Zeolite materials with Ni and Co: synthesis and catalytic potential in the selective hydrogenation of citral

• Inocente Rodríguez-Iznaga,
• Yailen Costa Marrero,
• Tania Farias Piñeira,
• Céline Fontaine,
• Lexane Paget,
• Beatriz Concepción Rosabal,
• Arbelio Penton Madrigal,
• Vitalii Petranovskii and
• Gwendoline Lafaye

Beilstein J. Nanotechnol. 2025, 16, 520–529, doi:10.3762/bjnano.16.40

• . Experimental Material and methods Natural zeolite from the San Andrés deposit in Cuba, with a particle size range of 40–160 μm, was used. This zeolitic material consists primarily of mordenite and clinoptilolite-type zeolites (around 80%), along with minor accompanying phases (quartz, montmorillonite, feldspar

• radiation (λ = 1.5406 Å). Data were collected at a scan speed of 2°/min with a step size of 0.05°. SEM images were acquired using a FEI Nova NanoSEM 450 electron microscope. For this purpose, samples were mounted on holders and coated with a thin layer of gold prior to observation. Temperature-programmed

N₂⁺-implantation-induced tailoring of structural, morphological, optical, and electrical characteristics of sputtered molybdenum thin films

• Usha Rani,
• Kafi Devi,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 495–509, doi:10.3762/bjnano.16.38

• (111) crystallographic plane. Further, the average crystallite size was calculated using the Scherrer equation [31][32][33]: where k is a constant (k = 0.94) [32][33], λ is the X-ray wavelength (λ = 1.5406 Å), θ is the Bragg angle, and β is the FWHM. Additionally, the microstrain (ε) developed in the

• thin films due to lattice distortions or mismatch was calculated using Wilson’s equation [31][33]: The dislocation density (δ) gives more information about the number of defects in the films; it was calculated from the relation [32]: where D is the average crystallite size. The interplanar spacing (d

• ) and lattice constant (a) were calculated using the relations [13][33]: where h,k, and l are the Miller indices of the corresponding diffraction peak [34]. The obtained values for average crystallite size, microstrain, dislocation density, and interplanar spacing for as-deposited and N2+-implanted Mo

Performance optimization of a microwave-coupled plasma-based ultralow-energy ECR ion source for silicon nanostructuring

• Joy Mukherjee,
• Safiul Alam Mollick,
• Tanmoy Basu and
• Tapobrata Som

Beilstein J. Nanotechnol. 2025, 16, 484–494, doi:10.3762/bjnano.16.37

• lens is employed. The shape and size of the beam are contingent on the extraction voltage applied at the grid and the corresponding ion energy. The directed beam impacts the silicon target kept in ultrahigh vacuum (UHV) within the target chamber. A Faraday cup, connected to a multimeter, measures the

• ions at different incidence angles and for various irradiation times is investigated using AFM in tapping mode. Si cantilevers with tip radii of 10 nm were employed, with scan rate of 1 µm/s and a fixed scan size of 5 µm × 5 µm. Quantitative analysis of the surface topography was conducted using WSxM

Impact of adsorbate–substrate interaction on nanostructured thin films growth during low-pressure condensation

• Alina V. Dvornichenko,
• Vasyl O. Kharchenko and
• Dmitrii O. Kharchenko

Beilstein J. Nanotechnol. 2025, 16, 473–483, doi:10.3762/bjnano.16.36

• increase in its coverage and the formation of a smaller number of adsorbate islands of larger size. At elevated adsorption rates, an increase in adsorbate–substrate interactions results in the transformation of the surface morphology and the formation of percolating adsorbate structures. Deposition onto

• multicomponent substrates leads to the formation of a stationary surface morphology with an elevated number of adsorbate islands of smaller size, compared to one-component substrates. This study provides a deep insight into the peculiarities of nanostructured thin films’ growth in low-pressure systems with

• well-defined islands or clusters. The strength and nature of these interactions play a pivotal role in determining whether the film growth follows layer-by-layer (Frank–van der Merwe) or island (Volmer–Weber) growth modes [22]. Therefore, central to achieving the control the type and size of surface

Effect of additives on the synthesis efficiency of nanoparticles by laser-induced reduction

• Rikuto Kuroda,
• Takahiro Nakamura,
• Hideki Ina and
• Shuhei Shibata

Beilstein J. Nanotechnol. 2025, 16, 464–472, doi:10.3762/bjnano.16.35

• oxidation; 2) 2–6 min of laser irradiation: particle formation and crystal growth reaction; 3) 6–26 min of laser irradiation: continuous reduction and particle size reduction by laser fragmentation in liquid. Therefore, this means that all reactions are complete after 26 min of laser irradiation in the

• with a wide particle size distribution of >10 nm, particles with a square shape of >50 nm were also observed. It is thought that the square-shaped particles were formed by crystal growth of the atoms produced by laser irradiation as nuclei, while consuming unreacted ions in the solution through a self

• -catalytic effect. This also suggests that the reduction reaction was not complete after 10 min of laser irradiation. The sample after 30 min of laser irradiation shows that particles with a narrow particle size distribution of less than 10 nm in diameter were formed. In contrast, in the sample with 10 vol

Synthetic-polymer-assisted antisense oligonucleotide delivery: targeted approaches for precision disease treatment

• Ana Cubillo Alvarez,
• Dylan Maguire and
• Ruairí P. Brannigan

Beilstein J. Nanotechnol. 2025, 16, 435–463, doi:10.3762/bjnano.16.34

• (e.g., generations 5 and 6) significantly improved the delivery efficiency of ASOs into HeLa cells, as evidenced by increased luciferase activity in a splicing correction assay. This was attributed to the higher charge density and molecular size of the higher-generation DPLs, which facilitated more

• reduction in tumour size and metastasis in both orthotopic and xenograft models. Importantly, the PEG-PLO-based delivery system showed a lower nitrogen-to-phosphate ratio requirement compared to similar systems using PEG-PLL, thereby reducing the amount of polymer needed for effective siRNA delivery. The

• gradual reduction in skin tumour size by up to 40% after a seven-day treatment with antisense dendriplexes while no significant changes were observed in mice treated with free ASOs. More recently, Tai et al. designed penetratin-conjugated PAMAM G5 dendrimers complexed with an ASO targeting luciferase

Quantification of lead through rod-shaped silver-doped zinc oxide nanoparticles using an electrochemical approach

• Ravinder Lamba,
• Gaurav Bhanjana,
• Neeraj Dilbaghi,
• Vivek Gupta and
• Sandeep Kumar

Beilstein J. Nanotechnol. 2025, 16, 422–434, doi:10.3762/bjnano.16.33

• response, and have a vast range of uses. Zinc oxide shows excellent features, such as nanoscale particles, highly crystalline nature, tunable shape, size and density, and a high aspect ratio. In summary, ZnO nanoparticles offer a versatile platform for technological advancements across fields such as

• particularly well-suited for ZnO doping because of its notable characteristics, including strong conductivity, solubility, favorable ionic size, and low orbital energy. These features contribute to the improvement of optical and electrical characteristics of ZnO. The incorporation of silver boosts the mobility

• the ZnO crystal lattice results in a decrement in the peak position values because Ag+ ion (12.2 nm) has a larger ionic size compared to that of the Zn2+ ion (7.4 nm). Consequently, the given data aligns with the decrease in the highest location of the point, indicating a reduction in the c-axis

Size control of nanoparticles synthesized by pulsed laser ablation in liquids using donut-shaped beams

• Abdel Rahman Altakroury,
• Oleksandr Gatsa,
• Farbod Riahi,
• Zongwen Fu,
• Miroslava Flimelová,
• Andrei Samokhvalov,
• Stephan Barcikowski,
• Carlos Doñate-Buendía,
• Alexander V. Bulgakov and
• Bilal Gökce

Beilstein J. Nanotechnol. 2025, 16, 407–417, doi:10.3762/bjnano.16.31

• GROC·UJI, Institute of New Imaging Technologies, Universitat Jaume I, Av. de Vicent Sos Baynat, s/n, 12071 Castellón, Spain 10.3762/bjnano.16.31 Abstract The potential to modify the size distribution of nanoparticles synthesized by pulsed laser ablation in liquids is demonstrated using a donut-shaped

• laser beam. In experiments on pulsed laser ablation in water of gold, yttrium oxide, and high-entropy alloy targets with both Gaussian and donut-shaped beams, we observed a significant reduction in particle size, narrowing of the size distribution width, and an improvement in sphericity when utilizing

• this pioneering study, further investigation with higher temporal and spatial resolution are warranted. Keywords: beam shaping; cavitation bubble; donut beam; gold nanoparticles; high-entropy alloy nanoparticles; nanoparticle size analysis; yttrium oxide nanoparticles; Introduction The demand for

ReactorAFM/STM – dynamic reactions on surfaces at elevated temperature and atmospheric pressure

• Tycho Roorda,
• Hamed Achour,
• Matthijs A. van Spronsen,
• Marta E. Cañas-Ventura,
• Sander B. Roobol,
• Willem Onderwaater,
• Mirthe Bergman,
• Peter van der Tuijn,
• Gertjan van Baarle,
• Johan W. Bakker,
• Joost W. M. Frenken and
• Irene M. N. Groot

Beilstein J. Nanotechnol. 2025, 16, 397–406, doi:10.3762/bjnano.16.30

• size distribution of the particles. While maintaining the gas flow, the sample’s temperature was increased with a rate of 1 K per 10 s up to 550 K; at this temperature FTS takes place. This is outside the possible temperature window of scanning with our tuning fork, as explained above. Therefore, we

• were only able to scan at 430 K before (Figure 6b) and after the reaction occurred (Figure 6c). As can be seen, the surface has undergone a change due to the reaction. The particle size distribution has changed; it appears that smaller particles are no longer visible and that there is an increase in

• , exploring the effects of varying support thicknesses and materials, as well as size distributions of metallic nanoparticles, and identifying which product gases are favored under specific reaction conditions, could extend our understanding of FTS. Schematic overview of the experimental setup (left side) and

Engineered PEG–PCL nanoparticles enable sensitive and selective detection of sodium dodecyl sulfate: a qualitative and quantitative analysis

• Soni Prajapati and
• Ranjana Singh

Beilstein J. Nanotechnol. 2025, 16, 385–396, doi:10.3762/bjnano.16.29

• manipulation of particles with a size less than 100 nm. These tiny particles possess unique physicochemical features, including optical, electrical, magnetic, and catalytic properties [23]. Indeed, the advanced properties of nanoparticles enables them to be used in different areas, such as biosensing, drug

• . Characterization of PEG–PCL nanoparticles The synthesized PEG–PCL nanoparticles were characterized by their unique physicochemical properties, such as size and surface charge. The average hydrodynamic size, monodispersity, and surface charge of the nanoparticles were measured using the ZetaSizer (Nano ZS, Malvern

• , UK). Dried 10 mg/mL PEG–PCL NPs were dissolved in PBS and sonicated for 30 min. The sonicated sample was taken in a cuvette for measurement. The sample pH was in the range of 7.2–7.4. Separate cuvettes (DTS1072 and DTS0012) were used to measure the surface charge and average size of the nanoparticles

Development of a mucoadhesive drug delivery system and its interaction with gastric cells

• Ahmet Baki Sahin,
• Serdar Karakurt and
• Deniz Sezlev Bilecen

Beilstein J. Nanotechnol. 2025, 16, 371–384, doi:10.3762/bjnano.16.28

• mucoadhesive drug delivery system that was developed to fulfill these requirements. Alginate nanoparticles were synthesized by water-in-oil emulsification followed by external gelation and then coated with the mucoadhesive polymer Eudragit RS100. The formulated nanoparticles had a mean size of 219 nm and

• adhere to the mucosa. The size of the microspheres, from which the drug was released over a period of 24 h, was in the range of 800–900 µm [26]. Although particulate systems with larger sizes could be advantageous in terms of higher encapsulation efficiency and slower release, they would have a reduced

• surface area for adhesion. Also, mucus penetration would be hindered because of the mesh-like structure of mucin. For therapeutics that have gastric mucosa as target, this might limit the efficiency and decrease the drug absorption at the site. A smaller particle size, however, is advantageous because of

Vortex lattices of layered HTSCs at different vortex–vortex interaction potentials

• Valerii P. Lenkov,
• Anastasia N. Maksimova,
• Anna N. Moroz and
• Vladimir A. Kashurnikov

Beilstein J. Nanotechnol. 2025, 16, 362–370, doi:10.3762/bjnano.16.27

• pancakes in the layer under consideration, is the vortex self-energy per superconducting layer with The simulation is performed for a vortex lattice in a sample whose size in the plane of the superconducting layer is 5 × 5 μm. To eliminate the influence of the boundary, the simulation region has periodic

• qualitatively preserved. The obtained results can be useful for designing superconducting devices of micrometer and submicrometer size. For the potential from Equation 2, vortex lattice melting with increasing temperature was studied. For the potential from Equation 3, the formation of a vortex lattice was

Pulsed laser in liquid grafting of gold nanoparticle–carbon support composites

• Madeleine K. Wilsey,
• Teona Taseska,
• Qishen Lyu,
• Connor P. Cox and
• Astrid M. Müller

Beilstein J. Nanotechnol. 2025, 16, 349–361, doi:10.3762/bjnano.16.26

• surfactants for size control [17][18][19]. Nanoparticles prepared by pulsed laser in liquid synthesis are surfactant-free [1], but the same binder strategies are used for nanoparticle–support composites as for conventionally made nanoparticles. Capping ligands and binders hinder intimate contact between

• ]. Pulsed laser-grafted and conventionally prepared electrodes had a mass loading of 70 and 8.5 µg·cm−2geometric, respectively. The diameters of laser-grafted and commercial gold nanoparticles were 200 and 100 nm, respectively. The larger size of laser-grafted gold nanoparticles is not an issue for the

• 200 W and 15 kV. Samples were washed with water, dried, and affixed to double-sided adhesive copper tape. Survey scans were averaged over five scans and spanned 0–1200 eV with a 1 eV step size, 200 ms dwell time, and 160 eV pass energy. High-resolution core level scans were averaged over five scans

Tailoring of physical properties of RF-sputtered ZnTe films: role of substrate temperature

• Kafi Devi,
• Usha Rani,
• Arun Kumar,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 333–348, doi:10.3762/bjnano.16.25

• temperature are amorphous; those deposited at other substrate temperatures are polycrystalline with a cubic zincblende structure and a preferred orientation along the [111] direction. An increase in crystallite size (from 37.60 ± 0.42 Å to 68.88 ± 1.04 Å) is observed with increased substrate temperature. This

• the optical bandgap of the films can be tuned from 1.47 ± 0.02 eV to 3.11 ± 0.14 eV. The surface morphology of the films studied using atomic force microscopy reveals that there is uniform grain growth on the surface. Various morphological parameters such as roughness, particle size, particle density

• to quantum confinement size effects, metal chalcogenides are of importance in different technological domains. Metal chalcogen compounds are composed of a transition metal with one or more members of the chalcogen family, and they exhibit semiconducting properties. Zinc telluride (ZnTe) is a binary

Graphene oxide–chloroquine conjugate induces DNA damage in A549 lung cancer cells through autophagy modulation

• Braham Dutt Arya,
• Sandeep Mittal,
• Prachi Joshi,
• Alok Kumar Pandey,
• Jaime E. Ramirez-Vick,
• Govind Gupta and
• Surinder P. Singh

Beilstein J. Nanotechnol. 2025, 16, 316–332, doi:10.3762/bjnano.16.24

• -based propidium iodide uptake analysis The efficacy of nanomedicines mainly depends upon the effective cellular internalization and their transport to the appropriate intercellular effector site [52][53]. Studies have shown that based on its size and surface characteristics (i.e., hydrophilicity or

Fabrication and evaluation of BerNPs regarding the growth and development of Streptococcus mutans

• Tuyen Huu Nguyen,
• Hong Thanh Pham,
• Kieu Kim Thanh Nguyen,
• Loan Hong Ngo,
• Anh Ngoc Tuan Mai,
• Thu Hoang Anh Lam,
• Ngan Thi Kim Phan,
• Dung Tien Pham,
• Duong Thuy Hoang,
• Thuc Dong Nguyen and
• Lien Thi Xuan Truong

Beilstein J. Nanotechnol. 2025, 16, 308–315, doi:10.3762/bjnano.16.23

• prepared using a wet-milling method with zirconium balls to enhance bioavailability and expand potential applications. The particle size and physicochemical properties of the BerNPs were analyzed using field-emission scanning electron microscopy (FE-SEM), UV–vis spectroscopy, X-ray diffraction, and Fourier

• formation. The results demonstrated that BerNPs were produced with an average particle size of 40–65 nm. The chemical structure of BerNPs remained consistent with that of berberine, with no modifications occurring during nanoparticle preparation. The BerNPs exhibited the ability to inhibit S. mutans, with

• an efficient technique for fabricating nanoparticles from crystalline structures of organic pharmaceutical raw materials [18]. Other studies have shown that incorporating surfactants into the wet ball milling process significantly enhances particle size reduction, facilitates the effective production

Enhancing mechanical properties of chitosan/PVA electrospun nanofibers: a comprehensive review

• Nur Areisman Mohd Salleh,
• Amalina Muhammad Afifi,
• Fathiah Mohamed Zuki and
• Hanna Sofia SalehHudin

Beilstein J. Nanotechnol. 2025, 16, 286–307, doi:10.3762/bjnano.16.22

• sensitive compounds [3]. Electrospun nanofibers exhibit a large surface area, high porosity, and small pore size, making them useful for a wide range of applications, as shown in Figure 1. Chitosan/polyvinyl alcohol (PVA) electrospun nanofibers have many applications, including water treatment, biomedical

Emerging strategies in the sustainable removal of antibiotics using semiconductor-based photocatalysts

• Yunus Ahmed,
• Keya Rani Dutta,
• Parul Akhtar,
• Md. Arif Hossen,
• Md. Jahangir Alam,
• Obaid A. Alharbi,
• Hamad AlMohamadi and
• Abdul Wahab Mohammad

Beilstein J. Nanotechnol. 2025, 16, 264–285, doi:10.3762/bjnano.16.21

• advanced methods, including sol–gel, hydrothermal, solvothermal, precipitation and template-assisted techniques [53]. The synthesis method chosen often depends on factors such as the desired crystal structure, particle size, surface area, and photocatalytic activity required for the specific application

• recombination rates, and the generated oxygen vacancies, ultimately enhancing catalytic efficiency in visible light or solar-simulated light. The durability of the modified TiO2 relied on the number of electrons in the dopants and their ionic size. Although researchers have significantly improved the catalytic

Preferential enrichment and extraction of laser-synthesized nanoparticles in organic phases

• Theo Fromme,
• Maximilian L. Spiekermann,
• Florian Lehmann,
• Stephan Barcikowski,
• Thomas Seidensticker and
• Sven Reichenberger

Beilstein J. Nanotechnol. 2025, 16, 254–263, doi:10.3762/bjnano.16.20

• ) was found to direct both the nanoparticles’ phase selectivity and recovery after cycling. The observed correlations provide potential guidelines for nanoparticle extraction and size separation, relevant for phase transfer and cycling during homogeneous catalysis. Keywords: catalysis; laser ablation

• in liquid; laser synthesis and processing of colloids; phase transfer; size separation; thermomorphic multiphase system; Introduction Laser ablation in liquids (LAL) provides nanoparticles without the need of external surfactants while retaining the initial composition of the educt material in the

• parameters. As such, nanoparticle size [32][33], colloidal stability [33], gas formation [11][34], degree of oxidation [35][36][37], and nanoparticle productivity [11][32][33][34] can be influenced and tailored to specific needs. Although it may be expected that the particles’ reactivity with the solvent and

Radiosensitizing properties of dual-functionalized carbon nanostructures loaded with temozolomide

• Radmila Milenkovska,
• Nikola Geskovski,
• Dushko Shalabalija,
• Ljubica Mihailova,
• Petre Makreski,
• Dushko Lukarski,
• Igor Stojkovski,
• Maja Simonoska Crcarevska and
• Kristina Mladenovska

Beilstein J. Nanotechnol. 2025, 16, 229–251, doi:10.3762/bjnano.16.18

• changes in the structure of the CNs and TMZ after irradiation were observed. With single and dual functionalization, formulations with relatively high TMZ loading efficiency and drug content were prepared. They exhibited homogeneous particle size distributions and mean particle sizes and surface charges

• formulations of the hybrid CN MWCNTs-G compared to the corresponding MWCNTs were characterized by a similar or slightly higher TMZ content, larger particle size, similar surface charge, and slightly faster TMZ release, which can be attributed to the planar structure of graphene that promotes TMZ binding to the

• surface on a larger scale. For the irradiated CNs, lower values for particle size, more positive values for surface charge, and accelerated TMZ release were observed, which could be explained by changes in the physicochemical characteristics of the prepared formulations upon irradiation. Significant

Synthesis and the impact of hydroxyapatite nanoparticles on the viability and activity of rhizobacteria

• Bedah Rupaedah,
• Indrika Novella,
• Atiek Rostika Noviyanti,
• Diana Rakhmawaty Eddy,
• Anna Safarrida,
• Abdul Hapid,
• Zhafira Amila Haqqa,
• Suryana Suryana,
• Irwan Kurnia and
• Fathiyah Inayatirrahmi

Beilstein J. Nanotechnol. 2025, 16, 216–228, doi:10.3762/bjnano.16.17

• using 16S rRNA gene sequencing, followed by analysis to construct a phylogenetic tree. nHA was found to meet the required quality criteria, exhibiting a spherical morphology with an average particle size of 68 nm and a porosity of 54.78%. The nHA carrier demonstrated favorable physical attributes to

• = 31.77°, which is the highest peak of HA, as reported by Noviyanti et al. [25] and Novella and coworkers [26]. Using the information obtained from the XRD pattern, the crystal size (D) of the sample can be calculated utilizing the Scherrer equation, as outlined by Monshi and coworkers [27]: where K is a

• constant (with a value of 0.89), λ represents the X-ray wavelength in nanometers (0.154 nm), β denotes the full width at half maximum (FWHM) of the diffraction peak, and θ is the Bragg angle. The crystal size of the sample was found to be 34.27 nm, with a full width at half maximum (FWHM) of 0.2384 radians

Recent advances in photothermal nanomaterials for ophthalmic applications

• Jiayuan Zhuang,
• Linhui Jia,
• Chenghao Li,
• Rui Yang,
• Jiapeng Wang,
• Wen-an Wang,
• Heng Zhou and
• Xiangxia Luo

Beilstein J. Nanotechnol. 2025, 16, 195–215, doi:10.3762/bjnano.16.16

• addition, the cornea, an ocular tissue, is relatively “immune amnestied” because of the absence of blood vessels and lymphatic vessels, which reduces the patient’s immune response and inflammation and improves the safety and efficacy of photothermal nanomaterials therapy [12][13]. The small size of

• efficient process with photothermal conversion nearing 100% efficiency (see below in Figure 2a) [45][46][47]. The specific absorption wavelength of these metals is closely linked to their extinction cross section and particle size and shape, which are greatly influenced by the chemical capping agents and

• ], and overcoming barriers in drug delivery [53]. Furthermore, the precise adjustment of the morphology and particle size of LSPR metals allows for the fine-tuning of their characteristic absorption within the range of 650 to 1350 nm. This range falls outside the absorption spectrum of the eye’s aqueous

Probing the potential of rare earth elements in the development of new anticancer drugs: single molecule studies

• Josiane A. D. Batista,
• Rayane M. de Oliveira,
• Carlos H. M. Lima,
• Milton L. Lana Júnior,
• Virgílio C. dos Anjos,
• Maria J. V. Bell and
• Márcio S. Rocha

Beilstein J. Nanotechnol. 2025, 16, 187–194, doi:10.3762/bjnano.16.15

• experiments performed here was to confirm the ability of neodymium and erbium to condense DNA at high concentrations (>0.5 μM for neodymium and >0.05 μM for erbium). Furthermore, these assays allowed us to estimate the typical shape and size of these condensates. They present a globular morphology with

A review of metal-organic frameworks and polymers in mixed matrix membranes for CO₂ capture

• Charlotte Skjold Qvist Christensen,
• Nicholas Hansen,
• Mahboubeh Motadayen,
• Nina Lock,
• Martin Lahn Henriksen and
• Jonathan Quinson

Beilstein J. Nanotechnol. 2025, 16, 155–186, doi:10.3762/bjnano.16.14

• ]. This strategy capitalizes on the combination of high surface areas and the tunable nature of pore openings and channels of MOFs, achieving selective CO2 adsorption by size exclusion [55], illustrated in Figure 2a. The kinetic diameter of competing adsorbates is the most commonly quoted metric for size

• comparison, that is, the size of the molecules based on the possibility of collision with other molecules [56]. Consequently, MOFs that exhibit pore sizes around the kinetic diameter of CO2 of 3.3 Å effectively allow for CO2 separation from gaseous mixtures containing larger molecules such as CH4 and N2 with

• did not persist when tested in a CO2/CH4 mixture with a 6/94 molar ratio (αCO2/CH4 = 61 ± 4), emphasizing the importance and the challenges related to developing MOF structures for CO2 capture [51]. While some MOFs do feature pore apertures within the narrow size range allowing for size exclusion (3.3

Clays enhanced with niobium: potential in wastewater treatment and reuse as pigment with antibacterial activity

• Silvia Jaerger,
• Patricia Appelt,
• Mario Antônio Alves da Cunha,
• Fabián Ccahuana Ayma,
• Ricardo Schneider,
• Carla Bittencourt and
• Fauze Jacó Anaissi

Beilstein J. Nanotechnol. 2025, 16, 141–154, doi:10.3762/bjnano.16.13

• radiation (λ = 1.5410 Å) operating at 40 kV and 30 mA. Data were collected in scanning mode in steps between 4° and 75° (2θ) with a step size of 0.05°/s. The basal distance was obtained using Bragg's Law. Fourier-transform infrared spectroscopy (FTIR) spectra were collected on a Perkin Elmer Frontier FTIR

• with 50 μm of diameter and gate delay of 0.5 μs. A static laser scattering (SLS) Horiba LA-960 equipment assessed the powder particle size distribution measurements using a 15 mL cuvette accessory and water as the dispersion medium. The refractive index was set to 1.640 for red and blue lines. Results

• reduced when the BE sample was modified with niobium compounds. The average particle size for the samples BE, NbPh, and NbOx were 12, 410, and 54 μm, respectively, and it is present in Supporting Information File 1, Figure S1. The BEPh and BEOx samples presented different particle size distributions, so