydrogels with specific adhesive and frictional properties

• Agnieszka Kreitschitz and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2024, 15, 1603–1618, doi:10.3762/bjnano.15.126

• its composition [14][15][16]. The nanoscale level of the spatial organisation of mucilage observed with scanning electron microscopy (SEM) reveals the complexity of the mucilage with special features, such as 3D organisation of polysaccharides in a net-like structure [7][13]. In the last years, the

• tasteless [11][21]. Its chemical composition and special physical properties allow many applications of mucilage, for example, as thickening and structuring (gel-forming) agent, emulsifier or stabiliser for food products, scaffold for tissue regeneration, additive in formation of medicinal tablets, and for

• ], or to animal bodies, promoting epizoochory [31][32][33]. These distinct physical features make mucilage also an important substrate for pharmaceutical, biomedical, and food industries [11][15][19][20][21]. Here, we briefly review the basic composition and structure of mucilage, its frictional and

Facile synthesis of size-tunable L-carnosine-capped silver nanoparticles and their role in metal ion sensing and catalytic degradation of p-nitrophenol

• Akash Kumar,
• Ridhima Chadha,
• Abhishek Das,
• Nandita Maiti and
• Rayavarapu Raja Gopal

Beilstein J. Nanotechnol. 2024, 15, 1576–1592, doi:10.3762/bjnano.15.124

• absorption peaks indicates that the nanoparticles aggregated. The results confirm that ʟ-car-AgNP2–5 nanoparticles are polydisperse. FTIR, Raman spectroscopy and X-ray diffraction In addition to TEM analysis, the interaction between functional groups of ʟ-carnosine and silver, the elemental composition, and

Green synthesis of silver nanoparticles derived from algae and their larvicidal properties to control Aedes aegypti

• Matheus Alves Siqueira de Assunção,
• Douglas Dourado,
• Daiane Rodrigues dos Santos,
• Gabriel Bezerra Faierstein,
• Mara Elga Medeiros Braga,
• Severino Alves Junior,
• Rosângela Maria Rodrigues Barbosa,
• Herminio José Cipriano de Sousa and
• Fábio Rocha Formiga

Beilstein J. Nanotechnol. 2024, 15, 1566–1575, doi:10.3762/bjnano.15.123

• (1 mM; 15:85 ratio) and incubated at 28 °C for 60 min. Composition of algae species, metal concentration, agitation, reaction time and temperature can impact the characteristics of AgNPs [57]. Thus, such systems must be well characterized, as discussed in the next section. Different chemical

Ultrablack color in velvet ant cuticle

• Vinicius Marques Lopez,
• Wencke Krings,
• Juliana Reis Machado,
• Stanislav Gorb and
• Rhainer Guillermo-Ferreira

Beilstein J. Nanotechnol. 2024, 15, 1554–1565, doi:10.3762/bjnano.15.122

• , Leica Biosystems, Solms, Germany) and contrasted with osmium tetroxide. Confocal laser scanning microscopy (CLSM) The capacity of insect cuticle to emit autofluorescence at various wavelengths is extensively documented, influenced by material composition, degree of sclerotization, and the presence of

The round-robin approach applied to nanoinformatics: consensus prediction of nanomaterials zeta potential

• Dimitra-Danai Varsou,
• Arkaprava Banerjee,
• Joyita Roy,
• Kunal Roy,
• Giannis Savvas,
• Haralambos Sarimveis,
• Ewelina Wyrzykowska,
• Mateusz Balicki,
• Tomasz Puzyn,
• Georgia Melagraki,
• Iseult Lynch and
• Antreas Afantitis

Beilstein J. Nanotechnol. 2024, 15, 1536–1553, doi:10.3762/bjnano.15.121

• generally more toxic than negatively charged particles of similar composition [28][29][30]. In fact, several in silico models for the ZP have been developed based on different theoretical and experimental descriptors employing a range of approaches, that is, quantitative structure–property/feature

• of the NMs’ composition, structure, and behaviour, thereby serving as vital predictors for the model’s predictive accuracy and interpretability. Model development and validation The selected descriptors were employed in the training of the final model, which adhered to the methodological framework

Electrochemical nanostructured CuBTC/FeBTC MOF composite sensor for enrofloxacin detection

• Thi Kim Ngan Nguyen,
• Tien Dat Doan,
• Huy Hieu Luu,
• Hoang Anh Nguyen,
• Thi Thu Ha Vu,
• Quang Hai Tran,
• Ha Tran Nguyen,
• Thanh Binh Dang,
• Thi Hai Yen Pham and
• Mai Ha Hoang

Beilstein J. Nanotechnol. 2024, 15, 1522–1535, doi:10.3762/bjnano.15.120

• volume of 0.544 cm3/g, and a capillary diameter of 1.50 nm. Additionally, energy-dispersive X-ray mapping demonstrated the uniform distribution of the two MOFs within the electrode composition. The synergistic effect of the electrocatalytic properties of CuBTC and the high conductivity of FeBTC

• electrode composition. For the determination of ENR, square wave adsorptive stripping voltammetry (SW-AdSV) was employed because of its superior performance in comparison to the cyclic voltammetric method. Figure 6b illustrates the square wave voltammograms (SWVs) depicting the electrochemical response of

• electrode has three components, namely, CuBTC, FeBTC, and carbon paste. The carbon paste content was maintained at 90%, resulting in the total of CuBTC and FeBTC being 10%. By altering the proportions of CuBTC and FeBTC in the electrode composition, significant variations in the ENR signal were observed

Integrating high-performance computing, machine learning, data management workflows, and infrastructures for multiscale simulations and nanomaterials technologies

• Fabio Le Piane,
• Mario Vozza,
• Matteo Baldoni and
• Francesco Mercuri

Beilstein J. Nanotechnol. 2024, 15, 1498–1521, doi:10.3762/bjnano.15.119

• materials research by extracting valuable patterns and correlations from vast amounts of experimental and computational data [6][7][8][9]. These approaches enable researchers to uncover hidden relationships between composition, structure, morphology, processing, and properties, accelerating the discovery of

Polymer lipid hybrid nanoparticles for phytochemical delivery: challenges, progress, and future prospects

• Iqra Rahat,
• Pooja Yadav,
• Aditi Singhal,
• Mohammad Fareed,
• Jaganathan Raja Purushothaman,
• Mohammed Aslam,
• Raju Balaji,
• Sonali Patil-Shinde and
• Md. Rizwanullah

Beilstein J. Nanotechnol. 2024, 15, 1473–1497, doi:10.3762/bjnano.15.118

• crucial for maintaining therapeutic drug levels over extended periods of time [20][21]. By adjusting the polymer composition and lipid matrix, researchers can fine-tune the release kinetics of phytochemicals, ensuring sustained therapeutic effects. This controlled release mechanism is particularly

Effect of radiation-induced vacancy saturation on the first-order phase transformation in nanoparticles: insights from a model

• Aram Shirinyan and
• Yuriy Bilogorodskyy

Beilstein J. Nanotechnol. 2024, 15, 1453–1472, doi:10.3762/bjnano.15.117

• literature review reveals that the stability of materials under irradiation is influenced by numerous factors. Some of these characteristic factors include the elemental composition and chemical structure, the microstructure of the material (including grain boundaries, defects, dislocations, and interfaces

• compared to similar materials lacking such precipitates. For example, nanocrystalline solids of ZrO2 or Pd demonstrate high resistance to radiation-induced defect production compared to coarse-grained polycrystals with the same chemical composition [3]. Consequently, a significant increase in radiation

• is worth noting that the thermodynamic analysis and conclusions drawn from this study are applicable for understanding amorphization and polymorphic phase transitions in both metals and ceramics. In the present study we investigate model systems with structure change, but without composition change

Ion-induced surface reactions and deposition from Pt(CO)₂Cl₂ and Pt(CO)₂Br₂

• Mohammed K. Abdel-Rahman,
• Patrick M. Eckhert,
• Atul Chaudhary,
• Johnathon M. Johnson,
• Jo-Chi Yu,
• Lisa McElwee-White and
• D. Howard Fairbrother

Beilstein J. Nanotechnol. 2024, 15, 1427–1439, doi:10.3762/bjnano.15.115

• transformations of precursor thin films. In this approach, the precursor is adsorbed onto a cooled substrate to form 1–2 nm thin films. The effects of ion beam exposure on the thin films are characterized by X-ray photoelectron spectroscopy to identify changes in the films’ composition and chemical environment

• , and mass spectrometry to identify the volatile species produced by ion beam irradiation. Insights from these studies have been used to rationalize the composition of thin films formed by ion-induced deposition of Pt(CO)2Cl2 in the presence of Ar+ irradiation under steady-state deposition conditions

• Pt(CO)2Cl2/He+ and Pt(CO)2Br2/H2+. Analysis of Figure 5 reveals that trends in film composition amongst all of the different precursor/ion combinations as a function of the ion dose are remarkably similar. This strongly suggests that the elementary reaction steps involved in the ion beam-induced

A biomimetic approach towards a universal slippery liquid infused surface coating

• Ryan A. Faase,
• Madeleine H. Hummel,
• AnneMarie V. Hasbrook,
• Andrew P. Carpenter and
• Joe E. Baio

Beilstein J. Nanotechnol. 2024, 15, 1376–1389, doi:10.3762/bjnano.15.111

• to use. These biomimetic surface functionalization steps were confirmed by several complimentary surface analysis techniques. The wettability of each surface was probed with water contact angle measurements, while the chemical composition of the layer was determined by X-ray photoelectron

• , which has the ability to probe vibrational modes at an interface, thereby, providing insight into the order and confirmation of molecules at an interface [26][27]. XPS is a surface-sensitive technique to determine the atomic composition of the outer ca. 10 nm of a surface [28]. As mentioned above, SLIPS

• composition of the layer was determined by XPS. Surface roughness was evaluated using AFM to confirm successful formation of a porous structure. Finally, ordering of specific chemical groups within our PDA SLIPS layer was explored via SFG spectroscopy. Initially, each functionalization step was assessed

Hymenoptera and biomimetic surfaces: insights and innovations

• Vinicius Marques Lopez,
• Carlo Polidori and
• Rhainer Guillermo Ferreira

Beilstein J. Nanotechnol. 2024, 15, 1333–1352, doi:10.3762/bjnano.15.107

• ), with the leaf-cutter genus Atta overrepresented in cuticular composition investigations (reviewed in [59]). Within Hymenoptera, ants are particularly fascinating because of their division into castes with distinct tasks and sizes, showcasing a hierarchical organization in their societies [60]. Among

• modulus [61]. Understanding the mechanical properties and composition of leafcutter ant mandibles could offer valuable insights into biomimetic design principles, potentially inspiring the development of innovative tools and instruments with enhanced performance and adaptability for various applications

Nanoarchitectonics with cetrimonium bromide on metal nanoparticles for linker-free detection of toxic metal ions and catalytic degradation of 4-nitrophenol

• Akash Kumar and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2024, 15, 1312–1332, doi:10.3762/bjnano.15.106

• , metal composition, centrifugation, and NaOH amount, were investigated for their impact on the performance of CTAB-capped nanoparticles in heavy metal detection and 4-NP degradation. CTAB-Au nanospheres demonstrated limited heavy metal ion detection capability but exhibited remarkable efficiency in

Interaction of graphene oxide with tannic acid: computational modeling and toxicity mitigation in C. elegans

• Romana Petry,
• James M. de Almeida,
• Francine Côa,
• Felipe Crasto de Lima,
• Diego Stéfani T. Martinez and
• Adalberto Fazzio

Beilstein J. Nanotechnol. 2024, 15, 1297–1311, doi:10.3762/bjnano.15.105

• composition analyzed by X-ray photoelectron spectroscopy (XPS) is 68% of carbon and 32% of oxygen. The functional groups and bonds of carbon are distributed among epoxy/hydroxy (C–O) (52%), carboxyl/esters (C=O) (9.4%), and π–π* (4.2%) moieties, besides graphitic/aromatic carbon (C sp2) (5.7%) and aliphatic

• according to data reported in the literature for graphene materials [38], to 2.0 nm in double-layer spots caused by the incubation in the EPA medium. Spectroscopy characterizations Spectroscopy analysis showed the main chemical groups on the material’s surface, and how their composition changed in the

• , to 1.02 ± 0.01 and 1.05 ± 0.005 when the material was incubated in EPA medium without and with TA, respectively (Figure 2b). All Raman spectra were normalized to the intensity of the respective G bands. X-ray photoelectron spectroscopy (XPS) presented the composition of GO surface in the presence of

Mn-doped ZnO nanopowders prepared by sol–gel and microwave-assisted sol–gel methods and their photocatalytic properties

• Cristina Maria Vlăduț,
• Crina Anastasescu,
• Silviu Preda,
• Oana Catalina Mocioiu,
• Simona Petrescu,
• Jeanina Pandele-Cusu,
• Dana Culita,
• Veronica Bratan,
• Ioan Balint and
• Maria Zaharescu

Beilstein J. Nanotechnol. 2024, 15, 1283–1296, doi:10.3762/bjnano.15.104

• distribution, improved purity, tailored shape, and morphological uniformity [21]. More crucially, the crystallization can be influenced by varying reaction temperature, reaction duration, and system composition [18][22]. According to the literature, MW has been predominantly employed for the thermal treatment

• samples were thermally treated at 350 °C and 500 °C for 1 h each. Scanning electron microscopy The morphology and chemical composition (inset) of the thermally treated samples is illustrated in Figure 4. Homogeneously distributed, quasi-spherical nanoparticles (mean size diameter of 70 nm) are observed in

• synthesis techniques are effective in producing photocatalytically active materials based on manganese-doped ZnO. Despite the similar start composition, obvious morphological differences, structural defects, and surface chemistry particularities were revealed for the investigated samples, which affected the

Functional morphology of cleaning devices in the damselfly Ischnura elegans (Odonata, Coenagrionidae)

• Silvana Piersanti,
• Gianandrea Salerno,
• Wencke Krings,
• Stanislav Gorb and
• Manuela Rebora

Beilstein J. Nanotechnol. 2024, 15, 1260–1272, doi:10.3762/bjnano.15.102

• concave cuticular lamina (L) collecting dirt particles (arrows). Confocal laser scanning micrographs (maximum intensity projections) showing differences in the autofluorescence composition present in the fore tibal grooming devices of Ischnura elegans. Red color indicates chitinous, sclerotized