Natural nanofibers embedded in the seed mucilage envelope: composite hydrogels with specific adhesive and frictional properties

• Agnieszka Kreitschitz and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2024, 15, 1603–1618, doi:10.3762/bjnano.15.126

• allows one to maintain the original 3D ultrastructure of the samples without collapsing after dehydration [40][41]. When hydrated hydrogel-like CNFs are gently dried using CPD, the result is an aerogel-like material [41][42] with extremely interesting frictional properties [43]. The cell wall is a

• the hydrated CNFs was an aerogel-like material with large surface area [41]. The freeze-drying process causes the formation of ice crystals, which destroy the delicate ultrastructure of the studied material [70]. As mentioned before, the mucilage envelope represents a special type of secondary cell

Aero-ZnS prepared by physical vapor transport on three-dimensional networks of sacrificial ZnO microtetrapods

• Veaceslav Ursaki,
• Tudor Braniste,
• Victor Zalamai,
• Emil Rusu,
• Vladimir Ciobanu,
• Vadim Morari,
• Daniel Podgornii,
• Pier Carlo Ricci,
• Rainer Adelung and
• Ion Tiginyanu

Beilstein J. Nanotechnol. 2024, 15, 490–499, doi:10.3762/bjnano.15.44

• phase content of the prepared aerogels by the duration of the technological procedure. A scheme of deep energy levels and electronic transitions in the ZnS skeleton of the aeromaterial was deduced from the PL analysis, suggesting that the produced aerogel is a potential candidate for photocatalytic and

Application of nanoarchitectonics in moist-electric generation

• Jia-Cheng Feng and
• Hong Xia

Beilstein J. Nanotechnol. 2022, 13, 1185–1200, doi:10.3762/bjnano.13.99

• . Wang; X. Ma; M. Li; C. Li, “Asymmetric ionic aerogel of biologic nanofibrils for harvesting electricity from moisture“, article no. 104610, Copyright Elsevier (2020). This content is not subject to CC BY 4.0. (e) Schematic diagram of a fabricated power generator with a g-PDA film and two spiral

Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries

• Marina Tabuyo-Martínez,
• Bernd Wicklein and
• Pilar Aranda

Beilstein J. Nanotechnol. 2021, 12, 995–1020, doi:10.3762/bjnano.12.75

• discharge process. Ma et al. [34] reported a conductive and flexible graphene aerogel cathode that effectively tolerated the volume changes under stabilization of the structure and led to an outstanding performance, showing an initial discharge capacity of 572.8 mAh·g−1 at 5C and an extremely low average

• that exhibited a capacity of 906 mAh·g−1 at 0.1C and a long cycling life. Another carbon–Co structure was reported by Ma et al. [34] who developed a cathode made of a flexible graphene aerogel matrix that shows an extremely low capacity fading of 0.01% per cycle from 200 to 1000 cycles (Figure 6B

• ). This performance was attributed to the enhanced reaction kinetics caused by the incorporated CoNPs and the accommodation of volume changes enabled by the flexible aerogel. Also, transition metal nanoclusters that are smaller than nanoparticles were shown to enhance sulfur reactivity and avoid the

Paper-based triboelectric nanogenerators and their applications: a review

• Jing Han,
• Nuo Xu,
• Yuchen Liang,
• Mei Ding,
• Junyi Zhai,
• Qijun Sun and
• Zhong Lin Wang

Beilstein J. Nanotechnol. 2021, 12, 151–171, doi:10.3762/bjnano.12.12

• schematic illustration of a TENG electrochemical system (including a TENG, a rectifier and a capacitor), which was used to improve the capacitance of the CNT electrode by PANI electropolymerization [162]. The TENG powering component was comprised of a cellulose/BaTiO3 aerogel paper as the positive friction

ZnO and MXenes as electrode materials for supercapacitor devices

• Ameen Uddin Ammar,
• Ipek Deniz Yildirim,
• Feray Bakan and
• Emre Erdem

Beilstein J. Nanotechnol. 2021, 12, 49–57, doi:10.3762/bjnano.12.4

• conditions of the MXene aerogel architectures affect the capacitance of the supercapacitor. MXene aerogels with lamellar structures were fabricated through the unidirectional freeze casting of 2D Ti3C2Tx aqueous colloidal suspensions. A maximum capacitance of 380 F·g−1 was measured with excellent cyclic

High-performance asymmetric supercapacitor made of NiMoO₄ nanorods@Co₃O₄ on a cellulose-based carbon aerogel

• Meixia Wang,
• Jing Zhang,
• Xibin Yi,
• Benxue Liu,
• Xinfu Zhao and
• Xiaochan Liu

Beilstein J. Nanotechnol. 2020, 11, 240–251, doi:10.3762/bjnano.11.18

• new nanoporous material comprising NiMoO4 nanorods and Co3O4 nanoparticles derived from ZIF-67 supported by a cellulose-based carbon aerogel (CA) has been successfully synthesized using a two-step hydrothermal method. Due to its chemical composition, the large specific surface and the hierarchical

• 2000 cycles), indicating its wide applicability in energy storage. Finally, our results provide a general approach to the construction of CA and MOF-based composite materials with hierarchical porous structure for potential applications in supercapacitors. Keywords: carbon aerogel; hierarchically

• but also provide 3D pathways for fast electrolyte ion diffusion and electron transport. To date, Ni foam [27], copper grid [28] and titanium mesh [29] have been mostly selected as collectors, whereas the high cost of these materials limited their practical application. Carbon aerogel (CA) has been

Graphene-enhanced metal oxide gas sensors at room temperature: a review

• Dongjin Sun,
• Yifan Luo,
• Marc Debliquy and
• Chao Zhang

Beilstein J. Nanotechnol. 2018, 9, 2832–2844, doi:10.3762/bjnano.9.264

• rGO, the large specific surface area of the composite sensor also contributed to the high response. Liu et al. [68] developed a 3D ZnO–rGO aerogel by heating (200 °C for 10 h) a mixture of ZnCl2, GO, sodium acetate and sodium citrate in an autoclave. Different from other drying processes, the hybrids

• room-temperature sensor composed of a 3D graphene aerogel and SnO2 nanoparticles, synthesized via the method mentioned above, exhibited a higher response to NO2 and faster response/recovery times than a 2D SnO2–graphene sensor, fabricated by the same method without freeze-drying process. Titanium

Nanocellulose: Recent advances and its prospects in environmental remediation

• Katrina Pui Yee Shak,
• Yean Ling Pang and
• Shee Keat Mah

Beilstein J. Nanotechnol. 2018, 9, 2479–2498, doi:10.3762/bjnano.9.232

• a specific type of nanocellulose-based material (either aerogel sorbents or adsorbents only) [11][20][21] or a specific type of treatment under environmental remediation (e.g., water treatment only) [22][23]. This review aims to provide an overview of the recent development and prospects of various

• investigated for their potential as adsorbent, catalyst, and membrane. BC-based adsorbent, catalyst, and aerogel membrane were applied for the removal of copper and lead [47], dye removal [44], and membrane distillation [48]. Ultimately, the current goal in BC production is linked to resolving the challenging

Anchoring Fe₃O₄ nanoparticles in a reduced graphene oxide aerogel matrix via polydopamine coating

• Błażej Scheibe,
• Radosław Mrówczyński,
• Natalia Michalak,
• Karol Załęski,
• Michał Matczak,
• Mateusz Kempiński,
• Zuzanna Pietralik,
• Mikołaj Lewandowski,
• Stefan Jurga and
• Feliks Stobiecki

Beilstein J. Nanotechnol. 2018, 9, 591–601, doi:10.3762/bjnano.9.55

• magnetic actuators. However, the tendency of magnetite particles to migrate within the matrix and, ultimately, escape from the aerogel structure, remains a technological challenge. In this article we show that coating magnetite particles with polydopamine anchors them on graphene oxide defects

• , immobilizing the particles in the matrix and, at the same time, improving the aerogel structure. Polydopamine coating does not affect the magnetic properties of magnetite particles, making the fabricated materials promising for industrial applications. Keywords: aerogel; composite; Fe3O4 nanoparticles

• ; polydopamine; reduced graphene oxide; Introduction Preparation of hybrid aerogels based on two-dimensional carbon nanomaterials with unique physicochemical properties is among the most popular recent nanotechnological trends [1]. With this respect, graphene oxide (GO) is one of the most exploited aerogel

Ultralight super-hydrophobic carbon aerogels based on cellulose nanofibers/poly(vinyl alcohol)/graphene oxide (CNFs/PVA/GO) for highly effective oil–water separation

• Zhaoyang Xu,
• Huan Zhou,
• Sicong Tan,
• Xiangdong Jiang,
• Weibing Wu,
• Jiangtao Shi and
• Peng Chen

Beilstein J. Nanotechnol. 2018, 9, 508–519, doi:10.3762/bjnano.9.49

• 10.3762/bjnano.9.49 Abstract With the worsening of the oil-product pollution problem, oil–water separation has attracted increased attention in recent years. In this study, a porous three-dimensional (3D) carbon aerogel based on cellulose nanofibers (CNFs), poly(vinyl alcohol) (PVA) and graphene oxide (GO

• ° (super-hydrophobic) and high oil absorption capacity (97 times its own weight). The carbonization treatment of the CNF/PVA/GO aerogel not only improved the hydrophobic properties but also enhanced the adsorption capacity and specific surface area. Given the many good performance characteristics and the

• facile preparation process of carbon aerogels, these materials are viable candidates for use in oil–water separation and environmental protection. Keywords: 3D network structure; carbon aerogel; cellulose nanofibers; graphene oxide; oil absorption; poly(vinyl alcohol); Introduction In recent years, oil

Engineering of oriented carbon nanotubes in composite materials

• Razieh Beigmoradi,
• Abdolreza Samimi and
• Davod Mohebbi-Kalhori

Beilstein J. Nanotechnol. 2018, 9, 415–435, doi:10.3762/bjnano.9.41

• CNT fibers are fabricated by drawing an aerogel of CNTs from the gas phase during growth [44]. The drawing orients the CNT bundles and can be combined with other techniques to fabricate diverse composites. The experimental works indicate the ability of the method to produce continuous CNT fibers with

Design of photonic microcavities in hexagonal boron nitride

• Sejeong Kim,
• Milos Toth and
• Igor Aharonovich

Beilstein J. Nanotechnol. 2018, 9, 102–108, doi:10.3762/bjnano.9.12

• cavity (and a similar effect is expected for the other cavities as well). This is, however, not a significant problem as the transfer of hBN flakes onto holey substrates is a straightforward process. Furthermore, use of aerogel material that is currently commercially available is another option to

L-Lysine-grafted graphene oxide as an effective adsorbent for the removal of methylene blue and metal ions

• Yan Yan,
• Jie Li,
• Fangbei Kong,
• Kuankuan Jia,
• Shiyu He and
• Baorong Wang

Beilstein J. Nanotechnol. 2017, 8, 2680–2688, doi:10.3762/bjnano.8.268

• graphene oxide (GO) with malononitrile can increase the solubility in either organic or aqueous environments [21]. However, no practical application for the malononitrile-modified GO was described. Interestingly, Ma et al. reported an polyethyleneimine-functionalized ultra-light graphene aerogel (PFGA

Two-dimensional carbon-based nanocomposites for photocatalytic energy generation and environmental remediation applications

• Suneel Kumar,
• Ashish Kumar,
• Ashish Bahuguna,
• Vipul Sharma and
• Venkata Krishnan

Beilstein J. Nanotechnol. 2017, 8, 1571–1600, doi:10.3762/bjnano.8.159

Synthesis of graphene–transition metal oxide hybrid nanoparticles and their application in various fields

• Arpita Jana,
• Elke Scheer and
• Sebastian Polarz

Beilstein J. Nanotechnol. 2017, 8, 688–714, doi:10.3762/bjnano.8.74

• superior electrical performance because the porous nature of the hybrid accommodates the volume change [146]. Wu et al. have use 3D N-doped graphene aerogel (GA) supported Fe3O4 NPs (Fe3O4/N-GA) as efficient cathode catalysts for ORR [147]. This Fe3O4/N-GA material shows excellent electrocatalytic activity

• applications [165]. This aerogel structure exhibits excellent rate capability and outstanding long-term cyclic stability at high current densities. Wang et al. have introduced a solvothermal-induced self-assembly approach to construct the monolithic 3D Fe2O3 and GS hybrids, which have excellent prolonged

The longstanding challenge of the nanocrystallization of 1,3,5-trinitroperhydro-1,3,5-triazine (RDX)

• Florent Pessina and
• Denis Spitzer

Beilstein J. Nanotechnol. 2017, 8, 452–466, doi:10.3762/bjnano.8.49

• . By drying with heating or at low pressure, a xerogel with higher density is obtained. If supercritical CO2 is used to extract the solvent, an aerogel with low density is formed. Therefore, the nanostructured nature of the explosive comes from the porous matrix: cavities of mesoporous gels are 2 to 50

• nm large and less than 2 nm for microporous gels. Macroporous materials have pore diameters greater than 50 nm [26]. An RDX/resorcinol formaldehyde (RF) nanocomposite has been synthesized [27] where 38 nm RDX crystallized in an RF aerogel matrix with a surface area of 551.5 m2/g (measurement taken

Synthesis and applications of carbon nanomaterials for energy generation and storage

• Marco Notarianni,
• Jinzhang Liu,
• Kristy Vernon and
• Nunzio Motta

Beilstein J. Nanotechnol. 2016, 7, 149–196, doi:10.3762/bjnano.7.17

Biopolymer colloids for controlling and templating inorganic synthesis

• Laura C. Preiss,
• Katharina Landfester and
• Rafael Muñoz-Espí

Beilstein J. Nanotechnol. 2014, 5, 2129–2138, doi:10.3762/bjnano.5.222

• example of a heterogeneous catalyst was reported by Taubert’s group with gold/cellulose nanocrystal hybrids produced in the presence of ionic liquids [88]. Also for catalytic applications, nanoparticles of silver, gold, and platinum were synthesized by using a cellulose aerogel [89]. Cellulose has been

• further used for silicates. Zhang et al. [90] presented the in situ formation of silica in a cellulose aerogel (Figure 8). The addition of the silicate precursor (TEOS) takes place first, followed by a sol–gel process and the cellulose/silica composite formation. The aerogel is formed by drying with

• . Reprinted with permission from [87]. Copyright 2008 John Wiley & Sons. Schematic representation of aerogel preparation. A nanoporous cellulose gel is impregnated with the silica precursor TEOS (a). Afterwards, the silica formation takes place by sol–gel process (hydrolysis and condensation), yielding a

Synthesis and catalytic applications of combined zeolitic/mesoporous materials

• Jarian Vernimmen,
• Vera Meynen and
• Pegie Cool

Beilstein J. Nanotechnol. 2011, 2, 785–801, doi:10.3762/bjnano.2.87

• technique with potential health, safety and environmental issues, because of the high production costs and the need for extensive combustion to remove the carbon [50]. Aerogel, polymer, resin and biological templates can also be used as hard templates [20][47], although the number of publications is lower