Atomistic insights into the morphological dynamics of gold and platinum nanoparticles: MD simulations in vacuum and aqueous media

• Evangelos Voyiatzis,
• Eugenia Valsami-Jones and
• Antreas Afantitis

Beilstein J. Nanotechnol. 2024, 15, 995–1009, doi:10.3762/bjnano.15.81

• information regarding the NP morphology is obtained from simulated X-ray powder diffraction patterns as determined by Debye functional analysis [80]. The intensity of the diffracted coherent radiation, I, is given by where β = 2sin(θ)/λ, λ is the wavelength of the incident radiation, and 2θ is the scattering

• lower density than FCC, becomes less energetically prohibitive. When focusing on the morphology of the NPs, the coexistence of several small crystal domains interconnected via amorphous grain boundaries is favoured at higher temperatures, while the crystallization process at lower temperatures leads to

Electrospun nanofibers: building blocks for the repair of bone tissue

• Tuğrul Mert Serim,
• Gülin Amasya,
• Tuğba Eren-Böncü,
• Ceyda Tuba Şengel-Türk and
• Ayşe Nurten Özdemir

Beilstein J. Nanotechnol. 2024, 15, 941–953, doi:10.3762/bjnano.15.77

• production. With a coaxial needle design, two different solutions can be electrospun simultaneously, and core–shell or hollow fibers can be formed [47]. The main parameters affecting fiber morphology are described in the following. Process parameters Flow rate, voltage, distance, collector type

• solvent, it affects the fiber formation and the diameter/morphology of the obtained fibers. Therefore, the distance for electrospinning needs to be optimized [59]. Electrospraying can be observed when the distance is too short or too long. Also, if the distance is too short, the solvent of the polymer

• . Controlling the temperature influences the electrospinning process and is important for reproducibility [81][82]. The morphology of the fibers is affected by temperature. With the increase in temperature, smaller fiber diameters and smoother fibers are observed [81][83]; also, viscosity decreases with

Effects of cutting tool geometry on material removal of a gradient nanograined CoCrNi medium entropy alloy

• Yu-Sheng Lu,
• Yu-Xuan Hung,
• Thi-Xuyen Bui and
• Te-Hua Fang

Beilstein J. Nanotechnol. 2024, 15, 925–940, doi:10.3762/bjnano.15.76

• radius was fixed at 1 nm to analyze the surface morphology, atomic-scale wear, shear strain distribution, temperature distribution, and crystal structure evolution during cutting. Figure 2a–f shows the atoms that pile-up on the surface of the CoCrNi MEA substrates. The number of wear atoms during cutting

• chip thickness has the lowest average resultant force, consistent with the results of the surface morphology analysis in Figure 2. The subsurface quality of the workpiece significantly affects accuracy and durability in the machining process. To investigate the deformation mechanism of the subsurface

Facile synthesis of Fe-based metal–organic frameworks from Fe₂O₃ nanoparticles and their application for CO₂/N₂ separation

• Van Nhieu Le,
• Hoai Duc Tran,
• Minh Tien Nguyen,
• Hai Bang Truong,
• Toan Minh Pham and
• Jinsoo Kim

Beilstein J. Nanotechnol. 2024, 15, 897–908, doi:10.3762/bjnano.15.74

• the obtained MIL-100(Fe) depending on the H3BTC concentration. To further reinforce this statement, the morphology of all materials was examined via SEM analysis. Figure 3 reveals that Fe2O3 nanoparticles appeared in spherical shapes, while MIL-100(Fe) crystals displayed an octahedral morphology with

• sizes around 1 μm. The SEM images of M-100Fe@Fe2O3 samples showed polyhedral nanoparticles, indicating the successful preparation of MIL-100(Fe) crystals. It is important to note that the morphology of the obtained MIL-100(Fe) crystals depends on both the source of Fe-based precursor and the synthetic

Water-assisted purification during electron beam-induced deposition of platinum and gold

• Cristiano Glessi,
• Fabian A. Polman and
• Cornelis W. Hagen

Beilstein J. Nanotechnol. 2024, 15, 884–896, doi:10.3762/bjnano.15.73

• both deposition and etching, resulting in partially purified material within the BSE range. In this case, with the injection of the water precursor only, cleaning of the silicon substrate is the only process observed. At a larger number of passes (5000–10000), a change in the morphology of the

• substantiated by the BSE images of 2a, 2c, 2d, and 2f (Supporting Information File 1, p S32). The images of the purified structures in Figure 8, sample 2a at 5000 and 10000 passes, as well as those of the samples 1d and 1e in Figure 5, show a granular morphology. To investigate the degree of granularity and to

The effect of age on the attachment ability of stick insects (Phasmatodea)

• Marie Grote,
• Stanislav N. Gorb and
• Thies H. Büscher

Beilstein J. Nanotechnol. 2024, 15, 867–883, doi:10.3762/bjnano.15.72

• Marie Grote Stanislav N. Gorb Thies H. Buscher Functional Morphology and Biomechanics, Kiel University, Am Botanischen Garten 1-9, D-24118 Kiel, Germany 10.3762/bjnano.15.72 Abstract Many insect species have found their way into ageing research as small and easy-to-keep model organisms. A major

• extending over a larger time frame. Ageing effects on the morphology of the attachment pads and the autofluorescence of the cuticle were documented using light, scanning electron, and confocal laser scanning microscopy. The results show that both adhesion and friction forces decline with age. Deflation of

• area with the substrate. Keywords: adhesion; attachment pads; friction; locomotion; morphology; material properties; wear; Introduction Ageing inexorably affects most living organisms, does not exclude insects, and makes different organs or tissues susceptible to wear or fatigue of material [1

Investigation on drag reduction on rotating blade surfaces with microtextures

• Qinsong Zhu,
• Chen Zhang,
• Fuhang Yu and
• Yan Xu

Beilstein J. Nanotechnol. 2024, 15, 833–853, doi:10.3762/bjnano.15.70

• and no obvious defects. In order to further analyze the processing quality, a HIROX KH-7700 three-dimensional video microscope was used to examine the microtexture and blade surface morphology, as shown in Figure 19. The rib surface morphology and dimensional data are shown in Figure 19a. The

• morphology and (b) blade surface morphology. Machining error analysis diagram of (a) the microtexture and (b) plane processing. Distribution of LCTP of the single flow channel at angles of attack of (a) 52.8°, (b) 54.8°, and (c) 57.0°. Distribution of Ma in the outlet of the single flow channel at angles of

Intermixing of MoS₂ and WS₂ photocatalysts toward methylene blue photodegradation

• Maryam Al Qaydi,
• Nitul S. Rajput,
• Michael Lejeune,
• Abdellatif Bouchalkha,
• Mimoun El Marssi,
• Steevy Cordette,
• Chaouki Kasmi and
• Mustapha Jouiad

Beilstein J. Nanotechnol. 2024, 15, 817–829, doi:10.3762/bjnano.15.68

• cocatalysts. Their catalytic properties can be tailored based on their crystal structure, their surface area, and their morphology [12][13]. When TMD catalysts are intermixed, they form semiconductor–semiconductor junctions, enhancing their photocatalytic properties by promoting charge separation and electron

• . The observed flakes have typical shapes such as triangular, hexagonal, pentagonal, and other irregular polygonal shapes. The size of the flakes is within the range of 1 µm. The morphology and the shape of the flakes have common microstructures of MoS2/WS2 materials grown using chemical vapor

Electrospun polysuccinimide scaffolds containing different salts as potential wound dressing material

• Veronika Pálos,
• Krisztina S. Nagy,
• Rita Pázmány,
• Krisztina Juriga-Tóth,
• Bálint Budavári,
• Judit Domokos,
• Dóra Szabó,
• Ákos Zsembery and
• Angela Jedlovszky-Hajdu

Beilstein J. Nanotechnol. 2024, 15, 781–796, doi:10.3762/bjnano.15.65

• adhesion, growth, proliferation, and differentiation. The electrospinning technique offers the possibility of using the formed scaffold as a wound dressing with fibers of proper size and morphology. The porous nature of the scaffold enables the drainage of wound fluids and facilitates the entry of oxygen

• from the atmosphere [17]. To achieve an antibacterial effect, one option is the introduction of salts to the polymer solution. The addition of salts to the electrospinning solution leads to changes in the conductivity, viscosity, shearing strength and morphology, and fiber diameter of the prepared

• cells were investigated under a phase-contrast microscope (Nikon Eclipse TS100, Nikon, Japan), and photomicrographs were taken using a CCD camera (COHU, USA) to track any changes in cell morphology. Then, 100 µL of old medium was replaced in each well with 200 µL of media: positive or negative control

Exploring surface charge dynamics: implications for AFM height measurements in 2D materials

• Mario Navarro-Rodriguez,
• Andres M. Somoza and
• Elisa Palacios-Lidon

Beilstein J. Nanotechnol. 2024, 15, 767–780, doi:10.3762/bjnano.15.64

• microscopy (AFM) techniques emerge as ideal tools to investigate them [26][27]. Depending on the operation mode and under controlled environmental conditions, AFM offers the possibility to record morphology along with relevant electronic, mechanical, or magnetic properties with nanoscale resolution. In

Simultaneous electrochemical determination of uric acid and hypoxanthine at a TiO₂/graphene quantum dot-modified electrode

• Vu Ngoc Hoang,
• Dang Thi Ngoc Hoa,
• Nguyen Quang Man,
• Le Vu Truong Son,
• Le Van Thanh Son,
• Vo Thang Nguyen,
• Le Thi Hong Phong,
• Ly Hoang Diem,
• Kieu Chan Ly,
• Ho Sy Thang and
• Dinh Quang Khieu

Beilstein J. Nanotechnol. 2024, 15, 719–732, doi:10.3762/bjnano.15.60

• , titanium alkoxides and halides are extensively used as precursors [20][21]. Because of their high reactivity, a complicate control over the reaction conditions is critical to achieve the desired crystalline structures and morphology [22]. Recently, a synthesis using stable water-soluble titanium complexes

• 1357 and 1593 cm−1, respectively, in the TiO2/GQDs spectrum. The difference in ID/IG ratio, 0.94 for GQDs and 0.71 for TiO2/GQDs, may be due to the interaction between TiO2 and GQDs. Figure 3 presents TEM observations of the obtained materials. The morphology of TiO2 shows agglomerates of around 50–80

Elastic modulus of β-Ga₂O₃ nanowires measured by resonance and three-point bending techniques

• Annamarija Trausa,
• Sven Oras,
• Sergei Vlassov,
• Mikk Antsov,
• Tauno Tiirats,
• Andreas Kyritsakis,
• Boris Polyakov and
• Edgars Butanovs

Beilstein J. Nanotechnol. 2024, 15, 704–712, doi:10.3762/bjnano.15.58

• the length and width of NWs for three-point bending were measured in SEM, the heights were taken from the topography data obtained by AFM in the adhered parts of the NW at each end. In Figure 5a, an SEM image captures the morphology of a Ga2O3 NW positioned over an inverted pyramid structure. Notably

• °C. Characterisation The morphology of as-grown NWs was examined using SEM (Helios 5 UX DualBeam). The measurements were carried out at an acceleration voltage of 5 keV and a beam current of 25 pA. Transmission electron microscopy (Tecnai GF20, FEI) at an accelerating voltage of 200 kV provided

Gold nanomakura: nanoarchitectonics and their photothermal response in association with carrageenan hydrogels

• Nabojit Das,
• Vikas,
• Akash Kumar,
• Sanjeev Soni and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2024, 15, 678–693, doi:10.3762/bjnano.15.56

• analysis at 670, 650, and 630 nm in CTAB-AuNM, MTAB-AuNM, and DTAB-AuNM, respectively. Furthermore, the impact of morphology and surrounding milieu of the synthesized nanomakuras on photothermal conversion is investigated owing to their retention of plasmonic stability. Interestingly, we found that

• purposes. Also, gold nanoparticles possess an intrinsic capacity to liberate heat upon irradiation of NIR/IR lasers making them a suitable candidate for photothermal therapy (PTT). Previous studies reported morphology-dependent heat liberation in gold nanoparticles where anisotropic particles (gold

• examined the effect of different carbon tail lengths of these surfactants in determining nanoparticle morphology (aspect ratio) and photothermal response. The growth solution used was kept uniform in case of all three surfactants to establish the specific effect of carbon tail length on the respective

Functional fibrillar interfaces: Biological hair as inspiration across scales

• Guillermo J. Amador,
• Brett Klaassen van Oorschot,
• Caiying Liao,
• Jianing Wu and
• Da Wei

Beilstein J. Nanotechnol. 2024, 15, 664–677, doi:10.3762/bjnano.15.55

• morphology, including shape and packing density, differ from terrestrial mammals in order to maintain a trapped air layer within the arrays of hair when submerged in water [30]. Hairs of aquatic animals have been found to be flatter, shorter, and packed in higher densities. Additionally, mammals that also

• still made of the protein complex keratin. Plants also make use of fibrillar structures to provide defense against predators. These structures are known as trichomes and vary in morphology and density. While trichomes may also secrete chemicals to warn predators, they can impale insects and their larvae

• when they have a hooked morphology or even sting herbivores [55]. It has been observed that plants with higher densities of trichomes suffer less from insect herbivory. Also, there is a reduced incidence of internal egg laying by insects with ovipositors [55]. Locomotion and feeding While hairs can

Exfoliation of titanium nitride using a non-thermal plasma process

• Priscila Jussiane Zambiazi,
• Dolores Ribeiro Ricci Lazar,
• Larissa Otubo,
• Rodrigo Fernando Brambilla de Souza,
• Almir Oliveira Neto and
• Cecilia Chaves Guedes-Silva

Beilstein J. Nanotechnol. 2024, 15, 631–637, doi:10.3762/bjnano.15.53

• cellulose acetate membrane with 200 nm pores. The process was concluded by drying to obtain the TiN nanosheets. The flowchart of the synthesis procedure is shown in Figure 1. The morphology of the exfoliated material was investigated by transmission electron microscopy (TEM) with a Jeol JEM-2100 electron

• -thermal plasma exfoliation process starting from micrometer-sized TiN powder. The resulting product exhibited a plate-like thin film morphology with an enlarged d-spacing of the (200) crystallographic planes and a relaxation of the Raman vibrational modes. While the cubic structure and chemical

Comparative analysis of the ultrastructure and adhesive secretion pathways of different smooth attachment pads of the stick insect Medauroidea extradentata (Phasmatodea)

• Julian Thomas,
• Stanislav N. Gorb and
• Thies H. Büscher

Beilstein J. Nanotechnol. 2024, 15, 612–630, doi:10.3762/bjnano.15.52

• Julian Thomas Stanislav N. Gorb Thies H. Buscher Functional Morphology and Biomechanics, Institute of Zoology, Kiel University, Am Botanischen Garten 9, 24118 Kiel, Germany 10.3762/bjnano.15.52 Abstract The mechanism by which insects achieve attachment and locomotion across diverse substrates has

• long intrigued scientists, prompting extensive research on the functional morphology of attachment pads. In stick insects, attachment and locomotion are facilitated by two distinct types of smooth cuticular attachment pads: the primary adhesion force-generating arolium and the friction force-generating

• euplantulae. They are both supported by an adhesive secretion delivered into the interspace between the attachment pads and the substrate. In this study, we analysed and compared internal morphology, material composition and ultrastructure, as well as the transportation pathways in both adhesive organs in the

Radiofrequency enhances drug release from responsive nanoflowers for hepatocellular carcinoma therapy

• Yanyan Wen,
• Ningning Song,
• Yueyou Peng,
• Weiwei Wu,
• Qixiong Lin,
• Minjie Cui,
• Rongrong Li,
• Qiufeng Yu,
• Sixue Wu,
• Yongkang Liang,
• Wei Tian and
• Yanfeng Meng

Beilstein J. Nanotechnol. 2024, 15, 569–579, doi:10.3762/bjnano.15.49

• indicating that RF hyperthermia could significantly enhance the antitumor effect of CUR-Fe@MnO2 NFs. However, there was no difference in cell morphology and viability in the control group. The reasons may be that (1) RF heating increased the degradation and release of CUR-Fe@MnO2 NFs and (2) RF heating

• CUR-Fe@MnO2 NFs were collected by magnetic separation and washed 3 times with deionized water. Characterization of the synthesized nanomaterials The morphology and size of Fe3O4 NCs, CUR-Fe NPs, and CUR-Fe@MnO2 NFs were determined via transmission electron microscopy (Tecnai F20, FEI, USA). The TEM

• sample was added to ethanol and ultrasonically dispersed. Then the dispersed liquid was added dropwise to the copper net. After drying, the US FEI Tecnai F20 TEM was used at an accelerated voltage of 200 kV to capture the morphology in high resolution. Zeta potentials and hydrodynamic diameters were

On the additive artificial intelligence-based discovery of nanoparticle neurodegenerative disease drug delivery systems

• Shan He,
• Julen Segura Abarrategi,
• Harbil Bediaga,
• Sonia Arrasate and
• Humberto González-Díaz

Beilstein J. Nanotechnol. 2024, 15, 535–555, doi:10.3762/bjnano.15.47

• databases Pubmed and SciFinder [63][64][65]. This dataset included 260 preclinical assays for 31 unique NPs. Therefore, the number of assays for each NP is about 8.39. Moreover, the data covered a huge range of properties of NPs such as morphology, physicochemical properties, coating agents, length, and

• ), cn1 = cell lines, cn2 = NP morphology, and cn3 = NP synthesis conditions. In addition, we acquired two types of IFPTML-LDA model for designing the N2D3Ss. On the one hand, we obtained the IFPTML-LDA by calculating the PTOs ΔDk(cj) as the difference between the average value ⟨Dk(cj)⟩ and the partition

• contains all indispensable variables for defining the NDD structures and the most significant parameters for NPs, such as morphology, size, and assay conditions, among other things. In the IFPTML-LDA with cross system, we included not only all essential variables but also two crossing PTOs. These new PTOs

Cholesterol nanoarchaeosomes for alendronate targeted delivery as an anti-endothelial dysfunction agent

• Horacio Emanuel Jerez,
• Yamila Roxana Simioni,
• Kajal Ghosal,
• Maria Jose Morilla and
• Eder Lilia Romero

Beilstein J. Nanotechnol. 2024, 15, 517–534, doi:10.3762/bjnano.15.46

• -inflammatory effects in any of the inflammation models (data not shown). A massive portion of endothelial cells is resistant to LPS challenge, entering a fibrotic program and exhibiting a fibroblast-like morphology through a process known as endothelial-to-mesenchymal transition (EndMT) typical from

• EndMT, that is, a predominance of tapered cells with little internal staining. These changes were not prevented by almost any treatment, except dexamethasone and nanoARC-Chol (ALN), which maintained the endothelial morphology and the intensity of actin filament staining to a higher extent and cell/field

• 30 min at 37 °C. Then, cells were washed with PBS, and the fluorescence intensity of whole cells was measured using a Cytation™ 5 instrument at λex = 490 nm and λem = 520 nm. Confocal microscopy was performed to study the morphology of HUVECs. Briefly, after incubation, cell monolayers were washed

Aero-ZnS prepared by physical vapor transport on three-dimensional networks of sacrificial ZnO microtetrapods

• Veaceslav Ursaki,
• Tudor Braniste,
• Victor Zalamai,
• Emil Rusu,
• Vladimir Ciobanu,
• Vadim Morari,
• Daniel Podgornii,
• Pier Carlo Ricci,
• Rainer Adelung and
• Ion Tiginyanu

Beilstein J. Nanotechnol. 2024, 15, 490–499, doi:10.3762/bjnano.15.44

• networks of microtetrapods and has been proposed for microfluidic applications. In this paper, a cost-effective technological approach is proposed for the fabrication of aero-ZnS by using physical vapor transport with Sn2S3 crystals and networks of ZnO microtetrapods as precursors. The morphology of the

• nanomaterials [45]. Because of similarities in the morphology of aero-ZnS materials obtained by physical vapor transport to those produced by HVPE, one can expect that the materials prepared by physical vapor transport will also exhibit hydrophobic/hydrophilic properties suitable for microfluidic applications

• 10 × 10 mm2 to prepare 2 mm thick sample tablets. In order to increase the mechanical stability, the tablets with a density of 0.5 g/cm3 were annealed at 1000 °C for 1 h in air. Morphology analysis was carried out with a VEGA TESCAN 5130 SEM instrument equipped with an EDX detector from Oxford

Photocatalytic degradation of methylene blue under visible light by cobalt ferrite nanoparticles/graphene quantum dots

• Vo Chau Ngoc Anh,
• Le Thi Thanh Nhi,
• Le Thi Kim Dung,
• Dang Thi Ngoc Hoa,
• Nguyen Truong Son,
• Nguyen Thi Thao Uyen,
• Nguyen Ngoc Uyen Thu,
• Le Van Thanh Son,
• Le Trung Hieu,
• Tran Ngoc Tuyen and
• Dinh Quang Khieu

Beilstein J. Nanotechnol. 2024, 15, 475–489, doi:10.3762/bjnano.15.43

• /GQDs nanoparticles. Magnetic properties, morphology, structure, and fluorescence of the nanocomposites were studied, and the photocatalytic degradation of methylene blue as a dye model and the mechanism of methylene degradation were also addressed. Experimental Materials Cobalt(II) nitrate hexahydrate

• CF/GQDs synthesized at hydrothermal temperatures of 140, 180 and 200 °C are shown in Figure 4a–c. The morphology reveals that CF/GQDs consist of heavily agglomerated particles, several hundreds of nanometers in diameter, because of their magnetic nature. Figure 4d and Figure 4e present the TEM images

Fabrication of nanocrystal forms of ᴅ-cycloserine and their application for transdermal and enteric drug delivery systems

• Hsuan-Ang Tsai,
• Tsai-Miao Shih,
• Theodore Tsai,
• Jhe-Wei Hu,
• Yi-An Lai,
• Jui-Fu Hsiao and
• Guochuan Emil Tsai

Beilstein J. Nanotechnol. 2024, 15, 465–474, doi:10.3762/bjnano.15.42

• antisolvent, and the mixing conditions. During precipitation, different solvents can affect the size, the structure, and the stability of polymorphous particles. To confirm the morphology of DCS nanocrystals, SEM and XRPD analyses were applied for the examination of particle size and structure, respectively

• distinct morphology of DCS nanocrystals when compared to that of commercial DCS. In order to confirm whether the crystalline DCS was a new crystal form, the XRPD patterns of the DCS nanocrystals were compared with those of the commercial DCS powder. As shown in Figure 2, the prominent peaks of the DCS

• nanocrystals were at 17.0°, 24.3°, 28.5°, and 34.3° (2θ), distinct from those of commercial DCS. These results indicated that the new crystalline DCS was a novel nanocrystal. The spectra demonstrate that the nanocrystal form of DCS was successfully generated. To exclude crystal polymorphism, the morphology and

Superconducting spin valve effect in Co/Pb/Co heterostructures with insulating interlayers

• Andrey A. Kamashev,
• Nadir N. Garif’yanov,
• Aidar A. Validov,
• Vladislav Kataev,
• Alexander S. Osin,
• Yakov V. Fominov and
• Ilgiz A. Garifullin

Beilstein J. Nanotechnol. 2024, 15, 457–464, doi:10.3762/bjnano.15.41

• to the quality of this interface in terms of its morphology, smoothness, and absence of intergrowth, which defines the mainstream approach in this field. At odds with this approach, a significant SSV effect of ΔTc ≈ 0.3 K in an FeNi/In/Ni heterostructure with intentionally oxidized F/S interfaces was

Heat-induced morphological changes in silver nanowires deposited on a patterned silicon substrate

• Elyad Damerchi,
• Sven Oras,
• Edgars Butanovs,
• Allar Liivlaid,
• Mikk Antsov,
• Boris Polyakov,
• Annamarija Trausa,
• Veronika Zadin,
• Andreas Kyritsakis,
• Loïc Vidal,
• Karine Mougin,
• Siim Pikker and
• Sergei Vlassov

Beilstein J. Nanotechnol. 2024, 15, 435–446, doi:10.3762/bjnano.15.39

• Tool (OVITO) [42]. The system time step was 10 fs. More technical details can be found in Supporting Information File 1. Results and Discussion Heat treatment First heating scheme No significant changes in the morphology of Ag NWs were detected for heat-treatment temperatures up to 275 °C. Starting

• affect the outcome of the experiment since in any case defects caused by heating/cooling (hence, tensile compression) cycles will result in reduced thermal stability of the suspended part compared to the adhered part. Note that, as mentioned earlier, the morphology evolution in the adhered parts is

Potential of a deep eutectic solvent in silver nanoparticle fabrication for antibiotic residue detection

• Le Hong Tho,
• Bui Xuan Khuyen,
• Ngoc Xuan Dat Mai and
• Nhu Hoa Thi Tran

Beilstein J. Nanotechnol. 2024, 15, 426–434, doi:10.3762/bjnano.15.38

• scholars, the rod-like morphology is better than a spherical one at increasing the extinction coefficient, about 109 to 1011 M−1·cm−1 higher [43][44], which proves the applicability of Ag NPs-DES in SERS biosensors. Furthermore, X-ray fluorescence mapping was used to evaluate the presence of silver in the

• the nanostructure and surface morphology of the nanoparticles, as well as the elemental distribution of silver on the substrate, a S4800 field-emission scanning electron microscope purchased from Hitachi, Japan, and an M4 TORNADOPlus Micro X-ray fluorescence spectrometer with a Rh tube at 30 W micro