A 3D-polyphenylalanine network inside porous alumina: Synthesis and characterization of an inorganic–organic composite membrane

• Jonathan Stott and
• Jörg J. Schneider

Beilstein J. Nanotechnol. 2020, 11, 938–951, doi:10.3762/bjnano.11.78

• electron microscopy (SEM), near-infrared spectroscopy (NIR) and contact angle measurements (CA) reveals a change in morphology of the grafted polymer films, which is due to the rearrangement of the secondary structure of the polypeptides. No significant loss of the surface-grafted polypeptides was

• hydrolyzed monomers or an alternative polymerization mechanism [40][41]. The characterization of these composite materials was performed by NIR-spectroscopy (NIR), water contact angle measurements (CA), scanning electron microscopy (SEM) and thermogravimetric (TG) measurements. Mid- and near-infrared

• rearrangement during the second dewetting process. At the outer surface the ability to rearrange is improved by convection initiated due to frequent mechanical agitation of the flask during the CHCl3/DCA treatment. NIR characterization of grafted polyphenylalanine Near-infrared spectroscopic analysis can

Key for crossing the BBB with nanoparticles: the rational design

• Sonia M. Lombardo,
• Marc Schneider,
• Akif E. Türeli and
• Nazende Günday Türeli

Beilstein J. Nanotechnol. 2020, 11, 866–883, doi:10.3762/bjnano.11.72

• , which allows them to strongly absorb light in the infrared region [177][178]. The advantage of AuNRs over AuNPs is that their aspect ratio (length divided by width) allows for the adjustment of the absorption wavelength in the near infrared (NIR) region (650–1350 nm), thus exploiting the so-called

Templating effect of single-layer graphene supported by an insulating substrate on the molecular orientation of lead phthalocyanine

• K. Priya Madhuri,
• Abhay A. Sagade,
• Pralay K. Santra and
• Neena S. John

Beilstein J. Nanotechnol. 2020, 11, 814–820, doi:10.3762/bjnano.11.66

• –molecule interactions [1][2][3][4]. Nonplanar MPcs, such as lead phthalocyanine (PbPc), are particularly interesting in the field of photovoltaics due to their extraordinary near-infrared (NIR) absorption. The chemical structure of a PbPc molecule is given in Figure 1. The well-known polymorphs of

Light–matter interactions in two-dimensional layered WSe₂ for gauging evolution of phonon dynamics

• Avra S. Bandyopadhyay,
• Chandan Biswas and
• Anupama B. Kaul

Beilstein J. Nanotechnol. 2020, 11, 782–797, doi:10.3762/bjnano.11.63

• the following in Equation 1 [7], among which A1g, E1g, are the Raman active optical modes, are the acoustic phonon modes, are the infrared active modes, and E2u, B1u, are the four optically inactive modes; however the mode is active for bilayer and thicker WSe2. In this study we focus on the

Hexagonal boron nitride: a review of the emerging material platform for single-photon sources and the spin–photon interface

• Stefania Castelletto,
• Faraz A. Inam,
• Shin-ichiro Sato and
• Alberto Boretti

Beilstein J. Nanotechnol. 2020, 11, 740–769, doi:10.3762/bjnano.11.61

• ) with proven single-photon emission from the visible to infrared, a quantum spin–photon interface, and ancilla qubits, it is expected that other material platforms could emerge with similar characteristics in the near future. These two materials also naturally lead to monolithic integrated photonics as

• -BN as an SPE is still thwarted by the wavelength variability of the ZPL from one emitter to another, which spans a broad spectral range from the UV to the visible up to the near-infrared regions [101][102]. As an example of some of the results, Figure 2 taken from [103] summarizes the photo-physics

Preparation, characterization and photocatalytic performance of heterostructured CuO–ZnO-loaded composite nanofiber membranes

• Wei Fang,
• Liang Yu and
• Lan Xu

Beilstein J. Nanotechnol. 2020, 11, 631–650, doi:10.3762/bjnano.11.50

• -transform infrared spectroscopy (FTIR, Nicolet5700, Thermo Nicolet Company, Waltham, MA, USA), carrying out 32 scans within the wavenumber range of 400–4000 cm−1 with a resolution of 4 cm−1. X-ray diffraction (XRD) analyses were carried out using a Philips X’Pert-Pro MPD (PANalytical, Almelo & Eindhoven

Silver-decorated gel-shell nanobeads: physicochemical characterization and evaluation of antibacterial properties

• Marta Bartel,
• Katarzyna Markowska,
• Marcin Strawski,
• Krystyna Wolska and
• Maciej Mazur

Beilstein J. Nanotechnol. 2020, 11, 620–630, doi:10.3762/bjnano.11.49

• calculated using the Smoluchowski equation. Spectroscopy Fourier-transform infrared data were collected with a Nicolet 6700 Continuum FTIR microscope (Thermo Electron Corporation). The chemical composition of the structure was examined using X-ray photoelectron spectroscopy (Kratos Analytical Axis Ultra DLD

Soybean-derived blue photoluminescent carbon dots

• Shanshan Wang,
• Wei Sun,
• Dong-sheng Yang and
• Fuqian Yang

Beilstein J. Nanotechnol. 2020, 11, 606–619, doi:10.3762/bjnano.11.48

• –visible spectrophotometer (Thermal Scientific Evolution 201). The Fourier-transform infrared spectroscopy (FTIR) analysis of the prepared carbon nanoparticles was conducted on a Fourier transform infrared instrument (Nicolet iS50) in the wavenumber range of 400 to 4000 cm−1 at a resolution of 4 cm−1

Luminescent gold nanoclusters for bioimaging applications

• Nonappa

Beilstein J. Nanotechnol. 2020, 11, 533–546, doi:10.3762/bjnano.11.42

• of colors covering ultraviolet to near-infrared (NIR). Furthermore, SCQDs offer better sensitivity, stability against photobleaching, and a narrow spectral bandwidth compared to conventional organic dyes. However, due to their cytotoxicity, the tendency to undergo aggregation inside the cells, and

• U87MG tumors engrafted in the brain (Figure 7F). Again, [Au25(ZWMe2)18] was found to yield a three times stronger signal than [Au25(SG)18] at 1 h post-injection. Chen et al. have shown that zwitterionic LA-sulfobetaine-capped AuNCs can be used for in vivo shortwave infrared imaging using a mouse model

Multilayer capsules made of weak polyelectrolytes: a review on the preparation, functionalization and applications in drug delivery

• Varsha Sharma and
• Anandhakumar Sundaramurthy

Beilstein J. Nanotechnol. 2020, 11, 508–532, doi:10.3762/bjnano.11.41

Interfacial charge transfer processes in 2D and 3D semiconducting hybrid perovskites: azobenzene as photoswitchable ligand

• Nicole Fillafer,
• Tobias Seewald,
• Lukas Schmidt-Mende and
• Sebastian Polarz

Beilstein J. Nanotechnol. 2020, 11, 466–479, doi:10.3762/bjnano.11.38

• presence of the azo compounds was verified using a combination of Fourier-transform infrared (FTIR) and UV–vis absorption spectroscopy. A characteristic vibration at 2991 cm−1, which can be associated to the N–H stretching vibrations of the ammonium headgroup (Figure 4E), vanishes completely for 3D-AzoC2

Electrochemically derived functionalized graphene for bulk production of hydrogen peroxide

• Munaiah Yeddala,
• Pallavi Thakur,
• Anugraha A and
• Tharangattu N. Narayanan

Beilstein J. Nanotechnol. 2020, 11, 432–442, doi:10.3762/bjnano.11.34

• EEG samples. This correlates with the Fourier-transform infrared spectroscopy (FTIR) based analysis (Figure S1b), which also shows the presence of covalent C–F functional groups in all the samples. The samples also contain fluorine as one of the dopants with a content varying from 2.3 to 3.9 atom

Synthesis and enhanced photocatalytic performance of 0D/2D CuO/tourmaline composite photocatalysts

• Changqiang Yu,
• Min Wen,
• Zhen Tong,
• Shuhua Li,
• Yanhong Yin,
• Xianbin Liu,
• Yesheng Li,
• Tongxiang Liang,
• Ziping Wu and
• Dionysios D. Dionysiou

Beilstein J. Nanotechnol. 2020, 11, 407–416, doi:10.3762/bjnano.11.31

• electric field can increase the separation of the photoinduced charge carriers [2][23][24]. Furthermore, tourmaline can augment the oxygen dissolved into water due to its infrared radiation effect [24][25], which contributes to accelerate the photocatalytic oxidation reactions. Tourmaline is a promising

• scanning electron microscope (SEM, Tescan, Czech) was used to observe the morphology. A Titan G2 60-300 transmission electron microscope (TEM, FEI, USA) was employed to analyze the microstructure. A NEXUS 670 spectrometer (Thermo Nicolet, USA) was employed for recording the Fourier transform infrared (FTIR

Poly(1-vinylimidazole) polyplexes as novel therapeutic gene carriers for lung cancer therapy

• Gayathri Kandasamy,
• Elena N. Danilovtseva,
• Vadim V. Annenkov and
• Uma Maheswari Krishnan

Beilstein J. Nanotechnol. 2020, 11, 354–369, doi:10.3762/bjnano.11.26

• reference. Fourier-transform infrared spectroscopy (FTIR): The FTIR spectra of the free siRNA, blank polymer nanoparticles and the polyplex were recorded between 4000 and 400 cm−1 averaging 10 scans per run in attenuated total reflection mode (ATR) using a Fourier-transform infrared spectrometer (Spectrum

Facile biogenic fabrication of hydroxyapatite nanorods using cuttlefish bone and their bactericidal and biocompatibility study

• Satheeshkumar Balu,
• Manisha Vidyavathy Sundaradoss,
• Swetha Andra and
• Jaison Jeevanandam

Beilstein J. Nanotechnol. 2020, 11, 285–295, doi:10.3762/bjnano.11.21

• ) nanorods using cuttlefish bone powder as a precursor (CB-Hap NRs). The obtained CB-Hap NRs were investigated using transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and thermogravimetric analysis (TGA) techniques to evaluate their

• setup via an oil bath approach to synthesize Hap nanorods from cuttlefish bone powders and optimize their synthesis parameters. The systematic characterization using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM) was performed to

• graphite mortar and pestle and placed on the sample holder. The crystallite size and phase formation of the cuttlefish-bone-derived Hap nanorods were identified and confirmed by comparing the data with standard XRD patterns from JCPDS. Fourier transform infrared spectroscopy The presence of functional

Using gold nanoparticles to detect single-nucleotide polymorphisms: toward liquid biopsy

• María Sanromán Iglesias and
• Marek Grzelczak

Beilstein J. Nanotechnol. 2020, 11, 263–284, doi:10.3762/bjnano.11.20

• optical properties not only in the visible but also in the near-infrared spectral range. Shape anisotropy (rods) and regiospecific surface functionalization (tip versus lateral parts) enable the fabrication of colloidal systems with limited degrees of freedom. In such systems, the possible orientations of

Phase inversion-based nanoemulsions of medium chain triglyceride as potential drug delivery system for parenteral applications

• Eike Folker Busmann,
• Dailén García Martínez,
• Henrike Lucas and
• Karsten Mäder

Beilstein J. Nanotechnol. 2020, 11, 213–224, doi:10.3762/bjnano.11.16

• – high glucose (DMEM), fetal calf serum (FCS), penicillin-streptomycin, ʟ-glutamine solution and sodium pyruvate solution as well as the fluorescent dye resazurin sodium salt were purchased from Sigma-Aldrich Chemie GmbH (Germany, Steinheim). The near infrared fluorescent dye DiR was purchased from

Rational design of block copolymer self-assemblies in photodynamic therapy

• Maxime Demazeau,
• Laure Gibot,
• Anne-Françoise Mingotaud,
• Patricia Vicendo,
• Clément Roux and
• Barbara Lonetti

Beilstein J. Nanotechnol. 2020, 11, 180–212, doi:10.3762/bjnano.11.15

• is an example of “all in one“ nanomedicine used for chemotherapy combining loading with doxorubicin, PDT and PTT. This is possible thanks to the activation of the photosensitizer and multimodal imaging using the fluorescence of the photosensitizer (near-infrared fluorescence imaging, NIRFI) and the

Size effects of graphene nanoplatelets on the properties of high-density polyethylene nanocomposites: morphological, thermal, electrical, and mechanical characterization

• Tuba Evgin,
• Alpaslan Turgut,
• Georges Hamaoui,
• Zdenko Spitalsky,
• Nicolas Horny,
• Matej Micusik,
• Mihai Chirtoc,
• Mehmet Sarikanat and
• Maria Omastova

Beilstein J. Nanotechnol. 2020, 11, 167–179, doi:10.3762/bjnano.11.14

• –85°, with a scanning speed of 0.03°/s. FTIR measurements were carried out with a Thermo Fisher Scientific iS10 infrared spectrometer in the range of 4000–650 cm−1 at room temperature. Broadband dielectric spectroscopy (BDS) measurements were conducted using a Novocontrol Concept 40 instrument with an

Plasmonic nanosensor based on multiple independently tunable Fano resonances

• Lin Cheng,
• Zelong Wang,
• Xiaodong He and
• Pengfei Cao

Beilstein J. Nanotechnol. 2019, 10, 2527–2537, doi:10.3762/bjnano.10.243

• proposed a compact plasmonic nanosensor, which is composed of one MDM waveguide, two side-coupled stubs, and three gap-coupled resonators (a T-shaped, a ring and a split-ring, respectively). The transmission features of the structure are numerically simulated in the near-infrared spectrum at 1000 to 2000

• . Next, we selected typical structures published in recent years for comparison [28][29], and the results are shown in Table 1 below. Obviously, the structure we propose has the most resonance peaks, covering a wavelength range of about 1000–2000 nm in the near-infrared region with relatively high

Mobility of charge carriers in self-assembled monolayers

• Zhihua Fu,
• Tatjana Ladnorg,
• Hartmut Gliemann,
• Alexander Welle,
• Asif Bashir,
• Michael Rohwerder,
• Qiang Zhang,
• Björn Schüpbach,
• Andreas Terfort and
• Christof Wöll

Beilstein J. Nanotechnol. 2019, 10, 2449–2458, doi:10.3762/bjnano.10.235

• °) to determine the molecular orientation. Infrared reflection-absorption spectroscopy (IRRAS) was performed on a Bruker VERTEX80 spectrometer (Bruker Optics GmbH) by investigating the PAT-SAM on Au/silicon wafers. As a background sample we used a SAM of deuterated octadecanethiol on an Au/silicon wafer

• , Figure S1). Further characterization methods such as infrared reflection absorption spectroscopy (IRRAS) and attenuated transmission reflection (ATR) spectroscopy were also applied. The assignment of the molecular vibrations was aided by quantum-chemical calculations, from which the transition dipole

pH-Controlled fluorescence switching in water-dispersed polymer brushes grafted to modified boron nitride nanotubes for cellular imaging

• Saban Kalay,
• Yurij Stetsyshyn,
• Volodymyr Donchak,
• Khrystyna Harhay,
• Ostap Lishchynskyi,
• Halyna Ohar,
• Yuriy Panchenko,
• Stanislav Voronov and
• Mustafa Çulha

Beilstein J. Nanotechnol. 2019, 10, 2428–2439, doi:10.3762/bjnano.10.233

• thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), dynamic light scattering (DLS), ultraviolet–visible spectrophotometry (UV–vis), laser scanning confocal microscopy (LSCM) and scanning electron microscopy (SEM). The DLS results demonstrated that P(AA-co-FA)-functionalized BNNTs

• ); characteristic infrared spectra bands – ν (С=О) in Ar-C(O)Cl, ν (С=О) in ester group at 1760 and 1752 cm−1; doublet at 1390, 1365 cm−1, referred to δ(C(CH3)3) and a band of tert-butoxy group at 848 cm−1. BNNT synthesis and purification The BNNTs were synthesized by chemical vapor deposition from colemanite (2 g

• heated from 30.00 to 600.00 °C at 10 °C/min. Fourier transform infrared spectroscopy (FTIR) FTIR spectra were recorded on a NICOLET iS50 FTIR spectrometer (Thermo Scientific, USA), equipped with a iS50 ATR multirange, diamond sampling station. The sample powders were either placed on diamond crystal or

Coating of upconversion nanoparticles with silica nanoshells of 5–250 nm thickness

• Cynthia Kembuan,
• Maysoon Saleh,
• Bastian Rühle,
• Ute Resch-Genger and
• Christina Graf

Beilstein J. Nanotechnol. 2019, 10, 2410–2421, doi:10.3762/bjnano.10.231

• nanocrystals have gained importance as inorganic optical reporters in recent years [1][2][3]. The doping of inorganic host NaYF4 matrices with different optically active lanthanide ions can result in so-called upconversion nanoparticles (UCNP) which can absorb photons of lower energy (e.g., near-infrared (NIR

Deterministic placement of ultra-bright near-infrared color centers in arrays of silicon carbide micropillars

• Stefania Castelletto,
• Abdul Salam Al Atem,
• Faraz Ahmed Inam,
• Hans Jürgen von Bardeleben,
• Sophie Hameau,
• Ahmed Fahad Almutairi,
• Gérard Guillot,
• Shin-ichiro Sato,
• Alberto Boretti and
• Jean Marie Bluet

Beilstein J. Nanotechnol. 2019, 10, 2383–2395, doi:10.3762/bjnano.10.229

• element method simulations. Our study provides the pathway for device design and fabrication with an integrated ultra-bright ensemble of VSi and NCVSi for in vivo imaging and sensing in the infrared. Keywords: color centers; micropillars; proton irradiation; quantum sensing; silicon carbide; vacancy

• simulations of the nitrogen vacancy, NCVSi(−) (NV), defect in SiC have been recently performed in [35][36][37][38], resulting in ZPLs at 1242, 1241, 1223 and 1180 nm [38]. This emission is very promising as it is further into the infrared compared to the divacancies. The association of ZPL lines with NV

• the near-infrared, there is a need to improve the spontaneous emission rate for room-temperature applications such as magnetic sensing and SPSs. For all the above applications, the fluorescence emission enhancement of the color centers is a crucial issue for room-temperature applications, specifically

Polyvinylpyrrolidone as additive for perovskite solar cells with water and isopropanol as solvents

• Chen Du,
• Shuo Wang,
• Xu Miao,
• Wenhai Sun,
• Yu Zhu,
• Chengyan Wang and
• Ruixin Ma

Beilstein J. Nanotechnol. 2019, 10, 2374–2382, doi:10.3762/bjnano.10.228

• monochromator. Infrared (IR) spectroscopy was performed using a Fourier transform IR spectrometer (VERTEX80v, Bruker). Photoluminescence (PL) spectra and the fluorescence decay curves were recorded with a computer controlled, modular spectro- fluorimeter (FLS980, Edinburgh). The active area of the cell was 0.1

• experimental data and solid lines correspond to the fits using the equivalent circuit (inset). (a) Infrared spectrum of pure PVP over the full scan range. (b, c) Infrared spectra of the perovskite films; (b) full scan range and (c) expanded fingerprint region from 1700 to 1600 cm−1. (d) Schematic diagram and