Improving control of carbide-derived carbon microstructure by immobilization of a transition-metal catalyst within the shell of carbide/carbon core–shell structures

• Teguh Ariyanto,
• Jan Glaesel,
• Andreas Kern,
• Gui-Rong Zhang and
• Bastian J. M. Etzold

Beilstein J. Nanotechnol. 2019, 10, 419–427, doi:10.3762/bjnano.10.41

• synthesis remains a challenge. In this work, the controllability of the synthesis route is enhanced by immobilizing the transition-metal graphitization catalyst on a porous carbon shell covering the carbide precursor prior to conversion of the carbide core to carbon. The catalyst loading was varied and the

• graphitization; graphitic carbon; pore structure; transition metal; Introduction Carbon is a versatile material that has been widely utilized in many applications such as adsorption [1][2][3], catalysis [4][5], catalyst support [6][7][8], molecular sieves [9][10] and energy storage [11][12][13], owing to its

• graphitic content is present, but the overall material is rather inhomogeneous [18][23]. Most likely the physical powder mixture or the simple dip coating of the powder carbide precursor with the transition-metal catalyst lead to a very inhomogeneous starting mixture, which is responsible for the final

A Ni(OH)₂ nanopetals network for high-performance supercapacitors synthesized by immersing Ni nanofoam in water

• Donghui Zheng,
• Man Li,
• Yongyan Li,
• Chunling Qin,
• Yichao Wang and
• Zhifeng Wang

Beilstein J. Nanotechnol. 2019, 10, 281–293, doi:10.3762/bjnano.10.27

• between active materials and electrolyte, for which transition metal oxides/hydroxides with multiple valence are used as electrode materials [8][9]. EDLCs hold a high power density and long cycling stability, but their practical application is limited by the low energy density. In comparison, pseudo

• -capacitors possess a higher energy density and are regarded as promising candidates for energy storage systems [10]. Among the various transition metal oxides/hydroxides, Ni(OH)2 is an ideal candidate for pseudo-capacitors due to its unique features such as high theoretical capacity and outstanding redox

Amorphous Ni_xCo_yP-supported TiO₂ nanotube arrays as an efficient hydrogen evolution reaction electrocatalyst in acidic solution

• Yong Li,
• Peng Yang,
• Bin Wang and
• Zhongqing Liu

Beilstein J. Nanotechnol. 2019, 10, 62–70, doi:10.3762/bjnano.10.6

• hurdle, but their exorbitant cost and scarcity seriously limit their large-scale application. Hence, it is quite appealing to develop inexpensive and earth-abundance electrocatalysts with higher electrolytic efficiency and lower dynamic overpotential [7][8]. More recently, transition-metal phosphides

Nanostructure-induced performance degradation of WO₃·nH₂O for energy conversion and storage devices

• Zhenyin Hai,
• Mohammad Karbalaei Akbari,
• Zihan Wei,
• Danfeng Cui,
• Chenyang Xue,
• Hongyan Xu,
• Philippe M. Heynderickx,
• Francis Verpoort and
• Serge Zhuiykov

Beilstein J. Nanotechnol. 2018, 9, 2845–2854, doi:10.3762/bjnano.9.265

• layered transition metal oxides. Keywords: 2D layered oxides; interlayer water; van der Waals interaction; WO3·nH2O; Introduction Within the less than 20 years since the successful exfoliation of atomically thin graphene, 2D layered nanomaterials have been contributing greatly to the advances of

• nanoscience and nanotechnology with their exotic properties and versatility of applications [1][2][3][4][5][6][7][8][9][10]. Among all 2D nanomaterials, 2D transition metal oxides (TMOs) are the group with the highest electrochemical activities for energy conversion and storage [11][12][13][14][15]. As the

Graphene-enhanced metal oxide gas sensors at room temperature: a review

• Dongjin Sun,
• Yifan Luo,
• Marc Debliquy and
• Chao Zhang

Beilstein J. Nanotechnol. 2018, 9, 2832–2844, doi:10.3762/bjnano.9.264

• metal oxides, is proposed. In detail, the enhanced sensing performance is accounted for by chemical bonds between graphene and metal oxides. Many XPS studies have claimed that there indeed exist chemical bonds between metal oxides and graphene. WO3, a transition-metal oxide semiconductor is widely used

Oriented zinc oxide nanorods: A novel saturable absorber for lasers in the near-infrared

• Pavel Loiko,
• Tanujjal Bora,
• Josep Maria Serres,
• Haohai Yu,
• Magdalena Aguiló,
• Francesc Díaz,
• Uwe Griebner,
• Valentin Petrov,
• Xavier Mateos and
• Joydeep Dutta

Beilstein J. Nanotechnol. 2018, 9, 2730–2740, doi:10.3762/bjnano.9.255

• + and O2− ions stacked along the [001]-axis. Thus, there are many options to accommodate intrinsic defects (e.g., interstitial Zn2+ ions, Zni, or O2− vacancies, VO, which are the most widespread ones), as well as external dopants (e.g., divalent transition-metal ions M2+ entering into the Td sites

• ” saturable absorbers (SAs) for lasers operating in the passively Q-switched (PQS) and mode-locked regimes. These include carbon nanostructures (e.g., graphene, graphene oxide, graphite nanoparticles, single-walled carbon nanotubes (SWCNTs)) [12][13][14][15], few-layer transition metal dichalcogenides (TMDs

• accommodate such transition-metal ions as Mn2+ or Co2+ in the Td sites. This coordination is attractive for high ground-state transition cross-sections, so that the absorption saturation in the visible and near-IR can be observed. Moreover, the dopant ions can promote the absorption saturation due to the

Two-dimensional semiconductors pave the way towards dopant-based quantum computing

• José Carlos Abadillo-Uriel,
• Belita Koiller and
• María José Calderón

Beilstein J. Nanotechnol. 2018, 9, 2668–2673, doi:10.3762/bjnano.9.249

• would give rise to an expected dispersion of the binding energy of dopants depending on external factors. Accordingly, it has been shown, using first principles calculations in transition-metal dichalcogenides, that dopants can be tuned from deep to shallow by using different substrates [34]. This

• binding energies of 51 transition-metal dichalcogenides. We follow the same approach here, taking a constant ε to estimate the binding energies. We adopt isotropic envelopes, simplifying the calculations while keeping the physical picture [37]. In this approximation, the 2D bound state of hydrogen is

Polarization-dependent strong coupling between silver nanorods and photochromic molecules

• Gwénaëlle Lamri,
• Alessandro Veltri,
• Jean Aubard,
• Pierre-Michel Adam,
• Nordin Felidj and
• Anne-Laure Baudrion

Beilstein J. Nanotechnol. 2018, 9, 2657–2664, doi:10.3762/bjnano.9.247

• approaches have been explored to actively control these plasmonic properties without changing the topographic features of the nanoparticles themselves. Liquid crystals [5], thermosensitive polymers [6], transition metal dichalcogenides [7] and graphene [8] monolayers have been used for this purpose. The

Improved catalytic combustion of methane using CuO nanobelts with predominantly (001) surfaces

• Qingquan Kong,
• Yichun Yin,
• Bing Xue,
• Yonggang Jin,
• Wei Feng,
• Zhi-Gang Chen,
• Shi Su and
• Chenghua Sun

Beilstein J. Nanotechnol. 2018, 9, 2526–2532, doi:10.3762/bjnano.9.235

• , such as transition metal (TM) oxides and various complex structures (e.g., perovskite, spinel and hexaaluminate) have been tested as catalysts for CH4 oxidation. But so far their performance is still much lower than noble metals. An ideal catalyst for CH4 oxidation should have a high capacity to adsorb

Thickness-dependent photoelectrochemical properties of a semitransparent Co₃O₄ photocathode

• Malkeshkumar Patel and
• Joondong Kim

Beilstein J. Nanotechnol. 2018, 9, 2432–2442, doi:10.3762/bjnano.9.228

• ][43], and the third is the combination with a catalyst such as NiMo and transition-metal dichalcogenide 2D materials [43][44]. Conclusion We fabricated porous, semitransparent Co3O4 working electrodes of varying thickness using Kirkendall diffusion thermal oxidation in air. The thickness-dependent

Light–Matter interactions on the nanoscale

• Mohsen Rahmani and
• Chennupati Jagadish

Beilstein J. Nanotechnol. 2018, 9, 2125–2127, doi:10.3762/bjnano.9.201

• , such as transition-metal dichalcogenides (TMDCs) or hexagonal boron nitride (hBN) [10] have also emerged as interesting platforms for nanophotonics. TMDCs, with their intrinsically broken inversion symmetry in crystal structure, have shown many advanced optical properties with potential applications

Synthesis of rare-earth metal and rare-earth metal-fluoride nanoparticles in ionic liquids and propylene carbonate

• Marvin Siebels,
• Lukas Mai,
• Laura Schmolke,
• Kai Schütte,
• Juri Barthel,
• Junpei Yue,
• Jörg Thomas,
• Bernd M. Smarsly,
• Anjana Devi,
• Roland A. Fischer and
• Christoph Janiak

Beilstein J. Nanotechnol. 2018, 9, 1881–1894, doi:10.3762/bjnano.9.180

• also abstract fluoride from [BF4]− anions. ILs are not only solvents but can also be reactants, e.g., [BMIm][PF6] in the synthesis of A2SiF6 nanoparticles (A = Li, Na, K, Rb, Cs) [46], in the synthesis of MFx nanoparticles (M = Mn, Fe, Co, Pr, Eu) from the decomposition of transition-metal amidinates

Improving the catalytic activity for hydrogen evolution of monolayered SnSe_2(1−x)S_2x by mechanical strain

• Sha Dong and
• Zhiguo Wang

Beilstein J. Nanotechnol. 2018, 9, 1820–1827, doi:10.3762/bjnano.9.173

• hydrogen. Two-dimensional (2D) atomic layer thin materials, such as monolayer transition-metal dichalcogenides (TMDs) [11][12][13][14][15][16][17][18][19], have demonstrated many fascinating properties, including the substitution of Pt as an electrocatalyst for HER. 2D MoS2 has been widely studied

• tuned by strain engineering. Results and Discussion 2D monolayer TMD is a three-atomic thickness structure with one transition-metal atom layer sandwiched by two chalcogen atom layers. A triangular prism or octahedron can be formed as the transition-metal atom is bonded with six chalcogen atoms, and the

Uniform cobalt nanoparticles embedded in hexagonal mesoporous nanoplates as a magnetically separable, recyclable adsorbent

• Can Zhao,
• Yuexiao Song,
• Tianyu Xiang,
• Wenxiu Qu,
• Shuo Lou,
• Xiaohong Yin and
• Feng Xin

Beilstein J. Nanotechnol. 2018, 9, 1770–1781, doi:10.3762/bjnano.9.168

• number of researches have demonstrated that carbon-based nanocomposites can serve as effective adsorbents for wastewater purification [6][7][8][9]. The introduction of transition metal nanoparticles into a mesoporous carbon matrix to form transition-metal-loaded mesoporous carbon nanocomposites (TM-MCNs

Free-radical gases on two-dimensional transition-metal disulfides (XS₂, X = Mo/W): robust half-metallicity for efficient nitrogen oxide sensors

• Chunmei Zhang,
• Yalong Jiao,
• Fengxian Ma,
• Sri Kasi Matta,
• Steven Bottle and
• Aijun Du

Beilstein J. Nanotechnol. 2018, 9, 1641–1646, doi:10.3762/bjnano.9.156

• observed after the adsorption of other free radical gases such as NO2. The unique change in electronic properties after the adsorption of NO on transition-metal sulfides highlights an effective strategy to distinguish NO from other gas species by experimentally measuring spin-resolved transmission. Our

Cr(VI) remediation from aqueous environment through modified-TiO₂-mediated photocatalytic reduction

• Rashmi Acharya,
• Brundabana Naik and
• Kulamani Parida

Beilstein J. Nanotechnol. 2018, 9, 1448–1470, doi:10.3762/bjnano.9.137

• . This also enhances the light absorption range towards longer wavelengths. The band edge potentials and band gaps of different semiconductor oxides and sulfides are given in Figure 2. Photocatalytic reduction of Cr(VI) over TiO2 modified with simple transition metal oxides under UV irradiation

• Transition metal oxides such as ZnO have been combined with TiO2 to form composite photocatalysts, which are used efficiently for photocatalytic reduction of Cr(VI). ZnO has been recognized as a potential photocatalyst for extensive environmental applications because of its availability and low cost. It also

• the nonsupported bulk TiO2 as well as calcined Fe3O4. In fact, 30% TiO2/Fe3O4 has shown the highest Cr(VI) photoreduction rate due to formation of effective heterojunction by the loading of 30% TiO2 over Fe3O4 [158]. Visible-light responsive, transition metal oxide modified TiO2 for photocatalytic

Electrodeposition of reduced graphene oxide with chitosan based on the coordination deposition method

• Mingyang Liu,
• Yanjun Chen,
• Chaoran Qin,
• Zheng Zhang,
• Shuai Ma,
• Xiuru Cai,
• Xueqian Li and
• Yifeng Wang

Beilstein J. Nanotechnol. 2018, 9, 1200–1210, doi:10.3762/bjnano.9.111

• plate. Chitosan possesses the capability to coordinate to transition metal ions (e.g., Cu2+ and Ag+ ions). This coordination capability is related to the existence of amino groups in chitosan. Consequently, chitosan molecules close to the copper plate are able to coordinate to these Cu2+ ions to form a

Review on nanoparticles and nanostructured materials: history, sources, toxicity and regulations

• Jaison Jeevanandam,
• Ahmed Barhoum,
• Yen S. Chan,
• Alain Dufresne and
• Michael K. Danquah

Beilstein J. Nanotechnol. 2018, 9, 1050–1074, doi:10.3762/bjnano.9.98

Valley-selective directional emission from a transition-metal dichalcogenide monolayer mediated by a plasmonic nanoantenna

• Haitao Chen,
• Mingkai Liu,
• Lei Xu and
• Dragomir N. Neshev

Beilstein J. Nanotechnol. 2018, 9, 780–788, doi:10.3762/bjnano.9.71

• 10.3762/bjnano.9.71 Abstract Background: Two-dimensional (2D) transition-metal dichalcogenides (TMDCs) with intrinsically crystal inversion-symmetry breaking have shown many advanced optical properties. In particular, the valley polarization in 2D TMDCs that can be addressed optically has inspired new

• structure. Conclusion: The scheme we propose here can potentially serve as an important component for valley-based applications, such as non-volatile information storage and processing. Keywords: 2D materials, multipolar emission; nanoantenna; plasmonic; transition-metal dichalcogenides; valley

Surface-plasmon-enhanced ultraviolet emission of Au-decorated ZnO structures for gas sensing and photocatalytic devices

• T. Anh Thu Do,
• Truong Giang Ho,
• Thu Hoai Bui,
• Quang Ngan Pham,
• Hong Thai Giang,
• Thi Thu Do,
• Duc Van Nguyen and
• Dai Lam Tran

Beilstein J. Nanotechnol. 2018, 9, 771–779, doi:10.3762/bjnano.9.70

• . Keywords: Au-decorated ZnO; carrier dynamics; gas sensors; photocatalyst; SPR effect; Introduction Inorganic transition metal oxide sensor devices have attracted attention in particular for improving gas sensing, energy conversion, electronics, photocatalysis and optoelectronic devices [1][2][3][4]. Among

Dynamics and fragmentation mechanism of (C₅H₄CH₃)Pt(CH₃)₃ on SiO₂ surfaces

• Kaliappan Muthukumar,
• Harald O. Jeschke and
• Roser Valentí

Beilstein J. Nanotechnol. 2018, 9, 711–720, doi:10.3762/bjnano.9.66

• ); focused electron beam induced deposition (FEBID); precursor; trimethyl(methylcyclopentadienyl)platinum(IV) ((CH3-C5H4)Pt(CH3)3); Introduction Nanoscale device applications require a growth of regular or specially patterned transition metal nanodeposits. Electron beam induced deposition (EBID), is a size

Sensing behavior of flower-shaped MoS₂ nanoflakes: case study with methanol and xylene

• Maryam Barzegar,
• Masoud Berahman and
• Azam Iraji zad

Beilstein J. Nanotechnol. 2018, 9, 608–615, doi:10.3762/bjnano.9.57

• emerging new group of materials known as transition metal dichalcogenides (TMDs), which have significant electrical, optical, and transport properties. MoS2 is one of the well-known 2D materials in this group, which is a semiconductor with controllable band gap based on its structure. The hydrothermal

• functional theory; gas sensor; hydrothermal method; methanol; MoS2 nanoflakes; xylene vapor; Introduction Recent efforts in exploring two-dimensional (2D) materials have led to the introduction of a new family of materials known as transition metal dichalcogenides (TMDs), which show remarkable electrical

• , optical and transport properties [1][2][3][4][5][6][7][8][9][10][11][12][13]. TMDs are a group of materials with the general formula MX2, where M is a transition metal element of group IV, V or VI, and X is a chalcogen (S, Se, or Te) [1][2][3][4][5][6][7][8][9][10][11][12][13]. Their properties, including

Facile synthesis of ZnFe₂O₄ photocatalysts for decolourization of organic dyes under solar irradiation

• Arjun Behera,
• Debasmita Kandi,
• Sanjit Manohar Majhi,
• Satyabadi Martha and
• Kulamani Parida

Beilstein J. Nanotechnol. 2018, 9, 436–446, doi:10.3762/bjnano.9.42

• ]. It is important to develop a suitable environmentally friendly material that can absorb the full range of the solar spectrum for solving energy and environmental challenges. Since last decade, ternary transition metal oxides (TTMOs) have gained tremendous popularity in the field of photocatalysis by

• the scientific community. To exploit solar light more efficiently, photocatalysts with narrow band gap (e.g., ZnSnO3 [2], Bi2WO6 [3], Ce(MoO4)2 [4] and ZnFe2O4 [5]) have been used, for absorbance of solar light in the visible region. Among ternary metal oxides, transition metal ferrites have drawn a

Review: Electrostatically actuated nanobeam-based nanoelectromechanical switches – materials solutions and operational conditions

• Liga Jasulaneca,
• Jelena Kosmaca,
• Raimonds Meija,
• Jana Andzane and
• Donats Erts

Beilstein J. Nanotechnol. 2018, 9, 271–300, doi:10.3762/bjnano.9.29

• nanowires’ surface [10][13]. Molybdenum–sulfur–iodine: Excellent functional properties of nanowires based on transition metal chalcogenide-halides, combined with easy synthesis and intrinsic absence of impurities make them attractive NEM switch elements. The properties of these materials include high

Synthesis and characterization of electrospun molybdenum dioxide–carbon nanofibers as sulfur matrix additives for rechargeable lithium–sulfur battery applications

• Ruiyuan Zhuang,
• Shanshan Yao,
• Maoxiang Jing,
• Xiangqian Shen,
• Jun Xiang,
• Tianbao Li,
• Kesong Xiao and
• Shibiao Qin

Beilstein J. Nanotechnol. 2018, 9, 262–270, doi:10.3762/bjnano.9.28

• . Molybdenum dioxide (MoO2) materials are particularly attractive among the transition-metal oxides due to their high melting point, high chemical stability and low electrical resistivity (190 S cm−1). This material has great potential for applications in several fields such as sensing, catalysis