Nanoarchitectonics of the cathode to improve the reversibility of Li–O₂ batteries

• Hien Thi Thu Pham,
• Jonghyeok Yun,
• So Yeun Kim,
• Sang A Han,
• Jung Ho Kim,
• Jong-Won Lee and
• Min-Sik Park

Beilstein J. Nanotechnol. 2022, 13, 689–698, doi:10.3762/bjnano.13.61

• metallic catalysts can also be obtained by adjusting metal ions for outstanding electrochemical reactions. In this study, various bimetallic zeolitic imidazolate framework (ZIF)-derived carbons were designed by varying the ratio of Zn to Co ions. Moreover, carbon nanotubes (CNTs) are added to improve the

• [38]. Herein, we demonstrate bimetallic ZIF-derived carbon materials to combine the advantages of both ZIF-8- and ZIF-67-derived carbon materials. For practical use, bimetallic ZIFs with different ratios of Zn/Co were directly grown on carbon nanotubes (CNTs) to secure electrical conductivity and

A non-enzymatic electrochemical hydrogen peroxide sensor based on copper oxide nanostructures

• Irena Mihailova,
• Vjaceslavs Gerbreders,
• Marina Krasovska,
• Eriks Sledevskis,
• Valdis Mizers,
• Andrejs Bulanovs and
• Andrejs Ogurcovs

Beilstein J. Nanotechnol. 2022, 13, 424–436, doi:10.3762/bjnano.13.35

• ]. Nanostructured materials are widely used as the working surface of the electrode [47][48][49]. The most common are transition metal nanoparticles [33][37][50][51][52][53][54], carbon nanotubes [8], metal oxides [55][56][57][58][59][60][61][62][63][64], graphene [32][33], and ordered mesoporous carbon [38][65][66

A chemiresistive sensor array based on polyaniline nanocomposites and machine learning classification

• Jiri Kroutil,
• Alexandr Laposa,
• Ali Ahmad,
• Jan Voves,
• Vojtech Povolny,
• Ladislav Klimsa,
• Marina Davydova and
• Miroslav Husak

Beilstein J. Nanotechnol. 2022, 13, 411–423, doi:10.3762/bjnano.13.34

• (carbon nanotubes (CNT), SnO2, TiO2) materials in a gas sensors based on nanocomposite layers with good sensitivity, temperature stability, reversibility, which was operating at room temperature. Herein, we extended our study by applying other nanocomposite sensing layers, namely PANI/ZnO, PANI/WO3

• (nanopowder), PANI/WO3 (nanotubes), PANI/In2O3, PANI/C60 (fullerene), PANI/nanocrystalline diamond (NCD), and PANI/BaTiO3, deposited on a flexible sensor array platform with a new design. Seven different nanocomposite sensing layers deposited on the array were exposed to six different gases (ammonia, carbon

Electrostatic pull-in application in flexible devices: A review

• Teng Cai,
• Yuming Fang,
• Yingli Fang,
• Ruozhou Li,
• Ying Yu and
• Mingyang Huang

Beilstein J. Nanotechnol. 2022, 13, 390–403, doi:10.3762/bjnano.13.32

• structure of the flexible devices. Nanoelectromechanical (NEM) switches made of carbon nanotubes (CNTs) [2][3][4], graphene (GR) [5][6][7], nanowires (NWs) [8][9][10], and other flexible materials are the most basic devices for a variety of component and system level applications, such as low-loss switches

• the first time. They used single-walled carbon nanotubes (SWCNTs) to prepare a suspended cross bistable switch array. Table 1 summarizes the structures and the voltage of CNT-NEM switches described in the literature. In addition to bridge and cantilever structures, the vertical structure further

• coating to disperse carbon nanotubes on a substrate by coating with a solution carbon nanotube powder in dichlorobenzene. In addition, a more general solution deposition process is AC dielectrophoretic technology [2][23]. The dielectrophoretic technology requires low voltage, high frequency, and can

Micro- and nanotechnology in biomedical engineering for cartilage tissue regeneration in osteoarthritis

• Zahra Nabizadeh,
• Mahmoud Nasrollahzadeh,
• Hamed Daemi,
• Mohamadreza Baghaban Eslaminejad,
• Ali Akbar Shabani,
• Mehdi Dadashpour,
• Majid Mirmohammadkhani and
• Davood Nasrabadi

Beilstein J. Nanotechnol. 2022, 13, 363–389, doi:10.3762/bjnano.13.31

• /nanoscale topographical cues, microspheres, nanoparticles, nanofibers, and nanotubes. Keywords: biological cues; cartilage regeneration; micro/nanotopographical cues; nanotechnology; osteoarthritis; regenerative medicine; Review 1 Introduction Osteoarthritis (OA) is a widespread degenerative disease of

• . Afterward, recent advances in osteochondral tissue engineering resulting from the application of microspheres, nanoparticles, nanofibers, and nanotubes in the structure of biomaterials will be covered (Figure 1). Finally, the role of various cues such as biological cues, microscale/nanoscale topographical

• . Micro- and nanostructures including microspheres, NPs, nanofibers, nanotubes, and nanofilms have been designed to construct new scaffolds and or incorporated into the hydrogel network to provide a controlled release or enhanced mechanical characteristics. Many of these substructures are widely used for

Investigation of a memory effect in a Au/(Ti–Cu)Ox-gradient thin film/TiAlV structure

• Damian Wojcieszak,
• Jarosław Domaradzki,
• Michał Mazur,
• Tomasz Kotwica and
• Danuta Kaczmarek

Beilstein J. Nanotechnol. 2022, 13, 265–273, doi:10.3762/bjnano.13.21

• [2][21][39]. Some examples of resistive switching behavior were also found in structures based on nanowires [40] or nanotubes [25][40], where the resistive switching device is characterized by the presence of a pinched or nonpinched hysteresis loop in the I–V characteristics in the DC plane. Our

Engineered titania nanomaterials in advanced clinical applications

• Padmavati Sahare,
• Paulina Govea Alvarez,
• Juan Manual Sanchez Yanez,
• Gabriel Luna-Bárcenas,
• Samik Chakraborty,
• Sujay Paul and
• Miriam Estevez

Beilstein J. Nanotechnol. 2022, 13, 201–218, doi:10.3762/bjnano.13.15

• nanotubes , nanobelts, mesostructured, nanoflowers, including many more as displayed in the SEM image of Figure 1 [3]. Moreover, TiO2 has recently been approved for use in food and drug products by the American Food and Drug Administration (FDA) [4]. The first clinical application of nanoscale TiO2 was

• minimize the risk of device-related infections, implants are usually coated with TiO2 nanotubes, which under UV irradiation, generate reactive oxygen species (ROS), resulting in the disinfection ability [13]. One of the most vital contributions of nanotechnology is the development of novel modes of drug

• nanostructures such as nanotubes and nanowires have been utilized in photoelectrochemical sensing for the rapid and precise identification of biological analytes at low concentrations, useful for clinical diagnosis. These nanostructures have been employed for sensing humidity, oxygen, and hydrogen, inclusive of

A comprehensive review on electrospun nanohybrid membranes for wastewater treatment

• Senuri Kumarage,
• Imalka Munaweera and
• Nilwala Kottegoda

Beilstein J. Nanotechnol. 2022, 13, 137–159, doi:10.3762/bjnano.13.10

• membrane incorporating halloysite nanotubes (HNTs) filled with lysozyme (50 wt % of lysozyme) into Polyamide 11 (PA11) as a bio-based pad for extending the shelf life of chicken slices and has found that the filled nanohybrid membrane resulted in a reduction of bacterial growth compared to electrospun PA11

Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• , nanobelts, and nanotubes. These morphologies can be controllably obtained by using polyvinylpyrrolidone (PVP), sodium dodecyl sulfonate (SDS), cetyl trimethyl ammonium bromide (CTAB), or tetrapropyl ammonium bromide (TPAB) as surfactants in a hydrothermal method [56][57][58][59]. The difference of

• ]. Huy et al. [38] hydrothermally synthesized SnO2 NPs adhering to TiO2 nanotubes (SnO2/TNTs) via a facile one-step method for the photocatalytic abatement of NO under visible light (Figure 9). At a NO concentration of 450 ppb in a continuous flow, SnO2/TNTs yields a photocatalytic degradation of NO of

• materials, preferably using two redox sites; (3) synthesizing other morphologies of SnO2 such as nanorods, nanotubes, or 3D structures to increase the specific surface area of the catalyst; (4) upscaling the syntheses and using other synthesis approaches such as sol–gel or chemical vapor deposition to form

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

• the La Mer model was not built based on experimental observations about the formation of metal NPs. Basically, La Mer and co-workers applied classical nucleation theory (CNT; this abbreviation was widely used by colloidal chemists years before carbon nanotubes became a hot research topic) that was

Two dynamic modes to streamline challenging atomic force microscopy measurements

• Alexei G. Temiryazev,
• Andrey V. Krayev and
• Marina P. Temiryazeva

Beilstein J. Nanotechnol. 2021, 12, 1226–1236, doi:10.3762/bjnano.12.90

• -walled carbon nanotubes (SWCNTs) [26]. This is very soft object that can be easily deformed by AFM probe. On the other hand, such a regime significantly reduces the likelihood of tip contamination. AFM image artifacts are often caused by a particle sticking to the tip (see Figure 2c). This not only

Impact of electron–phonon coupling on electron transport through T-shaped arrangements of quantum dots in the Kondo regime

• Patryk Florków and
• Stanisław Lipiński

Beilstein J. Nanotechnol. 2021, 12, 1209–1225, doi:10.3762/bjnano.12.89

• been observed in semiconductor-based quantum dots (QDs) [1][2][3][4], in carbon nanotubes [5], and in molecular nanostructures [6][7][8][9]. Besides the spin, also other degrees of freedom, for example, orbital [10] or charge [11][12] can give rise to Kondo correlations. For systems with higher

• degeneracy, for example, in the case of fourfold spin–orbital degeneracy not only spin, but also orbital pseudo-spin can be screened. Such SU(4) Kondo effect resonances have been observed in vertical QDs [10], in capacitively coupled dots [13], and in carbon nanotubes [14][15][16][17]. There is currently

Self-assembly of amino acids toward functional biomaterials

• Huan Ren,
• Lifang Wu,
• Lina Tan,
• Yanni Bao,
• Yuchen Ma,
• Yong Jin and
• Qianli Zou

Beilstein J. Nanotechnol. 2021, 12, 1140–1150, doi:10.3762/bjnano.12.85

• various nanostructures, such as nanowires [17], nanofibers [18], nanospheres [19], nanovesicles [20], nanogels [21], nanobelts [22], and nanotubes [23]. Self-assembly not only conveys higher stability and mechanical strength to proteins and peptides, but also further enhances their natural activity and

• and pH values [49]. Rizzo et al. studied camptothecin loaded into Fmoc-F hydrogels in the presence of haloalkyl nanotubes. Importantly, this hybrid co-assembly method could not only control the release of camptothecin in the form of active lactone, but also showed significant inhibitory activity on

Assessment of the optical and electrical properties of light-emitting diodes containing carbon-based nanostructures and plasmonic nanoparticles: a review

• Keshav Nagpal,
• Erwan Rauwel,
• Frédérique Ducroquet and
• Protima Rauwel

Beilstein J. Nanotechnol. 2021, 12, 1078–1092, doi:10.3762/bjnano.12.80

• . This review surveys the diverse possibilities to combine various inorganic, organic, and carbon nanostructures along with plasmonic nanoparticles. Such combinations would allow an enhancement in the overall properties of LED. Keywords: carbon nanotubes (CNT); graphene; light-emitting diodes (LED

• market as they suffer from energy losses due to total internal reflection at the emitter/air interface. Several methods have been proposed to tune the properties of LED. To that end, multiwall carbon nanotubes (MWNT) and single-wall carbon nanotubes (SWNT) have been applied to various layers in LED, such

• whereupon the luminous and internal quantum efficiencies of the device increase. However, SPR is very sensitive to the shape and size of MNP, which in turn directly influence the overall properties of LED. This manuscript reviews the effect of carbon nanostructures, such as carbon nanodots, carbon nanotubes

Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries

• Marina Tabuyo-Martínez,
• Bernd Wicklein and
• Pilar Aranda

Beilstein J. Nanotechnol. 2021, 12, 995–1020, doi:10.3762/bjnano.12.75

• based on nickel disulfide nanocrystals implanted in nitrogen-doped porous carbon nanotubes. It exhibits high reversible capacity of 650 mAh·g−1 after 200 cycles at 0.1 A·g−1 and excellent cycling stability for 3500 cycles. Additionally, Kumar et al. [51] described a cathode, based on manganese dioxide

• were synthesized inside carbon nanotubes by the melt diffusion method (Figure 7A) [54]. The resulting capacity of the Na–S battery after 2500 cycles at 1 A·g−1 was 80 mAh·g−1. Likewise, sulfur impregnation of hollow carbon nanocages rendered cathodes of 395 mAh·g−1 at 1 A·g−1 for 850 cycles [45

• , nanocarbon materials such as graphene and carbon aerogels, carbon microspheres, and mats, felts and papers based on carbon nanotubes and carbon fibers can also be efficiently soaked with Na and additionally provide bending and rolling flexibility, making them very attractive host materials [19][67][68][69

Comprehensive review on ultrasound-responsive theranostic nanomaterials: mechanisms, structures and medical applications

• Sepand Tehrani Fateh,
• Lida Moradi,
• Elmira Kohan,
• Michael R. Hamblin and
• Amin Shiralizadeh Dezfuli

Beilstein J. Nanotechnol. 2021, 12, 808–862, doi:10.3762/bjnano.12.64

Silver nanoparticles nucleated in NaOH-treated halloysite: a potential antimicrobial material

• Yuri B. Matos,
• Rodrigo S. Romanus,
• Mattheus Torquato,
• Edgar H. de Souza,
• Rodrigo L. Villanova,
• Marlene Soares and
• Emilson R. Viana

Beilstein J. Nanotechnol. 2021, 12, 798–807, doi:10.3762/bjnano.12.63

• + ions or growing up to the micrometer scale. Some routes stabilize Ag-NPs by nucleating silver into clay substrates [15][16], such as kaolinite [17][18][19], montmorillonite [18][19][20][21], and halloysite nanotubes [22][23][24]. The advantages are, for instance, preventing particle agglomeration

• aluminosilicate sheet that folds over itself in virtue of the internal stress inherent to the crystalline structure of the material, forming nanotubes [25]. As shown in Figure 1, it folds with a silicate phase facing outwards (Si-O), and an aluminol phase facing inwards (Al-OH). Since the internal and external

• induced major structural changes in the HNT substrates. As the treatment progressed, HNT nanotubes slowly unfolded into nanosheets, starting with the enlargement of the central lumen of HNT, as shown in the HNT-4 TEM image (Figure 4c). By day 8, most HNT nanotubes had already turned into nanosheets, as

Recent progress in actuation technologies of micro/nanorobots

• Ke Xu and
• Bing Liu

Beilstein J. Nanotechnol. 2021, 12, 756–765, doi:10.3762/bjnano.12.59

• -actuation. Magdanz et al. [46] proposed to use spermatozoa containing flagella as an actuation force for the preparation of micro/nanorobots. When combining sperm cells with nanotubes, the swing of the sperm flagella interacts with the microtubes to actuate the movement of the robot. Due to the high

Nanogenerator-based self-powered sensors for data collection

• Yicheng Shao,
• Maoliang Shen,
• Yuankai Zhou,
• Xin Cui,
• Lijie Li and
• Yan Zhang

Beilstein J. Nanotechnol. 2021, 12, 680–693, doi:10.3762/bjnano.12.54

• . Lee et al. proposed a based Hg2+ ion sensor based on ZnO nanowires and carbon nanotubes for detecting toxic pollutants [17]. The ZnO nanowire (NW) array acted as power source. When Hg2+ ions were detected, the system powered a light-emitting diode (LED). Li et al. designed a self-powered heavy metal

A review of defect engineering, ion implantation, and nanofabrication using the helium ion microscope

• Frances I. Allen

Beilstein J. Nanotechnol. 2021, 12, 633–664, doi:10.3762/bjnano.12.52

• electronic thermal conductivity of this material [72]. Additional defect engineering studies Defect formation in supported and free-standing multiwalled carbon nanotubes upon irradiation with both 25 keV helium and neon ions has also been investigated, since ion (and electron) irradiation can be used to

High-yield synthesis of silver nanowires for transparent conducting PET films

• Gul Naz,
• Hafsa Asghar,
• Muhammad Ramzan,
• Muhammad Arshad,
• Rashid Ahmed,
• Muhammad Bilal Tahir,
• Bakhtiar Ul Haq,
• Nadeem Baig and
• Junaid Jalil

Beilstein J. Nanotechnol. 2021, 12, 624–632, doi:10.3762/bjnano.12.51

• , carbon nanotubes (CNT), conductive polymers, and metallic nanowires, have been tested commercially as alternative to ITO films for flexible optoelectronic devices [6][7][8][9]. Amongst them, graphene and carbon materials, particularly CNTs, display low optical transparency and high sheet resistance owing

Solution combustion synthesis of a nanometer-scale Co₃O₄ anode material for Li-ion batteries

• Monika Michalska,
• Huajun Xu,
• Qingmin Shan,
• Shiqiang Zhang,
• Yohan Dall'Agnese,
• Yu Gao,
• Amrita Jain and
• Marcin Krajewski

Beilstein J. Nanotechnol. 2021, 12, 424–431, doi:10.3762/bjnano.12.34

• the formation of composite materials consisting of Co3O4 and different materials, including carbon-based materials, such as graphene [7][8], carbon nanotubes [9], carbon coatings [10], dictyophora indusiata-derived carbon [11], or other transition metal oxides [12]. This approach usually leads to a

A review on the biological effects of nanomaterials on silkworm (Bombyx mori)

• Sandra Senyo Fometu,
• Guohua Wu,
• Lin Ma and
• Joan Shine Davids

Beilstein J. Nanotechnol. 2021, 12, 190–202, doi:10.3762/bjnano.12.15

• observed [32]. TiO2 NPs have also been documented to increase the germination of lettuce seeds [33]. Recent reports indicate that multi-walled carbon nanotubes (MWCNTs) also increased the germination of tomato seeds by increasing the seed water uptake [34]. These reports of nanomaterials improving the

• al. [41] reported that the dietary uptake of carbon-based nanomaterials (fullerene C60, carbon black, single-walled nanotubes, multi-walled nanotubes) had no toxic effect on the growth and development of Drosophila melanogaster (fruit fly) from the egg stage to the adult form. However, the dietary

• uptake of carbon black and single-walled nanotubes caused impairment in the locomotor function of these flies. Demir et al. [42] reported that Ag NPs (0.1, 1, 5, and 10 mM) induced genotoxicity in the wing spot assay of fruit flies via somatic recombination. Carmona et al. [43] reported cytotoxic effects

Paper-based triboelectric nanogenerators and their applications: a review

• Jing Han,
• Nuo Xu,
• Yuchen Liang,
• Mei Ding,
• Junyi Zhai,
• Qijun Sun and
• Zhong Lin Wang

Beilstein J. Nanotechnol. 2021, 12, 151–171, doi:10.3762/bjnano.12.12

• changing the concentration of the conductive precursors (e.g., AgNWs, carbon nanotubes, and reduced graphene oxide). A special nanoscale paper composed of nanocellulose, which is easy to be synthesized/chemically modified/doped, has attracted great attention in recent years. Generally, cellulose-based

A review on the green and sustainable synthesis of silver nanoparticles and one-dimensional silver nanostructures

• Sina Kaabipour and
• Shohreh Hemmati

Beilstein J. Nanotechnol. 2021, 12, 102–136, doi:10.3762/bjnano.12.9