Quantification and coupling of the electromagnetic and chemical contributions in surface-enhanced Raman scattering

• Yarong Su,
• Yuanzhen Shi,
• Ping Wang,
• Jinglei Du,
• Markus B. Raschke and
• Lin Pang

Beilstein J. Nanotechnol. 2019, 10, 549–556, doi:10.3762/bjnano.10.56

• metal substrate [11][12]. Depending on the degree of EM enhancement the signal simply scales linearly in intensity. In contrast, CE in addition can give rise to changes in the spectral response in terms of peak position and line shape due to modifications in molecular structure when the molecule

Ceria/polymer nanocontainers for high-performance encapsulation of fluorophores

• Kartheek Katta,
• Dmitry Busko,
• Yuri Avlasevich,
• Katharina Landfester,
• Stanislav Baluschev and
• Rafael Muñoz-Espí

Beilstein J. Nanotechnol. 2019, 10, 522–530, doi:10.3762/bjnano.10.53

• polyoxyethanyl α-tocopheryl sebacate [37] significantly reduces oxygen quenching. Last but not least, another possibility is to attach an oxygen scavenger (e.g., diphenylanthracene moieties) to the emissive dye itself [38]. Decoration of the molecular structure of cyanine dyes including a cyclodextrin complex

• -tetramethylbutyl)phenoxy]terrylene-3,4,11,12-bis(dicarboximide) (TDI) was synthesized according to [26] (molecular structure and absorption/fluorescence emission spectra are given in Supporting Information File 1, Figures S1 and S2, respectively). The prepared TDI was dissolved in sufficient amounts of THF and

Recent highlights in nanoscale and mesoscale friction

• Andrea Vanossi,
• Dirk Dietzel,
• Andre Schirmeisen,
• Ernst Meyer,
• Rémy Pawlak,
• Thilo Glatzel,
• Marcin Kisiel,
• Shigeki Kawai and
• Nicola Manini

Beilstein J. Nanotechnol. 2018, 9, 1995–2014, doi:10.3762/bjnano.9.190

• interlocking of the RTIL molecular structure with the surface corrugation, but also by the surface charge, which is tunable (within reason) by the application of electric fields, with the effect of modifying the ordering of the boundary layers. Sliding in a confined geometry has been investigated with the

• porphyrin molecule functionalized by two meso-(3,5-dicyanophenyl) and two meso-(3,5-di-tert-butylphenyl) peripheral rings to the AFM apex, which was then dragged over the surface, as sketched in Figure 6a. Despite the complex molecular structure attached to the tip, atomic-scale patterns and sawtooth

Atomic-level characterization and cilostazol affinity of poly(lactic acid) nanoparticles conjugated with differentially charged hydrophilic molecules

• María Francisca Matus,
• Martín Ludueña,
• Cristian Vilos,
• Iván Palomo and
• Marcelo M. Mariscal

Beilstein J. Nanotechnol. 2018, 9, 1328–1338, doi:10.3762/bjnano.9.126

• selected as the best poses. Results and Discussion Poly(lactic acid) core Radius of gyration The radius of gyration (Rg) is related to the mean distance of atoms in a molecular structure with respect to its center of mass [49]. The radius of gyration is a good indicator of the spatial conformation of the

• ; oxygen–red) except the head, tail and chiral atoms. Evaluation of optimal separation distance between PLA chains. The energy was evaluated for two 20-monomer PLA chains at 3, 4, 5, 6, 7, 8, 9 and 10 Å. Molecular structure of DSPE–PEG(2000) carboxy-terminated, methoxy-terminated and amino-terminated

Chemistry for electron-induced nanofabrication

• Petra Swiderek,
• Hubertus Marbach and
• Cornelis W. Hagen

Beilstein J. Nanotechnol. 2018, 9, 1317–1320, doi:10.3762/bjnano.9.124

• may be removed more easily than previously anticipated, as exemplified by the electron-induced dissociation of benzene–Cr(CO)3 [17] and by FEBID using the fluorine-free precursor Cu(tbaoac)2 [18]. The most elegant approach to precursor design yet is to use a bimetallic molecular structure to predefine

Formation and development of nanometer-sized cybotactic clusters in bent-core nematic liquid crystalline compounds

• Yuri P. Panarin,
• Sithara P. Sreenilayam,
• Jagdish K. Vij,
• Anne Lehmann and
• Carsten Tschierske

Beilstein J. Nanotechnol. 2018, 9, 1288–1296, doi:10.3762/bjnano.9.121

• are members of a homologous series of 4-cyanoresorcinol. The molecular structure and the phase sequence of the compounds are shown in Figure 1. The first compound (BCN66) with a large flexoelectric polarization [52] is a member of the homologue series consisting of a bent core of five aromatic rings

• , enabling this finding to be used in practical devices. The molecular structure and phase transitions of two bent-core liquid crystal samples: BCN66 (m = n = 6): Cr 55 °C [37.1] NcybC 101 °C [0.5] Iso [52] and BCN84 (m = 8, n = 4): Cr 62 °C NcybC 96 °C Iso [51]. The transition temperatures were obtained on

Towards the third dimension in direct electron beam writing of silver

• Katja Höflich,
• Jakub Mateusz Jurczyk,
• Katarzyna Madajska,
• Maximilian Götz,
• Luisa Berger,
• Carlos Guerra-Nuñez,
• Caspar Haverkamp,
• Iwona Szymanska and
• Ivo Utke

Beilstein J. Nanotechnol. 2018, 9, 842–849, doi:10.3762/bjnano.9.78

• molecular structure of the precursors used. AgO2F5Prop contains only half of the amount of carbon compared to AgO2Me2Bu but a large portion of fluorine instead. Besides that the molecular structure is very similar, which leads to the expectation that also AgO2F5Prop will show a strong sensitivity to

• . Even though the molecular structure of the compounds is very similar, by varying dwell times and currents distinct differences in the deposition became obvious. AgO2Me2Bu showed strong depletion in the beam center for currents around 500 pA and no correlation of the deposit heights with the dwell time

Synthesis and characterization of two new TiO₂-containing benzothiazole-based imine composites for organic device applications

• Anna Różycka,
• Agnieszka Iwan,
• Krzysztof Artur Bogdanowicz,
• Michal Filapek,
• Natalia Górska,
• Damian Pociecha,
• Marek Malinowski,
• Patryk Fryń,
• Agnieszka Hreniak,
• Jakub Rysz,
• Paweł Dąbczyński and
• Monika Marzec

Beilstein J. Nanotechnol. 2018, 9, 721–739, doi:10.3762/bjnano.9.67

• confirm the molecular structure of investigated SP1 and SP2 compounds, FT-MIR spectroscopy was carried out at room temperature. In the case of SP1, the most intensive bands in the IR spectrum are located at 1263 and 1099 cm−1 and correspond to stretching modes ν(C–O) within the RCOOR ester and C–O–C ether

Tuning adhesion forces between functionalized gold colloidal nanoparticles and silicon AFM tips: role of ligands and capillary forces

• Sven Oras,
• Sergei Vlassov,
• Marta Berholts,
• Rünno Lõhmus and
• Karine Mougin

Beilstein J. Nanotechnol. 2018, 9, 660–670, doi:10.3762/bjnano.9.61

• of the present study. VdW calculation To validate our results, vdW force between the functionalized Au particles and AFM tip were calculated. The simulation of these dipole-induced forces involves a large number of molecular structure-specific variables. Therefore, only thiol as an example tail group

Engineering of oriented carbon nanotubes in composite materials

• Razieh Beigmoradi,
• Abdolreza Samimi and
• Davod Mohebbi-Kalhori

Beilstein J. Nanotechnol. 2018, 9, 415–435, doi:10.3762/bjnano.9.41

• molecular structure of the liquid crystal (LC) (i.e., that it can be simply oriented in the direction of an applied electric or magnetic field) the alignment and dispersion of the CNTs in a solution of liquid crystals is also achievable (Figure 15). The biggest advantage of this method is that small fields

Design of polar self-assembling lactic acid derivatives possessing submicrometre helical pitch

• Alexej Bubnov,
• Cyril Vacek,
• Michał Czerwiński,
• Terezia Vojtylová,
• Wiktor Piecek and
• Věra Hamplová

Beilstein J. Nanotechnol. 2018, 9, 333–341, doi:10.3762/bjnano.9.33

• recrystallized from methanol. The molecular structure was checked for all synthesised compounds by 1H NMR spectra recorded on a Varian VNMRS 300 instrument, where deuteriochloroform (CDCl3) served as a solvent. The signal of the solvent was used as an internal standard. The purity of the final compounds was

Wafer-scale bioactive substrate patterning by chemical lift-off lithography

• Chong-You Chen,
• Chang-Ming Wang,
• Hsiang-Hua Li,
• Hong-Hseng Chan and
• Wei-Ssu Liao

Beilstein J. Nanotechnol. 2018, 9, 311–320, doi:10.3762/bjnano.9.31

• created. This post lift-off region is found to be suitable for insertion of a variety of biological probes, which allows for the creation of different types of bioactive substrates. Depending on the modifications to the experimental conditions, the processes of direct probe insertion, molecular structure

Liquid-crystalline nanoarchitectures for tissue engineering

• Baeckkyoung Sung and
• Min-Ho Kim

Beilstein J. Nanotechnol. 2018, 9, 205–215, doi:10.3762/bjnano.9.22

• induced 2D and 3D aligned cell growth in response to the lamellar molecular structure of LCE matrices, with tunable porosity and crosslinking density [99][100][101]. In addition, the 3D anisotropic cell scaffolds can be fabricated by using nematic LCE microspheres as building blocks by tuning elastic

Electron-driven and thermal chemistry during water-assisted purification of platinum nanomaterials generated by electron beam induced deposition

• Ziyan Warneke,
• Markus Rohdenburg,
• Jonas Warneke,
• Janina Kopyra and
• Petra Swiderek

Beilstein J. Nanotechnol. 2018, 9, 77–90, doi:10.3762/bjnano.9.10

• dimer by thermal cracking above 172 °C. It was kept below −20 °C in the sample reservoir throughout the experiments to prevent the reverse reaction to the dimer. Molecular structure of the FEBID precursor trimethyl(methyl-cyclopentadienyl)platinum(IV) (MeCpPtMe3) (a), schematic of the FEBID process and

Electron beam induced deposition of silacyclohexane and dichlorosilacyclohexane: the role of dissociative ionization and dissociative electron attachment in the deposition process

• Ragesh Kumar T P,
• Sangeetha Hari,
• Krishna K Damodaran,
• Oddur Ingólfsson and
• Cornelis W. Hagen

Beilstein J. Nanotechnol. 2017, 8, 2376–2388, doi:10.3762/bjnano.8.237

• deposits on gold substrates, using an Oxford Instruments 80 mm2 detector. EDX was performed at two different incident energies of 5 keV and 20 keV, at beam currents of 1.6 nA and 240 pA, respectively. Molecular structure of (a) 1,1-dichloro-1-silacyclohexane (cyclo-C5H10SiCl2) and (b) silacyclohexane

Dissociative electron attachment to coordination complexes of chromium: chromium(0) hexacarbonyl and benzene-chromium(0) tricarbonyl

• Janina Kopyra,
• Paulina Maciejewska and
• Jelena Maljković

Beilstein J. Nanotechnol. 2017, 8, 2257–2263, doi:10.3762/bjnano.8.225

• that only one atom within the ligand binds to the central metal atom. C6H6 is a η6 (hexahapto) ligand which corresponds to a contiguous series of six atoms that coordinate to the metal center. The molecular structure of both complexes is depicted in Figure 1. Cr(CO)6 is a complex with 18 valence

Non-intuitive clustering of 9,10-phenanthrenequinone on Au(111)

• Ryan D. Brown,
• Rebecca C. Quardokus,
• Natalie A. Wasio,
• Jacob P. Petersen,
• Angela M. Silski,
• Steven A. Corcelli and
• S. Alex Kandel

Beilstein J. Nanotechnol. 2017, 8, 1801–1807, doi:10.3762/bjnano.8.181

• likely arises after adsorption of a cluster formed in solution. This behavior is not observed after the pulse deposition of 9-fluorenone (Figure 1), which indicates that the origin of this feature must be related to the molecular structure of 9,10-phenanthrenequinone. Results and Discussion Pulse

Charge transfer from and to manganese phthalocyanine: bulk materials and interfaces

• Florian Rückerl,
• Daniel Waas,
• Bernd Büchner,
• Martin Knupfer,
• Dietrich R. T. Zahn,
• Francisc Haidu,
• Torsten Hahn and
• Jens Kortus

Beilstein J. Nanotechnol. 2017, 8, 1601–1615, doi:10.3762/bjnano.8.160

• these respects. Molecular structure of (a) transition metal phthalocyanines, (b) 1,3,4,5,7,8-hexafluorotetracyanonaphthoquinodimethane (F6TCNNQ), and (c) 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4TCNQ). The transition-metal center in the phthalocyanine molecule can vary; in this work Mn

Adsorption and electronic properties of pentacene on thin dielectric decoupling layers

• Sebastian Koslowski,
• Daniel Rosenblatt,
• Alexander Kabakchiev,
• Klaus Kuhnke,
• Klaus Kern and
• Uta Schlickum

Beilstein J. Nanotechnol. 2017, 8, 1388–1395, doi:10.3762/bjnano.8.140

• in the gas phase superimposed with a ball-and-stick model of the molecular structure. Energy-level diagram depicting the relations between Ea, Ei, Φ and the energies measured in STS for the HOMO and the LUMO of pentacene. STS measurements of pentacene on various decoupling layers (see legend). In the

Deposition of exchange-coupled dinickel complexes on gold substrates utilizing ambidentate mercapto-carboxylato ligands

• Martin Börner,
• Laura Blömer,
• Marcus Kischel,
• Peter Richter,
• Georgeta Salvan,
• Dietrich R. T. Zahn,
• Pablo F. Siles,
• Maria E. N. Fuentes,
• Carlos C. B. Bufon,
• Daniel Grimm,
• Oliver G. Schmidt,
• Daniel Breite,
• Bernd Abel and
• Berthold Kersting

Beilstein J. Nanotechnol. 2017, 8, 1375–1387, doi:10.3762/bjnano.8.139

• Waals representation of the molecular structure of the [Ni2L(O2C(CH2)10SH)]+ cation in 7. The coligand is again coordinated via its carboxylate function, and the [Ni2L]2+ fragment is isostructural with that in 6. Twisting of the coligand is also encountered in this case (about the C40–C41 (β) and C41

• ) of the molecular structure of the [Ni2L(O2C(CH2)5SH)]+ cation in crystals of 6. The accessibility of the thiol head group (atom labeled S3a) is obvious from this view. Ball and stick (left) and van der Waals representations (right) of the molecular structure of the [Ni2L(O2C(CH2)10SH)]+ cation in

Charge transport in organic nanocrystal diodes based on rolled-up robust nanomembrane contacts

• Vineeth Kumar Bandari,
• Lakshmi Varadharajan,
• Longqian Xu,
• Abdur Rehman Jalil,
• Mirunalini Devarajulu,
• Pablo F. Siles,
• Feng Zhu and
• Oliver G. Schmidt

Beilstein J. Nanotechnol. 2017, 8, 1277–1282, doi:10.3762/bjnano.8.129

• including light-emitting diodes, transistors, sensors [1][2][3]. Because the large variety of physical properties can be conveniently tuned by manipulating the molecular structure, a clever design of the nanoscale device geometry opens up further intriguing options for novel applications in the fields of

Needs and challenges for assessing the environmental impacts of engineered nanomaterials (ENMs)

• Michelle Romero-Franco,
• Hilary A. Godwin,
• Muhammad Bilal and
• Yoram Cohen

Beilstein J. Nanotechnol. 2017, 8, 989–1014, doi:10.3762/bjnano.8.101

• composition, surface coating, molecular structure, crystal structure, physical, form/shape, particle size, size distribution and surface area, agglomeration state, particle density, ENM bulk density, porosity, dispersibility, solubility in water and biologically relevant fluids, surface charge, and surface

Nanoantenna-assisted plasmonic enhancement of IR absorption of vibrational modes of organic molecules

• Alexander G. Milekhin,
• Olga Cherkasova,
• Sergei A. Kuznetsov,
• Ilya A. Milekhin,
• Ekatherina E. Rodyakina,
• Alexander V. Latyshev,
• Sreetama Banerjee,
• Georgeta Salvan and
• Dietrich R. T. Zahn

Beilstein J. Nanotechnol. 2017, 8, 975–981, doi:10.3762/bjnano.8.99

• phthalocyanines. These molecules also offer the possibility of changing the spin-dependent transport mechanism by slightly modifying the molecular structure [6]. It has been previously shown that the molecular structure of a magnetic material can be probed by various spectroscopic techniques [11]. Under

Vapor-phase-synthesized fluoroacrylate polymer thin films: thermal stability and structural properties

• Paul Christian and
• Anna Maria Coclite

Beilstein J. Nanotechnol. 2017, 8, 933–942, doi:10.3762/bjnano.8.95

• deposition techniques (e.g., plasma-enhanced CVD). Therefore, depending on the application and on the desired polymer properties, one can choose to work in conditions that drive crystallinity and hydrophobicity or thermally stable surface properties instead. Molecular structure of the monomers PFDA and EGDMA

Relationships between chemical structure, mechanical properties and materials processing in nanopatterned organosilicate fins

• Gheorghe Stan,
• Richard S. Gates,
• Qichi Hu,
• Kevin Kjoller,
• Craig Prater,
• Kanwal Jit Singh,
• Ebony Mays and
• Sean W. King

Beilstein J. Nanotechnol. 2017, 8, 863–871, doi:10.3762/bjnano.8.88

• of relationships between molecular structure, physical properties and material processing at the nanoscale. Numerous metrologies capable of thermal, mechanical, and electrical characterization at the nanoscale have been demonstrated over the past two decades. However, the ability to perform nanoscale