Various CVD-grown ZnO nanostructures for nanodevices and interdisciplinary applications

• The-Long Phan,
• Le Viet Cuong,
• Vu Dinh Lam and
• Ngoc Toan Dang

Beilstein J. Nanotechnol. 2024, 15, 1390–1399, doi:10.3762/bjnano.15.112

• combs, there is also a sword-like nanocrystal, see Figure 6c. It is the comb ribbon formed before the teeth are constituted and developed. Combs reported by research groups have various morphologies and sizes, remarkably depending on fabrication conditions [46][52][53][54][55][56][57]. They are highly

Fabrication of nanocrystal forms of ᴅ-cycloserine and their application for transdermal and enteric drug delivery systems

• Hsuan-Ang Tsai,
• Tsai-Miao Shih,
• Theodore Tsai,
• Jhe-Wei Hu,
• Yi-An Lai,
• Jui-Fu Hsiao and
• Guochuan Emil Tsai

Beilstein J. Nanotechnol. 2024, 15, 465–474, doi:10.3762/bjnano.15.42

• and then to the in vitro Franz diffusion test with reservoir patch formulation as well as in vivo pharmacokinetics study with enteric capsules. We tested these formulations regarding their nanocrystal physical properties, size effect, and dissolution rate, respectively. We found that DCS nanocrystals

• showed good performance in the Franz diffusion test and rodent pharmacokinetic studies due to the nanoparticle size and faster dissolution as compared with the commercial DCS powder. These DCS nanocrystal formulations could offer a new approach for the development of an advanced drug delivery system for

• Franz diffusion cell system. Formulation of nanocrystal DCS and commercial DCS powder in enteric capsules Size 9 empty porcine hard gelatin capsules (Torpac) were used for the following experiments. The modified enteric capsules contained one of the nanocrystal forms or the commercial DCS powder, which

Nanomedicines against Chagas disease: a critical review

• Maria Jose Morilla,
• Kajal Ghosal and
• Eder Lilia Romero

Beilstein J. Nanotechnol. 2024, 15, 333–349, doi:10.3762/bjnano.15.30

• marketed nanocrystals are for intramuscular injection and provide long-time delivery of drugs such as paliperidone palmitate, an atypical antipsychotic, or antiretrovirals. Excluding the anti-fungal griseofulvin (not a nanocrystal, but a micrometer-sized crystal), and anti-retrovirals, the remaining drugs

Non-stoichiometric magnetite as catalyst for the photocatalytic degradation of phenol and 2,6-dibromo-4-methylphenol – a new approach in water treatment

• Joanna Kisała,
• Anna Tomaszewska and
• Przemysław Kolek

Beilstein J. Nanotechnol. 2022, 13, 1531–1540, doi:10.3762/bjnano.13.126

• catalysts were semiconductors rather than conductors. The morphology of the Fe3O4 catalysts is shown in Figure 2. The images show nanocrystal agglomerates with particle sizes of 100–400 nm for M1 and of 25–100 nm for M2 (Figure 2). The aggregation of M2 particles is much stronger than that of M1. Hence, M2

The effect of metal surface nanomorphology on the output performance of a TENG

• Yiru Wang,
• Xin Zhao,
• Yang Liu and
• Wenjun Zhou

Beilstein J. Nanotechnol. 2022, 13, 298–312, doi:10.3762/bjnano.13.25

• can be concluded that nanocrystal strips can yield a good electron output. Due to the different surface contact charge densities of the copper nanoscale morphology, under pressure, the curved PTFE structure transfers more friction charges, which contributes greatly to improving the output performance

Theranostic potential of self-luminescent branched polyethyleneimine-coated superparamagnetic iron oxide nanoparticles

• Rouhollah Khodadust,
• Ozlem Unal and
• Havva Yagci Acar

Beilstein J. Nanotechnol. 2022, 13, 82–95, doi:10.3762/bjnano.13.6

• capping layer from the nanocrystal and perform image processing on a squire containing two particles protruding under vacuum using a high-resolution transmission electron microscope. For this purpose, a reduced fast Fourier transform (FFT) of a region containing two SPION@bPEI crystal particles protrude

Plasmon-enhanced photoluminescence from TiO₂ and TeO₂ thin films doped by Eu³⁺ for optoelectronic applications

• Marcin Łapiński,
• Jakub Czubek,
• Katarzyna Drozdowska,
• Anna Synak,
• Wojciech Sadowski and
• Barbara Kościelska

Beilstein J. Nanotechnol. 2021, 12, 1271–1278, doi:10.3762/bjnano.12.94

• centrosymmetric structures. This led to the conclusion that there might be some nanocrystal areas in the TiO2:Eu films. It is in line with our previous structural investigations. XRD measurements showed an amorphous or nanocrystalline structure of the oxide layers deposited by magnetron sputtering [31]. The

Use of nanosystems to improve the anticancer effects of curcumin

• Andrea M. Araya-Sibaja,
• Norma J. Salazar-López,
• Krissia Wilhelm Romero,
• José R. Vega-Baudrit,
• J. Abraham Domínguez-Avila,
• Carlos A. Velázquez Contreras,
• Ramón E. Robles-Zepeda,
• Mirtha Navarro-Hoyos and
• Gustavo A. González-Aguilar

Beilstein J. Nanotechnol. 2021, 12, 1047–1062, doi:10.3762/bjnano.12.78

• of a drug which is stabilized by the use of surfactants [48]. Therefore, a nanosuspension can be prepared by dispersing a nanocrystal or any other powdered material in an outer liquid medium using a stabilizing agent [45]. Furthermore, these nanosystems have shown increased adhesion to surfaces. The

• cancer cells (HCT116) by promoting cell cycle arrest at the G2/M phase [49]. A CUR nanocrystal has been successfully prepared using melt sonocrystallization, in which its therapeutic potential was evidenced according to in vitro cytotoxicity studies against a human oral cancer cell line (KB). The results

• showed a growth inhibition (GI50) value <10 µg/mL, enhanced inhibition of proliferation, and higher cytotoxicity as compared to free CUR (F-CUR) [50]. Hu et al. [51] formulated a nanocrystal with curcumin and yttrium-stabilized zirconium oxide, which maintained the stability of CUR for 60 days (at 25 °C

A Au/CuNiCoS₄/p-Si photodiode: electrical and morphological characterization

• Adem Koçyiğit,
• Adem Sarılmaz,
• Teoman Öztürk,
• Faruk Ozel and
• Murat Yıldırım

Beilstein J. Nanotechnol. 2021, 12, 984–994, doi:10.3762/bjnano.12.74

• ± 1 nm. An interplanar spacing of d = 2.87 Å, corresponding to the (113) planes of the cubic crystal structure, was determined from the HR-TEM image in Figure 2c. Figure 2d shows a FE-SEM images of the agglomerated nanocrystals. The surface of the CuNiCoS4 nanocrystal layers is smooth and free from

A review of defect engineering, ion implantation, and nanofabrication using the helium ion microscope

• Frances I. Allen

Beilstein J. Nanotechnol. 2021, 12, 633–664, doi:10.3762/bjnano.12.52

• analysis of an isolated silicon nanocrystal from this work is shown in Figure 4c. The authors highlighted that the demonstration presents a promising new technique for the fabrication of single-electron transistor devices. This work is also closely related to the magnetic property tuning by Röder et al

Stability and activity of platinum nanoparticles in the oxygen electroreduction reaction: is size or uniformity of primary importance?

• Kirill O. Paperzh,
• Anastasia A. Alekseenko,
• Vadim A. Volochaev,
• Ilya V. Pankov,
• Olga A. Safronenko and
• Vladimir E. Guterman

Beilstein J. Nanotechnol. 2021, 12, 593–606, doi:10.3762/bjnano.12.49

• . Apparently, the degradation of the catalysts is not only due to a decrease in the ESA, but also due to a decrease in the fraction of the nanocrystal surface, which belongs to the regions with the highest catalytic activity. At the same time, the mass activity of the G series catalysts exceeds the mass

ZnO and MXenes as electrode materials for supercapacitor devices

• Ameen Uddin Ammar,
• Ipek Deniz Yildirim,
• Feray Bakan and
• Emre Erdem

Beilstein J. Nanotechnol. 2021, 12, 49–57, doi:10.3762/bjnano.12.4

• ≈ 2.004, which is very close to the value of g of free electrons. The surface defects accumulated in the shell of the nanocrystal give a value of g similar to that of free electrons due to their delocalization [2][3][5]. This information can only be obtained via EPR spectroscopy. The intensity of the

Bio-imaging with the helium-ion microscope: A review

• Matthias Schmidt,
• James M. Byrne and
• Ilari J. Maasilta

Beilstein J. Nanotechnol. 2021, 12, 1–23, doi:10.3762/bjnano.12.1

Magnetic-field-assisted synthesis of anisotropic iron oxide particles: Effect of pH

• Andrey V. Shibaev,
• Petr V. Shvets,
• Darya E. Kessel,
• Roman A. Kamyshinsky,
• Anton S. Orekhov,
• Sergey S. Abramchuk,
• Alexei R. Khokhlov and
• Olga E. Philippova

Beilstein J. Nanotechnol. 2020, 11, 1230–1241, doi:10.3762/bjnano.11.107

• properties is the pH during synthesis. This is due to the fact that the OH− ion concentration in the reaction mixture controls the reaction rate and, therefore, the nanocrystal growth mechanism. For instance, Ahn et al. [31] studied the formation of magnetite nanoparticles by performing co-precipitation

Implementation of data-cube pump–probe KPFM on organic solar cells

• Benjamin Grévin,
• Olivier Bardagot and
• Renaud Demadrille

Beilstein J. Nanotechnol. 2020, 11, 323–337, doi:10.3762/bjnano.11.24

• ][14] and nanocrystal-based [15] solar cells. However, there are some disadvantages to using this technique. First, at specific frequencies, the excitation signal used to generate charge carriers can interfere [16] with the cantilever oscillation or the ac voltage applied for the detection of the CPD

Nitrogen-vacancy centers in diamond for nanoscale magnetic resonance imaging applications

• Alberto Boretti,
• Lorenzo Rosa,
• Jonathan Blackledge and
• Stefania Castelletto

Beilstein J. Nanotechnol. 2019, 10, 2128–2151, doi:10.3762/bjnano.10.207

• . These dark defects limit the use of NVs in NDs for magnetic imaging. The composition and spin dynamics of a particle-hosted spin bath are examined in [62] by ODMR inside a 45 nm diamond nanocrystal, revealing nitrogen donors and an unidentified class of paramagnetic centers. Both show a spin lifetime

Preservation of rutin nanosuspensions without the use of preservatives

• Pascal L. Stahr and
• Cornelia M. Keck

Beilstein J. Nanotechnol. 2019, 10, 1902–1913, doi:10.3762/bjnano.10.185

• formulations. The destabilizing effect of PLX 188 in combination with other excipients in nanocrystal formulations was also shown by a study of Beirowski and co-workers, who showed that some combinations of poloxamer and cryoprotectant were unsuitable for stabilizing nanocrystals during a freezing process [22

Photoactive nanoarchitectures based on clays incorporating TiO₂ and ZnO nanoparticles

• Eduardo Ruiz-Hitzky,
• Pilar Aranda,
• Marwa Akkari,
• Nithima Khaorapapong and
• Makoto Ogawa

Beilstein J. Nanotechnol. 2019, 10, 1140–1156, doi:10.3762/bjnano.10.114

• (G) montmorillonite and (H) sepiolite clay minerals. TEM images of (A) ZnO NPs on montmorillonite with nanocrystal aggregation; reprinted with permission from [85], copyright 2004 American Chemical Society; (B) TiO2@HNTs nanoarchitecture showing the titania NP assembled inside the lumen of the

Structural and optical properties of penicillamine-protected gold nanocluster fractions separated by sequential size-selective fractionation

• Xiupei Yang,
• Zhengli Yang,
• Fenglin Tang,
• Jing Xu,
• Maoxue Zhang and
• Martin M. F. Choi

Beilstein J. Nanotechnol. 2019, 10, 955–966, doi:10.3762/bjnano.10.96

• ) structure of Au nanocrystal whereas the high-magnification TEM image also shows very clear fringes of the AuNC. These results infer that our AuNC product consists of highly crystalline nanocrystals. Figure 2B depicts the histogram of the size distribution obtained from the HRTEM image. The AuNC product

Magnetic field-assisted assembly of iron oxide mesocrystals: a matter of nanoparticle shape and magnetic anisotropy

• Julian J. Brunner,
• Marina Krumova,
• Helmut Cölfen and
• Elena V. Sturm (née Rosseeva)

Beilstein J. Nanotechnol. 2019, 10, 894–900, doi:10.3762/bjnano.10.90

• to further design novel superstructures including mesocrystals with outstanding morphologies and orientational relations of nanocrystals, which cannot be formed otherwise. In our previous study, the iron oxide nanocrystal synthesis and characterization as well as the formation of self-assembled

• within the superlattices remarkably differentiates from that obtained without magnetic field. For the formation of “directed mesocrystals”, a nanocrystal dispersion was left to dry within a homogeneous magnetic field (Figure 1). The homogenous magnetic field with a field strength is 120 mT was created by

• ) indicate the presence of the additional nanocrystal orientations within the mesocrystalline structure (aligned perpendicular to the substrate). The additional diffraction reflections can be indexed as [112]magnetite and [114]magnetite zone axis, indicating that some particles within adjacent layers orient

Site-specific growth of oriented ZnO nanocrystal arrays

• Rekha Bai,
• Dinesh K. Pandya,
• Sujeet Chaudhary,
• Veer Dhaka,
• Vladislav Khayrudinov,
• Jori Lemettinen,
• Christoffer Kauppinen and
• Harri Lipsanen

Beilstein J. Nanotechnol. 2019, 10, 274–280, doi:10.3762/bjnano.10.26

• electrodeposition technique. Further, vertically aligned periodic nanocrystal (NC) growth is engineered at predefined positions on polymer-coated ITO substrates patterned with ordered pores. The vertical alignment of ZnO NCs along the c-axis is achieved via ion-by-ion nucleation-controlled growth for patterned

• decreasing the growth temperature and growth rate); cost-effective (due to employing a simple electrolytic bath cell and current source) and ability to grow various nanostructures at ambient pressure and temperature. Moreover, the directed nanocrystal growth can be accomplished on a substrate, rather than in

• the solution. Furthermore, from the current reported work it is quite difficult to conclude about the nature of twinning, that is, whether twinning appears by joining two NCs or if a single nanocrystal gives rise to the twinned crystal. However, in the electrodeposition technique, since the growth

Zn/F-doped tin oxide nanoparticles synthesized by laser pyrolysis: structural and optical properties

• Florian Dumitrache,
• Iuliana P. Morjan,
• Elena Dutu,
• Ion Morjan,
• Claudiu Teodor Fleaca,
• Monica Scarisoreanu,
• Alina Ilie,
• Marius Dumitru,
• Cristian Mihailescu,
• Adriana Smarandache and
• Gabriel Prodan

Beilstein J. Nanotechnol. 2019, 10, 9–21, doi:10.3762/bjnano.10.2

• SnO2 in its undoped form is an n-type semiconductor with a direct bandgap of 3.6 eV at room temperature. Its n-type conductivity is due to oxygen vacancies in its rutile structure. The bandgap, starting from the bulk value, increases as the size of the nanocrystal decreases, due to electron confinement

Hybrid Au@alendronate nanoparticles as dual chemo-photothermal agent for combined cancer treatment

• Anouchka Plan Sangnier,
• Romain Aufaure,
• Laurence Motte,
• Claire Wilhelm,
• Erwann Guenin and
• Yoann Lalatonne

Beilstein J. Nanotechnol. 2018, 9, 2947–2952, doi:10.3762/bjnano.9.273

• suggest that alendronate was grafted onto the nanocrystal surface through the phosphonate groups and could be activated for further biocoupling [10]. The excellent coating density led to a good colloidal stability, as confirmed by dynamic light scattering (DLS) measurements at physiological pH values. A

Site-controlled formation of single Si nanocrystals in a buried SiO₂ matrix using ion beam mixing

• Xiaomo Xu,
• Thomas Prüfer,
• Daniel Wolf,
• Hans-Jürgen Engelmann,
• Lothar Bischoff,
• René Hübner,
• Karl-Heinz Heinig,
• Wolfhard Möller,
• Stefan Facsko,
• Johannes von Borany and
• Gregor Hlawacek

Beilstein J. Nanotechnol. 2018, 9, 2883–2892, doi:10.3762/bjnano.9.267

• irradiation area with a width of 4 nm. After RTA treatment, a single Si NC was isolated and observed in a TEM lamella. This result is corroborated by comparing the simulated and measured Si plasmon-loss signal for a single Si nanocrystal. The NC is centered between the adjacent Si/SiO2 interfaces at the

Comparative biological effects of spherical noble metal nanoparticles (Rh, Pd, Ag, Pt, Au) with 4–8 nm diameter

• Alexander Rostek,
• Marina Breisch,
• Kevin Pappert,
• Kateryna Loza,
• Marc Heggen,
• Manfred Köller,
• Christina Sengstock and
• Matthias Epple

Beilstein J. Nanotechnol. 2018, 9, 2763–2774, doi:10.3762/bjnano.9.258

• , the equilibrium shape of a nanocrystal can be predicted by minimization of the surface free energy of the crystal for a given enclosed volume. According to the Wulff construction, face-centered cubic (fcc) crystals tend to form truncated octahedral particles with large {111} and small {100} surfaces