Reliable fabrication of transparent conducting films by cascade centrifugation and Langmuir–Blodgett deposition of electrochemically exfoliated graphene

• Teodora Vićentić,
• Stevan Andrić,
• Vladimir Rajić and
• Marko Spasenović

Beilstein J. Nanotechnol. 2022, 13, 666–674, doi:10.3762/bjnano.13.58

• the Langmuir–Blodgett (LB) method to deposit graphene flakes from solution as uniform thin films. LB has proven to be a method that yields reliable graphene films that have been used as transparent conductors [27][32][33][34] and gas sensors [35][36]. By measuring optical transmittance and electrical

Investigation of electron-induced cross-linking of self-assembled monolayers by scanning tunneling microscopy

• Patrick Stohmann,
• Sascha Koch,
• Yang Yang,
• Christopher David Kaiser,
• Julian Ehrens,
• Jürgen Schnack,
• Niklas Biere,
• Dario Anselmetti,
• Armin Gölzhäuser and
• Xianghui Zhang

Beilstein J. Nanotechnol. 2022, 13, 462–471, doi:10.3762/bjnano.13.39

• been used to explain the synthesis of complex molecular species in the interstellar medium [3]. Electron–molecule collisions have been intensively studied in the gas phase and on surfaces. Depending on the electron energy and the molecular structure, several processes may occur, such as elastic

• general concept of self-assembly allows for the preparation of SAMs from the liquid or gas phase. Highly ordered TPT SAMs spontaneously form on Au(111) due to the formation of bonds between sulfur and gold atoms, which is accompanied by van der Waals interactions between the aromatic rings. The TPT SAMs

• elevated by ≈0.6–0.8 Å compared to the surrounding β-phase domains. To our surprise, TPT SAMs prepared from the gas phase exhibit only β-phase domains with sizes of 10–100 nm (Figure 2c). Notice that the sample was further annealed at 343 K for 15 min in order to remove physisorbed molecules, which results

Tubular glassy carbon microneedles with fullerene-like tips for biomedical applications

• Sharali Malik and
• George E. Kostakis

Beilstein J. Nanotechnol. 2022, 13, 455–461, doi:10.3762/bjnano.13.38

• pyrolysis of methane on a curved alumina surface. The surface provides the catalyst as well as the “strain” required to direct nucleation and growth. Figure 1a is a scanning electron microscopy (SEM) overview image showing a number of glassy carbon microneedles, which grow in the direction of the gas flow

• interlayer spacing in glassy carbon corresponds to the nature of the intercalating species [26]. Here the “stress” arises from the constraints of the growing glassy carbon layers from the curved alumina gas-flow tube and the intercalating species, which are gaseous species, generated when methane undergoes

• prepared by flowing methane (CH4) at a rate of 40 sccm for 12 h at p = 200 mbar and a gas temperature of 1020 °C through a 20 mm diameter alumina (Al2O3) tube (15 mm internal diameter), which was then cooled under argon (Ar). Characterization The prepared glassy carbon microneedles were characterized by

A chemiresistive sensor array based on polyaniline nanocomposites and machine learning classification

• Jiri Kroutil,
• Alexandr Laposa,
• Ali Ahmad,
• Jan Voves,
• Vojtech Povolny,
• Ladislav Klimsa,
• Marina Davydova and
• Miroslav Husak

Beilstein J. Nanotechnol. 2022, 13, 411–423, doi:10.3762/bjnano.13.34

• 1999/2, 182 21 Prague, Czech Republic 10.3762/bjnano.13.34 Abstract The selective detection of ammonia (NH3), nitrogen dioxide (NO2), carbon oxides (CO2 and CO), acetone ((CH3)2CO), and toluene (C6H5CH3) is investigated by means of a gas sensor array based on polyaniline nanocomposites. The array

• , namely k-nearest neighbors algorithm, support vector machine, random forest, decision tree classifier, and Gaussian process classification (GPC) are compared to evaluate the accuracy of target gas determination. We found the Gaussian process classification model trained on features extracted from the

• data by principal component analysis to be a highly accurate method reach to 99% of the classification of six different gases. Keywords: feature extraction; gas sensor; pattern recognition; sensor array; Introduction The control and monitoring of toxic gaseous substances, such as ammonia, nitrogen

Electrostatic pull-in application in flexible devices: A review

• Teng Cai,
• Yuming Fang,
• Yingli Fang,
• Ruozhou Li,
• Ying Yu and
• Mingyang Huang

Beilstein J. Nanotechnol. 2022, 13, 390–403, doi:10.3762/bjnano.13.32

• [61]. Schematic diagram of a flexible microvalve structure. Figure 8 was redrawn from [77]. Schematic diagram of a GR pump. Figure 9 was republished from [78] (D. Davidovikj et al., “Graphene gas pumps”, 2D Materials, vol. 5, article no. 031009, published on 11 May 2018; https://doi.org/10.1088/2053

Selected properties of Al_xZn_yO thin films prepared by reactive pulsed magnetron sputtering using a two-element Zn/Al target

• Witold Posadowski,
• Artur Wiatrowski,
• Jarosław Domaradzki and
• Michał Mazur

Beilstein J. Nanotechnol. 2022, 13, 344–354, doi:10.3762/bjnano.13.29

• increased optical transmission [10][20][21]. In the magnetron sputtering process, it is possible to influence the properties of deposited films by varying the composition of the sputtering gas atmosphere, the total gas pressure, substrate temperature and bias, the target–substrate distance, the target power

Interfacial nanoarchitectonics for ZIF-8 membranes with enhanced gas separation

• Season S. Chen,
• Zhen-Jie Yang,
• Chia-Hao Chang,
• Hoong-Uei Koh,
• Sameerah I. Al-Saeedi,
• Kuo-Lun Tung and
• Kevin C.-W. Wu

Beilstein J. Nanotechnol. 2022, 13, 313–324, doi:10.3762/bjnano.13.26

• Road, Taipei 10617, Taiwan Department of Chemistry, College of Science, Princess Nourah bint Abdulrahman University P.O.Box 84428. Riyadh 116711, Saudi Arabia 10.3762/bjnano.13.26 Abstract Metal-organic framework (MOF) membranes are potentially useful in gas separation applications. Conventional

• optimal synthesis conditions were determined (i.e., 80 °C for 12 h in 50 mM of 2-methylimidazole). The as-synthesized ZIF-8 membranes were then applied to CO2/N2 gas separation, which exhibited a maximum separation factor of 5.49 and CO2 gas permeance of 0.47 × 10−7 mol·m−2·s−1·Pa−1. Keywords: defect

• -free; gas separation; interfacial synthesis; metal-organic frameworks; ZIF membranes; Introduction Carbon dioxide (CO2) is one of the major greenhouse gases emitted through human activities contributing to global climate change. According to United States Environmental Protection Agency (US EPA), CO2

The effect of metal surface nanomorphology on the output performance of a TENG

• Yiru Wang,
• Xin Zhao,
• Yang Liu and
• Wenjun Zhou

Beilstein J. Nanotechnol. 2022, 13, 298–312, doi:10.3762/bjnano.13.25

• -renewable resources such as oil, coal, and natural gas. The consumption of fossil fuels, at the same time, causes many environmental problems. In this regard, looking for green renewable energies to replace fossil energies has become a future development trend. Especially the high degree of disorder that

Photothermal ablation of murine melanomas by Fe₃O₄ nanoparticle clusters

• Xue Wang,
• Lili Xuan and
• Ying Pan

Beilstein J. Nanotechnol. 2022, 13, 255–264, doi:10.3762/bjnano.13.20

• (DeTAB, 99%) and 1,2-hexadecanediol (97%) were purchased from TCI Chemical Industry Development Co., Ltd. (Shanghai). Chloroform (99%), ethylene glycol (96%), and ethanol (99.7%) were purchased from Beijing Chemical Works. Nitrogen gas was purchased from Juyang Gas (Changchun). Hela cells were purchased

Low-energy electron interaction and focused electron beam-induced deposition of molybdenum hexacarbonyl (Mo(CO)₆)

• Po-Yuan Shih,
• Maicol Cipriani,
• Christian Felix Hermanns,
• Jens Oster,
• Klaus Edinger,
• Armin Gölzhäuser and
• Oddur Ingólfsson

Beilstein J. Nanotechnol. 2022, 13, 182–191, doi:10.3762/bjnano.13.13

• , University of Iceland, Dunhagi 3, 107 Reykjavik, Iceland 10.3762/bjnano.13.13 Abstract Motivated by the potential role of molybdenum in semiconductor materials, we present a combined theoretical and experimental gas-phase study on dissociative electron attachment (DEA) and dissociative ionization (DI) of Mo

• electron transmission study. Relative contributions of individual ionic species obtained through DEA and DI of Mo(CO)6 and the average CO loss per incident are calculated and compared to the composition of the FEBID deposits produced. These are also compared to gas phase, surface science and deposition

• deposits composition with carbonyl loss through DEA vs DI. We compare this to previous gas phase, surface science and FEBID experiments on W(CO)6 and discuss these studies in context to the current findings and potential deposition mechanisms. Method Quantum chemical calculations Similar to the approach in

Thermal oxidation process on Si(113)-(3 × 2) investigated using high-temperature scanning tunneling microscopy

• Hiroya Tanaka,
• Shinya Ohno,
• Kazushi Miki and
• Masatoshi Tanaka

Beilstein J. Nanotechnol. 2022, 13, 172–181, doi:10.3762/bjnano.13.12

• was kept in that position for a while before the measurements were started. Pure oxygen gas was introduced using a variable leak valve. It took about 3–30 s to obtain each STM image so that the amount of oxygen exposure would differ slightly between the upper and lower parts of the STM image. We put

Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• the decomposition of gas pollutants are still being developed. In addition, previous studies have shown that the photocatalytic activity regarding NOx decomposition of SnO2 and other materials depends on many factors, such as physical structure and band energies, surface and defect states, and

• vacancy defects (OVs) [15][16]. Therefore, SnO2 is considered a potential material in various technological fields such as catalysis, optoelectronic devices, rechargeable lithium batteries, electrocatalysis, photocatalysis, solar energy conversion, and gas sensing [17][18][19][20][21][22][23][24]. In the

• morphologies will affect the properties of SnO2 regarding gas sensor activity and optical, electrical, and electrochemical properties [60][61][62][63]. The typical properties of SnO2 are significantly affected by the effective surface area of different nanomaterial morphologies [63][64][65]. Wang et al. [66

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

• reported data; we will address the influence of the sputtering parameters (sputter power, current, voltage, sputter time, working gas pressure, and the type of sputtering plasma) and host liquid properties (composition, temperature, viscosity, and surface tension) on the NP formation as well as a detailed

• in the synthesis procedures. The most common physical methods used to generate NPs are high-energy ball milling, laser ablation, electrospraying, inert gas condensation, PVD, laser pyrolysis, flash spray pyrolysis, and melt mixing [16]. Chemical methods are the traditional and most widely used

• designed to coat objects with thin film materials. Sputtering is the physical phenomenon describing the ejection of atoms from a surface bombarded by fast particles such as noble gas cations. These ions can be produced in a low-pressure plasma and accelerated towards a negatively biased surface, that is

Topographic signatures and manipulations of Fe atoms, CO molecules and NaCl islands on superconducting Pb(111)

• Carl Drechsel,
• Philipp D’Astolfo,
• Jung-Ching Liu,
• Thilo Glatzel,
• Rémy Pawlak and
• Ernst Meyer

Beilstein J. Nanotechnol. 2022, 13, 1–9, doi:10.3762/bjnano.13.1

• nm with an apparent depression of 0.14 Å. They result from the interference of bulk electrons with trapped subsurface Ar gas bubbles after sputtering [52][53]. After CO dosing in the microscope chamber (see section “Sample preparation”), a coverage of 0.1–0.2 monolayers is expected to adsorb on the

Design aspects of Bi₂Sr₂CaCu₂O_8+δ THz sources: optimization of thermal and radiative properties

• Mikhail M. Krasnov,
• Natalia D. Novikova,
• Roger Cattaneo,
• Alexey A. Kalenyuk and
• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2021, 12, 1392–1403, doi:10.3762/bjnano.12.103

• = 85.2 K. Figure 3f–h show simulations for the same device in exchange 4He gas. Clearly, it helps to cool down the device, although self-heating still remains substantial, Tmax = 56.7 K. Figure 4 shows simulations for the whisker-based device with a top Au electrode. Outside the whisker the electrode is

• in a direct contact with the sapphire substrate (no epoxy). This creates a good thermal sink and, as a result, Tmax falls to ≈23 K. Addition of an exchange gas does not play a major role in this case because the main heat sink channel is provided by the electrode [33][34] acting as a heat spreading

• the substrate. This occurs because the heat resistance, Rh = d/(κA), is inversely proportional to the area A. Due to a much larger crystal area, Rh of epoxy is negligible despite a low κ and larger de = 5 μm. Adding an electrode and He exchange gas further reduces self-heating, but their effect is not

Measurement of polarization effects in dual-phase ceria-based oxygen permeation membranes using Kelvin probe force microscopy

• Kerstin Neuhaus,
• Christina Schmidt,
• Liudmila Fischer,
• Wilhelm Albert Meulenberg,
• Ke Ran,
• Joachim Mayer and
• Stefan Baumann

Beilstein J. Nanotechnol. 2021, 12, 1380–1391, doi:10.3762/bjnano.12.102

• environment are the strong decrease in oxygen ion mobility below 600 °C, mechanical stability and chemical stability against the used reactive gases, and local chemical reactions at the triple-phase boundaries (ceria|electron conductor|gas) as well as at the interfaces between the different components (ceria

Chemical vapor deposition of germanium-rich CrGe_x nanowires

• Vladislav Dřínek,
• Stanislav Tiagulskyi,
• Roman Yatskiv,
• Jan Grym,
• Radek Fajgar,
• Věra Jandová,
• Martin Koštejn and
• Jaroslav Kupčík

Beilstein J. Nanotechnol. 2021, 12, 1365–1371, doi:10.3762/bjnano.12.100

• in mind that the melting point of nanodroplets may be reduced by hundreds of kelvins [19]. Tapering of the CrGex coating is observed during the whole experiment as Cr and Ge atoms migrate from the NW bottom and/or are transferred directly from the gas phase [20]. Several attempts were made to

• with the Ga+ focused ion beam (FIB), gas injection system (GIS), and nanomanipulator OmniProbe 400 (Oxford Instruments) with a tungsten tip. The nanomanipulator enabled a direct contact of single as-grown NWs. The current–voltage (I–V) characteristics were measured using a Keithley 237 source

Identifying diverse metal oxide nanomaterials with lethal effects on embryonic zebrafish using machine learning

• Richard Liam Marchese Robinson,
• Haralambos Sarimveis,
• Philip Doganis,
• Xiaodong Jia,
• Marianna Kotzabasaki,
• Christiana Gousiadou,
• Stacey Lynn Harper and
• Terry Wilkins

Beilstein J. Nanotechnol. 2021, 12, 1297–1325, doi:10.3762/bjnano.12.97

• ].) Here, molecular descriptors were calculated for the gas phase, neutral forms of the molecular constituents of the surface components. (This approach is similar to previous modelling studies of NBI Knowledgebase data, where, in addition to exploring the identities of the surface functional groups as

• variables related to biological effects, surface chemical composition was encoded using molecular descriptors computed for the gas phase molecules [28][29], with pH value-dependent ionization state reported to have been taken into account in one study [29].) In reality, these molecules are likely to be

A review on slip boundary conditions at the nanoscale: recent development and applications

• Ruifei Wang,
• Jin Chai,
• Bobo Luo,
• Xiong Liu,
• Jianting Zhang,
• Min Wu,
• Mingdan Wei and
• Zhuanyue Ma

Beilstein J. Nanotechnol. 2021, 12, 1237–1251, doi:10.3762/bjnano.12.91

• Ruifei Wang Jin Chai Bobo Luo Xiong Liu Jianting Zhang Min Wu Mingdan Wei Zhuanyue Ma Shaanxi Key Laboratory of Well Stability and Fluid & Rock Mechanics in Oil and Gas Reservoirs, College of Petroleum Engineering, Xi’an Shiyou University, 710065, China Research Institute of Exploration and

• liquid–liquid or liquid–gas interface rather than at the liquid–solid interface, as shown in Figure 1c. It should be noted that the value of the apparent slip length can be positive or negative. For a negative apparent slip length, or negative slip length for short, the no-slip boundary condition holds

• at the liquid–liquid interface with a thin immobile liquid layer in the vicinity of the solid surface. In practice, however, the actual flow system is complex owing to the heterogeneous and rough surfaces, or to the existence of gas bubbles. Therefore, the slip length may be nonuniformly distributed

Morphology-driven gas sensing by fabricated fractals: A review

• Vishal Kamathe and
• Rupali Nagar

Beilstein J. Nanotechnol. 2021, 12, 1187–1208, doi:10.3762/bjnano.12.88

• connectors that structurally bridge the gap between the nano- and the macroscopic worlds and have a hybrid structure of pores and repeating units. This article presents a comprehensive review on inorganic fabricated fractals (fab-fracs) synthesized in labs and employed as gas sensors across materials

• , morphologies, and gas analytes. The focus is to investigate the morphology-driven gas response of these fab-fracs and identify key parameters of fractal geometry in influencing gas response. Fab-fracs with roughened microstructure, pore-network connectivity, and fractal dimension (D) less than 2 are projected

• to be possessing better gas sensing capabilities. Fab-fracs with these salient features will help in designing the commercial gas sensors with better performance. Keywords: adsorption sites; fabricated fractal; fractal dimension; gas sensor; morphology; pore network; recovery time; response time

The effect of cobalt on morphology, structure, and ORR activity of electrospun carbon fibre mats in aqueous alkaline environments

• Markus Gehring,
• Tobias Kutsch,
• Osmane Camara,
• Alexandre Merlen,
• Hermann Tempel,
• Hans Kungl and
• Rüdiger-A. Eichel

Beilstein J. Nanotechnol. 2021, 12, 1173–1186, doi:10.3762/bjnano.12.87

• , especially the lithium and silicon systems, on account of their different mechanism involving the cathode as an explicit reaction site of the metal redox chemistry [7][8][9]. From a scientific point of view, in aqueous systems, an air electrode needs to allow gas to diffuse in appropriate amounts towards the

Irradiation-driven molecular dynamics simulation of the FEBID process for Pt(PF₃)₄

• Alexey Prosvetov,
• Alexey V. Verkhovtsev,
• Gennady Sushko and
• Andrey V. Solov’yov

Beilstein J. Nanotechnol. 2021, 12, 1151–1172, doi:10.3762/bjnano.12.86

• loss spectra for Pt(PF3)4 molecules in the gas phase were measured experimentally and compared with time-dependent DFT (TDDFT) calculations in [26]. In the simulations presented below two values of the energy deposited into the molecule, namely 205 kcal/mol (8.9 eV) and 300 kcal/mol (13 eV) were

• selected. These values correspond to positions of the peaks in the experimentally measured electron energy loss spectra for Pt(PF3)4 [26]. Step 3. Initial state of the system In FEBID experiments precursor molecules are delivered through the gas injection system and fill the scanning electron microscope

• chamber. Depending on the experimental conditions (temperature, precursor gas pressure, geometry, and position of the gas inlet), precursor molecules adsorb on the substrate surface and form a thin (from sub-monolayer to several monolayer thickness) film. An explicit evaluation of adsorption and

Criteria ruling particle agglomeration

• Dieter Vollath

Beilstein J. Nanotechnol. 2021, 12, 1093–1100, doi:10.3762/bjnano.12.81

• . Synthesis of larger particles may be carried out in the gas phase, where the probability of collision is controlled by the geometry of the particles or forces among the particles [1]. Alternatively, in case of existing particles, the agglomeration is controlled by the minimum of free enthalpy. In this case

An overview of microneedle applications, materials, and fabrication methods

• Zahra Faraji Rad,
• Philip D. Prewett and
• Graham J. Davies

Beilstein J. Nanotechnol. 2021, 12, 1034–1046, doi:10.3762/bjnano.12.77

• after micropores have been formed by the insertion of microneedles [12]. Therapeutics pre-coated on solid microneedles may dissolve off them after insertion into the skin. Gas-jet dry coating [56], liquid methods including repeated immersion and dip-in coating [57][58], and spray coating [56][59] are

• chamber where a plasma of reactive ions is formed on the material surface. Etching can be either isotropic, at higher gas pressures, or anisotropic when lower pressures are employed. The most common silicon etchant is sulphur hexafluoride (SF6 + O2) in an inductively coupled plasma etch tool. High aspect

• ratio etches are achieved by multiplex switching of gas feed between SF6 + O2 (etch) and C4F8 (sidewall passivation) in the Bosch process [86][87]. Dry etching allows better control over microneedle density and geometry and the absence of crystal plane effects allows microneedles with cylindrical

Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries

• Marina Tabuyo-Martínez,
• Bernd Wicklein and
• Pilar Aranda

Beilstein J. Nanotechnol. 2021, 12, 995–1020, doi:10.3762/bjnano.12.75

• storage systems is essential for sustainable development [1][2]. Not only would it allow for a longer operation range of electronic devices such as mobile consumer electronics, electric vehicles, and stationary energy storage systems. It would also reduce fossil fuel reliance and greenhouse gas emissions

• elemental sulfur at 450 °C for 6 h in an inert gas atmosphere. Both electrodes exhibit an excellent cycling performance because the shuttle effect and the low conductivity of elemental sulfur are avoided [39][40]. However, its applicability is hindered due to the low capacity values achieved. The former