Transformation of hydrogen titanate nanoribbons to TiO₂ nanoribbons and the influence of the transformation strategies on the photocatalytic performance

• Melita Rutar,
• Nejc Rozman,
• Matej Pregelj,
• Carla Bittencourt,
• Romana Cerc Korošec,
• Andrijana Sever Škapin,
• Aleš Mrzel,
• Srečo D. Škapin and
• Polona Umek

Beilstein J. Nanotechnol. 2015, 6, 831–844, doi:10.3762/bjnano.6.86

• titanate 1D nanostructures such as nanotubes [9][12], nanowires [13], nanofibers or nanoribbons [12] (NR) morphologies can be obtained. Transformations from the layered titanate structure to TiO2-B and then to the anatase structure (H2Ti3O7 → TiO2-B → anatase) are considered to be topotactic reactions [14

Applications of three-dimensional carbon nanotube networks

• Manuela Scarselli,
• Paola Castrucci,
• Francesco De Nicola,
• Ilaria Cacciotti,
• Francesca Nanni,
• Emanuela Gatto,
• Mariano Venanzi and
• Maurizio De Crescenzi

Beilstein J. Nanotechnol. 2015, 6, 792–798, doi:10.3762/bjnano.6.82

• presence of both (i) carbon sp2 species (e.g., nanofibers), characterized by a rough surface, and (ii) the high porosity. In fact, it is known that irregular surfaces make adsorption of organics much easier than smooth ones [24]. The adsorbed oil can easily be removed after the sponge is saturated simply

Filling of carbon nanotubes and nanofibres

• Reece D. Gately and
• Marc in het Panhuis

Beilstein J. Nanotechnol. 2015, 6, 508–516, doi:10.3762/bjnano.6.53

• filling these carbon nanostructures. We highlight that filled carbon nanostructures are an emerging material for biomedical applications. Keywords: applications; carbon nanostructures; filling; nanofibers; nanotubes; Introduction Carbon nanotubes are well-known, 1D nanostructures, which are comprised of

Tunable white light emission by variation of composition and defects of electrospun Al₂O₃–SiO₂ nanofibers

• Jinyuan Zhou,
• Gengzhi Sun,
• Hao Zhao,
• Xiaojun Pan,
• Zhenxing Zhang,
• Yujun Fu,
• Yanzhe Mao and
• Erqing Xie

Beilstein J. Nanotechnol. 2015, 6, 313–320, doi:10.3762/bjnano.6.29

• Avenue, 639798, Singapore 10.3762/bjnano.6.29 Abstract Composite nanofibers consisting of Al2O3–SiO2 were prepared by electrospinning in combination with post-calcination in air. X-ray diffraction, scanning electron microscopy, and transmission electron microscopy were used to investigate the

• crystalline phase and microstructure of the composite nanofibers. Photoluminescence experiments indicated that the resulting white light emission can be tuned by the relative intensity of the individual spectral components, which are related to the individual defects such as: violet-blue emission from O

• materials. Keywords: Al2O3–SiO2; defects; electrospinning; nanofibers; photoluminescence; white light emission; Introduction During the last decade, nanoscale SiO2 has been intensely investigated as a new silicon-based light-emitting material. Its wide photoluminescence (PL) band ranges from the UV to red

Oxygen-plasma-modified biomimetic nanofibrous scaffolds for enhanced compatibility of cardiovascular implants

• Anna Maria Pappa,
• Varvara Karagkiozaki,
• Silke Krol,
• Spyros Kassavetis,
• Dimitris Konstantinou,
• Charalampos Pitsalidis,
• Lazaros Tzounis,
• Nikos Pliatsikas and
• Stergios Logothetidis

Beilstein J. Nanotechnol. 2015, 6, 254–262, doi:10.3762/bjnano.6.24

• of these biomimetic tissue-engineering constructs as efficient coatings for enhanced compatibility of cardiovascular implants. Keywords: cardiovascular implants; electrospun nanofibers; plasma treatment; scaffold; tissue engineering; Introduction Cardiovascular diseases represent one of the major

• hydrophobic character [19]. To date, several surface-engineering techniques have been applied in order to chemically modify surfaces of electrospun nanofibers [9][20][21][22], including treatments by flame, corona discharge, plasma, photons, electron beam, ion beam, X-rays, and gamma rays. Among them

• plasma-treated electrospun scaffolds are shown in Figure 1a–c. The images clearly indicate the effect of the plasma modification on the structural and surface integrity of the electrospun scaffolds. The unmodified fabricated nanofibers appeared interconnected and randomly stacked in a layer-by-layer

Functionalization of α-synuclein fibrils

• Simona Povilonienė,
• Vida Časaitė,
• Virginijus Bukauskas,
• Arūnas Šetkus,
• Juozas Staniulis and
• Rolandas Meškys

Beilstein J. Nanotechnol. 2015, 6, 124–133, doi:10.3762/bjnano.6.12

• ]. These natural building blocks with a wide range of modifiable properties have become very attractive tools for applications in biotechnology, material science, molecular electronics and related fields [6]. A variety of nanostructures, including nanotubes, nanospheres, nanofibers, nanotapes and hydrogels

Liquid-phase exfoliated graphene: functionalization, characterization, and applications

• Mildred Quintana,
• Jesús Iván Tapia and
• Maurizio Prato

Beilstein J. Nanotechnol. 2014, 5, 2328–2338, doi:10.3762/bjnano.5.242

• to pure DMF. In this process, carbon nanofibers (CNFs) are formed revealing the occurrence of chemical reactions. During the ultrasonication process, graphene sheets were cut close to the edges, producing small fragments which later aggregate into CNFs. To verify the mechanism of CNF formation, gold

• nanoparticles (Au NPs) were introduced as contrast markers. Tiopronin and its fragments are well-known stabilizers for Au NPs. The analysis by transmission electron microscopy (TEM) showed Au NPs mostly resided on the nanofibers, thus supporting the proposed mechanism as shown in Figure 2. This methodology

• graphene layers and carbon nanofibers. (b) Carbon nanofibers marked with Au Nanorods. (c) Representative TEM micrograph of a graphene sheet. (d) HR-TEM image of graphene. Reprinted with permission from [9], copyright 2012 The Royal Society of Chemistry. Ultrasound-assisted synthesis of MWNTs from graphite

Growth and structural discrimination of cortical neurons on randomly oriented and vertically aligned dense carbon nanotube networks

• Christoph Nick,
• Sandeep Yadav,
• Ravi Joshi,
• Christiane Thielemann and
• Jörg J. Schneider

Beilstein J. Nanotechnol. 2014, 5, 1575–1579, doi:10.3762/bjnano.5.169

• growth. The use of vertically aligned CNTs for the design of 3D electrodes was proposed [22]. The interface between dense vertically aligned carbon nanofibers and neurons derived from the rat pheochromocytoma (PC12 cell line) was also studied [10]. However, although vertically grown CNTs have been

Organic and inorganic–organic thin film structures by molecular layer deposition: A review

• Pia Sundberg and
• Maarit Karppinen

Beilstein J. Nanotechnol. 2014, 5, 1104–1136, doi:10.3762/bjnano.5.123

Nanostructure sensitization of transition metal oxides for visible-light photocatalysis

• Hongjun Chen and
• Lianzhou Wang

Beilstein J. Nanotechnol. 2014, 5, 696–710, doi:10.3762/bjnano.5.82

• ][44], CdTe quantum dot monolayer sensitized ZnO nanowire [45], CdS nanoparticle/ZnO nanowire array [46][47], CdS/ TiO2 nanofibers heteroarchitectures [48], ZnO/CdS core/shell nanowire [49], CdS nanowires decorated with TiO2 nanoparticles [50], and their potential applications for photoelectrochemical

DNA origami deposition on native and passivated molybdenum disulfide substrates

• Xiaoning Zhang,
• Masudur Rahman,
• David Neff and
• Michael L. Norton

Beilstein J. Nanotechnol. 2014, 5, 501–506, doi:10.3762/bjnano.5.58

• energy harvesting applications [17]. Compared to conventional semiconductor materials such as silicon, MoS2 is readily processed as a prototypical nanomaterial. MoS2 nanosheets, nanofibers, and nanorods have been prepared [15], which means the material could readily be used to construct electronic

A catechol biosensor based on electrospun carbon nanofibers

• Dawei Li,
• Zengyuan Pang,
• Xiaodong Chen,
• Lei Luo,
• Yibing Cai and
• Qufu Wei

Beilstein J. Nanotechnol. 2014, 5, 346–354, doi:10.3762/bjnano.5.39

• Dawei Li Zengyuan Pang Xiaodong Chen Lei Luo Yibing Cai Qufu Wei Key Laboratory of Eco-Textiles of Ministry of Education, Jiangnan University, Wuxi 214122, P. R. China 10.3762/bjnano.5.39 Abstract Carbon nanofibers (CNFs) were prepared by combining electrospinning with a high-temperature

• water samples. Keywords: biosensor; carbon nanofibers; catechol; electrospinning; laccase; Introduction Nowadays, carbon nanomaterials attract a great deal of attention due to their high surface area, excellent electronic conduction and biocompatibility. Among these, mesoporous carbon [1][2][3][4][5

• ][6][7][8], activated or porous carbon nanofibers [9][10][11][12][13][14][15][16][17][18][19] have been widely studied. Notably, the carbon nanofibers (CNFs) possess a history of more than a century, the carbon filaments discovered in 1889 may be the earliest CNFs [20]. After more than a century of

Design criteria for stable Pt/C fuel cell catalysts

• Josef C. Meier,
• Carolina Galeano,
• Ioannis Katsounaros,
• Jonathon Witte,
• Hans J. Bongard,
• Angel A. Topalov,
• Claudio Baldizzone,
• Stefano Mezzavilla,
• Ferdi Schüth and
• Karl J. J. Mayrhofer

Beilstein J. Nanotechnol. 2014, 5, 44–67, doi:10.3762/bjnano.5.5

• [23]. Due to the large versatility of carbon structures, many research groups have focused on a variety of alternative carbon materials [24] as supports for fuel cell applications such as single walled and multi-walled carbon nanotubes (SWCNTs, MWCNTs) [25][26], graphene [27], carbon nanofibers [28

Controlled synthesis and tunable properties of ultrathin silica nanotubes through spontaneous polycondensation on polyamine fibrils

• Jian-Jun Yuan,
• Pei-Xin Zhu,
• Daisuke Noda and
• Ren-Hua Jin

Beilstein J. Nanotechnol. 2013, 4, 793–804, doi:10.3762/bjnano.4.90

• . Further studies indicated that this method of cooling a hot solution normally produced a mixture of nanoribbons and nanofibers with diameters ranging from 30 to 150 nm [36]. A removal of the LPEI core from the nanofibers led to the formation of hollow silica but without control over the final structures

• performed by using a molar ratio [OH]/[EI] = 3.2. As shown in Figure 7E and Figure 7F, large aggregates composed of a mixture of small silica nanoribbons and nanofibers were formed. The BET study did not show any obvious proof for a uniform formation of nanotube structures (run 11 in Table 1, Figure S4 in

• because of the hybrid nature of the framework. The carbonization of the sample after the adsorption of one layer of PSS (polymer content: 47.9 wt %) produced silica/carbon composites with a much higher of carbon content (7.9 wt %, “b” in Figure 9A). The network structure of nanofibers of this silica

Electrospinning preparation and electrical and biological properties of ferrocene/poly(vinylpyrrolidone) composite nanofibers

• Ji-Hong Chai and
• Qing-Sheng Wu

Beilstein J. Nanotechnol. 2013, 4, 189–197, doi:10.3762/bjnano.4.19

• 200433, PR China 10.3762/bjnano.4.19 Abstract Nanofibers containing ferrocene (Fc) have been prepared for the first time by electrospinning. In this paper, Fc was dispersed uniformly throughout the poly(vinypyrrolidone) (PVP) matrix for the purpose of combining the properties of PVP and Fc. The effects

• of solvents and Fc concentration on the morphologies and diameters of nanofibers were investigated. In the DMF/ethanol solvent, the morphologies of the obtained nanofibers significantly changed with the increase of Fc concentration. The results demonstrated that the morphologies of the nanofibers

• PVP nanofibers. X-ray diffraction (XRD) results showed that the crystalline structure of Fc in the fibers was amorphous after the electrospinning process. A biological evaluation of the antimicrobial activity of Fc/PVP nanofibers was carried out by using Gram-negative Escherichia coli (E. coli) as

Functionalization of vertically aligned carbon nanotubes

• Eloise Van Hooijdonk,
• Carla Bittencourt,
• Rony Snyders and
• Jean-François Colomer

Beilstein J. Nanotechnol. 2013, 4, 129–152, doi:10.3762/bjnano.4.14

• -emission performance. However, it was demonstrated that a fluorine-based functionalization of carbon nanomaterials such as diamond films [83] or amorphous carbon nanoparticle films [84] increases the yield of the phenomenon. The fluorination of carbon nanofibers [85] and SWCNTs [86] was also underlined

• membrane. Feng et al. [140] opted for a polyaniline (PANI) matrix. This material is one of the most conducting polymers (Figure 18). Synthesis and characterization of conducting polymer polyaniline nanofibers was reported by Huang [141]. The major issue related to great disorder of the functionalized

Surface functionalization of aluminosilicate nanotubes with organic molecules

• Wei Ma,
• Weng On Yah,
• Hideyuki Otsuka and
• Atsushi Takahara

Beilstein J. Nanotechnol. 2012, 3, 82–100, doi:10.3762/bjnano.3.10

• proposed as the inorganic nanotube to be hybridized with P3HT nanofibers. Reinforcement of P3HT nanofibers by imogolite is expected to impart additional mechanical and thermal stability to organic compounds, making the resulted hybrid material more durable under the outer environmental conditions

• -defined low-dimensional structures. In order to improve compatibility with the P3HT nanofibers, hydrophilic Al–OH groups on the imogolite surface were modified with alkyl phosphonic acid substituted terthiophene (HT3P), as shown in Figure 21. The molecular aggregation states and molecular orientation of

• powerful tool for the direct observation of the aggregation of polymeric nanofibers. By spin coating a dilute solution in anisole, a network of nanofibers more or less entirely covers the silicon substrate. The dimensions of the nanofiber were determined from DFM images; as shown in Figure 23a, P3HT

Synthesis and catalytic applications of combined zeolitic/mesoporous materials

• Jarian Vernimmen,
• Vera Meynen and
• Pegie Cool

Beilstein J. Nanotechnol. 2011, 2, 785–801, doi:10.3762/bjnano.2.87

• carbons (CMKs) [102][103], carbon nanotubes [104], and carbon nanofibers [105]. The choice of template is crucial for the final material, since the mesoporous zeolites essentially become replicas of the carbon pore system in which they grow. For example, with carbon black, the resulting pores will be

Approaches to nanostructure control and functionalizations of polymer@silica hybrid nanograss generated by biomimetic silica mineralization on a self-assembled polyamine layer

• Jian-Jun Yuan and
• Ren-Hua Jin

Beilstein J. Nanotechnol. 2011, 2, 760–773, doi:10.3762/bjnano.2.84

• [8][9][10][11]. On the other hand, silica films consisted of a network of interwoven nanofibers were also reported as produced by flame spray pyrolysis of organometallic solutions with the deposition and annealing temperature of silica in the range from 500 to 800 °C [12]. However, these conventional

Self-organizing bioinspired oligothiophene–oligopeptide hybrids

• Alexey K. Shaytan,
• Eva-Kathrin Schillinger,
• Elena Mena-Osteritz,
• Sylvia Schmid,
• Pavel G. Khalatur,
• Peter Bäuerle and
• Alexei R. Khokhlov

Beilstein J. Nanotechnol. 2011, 2, 525–544, doi:10.3762/bjnano.2.57

• theoretical considerations of the experimentally observed nanofibers, the molecular structure of the molecule was constructed. Our theoretical research methodology consists of four main steps schematically depicted in Figure 11. First, the available experimental data, including available X-ray structural data

• the A–B system 6 in the native state of the peptide. In principle both parts of this hybrid molecule (thiophene part and peptide part) may be capable of strong intermolecular interactions, thus leading to the formation of highly anisotropic structures such as nanofibers, nanorods, etc. However, the IR

• spectroscopic data for the compound under study revealed that the β-sheet structure formation was at least involved in the self-assembly mechanism of our nanofibers. While the formation of fibers at the nanometer scale (especially amyloid-like fibers) from separate peptide moieties due to β-sheet aggregation is