Zeolite materials with Ni and Co: synthesis and catalytic potential in the selective hydrogenation of citral

• Inocente Rodríguez-Iznaga,
• Yailen Costa Marrero,
• Tania Farias Piñeira,
• Céline Fontaine,
• Lexane Paget,
• Beatriz Concepción Rosabal,
• Arbelio Penton Madrigal,
• Vitalii Petranovskii and
• Gwendoline Lafaye

Beilstein J. Nanotechnol. 2025, 16, 520–529, doi:10.3762/bjnano.16.40

• with Ni2+ and Co2+ chloride solutions through traditional ion exchange (IE) and impregnation (Imp) processes. Special attention was given to analyzing the cationic and anionic composition of the resulting materials. The catalytic potential was evaluated in the selective hydrogenation of citral, focused

• produce unsaturated alcohols, suggesting that synergistic Ni–Co interactions played a role in their formation. Keywords: citral hydrogenation; cobalt–nickel mixture; impregnation; ion exchange; natural zeolite; Introduction Numerous publications in the literature highlight zeolites modified with

• metallic species for various applications, leading to the invention of new functional materials for sustainable development, such as catalysts [1][2][3]. Among the various methods used to modify zeolites, ion exchange is the most widely employed. Different ion exchange methods are known, such as ion

Theoretical study of the electronic and optical properties of a composite formed by the zeolite NaA and a magnetite cluster

• Joel Antúnez-García,
• Roberto Núñez-González,
• Vitalii Petranovskii,
• H’Linh Hmok,
• Armando Reyes-Serrato,
• Fabian N. Murrieta-Rico,
• Mufei Xiao and
• Jonathan Zamora

Beilstein J. Nanotechnol. 2025, 16, 44–53, doi:10.3762/bjnano.16.5

• characteristics of zeolites depend largely on the chemical composition of the framework, specifically the Si/Al ratio [1][2]. These characteristics make zeolites highly appealing for a wide range of applications, including the production of fine chemicals [3][4], gas separation [5][6][7], ion exchange [8][9][10

• ]. Because of the remarkable ion-exchange capacity of zeolites, their large surface area, and the well-organized porous systems with molecular sieve functionality, zeolites have long been fruitfully used in important industrial applications, mainly related to catalysis and wastewater treatment. The rapid

Classification and application of metal-based nanoantioxidants in medicine and healthcare

• Nguyen Nhat Nam,
• Nguyen Khoi Song Tran,
• Tan Tai Nguyen,
• Nguyen Ngoc Trai,
• Nguyen Phuong Thuy,
• Hoang Dang Khoa Do,
• Nhu Hoa Thi Tran and
• Kieu The Loan Trinh

Beilstein J. Nanotechnol. 2024, 15, 396–415, doi:10.3762/bjnano.15.36

• nanomaterials with more hydroxy groups in the stoichiometric composition generally tend to exhibit higher CAT activity because hydroxy groups enhance ion exchange on the surface of nanomaterials by providing active sites [35][36]. The CAT-like activity was also investigated in copper-based nanomaterials by

Isolation of cubic Si₃P₄ in the form of nanocrystals

• Polina K. Nikiforova,
• Sergei S. Bubenov,
• Vadim B. Platonov,
• Andrey S. Kumskov,
• Nikolay N. Kononov,
• Tatyana A. Kuznetsova and
• Sergey G. Dorofeev

Beilstein J. Nanotechnol. 2023, 14, 971–979, doi:10.3762/bjnano.14.80

• number of potential benefits to both science and industry. These methods often employ new strategies for the synthesis of specific classes of substances. For example, the widely known development of perovskite synthesis through ion exchange reactions has attracted attention in scientific as well as

Metal-organic framework-based nanomaterials for CO₂ storage: A review

• Ha Huu Do,
• Iqra Rabani and
• Hai Bang Truong

Beilstein J. Nanotechnol. 2023, 14, 964–970, doi:10.3762/bjnano.14.79

• the linker molecules but have also involved the metal ions. For example, Lau et al. used an ion exchange strategy to boost the amount of adsorbed CO2 in UiO-66 (Figure 4) [38]. After replacing approximately 50% of the Zr4+ ions in UiO-66 with Ti4+, a significant increase in CO2 adsorption capacity (81

• view of the channels displaying the cylindrical pores. Figure 3 was reprinted with permission from [34]. Copyright 2015 American Chemical Society. This content is not subject to CC BY 4.0. Graphic illustration of the ion exchange by Ti(IV) in UiO-66. Figure 4 was republished with permission of The

Nanoarchitectonics to entrap living cells in silica-based systems: encapsulations with yolk–shell and sepiolite nanomaterials

• Celia Martín-Morales,
• Jorge Fernández-Méndez,
• Pilar Aranda and
• Eduardo Ruiz-Hitzky

Beilstein J. Nanotechnol. 2023, 14, 522–534, doi:10.3762/bjnano.14.43

• culture medium and used immediately for gel synthesis. In parallel, the gel precursor was prepared from 37% (v/v) commercial sodium silicate, which was ion-exchanged using a custom-made acidic ion exchange column. After ion exchange, the resulting silica precursor was mixed with LUDOX® TMA silica

Recent trends in Bi-based nanomaterials: challenges, fabrication, enhancement techniques, and environmental applications

• Vishal Dutta,
• Ankush Chauhan,
• Ritesh Verma,
• C. Gopalkrishnan and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 1316–1336, doi:10.3762/bjnano.13.109

• applications [62]. A very good micro-/nanoscale hierarchical Bi7O9I3/NTC photocatalyst was created in a one-step, easy, and environmentally friendly way by Hou et al., who used an in situ ion exchange–recrystallization approach [63]. The used buffer provided a relatively stable environment for producing

Application of nanoarchitectonics in moist-electric generation

• Jia-Cheng Feng and
• Hong Xia

Beilstein J. Nanotechnol. 2022, 13, 1185–1200, doi:10.3762/bjnano.13.99

• gradient structure can be constructed relative to any direction in space to meet the needs. Moisture-electric conversion devices in nanofluids have also been recently reported. An ionic liquid film of Omim+ Cl− was selected as the ion-exchange layer [88]. In a moisture-gradient environment (Figure 9) on

Fate and transformation of silver nanoparticles in different biological conditions

• Barbara Pem,
• Marija Ćurlin,
• Darija Domazet Jurašin,
• Valerije Vrček,
• Rinea Barbir,
• Vedran Micek,
• Raluca M. Fratila,
• Jesus M. de la Fuente and
• Ivana Vinković Vrček

Beilstein J. Nanotechnol. 2021, 12, 665–679, doi:10.3762/bjnano.12.53

• association of Ag with sulphur and the formation of Ag2S granules from ion exchange or Ag–thiol complexes is known as sulphidation [28][29]. However, many other scenarios should be considered during an in vivo journey of AgNPs and Ag+ ions, especially their interactions with biomolecules, such as lipids

Self-standing heterostructured NiC_x-NiFe-NC/biochar as a highly efficient cathode for lithium–oxygen batteries

• Shengyu Jing,
• Xu Gong,
• Shan Ji,
• Linhui Jia,
• Bruno G. Pollet,
• Sheng Yan and
• Huagen Liang

Beilstein J. Nanotechnol. 2020, 11, 1809–1821, doi:10.3762/bjnano.11.163

• structure. As shown in the inset of Figure 2d, the main diffraction peaks of the Ni–Fe PBA precursor are consistent with the standard patterns of Ni3[Fe(CN)6]2 (JCPDS: 51-1897). During a hydrothermal pretreatment, the ion-exchange reaction of OH−/[Fe(CN)6]3− occurred at the interface between NiFe-PBA cubes

• activity. In this work, during hydrothermal pretreatment, the ion-exchange reaction of OH−/[Fe(CN)6]3− occurred at the interface between NiFe-PBA cubes and NaOH solution, resulting in Ni(OH)2/NiFe-PBA core–shell structure [44][45][46]. During the calcination process, Ni(OH)2 was converted to NiCx, and the

Plant growth regulation by seed coating with films of alginate and auxin-intercalated layered double hydroxides

• Vander A. de Castro,
• Valber G. O. Duarte,
• Danúbia A. C. Nobre,
• Geraldo H. Silva,
• Vera R. L. Constantino,
• Frederico G. Pinto,
• Willian R. Macedo and
• Jairo Tronto

Beilstein J. Nanotechnol. 2020, 11, 1082–1091, doi:10.3762/bjnano.11.93

• (CO32− ≈ SO42− > Cl−). According to the authors, this is related to the ion exchange capacity of the interfering anions. To the best of our knowledge, this is the first study reporting the direct application of an organic–inorganic hybrid with NAA intercalated into a LDH in the evaluation of plant

Atomic layer deposition for efficient oxygen evolution reaction at Pt/Ir catalyst layers

• Stefanie Schlicht,
• Korcan Percin,
• Stefanie Kriescher,
• André Hofer,
• Claudia Weidlich,
• Matthias Wessling and
• Julien Bachmann

Beilstein J. Nanotechnol. 2020, 11, 952–959, doi:10.3762/bjnano.11.79

• conditions. For example, in vanadium–air redox flow batteries the crossover of vanadium ions through the ion exchange membrane renders the electrolyte even more corrosive. To simulate electrode ageing under accelerated conditions, we study the activity loss of catalyst-coated electrodes after soaking for one

Synthesis of highly active ETS-10-based titanosilicate for heterogeneously catalyzed transesterification of triglycerides

• Muhammad A. Zaheer,
• David Poppitz,
• Khavar Feyzullayeva,
• Marianne Wenzel,
• Jörg Matysik,
• Radomir Ljupkovic,
• Aleksandra Zarubica,
• Alexander A. Karavaev,
• Andreas Pöppl,
• Roger Gläser and
• Muslim Dvoyashkin

Beilstein J. Nanotechnol. 2019, 10, 2039–2061, doi:10.3762/bjnano.10.200

• -synthetic modification of the ETS-10: an ion-exchange method [27], acidic treatment [28][29], and treatment with hydrogen peroxide (H2O2) [26][30][31]. The latter approach resulted in a notable pore network modification by introducing larger micropores (≈1–2 nm) and mesopores (≈5–30 nm) in a controllable

• temperatures [52], ion exchange [53][54], UV [55] or γ-irradiation [51]. To characterize the state of Ti in the titanosilicates participating in catalytic tests and the possible presence of impurities, the EPR spectra of these samples were measured at 70 K (Figure 14). The spectrum of the parent K,Na-ETS-10

Layered double hydroxide/sepiolite hybrid nanoarchitectures for the controlled release of herbicides

• Ediana Paula Rebitski,
• Margarita Darder and
• Pilar Aranda

Beilstein J. Nanotechnol. 2019, 10, 1679–1690, doi:10.3762/bjnano.10.163

• coprecipitation step by assembling magnesium–aluminum layered double hydroxides (MgAl-LDH) and a sepiolite fibrous clay, with the simultaneous encapsulation of the herbicide 2-methyl-4-chlorophenoxyacetic acid (MCPA) as the MgAl-LDH retains its ion exchange properties. The synthetic procedure was advantageous in

• comparison to the incorporation of MCPA by ion exchange after the formation of the LDH/sepiolite nanoarchitecture in a previous step, as it was less time consuming and gave rise to a higher loading of MCPA. The resulting MCPA-LDH/sepiolite nanoarchitectures were characterized by various physicochemical

• characteristic sandrose structure surrounding the clay fibers [31]. The resulting materials may show dual ion exchange behavior due to the anion and cation exchange properties of LDH and sepiolite components, respectively. This type of nanoarchitectonic materials could be of interest as adsorbents for the

Photoactive nanoarchitectures based on clays incorporating TiO₂ and ZnO nanoparticles

• Eduardo Ruiz-Hitzky,
• Pilar Aranda,
• Marwa Akkari,
• Nithima Khaorapapong and
• Makoto Ogawa

Beilstein J. Nanotechnol. 2019, 10, 1140–1156, doi:10.3762/bjnano.10.114

• irradiation (Table 1). Among the 2D clay-based solids (layered silicates), montmorillonite and other smectites used for assembly with diverse NPs exhibit excellent adsorption, rheological, ion-exchange, and swelling properties as well as a large relative surface area for incorporating the NPs. Kaolinite clay

• presents lower values of ion-exchange capacity and a smaller relative surface area as, in general, the interactions only involve its external surface. However, the latter aluminosilicate shows a chemical inertness that is useful for its use as support of the semiconducting NPs considered here. According to

• their unique structural and textural features. It is well known that these silicates show different nanostructures and particle shapes, such as lamellar (smectites and kaolinites), fibrous (sepiolite and palygorskite), and tubular (halloysite) morphologies (Figure 1). Mainly on the basis of the ion

Enhanced inhibition of influenza virus infection by peptide–noble-metal nanoparticle conjugates

• Zaid K. Alghrair,
• David G. Fernig and
• Bahram Ebrahimi

Beilstein J. Nanotechnol. 2019, 10, 1038–1047, doi:10.3762/bjnano.10.104

• then further separated from excess ligands by applying them (100 µL) to a 5 mL Sephadex G25 gel filtration column with PBS as a mobile phase. Ion-exchange chromatography Ion-exchange chromatography was performed on custom-made mini columns of diethylaminoethyl (DEAE) and carboxymethyl (CM) Sepharose

Outstanding chain-extension effect and high UV resistance of polybutylene succinate containing amino-acid-modified layered double hydroxides

• Adam A. Marek,
• Vincent Verney,
• Christine Taviot-Gueho,
• Grazia Totaro,
• Laura Sisti,
• Annamaria Celli and
• Fabrice Leroux

Beilstein J. Nanotechnol. 2019, 10, 684–695, doi:10.3762/bjnano.10.68

• preparation involving soft chemistry routes. Layered double hydroxides can be obtained as naturally existing materials or can be produced by synthetic routes (e.g., co-precipitation or ion exchange). They are also known as anionic clays or hydrotalcite-like materials and are described by the general formula

Nanocellulose: Recent advances and its prospects in environmental remediation

• Katrina Pui Yee Shak,
• Yean Ling Pang and
• Shee Keat Mah

Beilstein J. Nanotechnol. 2018, 9, 2479–2498, doi:10.3762/bjnano.9.232

• sulphate groups. Alternatively, amine modification aids the chelating action on the desired pollutant anions, thereby enhancing the adsorption capacity of the nanocellulose adsorbent materials. Metal ions can adsorb onto the adsorbent via electrostatic interaction and ion exchange since amino groups are

Lead-free hybrid perovskites for photovoltaics

• Oleksandr Stroyuk

Beilstein J. Nanotechnol. 2018, 9, 2209–2235, doi:10.3762/bjnano.9.207

Filling nanopipettes with apertures smaller than 50 nm: dynamic microdistillation

• Evelyne Salançon and
• Bernard Tinland

Beilstein J. Nanotechnol. 2018, 9, 2181–2187, doi:10.3762/bjnano.9.204

• is recorded at the same time. The first measurement is made directly after the first electrolyte loading at a concentration of [KCl] = 10−4 mol·L−1. This first electrical measurement confirms that the nanopipette is filled: The current flows and ion exchange is ensured between the Ag/AgCl electrodes

• performed (Figure 2b), i.e., ion exchange is enforced through voltage applied for a given time. Here, electromigration is performed by maintaining the power supply at V = −300 mV over a period of time of t = 10 min. During these 10min, the intensity level increases from I−300mV = −30 pA to an upper limit of

Cr(VI) remediation from aqueous environment through modified-TiO₂-mediated photocatalytic reduction

• Rashmi Acharya,
• Brundabana Naik and
• Kulamani Parida

Beilstein J. Nanotechnol. 2018, 9, 1448–1470, doi:10.3762/bjnano.9.137

• industrial processes pose threat to aquatic life and downstream users. Various treatment techniques, such as chemical reduction, ion exchange, bacterial degradation, adsorption and photocatalysis, have been exploited for remediation of Cr(VI) from wastewater. Among these, photocatalysis has recently gained

• pollutants and has mandated a maximum acceptable concentration of 50 μg L−1 in potable water [13][14][15]. Therefore, it is now of great importance to explore the efficient and economical ways for the treatment of Cr(VI)-rich wastewater. Various techniques, such as chemical reduction, ion exchange, bacterial

Ag₂WO₄ nanorods decorated with AgI nanoparticles: Novel and efficient visible-light-driven photocatalysts for the degradation of water pollutants

• Shijie Li,
• Shiwei Hu,
• Wei Jiang,
• Yanping Liu,
• Yu Liu,
• Yingtang Zhou,
• Liuye Mo and
• Jianshe Liu

Beilstein J. Nanotechnol. 2018, 9, 1308–1316, doi:10.3762/bjnano.9.123

• , to enhance the photocatalytic performance of Ag2WO4, AgI (possessing matched energy band levels) was chosen as a suitable component to combine with Ag2WO4, AgI/Ag2WO4 heterojunctions at different mole ratios. These heterojunctions were prepared via an in situ ion-exchange approach, utilizing Ag2WO4

A review of carbon-based and non-carbon-based catalyst supports for the selective catalytic reduction of nitric oxide

• Shahreen Binti Izwan Anthonysamy,
• Syahidah Binti Afandi,
• Mehrnoush Khavarian and
• Abdul Rahman Bin Mohamed

Beilstein J. Nanotechnol. 2018, 9, 740–761, doi:10.3762/bjnano.9.68

• temperature window of 150–500 °C in a diesel engine as well as the low energy consumption and economy of NH3-SCR [9]. In the literature, abundant catalysts at low temperature have been explored such as transitional metals (Mn, Cu, Ce, Fe, Co, Mo) [10][11][12][13], novel metals (Pt, Pd) [14], and metal ion

• -exchange zeolite catalysts [15]. The Mn-based catalyst is one of the most active metal oxide catalysts for high N2 selectivity at low temperature and is recognised by many researchers as a potential alternative for the common catalyst. Jin et al. [16] successfully used a Mn-based catalyst with the addition

Photocatalytic and adsorption properties of TiO₂-pillared montmorillonite obtained by hydrothermally activated intercalation of titanium polyhydroxo complexes

• Mikhail F. Butman,
• Nikolay L. Ovchinnikov,
• Nikita S. Karasev,
• Nataliya E. Kochkina,
• Alexander V. Agafonov and
• Alexandr V. Vinogradov

Beilstein J. Nanotechnol. 2018, 9, 364–378, doi:10.3762/bjnano.9.36

• distribution curve features a peak at 1.5 nm, which corresponds to polymeric forms of the (TiO)8(OH)124+ polycations, as mentioned previously [8][26]. Intercalated and TiO2-pillared montmorillonite The intercalation of montmorillonite with titanium polyhydroxo complexes was performed by ion exchange in a 1

Laser-assisted fabrication of gold nanoparticle-composed structures embedded in borosilicate glass

• Nikolay Nedyalkov,
• Mihaela Koleva,
• Nadya Stankova,
• Rosen Nikov,
• Mitsuhiro Terakawa,
• Yasutaka Nakajima,
• Lyubomir Aleksandrov and
• Reni Iordanova

Beilstein J. Nanotechnol. 2017, 8, 2454–2463, doi:10.3762/bjnano.8.244

• , ion exchange, and co-deposition [12][13][14] have been developed, major requirements for production efficiency, including reducing production time and cost, have yet to be met. The existing technologies cannot provide efficient control and reproducibility of the spatial characteristics of complex 3D