Structure-dependent thermochromism of PAZO thin films: theory and experiment

• Georgi Mateev,
• Dean Dimov,
• Nataliya Berberova-Buhova,
• Nikoleta Kircheva,
• Todor Dudev,
• Ludmila Nikolova,
• Elena Stoykova,
• Keehoon Hong,
• Dimana Nazarova,
• Silvia Angelova and
• Lian Nedelchev

Beilstein J. Nanotechnol. 2026, 17, 186–199, doi:10.3762/bjnano.17.12

• thickness, and thermal treatment conditions. The observed changes in optical properties suggest that this response is governed by temperature-induced modulation of molecular ordering and aggregation state, which in turn alters the electronic transitions responsible for light absorption. Theoretical

• thin layers subjected to thermal treatment at temperatures up to 300 °C. Particular attention is given to the changes in absorption features and spectral shifts that may arise from structural rearrangements within the material. To rationalize the experimental findings, density functional theory (DFT

• undergo photoinduced isomerization in the temperature range of 280–300 °C, even though some chemical changes cannot be completely ruled out. According to differential thermal (DTA) and thermogravimetric (TGA) analyses, PAZO remains chemically stable up to about 280 °C, with indications of decomposition

From shield to spear: Charge-reversible nanocarriers in overcoming cancer therapy barriers

• Madhuri Yeduvaka,
• Pooja Mittal,
• Ameer Boyalakuntla,
• Usman Bee Shaik,
• Himanshu Sharma,
• Thakur Gurjeet Singh,
• Siva Nageswara Rao Gajula and
• Lakshmi Vineela Nalla

Beilstein J. Nanotechnol. 2026, 17, 159–175, doi:10.3762/bjnano.17.10

• doxorubicin release at temperatures of ≥44 °C, effectively targeting resistant and quiescent cancer stem cells. Combined TR-DOXO and magnetic field treatment achieved complete tumour inhibition in mice, demonstrating strong hyperthermia–chemotherapy synergy [67]. The combination of magnetic targeting, thermal

Functional surface engineering for cultural heritage protection: the role of superhydrophobic and superoleophobic coatings – a comprehensive review

• Giuseppe Cesare Lama,
• Marino Lavorgna,
• Letizia Verdolotti,
• Federica Recupido,
• Giovanna Giuliana Buonocore and
• Bharat Bhushan

Beilstein J. Nanotechnol. 2026, 17, 63–96, doi:10.3762/bjnano.17.6

• transparency; however, several limitations can be highlighted. The resins are not always compatible with metal patina [49] and are also easily prone to yellowing due to ageing from ultraviolet (UV) radiation or thermal stress [50], while the waxes guarantee a protection from corrosion, but only in the early

• presented a multifunctional thermal insulation coating incorporating modified vacuum ceramic microbeads (VCMs) to enhance energy efficiency and protection of concrete structures. The VCMs were modified through the polymerization of catechol and hexamethylene diamine, forming a thin poly(catecholamine) (PCA

• ) layer. Subsequently, the authors incorporated the PCA-coated VCMs into a polydimethylsiloxane (PDMS) matrix, significantly reducing the thermal conductivity of the coatings and improving their surface hydrophobicity. The coating provided robust protection for concrete, enhancing abrasion resistance and

Reduced graphene oxide paper electrode for lithium-ion cells – towards optimized thermal reduction

• Agata Pawłowska,
• Magdalena Baran,
• Stefan Marynowicz,
• Aleksandra Izabela Banasiak,
• Adrian Racki,
• Adrian Chlanda,
• Tymoteusz Ciuk,
• Marta Wolczko and
• Andrzej Budziak

Beilstein J. Nanotechnol. 2026, 17, 24–37, doi:10.3762/bjnano.17.3

• electrode material in lithium-ion cells. Mildly reduced graphene oxide paper underwent further thermal reduction steps. The structural and chemical properties of the obtained materials were determined using Raman and Fourier-transform infrared spectroscopies and elemental combustion analysis. The morphology

• . Keywords: electrode material; graphene paper; lithium-ion batteries; reduced graphene oxide; thermal reduction; Introduction Electrode materials comprising reduced graphene oxide (rGO) for energy storage in lithium-ion-based or sodium-ion-based technologies have been the subject of over 3800 publications

• description of oxygen species and their behavior during the thermal annealing of GO, allowing them to specify a temperature range expected to provide optimal type and amount of oxygen species [27]. According to this article, the desired ketone groups partially remain, while carboxyl, epoxy, and hydroxy groups

Quantitative estimation of nanoparticle/substrate adhesion by atomic force microscopy

• Aydan Çiçek,
• Markus Kratzer,
• Christian Teichert and
• Christian Mitterer

Beilstein J. Nanotechnol. 2026, 17, 1–14, doi:10.3762/bjnano.17.1

• . Note that consecutively recorded AFM images (see below in Figure 2) usually exhibit a slight thermal drift. However, this does not interfere with the data evaluation. During AFM manipulation, NPs do not always move along straight lines. Small deviations, jumps, or irregular paths can occur, depending

• requirements of each experimental setup. The normal spring constant was determined using the thermal sweep method [40] implemented by default in the Asylum Research MFP-3D system. Table 1 summarizes the calibration constants and applied normal forces obtained for both wedge and D-LFC methods, which were used

Internal 3D temperature mapping in biological systems using ratiometric light-sheet imaging and lipid-coated upconversion nanothermometers

• Dannareli Barron-Ortiz,
• Enric Pérez-Parets,
• Rubén D. Cadena-Nava,
• Emilio J. Gualda,
• Jacob Licea-Rodríguez,
• Juan Hernández-Cordero,
• Pablo Loza-Álvarez and
• Israel Rocha-Mendoza

Beilstein J. Nanotechnol. 2025, 16, 2306–2316, doi:10.3762/bjnano.16.159

• enables real-time thermal mapping with both high spatial and temporal resolution at the cellular and subcellular levels. To validate the method, we performed 3D temperature imaging on fixed Caenorhabditis elegans (C. elegans) after UCNP ingestion. The proposed technique represents a cutting-edge method

• from dysregulated metabolism (i.e., the Warburg effect) [3][4] and chaotic vasculature that impairs heat dissipation [5][6]. These factors can create thermal gradients of 0.5–2.0 °C between tumors and healthy tissue, with even greater differences at the subcellular level [7][8][9]. Consequently, the

• and non-biological applications. LNTs rely on the emission properties of a fluorophore and its thermal dependence to measure temperature changes, which can be measured as variations in the emission intensity [10][11][12][13] and lifetime [8][14][15][16], spectral shift [17], as well as intensity

Terahertz-range on-chip local oscillator based on Josephson junction arrays for superconducting quantum-limited receivers

• Fedor V. Khan,
• Lyudmila V. Filippenko,
• Andrey B. Ermakov,
• Mikhail Yu. Fominsky and
• Valery P. Koshelets

Beilstein J. Nanotechnol. 2025, 16, 2296–2305, doi:10.3762/bjnano.16.158

• about 1 min, and it is done after each thermal cycling [13]. Also, the ratio of the radiated power to the consumed DC power is slightly higher than 5%. Some of the aforementioned problems can be solved by the use of Josephson junction arrays as LO for the SIR. The junctions can be fabricated by the use

• ][41] formula with the differential resistance normalized to a single junction yields the value of approx. 0.1 MHz. This is somewhat lower than the experimental value, probably due to the presence of the thermal noise arising from the current flowing through the shunts and other low-frequency

• IVC of the JJ array when the PLL mode is active is shown in Figure 10. The current step induced by the PLL system is approx. 0.5 mA, which is three orders of magnitude higher than the characteristic noise level in the current bias system (≈0.5 μA) and thermal noise. This shows the robust nature of the

Improving magnetic properties of Mn- and Zn-doped core–shell iron oxide nanoparticles by tuning their size

• Dounia Louaguef,
• Ghouti Medjahdi,
• Sébastien Diliberto,
• Klaus M. Seemann,
• Thomas Gries,
• Joelle Bizeau,
• Damien Mertz,
• Eric Gaffet and
• Halima Alem

Beilstein J. Nanotechnol. 2025, 16, 2285–2295, doi:10.3762/bjnano.16.157

• , we report on the synthesis of polyhedral core–shell SPIONs. Their size was tuned to improve their magnetic properties. Furthermore, by hybridizing into a core–shell inorganic/inorganic structure, the nanoparticles can achieve significantly improved magnetic-to-thermal energy conversion efficiency (at

• focused on precise control of shape and size, critical factors for tuning magnetic behavior. By employing thermal decomposition, Zn0.4Fe2.6O4 NPs were synthesized with a well-defined polyhedral morphology, as confirmed by high-resolution transmission electron microscopy (HRTEM) (Figure 1). This morphology

• the core–shell system. Furthermore, the superparamagnetic behavior of both Zn0.4Fe2.6O4 and Zn0.4Fe2.6O4@MnFe2O4 NPs was confirmed by the absence of hysteresis in the magnetization curves. This behavior is characteristic of superparamagnetic NPs, where thermal energy is sufficient to overcome magnetic

Geometry-controlled engineering of the low-temperature proximity effect in normal metal–superconductor junctions

• Munisa A. Tomayeva,
• Vyacheslav D. Neverov,
• Andrey V. Krasavin,
• Alexei Vagov and
• Mihail D. Croitoru

Beilstein J. Nanotechnol. 2025, 16, 2265–2273, doi:10.3762/bjnano.16.155

• spatial dimensionality of the system [33], taking values of α = 1 in 3D [7][29][32], α = 1/2 in 2D [34][35], and α = 0 in 1D [36]. This behavior holds for distances z smaller than both the thermal decay length and the mean free path l = vnτ, where τ is the impurity scattering time [32]. Beyond these

Chiral plasmonic nanostructures fabricated with circularly polarized light

• Tian Qiao and
• Ming Lee Tang

Beilstein J. Nanotechnol. 2025, 16, 2245–2264, doi:10.3762/bjnano.16.154

• with large g-factors. Section 2.3 will address this issue with the strategy of modifying the surface ligands on PNSs to create chiral PNSs. The non-radiative decay of hot carriers can heat the PNSs. Due to the high thermal conductivity of metals, isolated PNSs usually feature uniform temperature

• distribution when exposed to CPL. Additionally, the local thermal effects that may lead to isotropic photochemical deposition on the achiral PNSs require further investigation and must be taken into account. Furthermore, the interactions between the achiral PNS seeds and the substrates on which they are

Optical bio/chemical sensors for vitamin B₁₂ analysis in food and pharmaceuticals: state of the art, challenges, and future outlooks

• Seyed Mohammad Taghi Gharibzahedi and
• Zeynep Altintas

Beilstein J. Nanotechnol. 2025, 16, 2207–2244, doi:10.3762/bjnano.16.153

Microplastic pollution in Himalayan lakes: assessment, risks, and sustainable remediation strategies

• Sameeksha Rawat,
• S. M. Tauseef and
• Madhuben Sharma

Beilstein J. Nanotechnol. 2025, 16, 2144–2167, doi:10.3762/bjnano.16.148

• ]. The combined analytical flow and instrumentation for MP characterization, such as digestion, preparation, and analytical processes like microscopy, spectroscopy, and thermal analysis, is presented in Figure 4. 4.3 Challenges in quantification and identification under alpine conditions MPs assessment

• samples from the environment makes nanoscale plastics yet another challenge. Sophisticated methods such as thermal extraction desorption (TED) and gas chromatography-mass spectrometry (GC-MS) are now routinely used to detect these particles. But these methods involve a lot of expertise and equipment. The

• and increases ROS generation, even below freezing temperatures. It has also been suggested that hybrid nanomaterials, which include photocatalysts and thermal insulators, can minimize the impacts of temperature during remediation while maintaining optimum activity [77]. GO–metal oxide composites are

Electron transport through nanoscale multilayer graphene and hexagonal boron nitride junctions

• Aleksandar Staykov and
• Takaya Fujisaki

Beilstein J. Nanotechnol. 2025, 16, 2132–2143, doi:10.3762/bjnano.16.147

• graphene-based electronics and as a dielectric material in nanoelectronics devices. It finds application regarding corrosion resistance and antioxidation protective coatings [19]. Due to its high thermal conductivity and electrical insulation, h-BN is used in thermal management applications. h-BN is used

• electronic properties of pristine graphene [7]. Here, we consider the effect of the Stone–Wales defect; this is a result of thermal structural isomerization of the graphene lattice where a bond is rotated by 90°, resulting to the isomerization of a 6–6 ring structure to an isoelectronic 7–5 ring structure

Quality by design optimization of microemulsions for topical delivery of Passiflora setacea seed oil

• Daniel T. Pereira,
• Douglas Dourado,
• Danielle T. Freire,
• Dayanne L. Porto,
• Cícero F. S. Aragão,
• Myla L. de Souza,
• Guilherme R. S. de Araujo,
• Ana Maria Costa,
• Wógenes N. Oliveira,
• Anne Sapin-Minet,
• Éverton N. Alencar and
• Eryvaldo Sócrates T. Egito

Beilstein J. Nanotechnol. 2025, 16, 2116–2131, doi:10.3762/bjnano.16.146

• chromatography–mass spectrometry and thermal analysis. A full factorial design, followed by a Box–Behnken design, was employed to optimize the formulation based on critical quality attributes and the defined quality target product profile. The optimized ME presented a hydrodynamic diameter of approximately 22 nm

• healing [17][18][19]. In addition to its chemical characterization, the thermal stability in inert atmosphere (N2) of OPS was assessed. Thermogravimetric analysis (TGA) revealed an initial mass loss of less than 1% (Tonset = 60 °C), likely associated with the evaporation of residual solvent entrapped in

• the oil matrix. A second thermal event began (Tonset = 384 °C) corresponding to the thermal degradation of the oil (Figure 1). This thermal behavior is consistent with that reported for P. edulis seed oil, which exhibited a similar decomposition profile [20]. Quality by design approach Defining the

Calibration of piezo actuators and systems by dynamic interferometry

• Knarik Khachatryan and
• Michael Reichling

Beilstein J. Nanotechnol. 2025, 16, 2086–2091, doi:10.3762/bjnano.16.143

• be possible to reduce the bow effect observed for the tube piezo extension by leaving more accommodation time between the voltage steps. However, in this case, thermal drift is likely to deteriorate the measurement by similar amounts as the observed creep. The fact that the measured tube piezo

Multifrequency AFM integrating PeakForce tapping and higher eigenmodes for heterogeneous surface characterization

• Yanping Wei,
• Jiafeng Shen,
• Yirong Yao,
• Xuke Li,
• Ming Li and
• Peiling Ke

Beilstein J. Nanotechnol. 2025, 16, 2077–2085, doi:10.3762/bjnano.16.142

• at least five force–distance curves acquired on a rigid sapphire surface. The standard deviation of these measurements was consistently less than 5%. Subsequently, the spring constant was calibrated using the thermal tune method. The cantilever was retracted more than 5 μm from the sample surface to

• record its thermal vibration power spectral density. A fit to the fundamental resonance peak, based on the equipartition theorem, yielded the spring constant. Characterization of higher eigenmodes The resonant frequencies of the higher eigenmodes were characterized by performing a frequency sweep using

Stereodiscrimination of guests in chiral organosilica aerogels studied by ESR spectroscopy

• Sebastian Polarz,
• Yasar Krysiak,
• Martin Wessig and
• Florian Kuhlmann

Beilstein J. Nanotechnol. 2025, 16, 2034–2054, doi:10.3762/bjnano.16.140

• (Figure 8f). The thermal energy at T = 260 K is approximately 2 kJ·mol−1. The difference in interaction enthalpies of two enantiomers with a chiral surface depends on many factors, but it is exactly in the range of 1–2 kJ·mol−1 [18][67], which we could deduce from ESR spectroscopy. If (+)-3CP is more

Beyond the shell: exploring polymer–lipid interfaces in core–shell nanofibers to carry hyaluronic acid and β-caryophyllene

• Aline Tavares da Silva Barreto,
• Francisco Alexandrino-Júnior,
• Bráulio Soares Arcanjo,
• Paulo Henrique de Souza Picciani and
• Kattya Gyselle de Holanda e Silva

Beilstein J. Nanotechnol. 2025, 16, 2015–2033, doi:10.3762/bjnano.16.139

• membrane applications. Thermal and crystalline analyses demonstrated improved thermal stability upon NE-βCp incorporation. Collectively, these results provide robust evidence for the feasibility of producing multifunctional nanofiber membranes that successfully integrate a polymer–lipid hybrid core

• the nanofiber spectra confirmed the complete encapsulation of the core material by the PLA shell. This observation aligns with the cross-sectional analysis results, where a coated core–shell structure was evident following the removal of the HA+NE2 core. Thermal behavior and crystallinity of

• nanofibers The thermal properties and crystallinity of NF-PLA (monolithic), NF-HA/PLA, and NF-HA+NE2/PLA nanofibers were analyzed using thermogravimetric analysis (TGA), X-ray diffraction (XRD), and differential scanning calorimetry (DSC). Thermal behavior and crystallinity of the nanofibers mats of βCp

Laser ablation in liquids for shape-tailored synthesis of nanomaterials: status and challenges

• Natalie Tarasenka

Beilstein J. Nanotechnol. 2025, 16, 1963–1997, doi:10.3762/bjnano.16.137

• : thermal evaporation and explosive ejection [1]. According to the thermal evaporation mechanism, the action of a laser beam on the surface of a solid target initiates the absorption of the laser pulse energy. This results in initiation of melting and ionization with the formation of a plasma plume near the

• ), the thermal evaporation is preferential [1], while for picosecond and femtosecond laser pulses of lower power density, the explosive ejection mechanism typically prevails resulting in NP formation at earlier stages from the ejected droplets or fragments. 1.3 Nanoparticle nucleation and growth After

• sufficient time for thermal processes of heating and melting to occur (Figure 7a,f). These mild conditions favour the heating and melting of NPs instead of their fragmentation, which is required for targeted shape change. The laser parameters required to melt the particles by laser pulses can be determined

Mechanical property measurements enabled by short-term Fourier-transform of atomic force microscopy thermal deflection analysis

• Thomas Mathias,
• Roland Bennewitz and
• Philip Egberts

Beilstein J. Nanotechnol. 2025, 16, 1952–1962, doi:10.3762/bjnano.16.136

• reference material, rather than calculated directly from the dynamics models of the cantilever. We measured the cantilever displacement with very high sampling frequencies over the course of the experiment and captured its oscillations that result from thermal energy. Using short-term Fourier

• transformations, it was possible to fit the thermal resonance peak of the normal displacement to track the frequency and Q-factor of the cantilever during an experiment, using a similar process to that used to calibrate the normal bending stiffness of cantilevers. With this quantitative data, we have used the

• technique, spectral analysis of the thermal motion in the deflection of AFM cantilevers has shown promise as a lower-cost, less equipment-intensive mechanism to access the dynamic and time-evolving oscillatory characteristics of the cantilever [11][12][13][14][15][16]. In these techniques, the cantilever

Quantum circuits with SINIS structures

• Mikhail Tarasov,
• Mikhail Fominskii,
• Aleksandra Gunbina,
• Artem Krasilnikov,
• Maria Mansfeld,
• Dmitrii Kukushkin,
• Andrei Maruhno,
• Valeria Ievleva,
• Mikhail Strelkov,
• Daniil Zhogov,
• Konstantin Arutyunov,
• Vyacheslav Vdovin,
• Vladislav Stolyarov and
• Valerian Edelman

Beilstein J. Nanotechnol. 2025, 16, 1931–1941, doi:10.3762/bjnano.16.134

• not very high reproducibility and stability. Another fabrication method is the Manhattan technology [28] with deep orthogonal groves in the resist, see Figure 1b,c. Both methods are based on thermal evaporation at different angles and rotation of substrate, requiring rather sophisticated and expensive

• deposition plants with thermal or e-beam evaporation. A much more available and simple deposition equipment is magnetron sputtering, but it provides only isotropic deposition, which is incompatible with anisotropic shadow evaporation. The practical solution for a magnetron sputtering is selective etching of

• electrical response to thermal heating of the absorber by direct current, for example, in [12][14][33][34][35]. But in practice, the electrical response to heating by direct current is always significantly higher than the optical response for microwave, terahertz, or IR radiation. This is explained by the

Targeting the vector of arboviruses Aedes aegypti with nanoemulsions based on essential oils: a review with focus on larvicidal and repellent properties

• Laryssa Ferreira do Nascimento Silva,
• Douglas Dourado,
• Thayse Silva Medeiros,
• Mariana Alice Gonzaga Gabú,
• Maria Cecilia Queiroga dos Santos,
• Daiane Rodrigues dos Santos,
• Mylena Lemos dos Santos,
• Gabriel Bezerra Faierstein,
• Rosângela Maria Rodrigues Barbosa and
• Fabio Rocha Formiga

Beilstein J. Nanotechnol. 2025, 16, 1894–1913, doi:10.3762/bjnano.16.132

• . aegypti mosquitoes using thermal fogging techniques in outdoor environments [104]. This superior performance was attributed to the reduced droplet size, which facilitates penetration through mesothoracic spiracles and into the inner walls of the mesothoracic trachea, thereby increasing insect mortality

• ultrasound, with a ratio of 1:0.5 (oil/surfactant, polysorbate 80) and Milli-Q water. It presented an average size of 52.18 nm (±4.53), a polydispersity index of 0.237 (±0.006), and thermal stability. In bioassays, third instar larvae exposed to concentrations between 5 and 150 ppm showed LC50 of 58.72 ppm

Low-temperature AFM with a microwave cavity optomechanical transducer

• Ermes Scarano,
• Elisabet K. Arvidsson,
• August K. Roos,
• Erik Holmgren,
• Riccardo Borgani,
• Mats O. Tholén and
• David B. Haviland

Beilstein J. Nanotechnol. 2025, 16, 1873–1882, doi:10.3762/bjnano.16.130

• noise, pointing to its crucial role in the context of force sensitivity. Through analysis of noise measurements we determine the effective temperature of the cantilever eigenmode and we determine the region of detector operation in which the sensor is thermal-noise-limited. Our analysis shows that the

• can therefore be made light and compact, significantly reducing their susceptibility to external vibrations, the complexity of vibration isolation, and their thermal mass. For this prototype, we implement a rather simple vibration isolation which, as we will show, is sufficient to demonstrate imaging

• determined by all sources of noise. The total noise can be expressed as the sum of the power spectral densities (PSDs) of uncorrelated contributions such as the thermal fluctuations in cantilever deflection (Ω) [m2/Hz] at the effective mode temperature T, measurement back action noise , and the frequency

Current status of using adsorbent nanomaterials for removing microplastics from water supply systems: a mini review

• Nguyen Thi Nhan and
• Tran Le Luu

Beilstein J. Nanotechnol. 2025, 16, 1837–1850, doi:10.3762/bjnano.16.127

• performance for six cycles with only a 5% efficiency loss, and enabled in situ degradation of MPs through thermal treatment to prevent desorption risks [75]. A high capture efficiency of microplastics was also achieved using novel magnetic composite nanoparticles composed of silica, gelatin, and chitosan. At

• degradation, indicating their potential as next-generation solutions. By using coprecipitation and thermal decomposition, Aragón et al. synthesized magnetic nanoparticles to capture PE MPs. The results demonstrated that the thermal decomposition method achieved a capture efficiency of 69.3 ± 2.1% [89

• ., “Catalytic degradation of polyethylene terephthalate microplastics by Co-N/C@CeO2 composite in thermal-assisted activation PMS system: Process mechanism and toxicological analysis”, Article No. 163192, Copyright (2025), with permission from Elsevier. This content is not subject to CC BY 4.0. Illustration of

Phytol-loaded soybean oil nanoemulsion as a promising alternative against Leishmania amazonensis

• Victória Louise Pinto Freire,
• Mariana Farias Alves-Silva,
• Johny W. de Freitas Oliveira,
• Matheus de Freitas Fernandes-Pedrosa,
• Alianda Maira Cornélio,
• Marcelo de Souza-Silva,
• Thayse Silva Medeiros and
• Arnóbio Antônio da Silva Junior

Beilstein J. Nanotechnol. 2025, 16, 1826–1836, doi:10.3762/bjnano.16.126

• thermal degradation of sensitive compounds, as well as excessive loss of volatile substances such as PHYT [30]. The small droplet size results in a large surface area, which enables effective interaction with biological membranes and consequently enhances drug penetration and retention [31]. Key