Electrosynthesis II
Johannes Gutenberg-Universität Mainz
Since electricity will be the prime energy of the future being provided mostly by regenerative resources such as wind power and photovoltaics, its direct use in chemical conversion represents a reemerging field in chemical synthesis. Electro-organic synthesis as methodology is inherently safe, outstanding sustainable because reagent waste is avoided. Novel concepts for electrolytes, strategies for reaction screening, and electrode materials pave the way to a disruptive synthetic methodology which might be a game changer for future chemistry. The articles will deal with the latest electrosynthetic innovations and electro-organic transformations.
Synthesis of naturally-derived macromolecules through simplified electrochemically mediated ATRP
- Paweł Chmielarz,
- Tomasz Pacześniak,
- Katarzyna Rydel-Ciszek,
- Izabela Zaborniak,
- Paulina Biedka and
- Andrzej Sobkowiak
Beilstein J. Org. Chem. 2017, 13, 2466–2472, doi:10.3762/bjoc.13.243
The selective electrochemical fluorination of S-alkyl benzothioate and its derivatives
- Shunsuke Kuribayashi,
- Tomoyuki Kurioka,
- Shinsuke Inagi,
- Ho-Jung Lu,
- Biing-Jiun Uang and
- Toshio Fuchigami
Beilstein J. Org. Chem. 2018, 14, 389–396, doi:10.3762/bjoc.14.27
Functionalization of N-arylglycine esters: electrocatalytic access to C–C bonds mediated by n-Bu4NI
- Mi-Hai Luo,
- Yang-Ye Jiang,
- Kun Xu,
- Yong-Guo Liu,
- Bao-Guo Sun and
- Cheng-Chu Zeng
Beilstein J. Org. Chem. 2018, 14, 499–505, doi:10.3762/bjoc.14.35
An alternative to hydrogenation processes. Electrocatalytic hydrogenation of benzophenone
- Cristina Mozo Mulero,
- Alfonso Sáez,
- Jesús Iniesta and
- Vicente Montiel
Beilstein J. Org. Chem. 2018, 14, 537–546, doi:10.3762/bjoc.14.40
Electrochemical Corey–Winter reaction. Reduction of thiocarbonates in aqueous methanol media and application to the synthesis of a naturally occurring α-pyrone
- Ernesto Emmanuel López-López,
- José Alvano Pérez-Bautista,
- Fernando Sartillo-Piscil and
- Bernardo A. Frontana-Uribe
Beilstein J. Org. Chem. 2018, 14, 547–552, doi:10.3762/bjoc.14.41
Investigating radical cation chain processes in the electrocatalytic Diels–Alder reaction
- Yasushi Imada,
- Yohei Okada and
- Kazuhiro Chiba
Beilstein J. Org. Chem. 2018, 14, 642–647, doi:10.3762/bjoc.14.51
Stepwise radical cation Diels–Alder reaction via multiple pathways
- Ryo Shimizu,
- Yohei Okada and
- Kazuhiro Chiba
Beilstein J. Org. Chem. 2018, 14, 704–708, doi:10.3762/bjoc.14.59
Anodic oxidation of bisamides from diaminoalkanes by constant current electrolysis
- Tatiana Golub and
- James Y. Becker
Beilstein J. Org. Chem. 2018, 14, 861–868, doi:10.3762/bjoc.14.72
Electrochemically modified Corey–Fuchs reaction for the synthesis of arylalkynes. The case of 2-(2,2-dibromovinyl)naphthalene
- Fabiana Pandolfi,
- Isabella Chiarotto and
- Marta Feroci
Beilstein J. Org. Chem. 2018, 14, 891–899, doi:10.3762/bjoc.14.76
Polysubstituted ferrocenes as tunable redox mediators
- Sven D. Waniek,
- Jan Klett,
- Christoph Förster and
- Katja Heinze
Beilstein J. Org. Chem. 2018, 14, 1004–1015, doi:10.3762/bjoc.14.86
Stereoselective nucleophilic addition reactions to cyclic N-acyliminium ions using the indirect cation pool method: Elucidation of stereoselectivity by spectroscopic conformational analysis and DFT calculations
- Koichi Mitsudo,
- Junya Yamamoto,
- Tomoya Akagi,
- Atsuhiro Yamashita,
- Masahiro Haisa,
- Kazuki Yoshioka,
- Hiroki Mandai,
- Koji Ueoka,
- Christian Hempel,
- Jun-ichi Yoshida and
- Seiji Suga
Beilstein J. Org. Chem. 2018, 14, 1192–1202, doi:10.3762/bjoc.14.100
Spectroelectrochemical studies on the effect of cations in the alkaline glycerol oxidation reaction over carbon nanotube-supported Pd nanoparticles
- Dennis Hiltrop,
- Steffen Cychy,
- Karina Elumeeva,
- Wolfgang Schuhmann and
- Martin Muhler
Beilstein J. Org. Chem. 2018, 14, 1428–1435, doi:10.3762/bjoc.14.120
Cobalt–metalloid alloys for electrochemical oxidation of 5-hydroxymethylfurfural as an alternative anode reaction in lieu of oxygen evolution during water splitting
- Jonas Weidner,
- Stefan Barwe,
- Kirill Sliozberg,
- Stefan Piontek,
- Justus Masa,
- Ulf-Peter Apfel and
- Wolfgang Schuhmann
Beilstein J. Org. Chem. 2018, 14, 1436–1445, doi:10.3762/bjoc.14.121
Direct electrochemical generation of organic carbonates by dehydrogenative coupling
- Tile Gieshoff,
- Vinh Trieu,
- Jan Heijl and
- Siegfried R. Waldvogel
Beilstein J. Org. Chem. 2018, 14, 1578–1582, doi:10.3762/bjoc.14.135
Synergistic electrodeposition of bilayer films and analysis by Raman spectroscopy
- Saadeldin E. T. Elmasly,
- Luca Guerrini,
- Joseph Cameron,
- Alexander L. Kanibolotsky,
- Neil J. Findlay,
- Karen Faulds and
- Peter J. Skabara
Beilstein J. Org. Chem. 2018, 14, 2186–2189, doi:10.3762/bjoc.14.191
