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Search for "metal oxide" in Full Text gives 276 result(s) in Beilstein Journal of Nanotechnology. Showing first 200.

Experimental study of an evanescent-field biosensor based on 1D photonic bandgap structures

  • Jad Sabek,
  • Francisco Javier Díaz-Fernández,
  • Luis Torrijos-Morán,
  • Zeneida Díaz-Betancor,
  • Ángel Maquieira,
  • María-José Bañuls,
  • Elena Pinilla-Cienfuegos and
  • Jaime García-Rupérez

Beilstein J. Nanotechnol. 2019, 10, 967–974, doi:10.3762/bjnano.10.97

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  • , due to the various advantages it provides, e.g., high sensitivity, miniaturization, high multiplexing level, fast response, need for very low sample and reagent volumes and the compatibility to complementary metal-oxide semiconductor (CMOS) fabrication [3]. Chip-integrated photonic biosensors have
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Published 26 Apr 2019

Comparing a porphyrin- and a coumarin-based dye adsorbed on NiO(001)

  • Sara Freund,
  • Antoine Hinaut,
  • Nathalie Marinakis,
  • Edwin C. Constable,
  • Ernst Meyer,
  • Catherine E. Housecroft and
  • Thilo Glatzel

Beilstein J. Nanotechnol. 2019, 10, 874–881, doi:10.3762/bjnano.10.88

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  • Kelvin probe force microscopy measurements. Keywords: coumarin; Kelvin probe force microscopy; metal oxide; molecular resolution; nickel oxide (NiO); non-contact atomic force microscopy; porphyrin; Introduction With regard to its use in dye-sensitized solar cells (DSSCs), the wide-bandgap n-type
  • investigated by Kelvin probe force microscopy (KPFM) [25]. This technique is used to observe and quantify the contact potential difference (CPD) changes between the metal oxide surface and the molecular layers and to determine the corresponding dipole moments. Results and Discussion Atomically clean NiO
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Published 15 Apr 2019

Synthesis of MnO2–CuO–Fe2O3/CNTs catalysts: low-temperature SCR activity and formation mechanism

  • Yanbing Zhang,
  • Lihua Liu,
  • Yingzan Chen,
  • Xianglong Cheng,
  • Chengjian Song,
  • Mingjie Ding and
  • Haipeng Zhao

Beilstein J. Nanotechnol. 2019, 10, 848–855, doi:10.3762/bjnano.10.85

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  • , only a weak peak of MnO2 (PDF#53-0633) can be observed when the loading was greater than or equal to 4%, whereas no diffraction peaks of metal oxides could be found, suggesting the formation of amorphous metal oxide phases. Amorphous catalytic materials are conducive to SCR activity [19], which is also
  • shown in the results of NO conversion (Figure 1) and our previous studies [6][16][17]. In the case of Mn–Cu–FeOx/CNTs-IWIM, a series of peaks corresponding to Mn3O4 (PDF#18-0803) can be seen. Metal oxide catalysts with higher crystallinity show a smaller catalytic activity [20]. This is corroborated by
  • the results of NO conversion. Besides, the intensities of the graphite peaks declines with increased loading, which is due to the interaction between the metal oxide catalysts and CNTs [21][22][23][24][25]. Transmission electron microscopy and energy dispersive X-ray spectrometry The morphologies of
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Published 11 Apr 2019

An efficient electrode material for high performance solid-state hybrid supercapacitors based on a Cu/CuO/porous carbon nanofiber/TiO2 hybrid composite

  • Mamta Sham Lal,
  • Thirugnanam Lavanya and
  • Sundara Ramaprabhu

Beilstein J. Nanotechnol. 2019, 10, 781–793, doi:10.3762/bjnano.10.78

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  • density of 45.83 Wh kg−1 at a power density of 1.27 kW kg−1 was also realized. The developed electrode material provides new insight into ways to enhance the electrochemical properties of solid-state supercapacitors, based on the synergistic effect of porous carbon nanofibers, metal and metal oxide
  • energy density and specific power of supercapacitors owing to the pseudo-capacitance action of the metal oxide. Additionally, the uniform distribution of TiO2 nanoparticles on the surface of the Cu/CuO/PCNF composite material could provide strong mechanical strength to the composite that relegates
  • , 297.5, 262.5, 245, 233.7 and 200 F g−1 at a current density of 1, 3.5, 5, 7, 8.5 and 10 A g−1, respectively. To the best of our knowledge, this is the best capacitance value ever achieved by solid state supercapacitors using metal oxide/carbon composite materials based on polymer gel electrolyte, and we
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Published 01 Apr 2019

Trapping polysulfide on two-dimensional molybdenum disulfide for Li–S batteries through phase selection with optimized binding

  • Sha Dong,
  • Xiaoli Sun and
  • Zhiguo Wang

Beilstein J. Nanotechnol. 2019, 10, 774–780, doi:10.3762/bjnano.10.77

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  • [11]. Polar materials were explored to trap LPSs, such as metal oxide [12][13] and metal-carbide nanoparticles [14]. Many two-dimensional (2D) materials, such as borophene [15], silicene [16], phosphorene [17], Mxene [18] and MoS2 [8], have been investigated as anchoring materials due to their large
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Published 26 Mar 2019

On the transformation of “zincone”-like into porous ZnO thin films from sub-saturated plasma enhanced atomic layer deposition

  • Alberto Perrotta,
  • Julian Pilz,
  • Stefan Pachmajer,
  • Antonella Milella and
  • Anna Maria Coclite

Beilstein J. Nanotechnol. 2019, 10, 746–759, doi:10.3762/bjnano.10.74

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  • element, oxygen, and an organic backbone, and are referred to as metal alkoxides or ‘metalcones’, e.g., alucones, zincones, and titanicones [2][4]. From the metal alkoxide produced with MLD, porous metal oxide thin films can be achieved through water etching or thermal treatments in the presence of oxygen
  • and, in turn, on the consequent possible clogging of the forming pores. Moreover, there are thorough investigations on the formation of porous oxides and metal-oxide/carbon composite films starting from MLD-derived metal alkoxides for Al-based [8][29] and Ti-based [11] materials. In these studies
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Published 21 Mar 2019

Hydrophilicity and carbon chain length effects on the gas sensing properties of chemoresistive, self-assembled monolayer carbon nanotube sensors

  • Juan Casanova-Cháfer,
  • Carla Bittencourt and
  • Eduard Llobet

Beilstein J. Nanotechnol. 2019, 10, 565–577, doi:10.3762/bjnano.10.58

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  • functionalized by introducing reactive groups onto their sidewalls, such as carboxylic acid [12][13], hydroxy [14] or carbonyl [15] groups, by decorating them with metal or metal oxide nanoparticles [10][16][17][18][19], or by creating CNT–polymer [20] or CNT–chalcogenide [21] hybrids. Employing these approaches
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Published 27 Feb 2019

Ceria/polymer nanocontainers for high-performance encapsulation of fluorophores

  • Kartheek Katta,
  • Dmitry Busko,
  • Yuri Avlasevich,
  • Katharina Landfester,
  • Stanislav Baluschev and
  • Rafael Muñoz-Espí

Beilstein J. Nanotechnol. 2019, 10, 522–530, doi:10.3762/bjnano.10.53

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  • miniemulsion techniques will be protected by depositing metal-oxide particles on the surface, as proposed in a previous minireview from our team [21]. Deposition of metal-oxide particles on the surface of polymer hybrid nanoparticles via controlled surface crystallization was shown in previous works of our
  • group [10][12]. The regular arrangement of functional groups on the nanocapsule surface can provide nucleation and structure-directing centers for the controlled crystallization of metal-oxide particles. We have chosen cerium(IV) oxide nanoparticles to be deposited on the nanocapsule surface in order to
  • combine biocompatibility with a high oxygen-scavenging ability. Cerium oxide is a lanthanide metal oxide with a redox potential behavior that can easily switch between cerium(IV) and cerium(III) and has the capability to leave oxygen vacancies in the crystal lattice [39]. Cerium(IV) oxide exhibits
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Published 22 Feb 2019

A porous 3D-RGO@MWCNT hybrid material as Li–S battery cathode

  • Yongguang Zhang,
  • Jun Ren,
  • Yan Zhao,
  • Taizhe Tan,
  • Fuxing Yin and
  • Yichao Wang

Beilstein J. Nanotechnol. 2019, 10, 514–521, doi:10.3762/bjnano.10.52

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  • sites for strong S–metal bonding that have been reported to suppress the shuttle effect in polysulfides [13][14][15][16]. Moreover, designing metal oxides into various unique morphologies, e.g., hollow structures, can also provide a physical (or structural) confinement for sulfur [17]. Metal-oxide
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Published 21 Feb 2019

Sub-wavelength waveguide properties of 1D and surface-functionalized SnO2 nanostructures of various morphologies

  • Venkataramana Bonu,
  • Binaya Kumar Sahu,
  • Arindam Das,
  • Sankarakumar Amirthapandian,
  • Sandip Dhara and
  • Harish C. Barshilia

Beilstein J. Nanotechnol. 2019, 10, 379–388, doi:10.3762/bjnano.10.37

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  • to carry out logic operations in computing and communications and in optoelectronic devices. In this regard, metal oxide NWs play a pivotal role with their wide range of applications in lasers [1][2], medicine [3], chemical sensing [4][5], fabrication of efficient components in nanometer-sized
  • SnO2 NSs. Depending on the growth procedure, these metal oxide nanostructures offer varied structural and electrical properties. For instance, Zhu et al. [23] demonstrated a huge variation in the electrical conductivity in NWs grown at the liquid–solid (LS) interface and VS interface. In this article
  • section. OTS molecules are more reactive with –OH groups on the metal oxide surfaces [31][32][33]. Molecular dynamics simulations revealed that the OB site of SnO2 was the most preferable site for the formation of –OH groups [34][35]. Thus, OTS binds dominantly at OB sites over the OP sites of SnO2 NPs
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Published 07 Feb 2019

One-step nonhydrolytic sol–gel synthesis of mesoporous TiO2 phosphonate hybrid materials

  • Yanhui Wang,
  • P. Hubert Mutin and
  • Johan G. Alauzun

Beilstein J. Nanotechnol. 2019, 10, 356–362, doi:10.3762/bjnano.10.35

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  • case of metals, as M–C bonds are (in most cases) quite unstable, the organic groups can be linked to the metal oxide network via carboxylate or β-diketonate ligands [5][10][11]. Organophosphorus ligands such as phosphonates appear quite promising as they form strong ionocovalent M–O–P bonds with many
  • use an excess of metal precursor in order to form a metal oxide–phosphonate hybrid material. There are very few examples of the preparation of such materials by sol–gel methods [15][16], and the texture of these materials has not been reported. Actually, most metal oxide–phosphonate-based porous
  • hybrids are obtained in two steps, by surface modification of a porous metal oxide support [17][18][19]. Nonhydrolytic (or nonaqueous) sol–gel (NHSG) chemistry has provided simple and powerful routes to synthesize oxides or mixed oxides with different morphologies (e.g., nanoparticles) or textures (e.g
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Published 05 Feb 2019

Site-specific growth of oriented ZnO nanocrystal arrays

  • Rekha Bai,
  • Dinesh K. Pandya,
  • Sujeet Chaudhary,
  • Veer Dhaka,
  • Vladislav Khayrudinov,
  • Jori Lemettinen,
  • Christoffer Kauppinen and
  • Harri Lipsanen

Beilstein J. Nanotechnol. 2019, 10, 274–280, doi:10.3762/bjnano.10.26

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  • ; growth kinetics; nanocrystals; nucleation; twinning; zinc oxide; Introduction Metal oxide semiconductor nanostructures are quite interesting not only in terms of the basic growth mechanism involved in their fabrication, but also due to the large number of applications based on them in the field of
  • nanoscale optoelectronics [1][2][3][4]. ZnO is an important direct band gap (≈3.3 eV), nontoxic, metal oxide semiconductor, which can readily be used for optoelectronic applications. The properties of ZnO can be tailored by changing the morphology of the structures. Thus, fabrication of ZnO having different
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Published 24 Jan 2019

Wet chemistry route for the decoration of carbon nanotubes with iron oxide nanoparticles for gas sensing

  • Hussam M. Elnabawy,
  • Juan Casanova-Chafer,
  • Badawi Anis,
  • Mostafa Fedawy,
  • Mattia Scardamaglia,
  • Carla Bittencourt,
  • Ahmed S. G. Khalil,
  • Eduard Llobet and
  • Xavier Vilanova

Beilstein J. Nanotechnol. 2019, 10, 105–118, doi:10.3762/bjnano.10.10

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  • tailoring the selectivity of CNTs towards target gases, one of the simplest consists of decorating the outer wall of CNTs with metal or metal oxide nanoparticles [6][7][8][9]. In some cases, metal or metal oxide nanoparticles show interesting catalytic properties for the decomposition of target molecules
  • improving their interaction with gas molecules. Sensitivity and selectivity can be tailored by selecting the type of metal oxide employed, the size of nanoparticles and the decoration density or loading [6][10][11]. Metal oxides have been extensively investigated for sensing a wide range of gases [12][13
  • adsorption of NO2 on iron oxide nanoparticles, as previously reported for semiconductor metal oxide chemoresistors [35]. A deeper analysis of the sensor behavior reflected in Figure 7 and Figure 11 shows that both pristine and decorated CNT films behave as a p-type semiconductor. When nitrogen dioxide reacts
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Published 09 Jan 2019

Zn/F-doped tin oxide nanoparticles synthesized by laser pyrolysis: structural and optical properties

  • Florian Dumitrache,
  • Iuliana P. Morjan,
  • Elena Dutu,
  • Ion Morjan,
  • Claudiu Teodor Fleaca,
  • Monica Scarisoreanu,
  • Alina Ilie,
  • Marius Dumitru,
  • Cristian Mihailescu,
  • Adriana Smarandache and
  • Gabriel Prodan

Beilstein J. Nanotechnol. 2019, 10, 9–21, doi:10.3762/bjnano.10.2

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  • from all ZTO powders) and this fact can be attributed to an insufficient diffusion between the oxygen from the annular flow and alkylmetals vapors from the central flow. Also, for the undoped sample, the ethylene sensitizer seems to be another major carbon source in the resulting metal-oxide-based
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Published 02 Jan 2019

Ternary nanocomposites of reduced graphene oxide, polyaniline and hexaniobate: hierarchical architecture and high polaron formation

  • Claudio H. B. Silva,
  • Maria Iliut,
  • Christopher Muryn,
  • Christian Berger,
  • Zachary Coldrick,
  • Vera R. L. Constantino,
  • Marcia L. A. Temperini and
  • Aravind Vijayaraghavan

Beilstein J. Nanotechnol. 2018, 9, 2936–2946, doi:10.3762/bjnano.9.272

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  • the preparation of nanocomposites that exhibit improved electrochemical, mechanical or thermal behaviour [8][26][27]. Hexaniobate (hexNb) is a semiconducting metal oxide composed of negatively charged layers of [NbO6] octahedral units and interlayer cations, such as potassium ions (precursor form
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Published 26 Nov 2018

Site-controlled formation of single Si nanocrystals in a buried SiO2 matrix using ion beam mixing

  • Xiaomo Xu,
  • Thomas Prüfer,
  • Daniel Wolf,
  • Hans-Jürgen Engelmann,
  • Lothar Bischoff,
  • René Hübner,
  • Karl-Heinz Heinig,
  • Wolfhard Möller,
  • Stefan Facsko,
  • Johannes von Borany and
  • Gregor Hlawacek

Beilstein J. Nanotechnol. 2018, 9, 2883–2892, doi:10.3762/bjnano.9.267

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  • particular, various groups have demonstrated the usage of a Si NC embedded in an SiO2 matrix as a Coulomb island for a single electron transistor (SET) device [7][8][9]. However, so far Si NC-based SET devices lack either the ability of room-temperature operation or the compatibility to complimentary metal
  • -oxide-semiconductor (CMOS) technology and thus have yet to be integrated into a cost-efficient Si-based technology. Multiple methods have been proposed and optimized for Si NC fabrication, including plasma-enhanced chemical vapor deposition (PECVD) [4][10], magnetron sputtering [11][12], laser-induced
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Published 16 Nov 2018

Graphene-enhanced metal oxide gas sensors at room temperature: a review

  • Dongjin Sun,
  • Yifan Luo,
  • Marc Debliquy and
  • Chao Zhang

Beilstein J. Nanotechnol. 2018, 9, 2832–2844, doi:10.3762/bjnano.9.264

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  • Dongjin Sun Yifan Luo Marc Debliquy Chao Zhang College of Mechanical Engineering, Yangzhou University, Yangzhou 225127, China Department of Materials Science, University of Mons, 7000 Mons, Belgium 10.3762/bjnano.9.264 Abstract Owing to the excellent sensitivity to gases, metal-oxide
  • , which reduces power consumption. However, the low sensitivity and long recovery time of the graphene-based sensors limit its further development. The combination of metal-oxide semiconductors and graphene may significantly improve the sensing performance, especially the selectivity and response/recovery
  • rate at room temperature. In this review, we have summarized the latest progress of graphene/metal-oxide gas sensors for the detection of NO2, NH3, CO and some volatile organic compounds (VOCs) at room temperature. Meanwhile, the sensing performance and sensing mechanism of the sensors are discussed
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Published 09 Nov 2018

Improved catalytic combustion of methane using CuO nanobelts with predominantly (001) surfaces

  • Qingquan Kong,
  • Yichun Yin,
  • Bing Xue,
  • Yonggang Jin,
  • Wei Feng,
  • Zhi-Gang Chen,
  • Shi Su and
  • Chenghua Sun

Beilstein J. Nanotechnol. 2018, 9, 2526–2532, doi:10.3762/bjnano.9.235

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  • exceptionally high performance for methane oxidation, achieving complete conversion even below 400 °C [6]. Different from Pd catalysts, CuO NBs, as a low-cost metal oxide material, do not have to be loaded on a support and do not use additional dispersion agents, and are thus a more effective catalyst per
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Published 24 Sep 2018

Nanocellulose: Recent advances and its prospects in environmental remediation

  • Katrina Pui Yee Shak,
  • Yean Ling Pang and
  • Shee Keat Mah

Beilstein J. Nanotechnol. 2018, 9, 2479–2498, doi:10.3762/bjnano.9.232

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  • ]. Although cellulose alone exhibits limited photocatalytic activity under UV or visible light irradiation, many semiconductor materials have been added to enhance the photocatalytic activity. Several research groups have demonstrated photocatalytic wastewater treatment using cellulose-based metal oxide
  • nanostructures in the form of thin film, membrane, fibre and hybrid materials under UV and visible light irradiation. Nanocellulose–metal oxide (TiO2, ZnO, graphene oxide, and Fe2O3) composites have been used as photocatalysts to improve the degradation rate of organic pollutants as compared to individual
  • materials. Table 2 summarizes the application of cellulose-based photocatalyst nanostructured materials for photocatalytic degradation of various organic pollutants. Cellulose derivatives can easily adsorb on metal oxide surface layers and provide additional –OH groups on the surface of metal alkoxides [116
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Published 19 Sep 2018

Thickness-dependent photoelectrochemical properties of a semitransparent Co3O4 photocathode

  • Malkeshkumar Patel and
  • Joondong Kim

Beilstein J. Nanotechnol. 2018, 9, 2432–2442, doi:10.3762/bjnano.9.228

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  • respect to the water redox potential [3][9][10]. The spinel Co3O4 is interesting because of its dual bandgap (1.5 and 2.2 eV), high absorption coefficient, intrinsic p-type doping and chemical stability. It has found application as a light-absorbing entity in all-metal-oxide photovoltaic cells [11][12][13
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Published 12 Sep 2018

Directional light beams by design from electrically driven elliptical slit antennas

  • Shuiyan Cao,
  • Eric Le Moal,
  • Quanbo Jiang,
  • Aurélien Drezet,
  • Serge Huant,
  • Jean-Paul Hugonin,
  • Gérald Dujardin and
  • Elizabeth Boer-Duchemin

Beilstein J. Nanotechnol. 2018, 9, 2361–2371, doi:10.3762/bjnano.9.221

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  • with a minor linear contribution (along the major axis) that increases with eccentricity. Future improvements of these optical antennas include the integration of the electrical SPP nanosource in the design of the microstructure (e.g., as an integrated metal-oxide–metal tunnel junction) and the
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Published 03 Sep 2018

Lead-free hybrid perovskites for photovoltaics

  • Oleksandr Stroyuk

Beilstein J. Nanotechnol. 2018, 9, 2209–2235, doi:10.3762/bjnano.9.207

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  • mesoporous metal oxide (TiO2) scaffold [67]. Later, it was recognized that Pb-based HPs are incomparably more efficient when applied as light harvesters in photovoltaic planar or bulk heterojunction solar cells. Such cells have two designs – a “conventional” n–i–p design with a HP layer deposited onto the
  • metal oxide electron transport layer (ETL) and then covered with an organic hole transport layer (HTL) and an “inverted” p–i–n design, where an HP layer is formed on an HTL support and covered with an organic ETL, such as fullerene derivatives (see below in Figure 2). The conventional n–i–p scheme
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Published 21 Aug 2018

Electrospun one-dimensional nanostructures: a new horizon for gas sensing materials

  • Muhammad Imran,
  • Nunzio Motta and
  • Mahnaz Shafiei

Beilstein J. Nanotechnol. 2018, 9, 2128–2170, doi:10.3762/bjnano.9.202

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  • materials used as an active sensing layer, including polymers, metal oxide semiconductors, graphene, and their composites or their functionalized forms. The material properties of these electrospun fibers and their sensing performance toward different analytes are explained in detail and correlated to the
  • review and summarize the fabrication of electrospun 1D nanostructures based on diverse range of materials (including polymers, metal oxide semiconductors, graphene, and their composites or their functionalized forms) and their gas sensing performance in all available sensing architectures (including
  • electrospun nanofibers as the sensing layer. These materials include: metal oxide (MOx) semiconductors (e.g., SnO2, TiO2, SiO2) [83][84], doped MOx semiconductors [4][5][6][7][8][9][10][11], composite materials made of MOx semiconducting materials (e.g., ZnO-In2O3) [86], conducting polymer-based gas sensors
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Published 13 Aug 2018

Phosphorus monolayer doping (MLD) of silicon on insulator (SOI) substrates

  • Noel Kennedy,
  • Ray Duffy,
  • Luke Eaton,
  • Dan O’Connell,
  • Scott Monaghan,
  • Shane Garvey,
  • James Connolly,
  • Chris Hatem,
  • Justin D. Holmes and
  • Brenda Long

Beilstein J. Nanotechnol. 2018, 9, 2106–2113, doi:10.3762/bjnano.9.199

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  • being deemed detrimental to current and future device production. Semiconductor substrates require doping to reduce their resistivity and enable their use in electronic devices such as metal-oxide semiconductor field-effect transistors (MOSFETs). Traditionally, ex situ doping was carried out using ion
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Published 06 Aug 2018

Localized photodeposition of catalysts using nanophotonic resonances in silicon photocathodes

  • Evgenia Kontoleta,
  • Sven H. C. Askes,
  • Lai-Hung Lai and
  • Erik C. Garnett

Beilstein J. Nanotechnol. 2018, 9, 2097–2105, doi:10.3762/bjnano.9.198

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  • ][31]. An exception is the work of Li et al. [27], where charge separation was achieved at different crystal facets of BiVO4 nanocrystals for selective photodeposition of metal and metal oxide catalytic nanoparticles. Nevertheless, this method for the moment is limited to this specific material and
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Published 03 Aug 2018
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