A non-enzymatic electrochemical hydrogen peroxide sensor based on copper oxide nanostructures

• Irena Mihailova,
• Vjaceslavs Gerbreders,
• Marina Krasovska,
• Eriks Sledevskis,
• Valdis Mizers,
• Andrejs Bulanovs and
• Andrejs Ogurcovs

Beilstein J. Nanotechnol. 2022, 13, 424–436, doi:10.3762/bjnano.13.35

• concentration of H2O2 in the range from 10 to 1800 μM was obtained. The sensitivity of the obtained CuO electrode is 439.19 μA·mM−1. The calculated limit of detection is 1.34 μM, assuming a signal-to-noise ratio of 3. The investigation of the system for sensitivity to interference showed that the most common

• focused on the development of non-enzymatic electrochemical sensors for the detection of H2O2 [37][38][39]. In this type of sensor, H2O2 interacts with the electrode material directly. Certain catalytic processes occurring between H2O2 and the electrode material provide an unambiguous electrochemical

• ]. Nanostructured materials are widely used as the working surface of the electrode [47][48][49]. The most common are transition metal nanoparticles [33][37][50][51][52][53][54], carbon nanotubes [8], metal oxides [55][56][57][58][59][60][61][62][63][64], graphene [32][33], and ordered mesoporous carbon [38][65][66

A chemiresistive sensor array based on polyaniline nanocomposites and machine learning classification

• Jiri Kroutil,
• Alexandr Laposa,
• Ali Ahmad,
• Jan Voves,
• Vojtech Povolny,
• Ladislav Klimsa,
• Marina Davydova and
• Miroslav Husak

Beilstein J. Nanotechnol. 2022, 13, 411–423, doi:10.3762/bjnano.13.34

• electrode systems was manufactured as a flexible printed circuit board (DuPont Pyralux AP8535 with 75 µm thickness, double-sided, copper-clad laminate in an all-polyimide composite of polyimide film bonded to copper foil). It contains the heating elements and the temperature sensors for the temperature

• dispersion solutions were deposited by a micropipette on the interdigitated electrode arrays. After that, the deposited sensor layers were dried using the integrated heating elements at 60 °C for 2 h and whole sensor array was subsequently dried in a desiccator over silica gel for 24 h. Before the deposition

Electrostatic pull-in application in flexible devices: A review

• Teng Cai,
• Yuming Fang,
• Yingli Fang,
• Ruozhou Li,
• Ying Yu and
• Mingyang Huang

Beilstein J. Nanotechnol. 2022, 13, 390–403, doi:10.3762/bjnano.13.32

• , phase shifts, and relays. In this paper, the state of the art of electrostatic pull-in phenomena in flexible devices is discussed, and the influence of different electrode structures in NEM switches is classified and discussed. In addition, the applications of NEM switches in radio frequency (RF

• functionality of nanostructures to process external stimuli applied to the device controlling the electrical current [12]. The lower pull-in voltage and the improved durability of the NEM switches require electrode materials with high Young’s modulus, conductivity, and Poisson's ratio. The flexible suspension

• electrode materials include CNTs, GR, and silicon/germanium nanowires. CNT-NEM switches CNTs are an ideal flexible material for NEM electrodes because of the high aspect ratio, current density, and excellent tensile strength. In 2000, Rueckes et al. [13] observed the electromechanical conversion in CNTs for

The effect of metal surface nanomorphology on the output performance of a TENG

• Yiru Wang,
• Xin Zhao,
• Yang Liu and
• Wenjun Zhou

Beilstein J. Nanotechnol. 2022, 13, 298–312, doi:10.3762/bjnano.13.25

• . Hence, electric charges can move from one electrode to the other through an electrostatic field. When the materials are brought in contact again, the electrostatic field will disappear. Finally, the electrons flow in the opposite direction. An alternating current will be generated through the repetition

• positive, and that on PTFE is negative (Figure 3a). A separation is caused by the removal of the external force, and electrons flow from the PTFE electrode to the Cu electrode (Figure 3b). Then, charge exchange is carried out at the contacts. Electrical equilibrium is formed when the Cu and the PTFE are

• separated by a greater distance (Figure 3c). When the external force is applied again to bring Cu and PTFE into contact, electrons will flow from the Cu electrode through an external load to the PTFE electrode (Figure 3d). According to the observation of the diameter of the nanoscale blocks grown in the

Relationship between corrosion and nanoscale friction on a metallic glass

• Haoran Ma and
• Roland Bennewitz

Beilstein J. Nanotechnol. 2022, 13, 236–244, doi:10.3762/bjnano.13.18

• measurements. In order to establish differences in corrosion of ZrNiTi MGs between the solutions using a standard procedure, potentiodynamic polarization experiments were performed in the range of −0.5 to 1.5 V at a potential sweep rate of 1.0 mV·s−1, in a custom-made cell with a three-electrode setup. The MG

• ribbon, a miniature Ag/AgCl electrode, and a Au wire served as working, reference, and counter electrode, respectively. The polarization test was a separate experiment and subsequent friction experiments were performed using new samples, which were immersed without applying a potential. (a

Impact of device design on the electronic and optoelectronic properties of integrated Ru-terpyridine complexes

• Max Mennicken,
• Sophia Katharina Peter,
• Corinna Kaulen,
• Ulrich Simon and
• Silvia Karthäuser

Beilstein J. Nanotechnol. 2022, 13, 219–229, doi:10.3762/bjnano.13.16

• rinsed three times in either ethanol or chloroform. Nanodevice fabrication The fabrication of nanoelectrode samples, each equipped with twelve nanoelectrode pairs (consisting of an AuPd and a Pt electrode with a nanometer-sized gap in between), was performed according to a recently described process

• gaps almost unaffected. Thus, only a part of the orbitals relevant for a continuous conductive path from one electrode to the other is shifted into the respective voltage window defined by the measurement conditions. This kind of voltage divider, determined by the few-Ru(MPTP)2–AuNP device geometry, in

• ratio. Since it will be difficult to increase ΔIL_D, a straightforward way to improve the on/off ratio of Ru(MPTP)2–AuNP devices would be to increase the distance between adjacent AuNPs in the electrode gap, for example by employing longer ligand molecules. This will cause a decrease of the tunneling

Design aspects of Bi₂Sr₂CaCu₂O_8+δ THz sources: optimization of thermal and radiative properties

• Mikhail M. Krasnov,
• Natalia D. Novikova,
• Roger Cattaneo,
• Alexey A. Kalenyuk and
• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2021, 12, 1392–1403, doi:10.3762/bjnano.12.103

• crystal and the electrode leads to appearance of a large parasitic capacitance, which shunts terahertz emission and prevents impedance matching with open space. The overlap is avoided in whisker-based devices. Furthermore, the whisker and the electrodes form a turnstile (crossed-dipole) antenna

• are made for the base temperature T0 = 10 K and for sizes similar to the actual devices, shown in Figure 1: substrate 5 × 5 × 0.3 mm3, crystal 1 × 1 × 0.3 mm3, whisker 300 × 30 × 3 μm3 and mesa 30 × 30 × 0.3 μm3. The thickness of gold electrode is 200 nm. The thickness of epoxy layer, de, depends on

• the mesa volume with a total power of 1 mW and uniform density. Figure 3 represents heat transfer simulations for a whisker without an electrode. Figure 3a,b shows sketches of the device and the x–z cross-section through the mesa (not to scale), respectively. Figure 3c–e shows the temperature

Measurement of polarization effects in dual-phase ceria-based oxygen permeation membranes using Kelvin probe force microscopy

• Kerstin Neuhaus,
• Christina Schmidt,
• Liudmila Fischer,
• Wilhelm Albert Meulenberg,
• Ke Ran,
• Joachim Mayer and
• Stefan Baumann

Beilstein J. Nanotechnol. 2021, 12, 1380–1391, doi:10.3762/bjnano.12.102

• nanoscale electrode, a constant voltage pulse was applied to the sample in order to achieve a local polarization with distinctly changed redox state and defect concentrations. In a subsequent mapping experiment, the AFM tip was used as Kelvin probe to scan the locally changed surface potential distribution

Enhancement of the piezoelectric coefficient in PVDF-TrFe/CoFe₂O₄ nanocomposites through DC magnetic poling

• Marco Fortunato,
• Alessio Tamburrano,
• Maria Paola Bracciale,
• Maria Laura Santarelli and
• Maria Sabrina Sarto

Beilstein J. Nanotechnol. 2021, 12, 1262–1270, doi:10.3762/bjnano.12.93

• the use of a top electrode or of high magnetic fields (the maximum value of d33 was obtained at 50 mT, using a current of 0.4 A) making the PVDF-TrFE/CoFe2O4 nanocomposite suitable for the fabrication of highly efficient devices for energy harvesting and wearable sensors. Keywords: CoFe2O4; magnetic

Electrical, electrochemical and structural studies of a chlorine-derived ionic liquid-based polymer gel electrolyte

• Ashish Gupta,
• Amrita Jain,
• Manju Kumari and
• Santosh K. Tripathi

Beilstein J. Nanotechnol. 2021, 12, 1252–1261, doi:10.3762/bjnano.12.92

• availability in the Earth’s crust, low atomic weight, low price, high electrochemical reduction potential of −2.3 V versus the standard hydrogen electrode. Moreover, most of the Mg compounds are usually nontoxic and also Mg is chemically stable as compared to lithium and sodium [31]. In the present study, the

• due to the dissociation of salts and ion aggregates at higher temperatures. The analysis of the modulus is very useful in distinguishing between electrode polarization with that of other interfacial effects. Figure 7a and Figure 7b show the real part Mr and the imaginary part Mi of the electrical

• observed that the height of the peak decreases by increasing the temperature, which suggests a plurality of relaxation mechanisms. At low frequencies, the values of both real and imaginary moduli decrease to almost zero, indicating a negligible contribution of the electrode polarization phenomenon. The

Impact of electron–phonon coupling on electron transport through T-shaped arrangements of quantum dots in the Kondo regime

• Patryk Florków and
• Stanisław Lipiński

Beilstein J. Nanotechnol. 2021, 12, 1209–1225, doi:10.3762/bjnano.12.89

• the upper (j = 1) and the lower (j = 2) TQD subsystems visualized on Figure 1 and α numbers left or right electrode. The terms parametrized by U and U’ describe intra- and interdot Coulomb interactions, respectively, with denoting the occupation operators of IQDs. The last two terms stand for

Morphology-driven gas sensing by fabricated fractals: A review

• Vishal Kamathe and
• Rupali Nagar

Beilstein J. Nanotechnol. 2021, 12, 1187–1208, doi:10.3762/bjnano.12.88

• by applying it to the random movement of a metallic ion in a low concentration of electrolyte near a negatively charged electrode [52]. The process resulted in a tree-like scale-invariant structure [52][53]. Figure 2b demonstrates the growth mechanism of a fractal proposed by DLA. Theories of non

• electrode resulting in a sensor prototype and were later used for UV-assisted acetone sensing. Figure 12a and Figure 12b show SEM images of top-view morphology and thickness of the sample at low and high magnifications, respectively. Figure 12c shows an energy-dispersive X-ray spectroscopy (EDS) mapping of

• fractals, can aid in better sensing. Connectivity, exposure to gaseous environment, nanoscale 3D coarsening, and roughness generate many secondary and tertiary adsorption sites that result in better sensitivity. If somehow the interconnectivity can be improved with the help of an artificial electrode

The effect of cobalt on morphology, structure, and ORR activity of electrospun carbon fibre mats in aqueous alkaline environments

• Markus Gehring,
• Tobias Kutsch,
• Osmane Camara,
• Alexandre Merlen,
• Hermann Tempel,
• Hans Kungl and
• Rüdiger-A. Eichel

Beilstein J. Nanotechnol. 2021, 12, 1173–1186, doi:10.3762/bjnano.12.87

• . Many researchers focus on the active material, that is, the catalyst, which enhances the ORR, and many promising systems have been reported and extensively reviewed [5]. The electrode scaffold receives far less attention. Only few reports elaborate on the importance of the electrode architecture for

• , especially the lithium and silicon systems, on account of their different mechanism involving the cathode as an explicit reaction site of the metal redox chemistry [7][8][9]. From a scientific point of view, in aqueous systems, an air electrode needs to allow gas to diffuse in appropriate amounts towards the

• active sites, that is, triple-phase contact points. These contact points of air, solid catalyst, and liquid electrolyte, need to be high in number or area. This entails a partial wetting of the electrode to ensure accessibility of the sites for gaseous oxygen. From a more industrial perspective

Assessment of the optical and electrical properties of light-emitting diodes containing carbon-based nanostructures and plasmonic nanoparticles: a review

• Keshav Nagpal,
• Erwan Rauwel,
• Frédérique Ducroquet and
• Protima Rauwel

Beilstein J. Nanotechnol. 2021, 12, 1078–1092, doi:10.3762/bjnano.12.80

• combining them with other polymers. Nevertheless, this work demonstrates that SWNT can be used as cathode materials in LED, if improved. The successful implementation of such an electrode would open new possibilities to fabricate fully transparent OLED. Conclusion This article has provided an overview of

Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries

• Marina Tabuyo-Martínez,
• Bernd Wicklein and
• Pilar Aranda

Beilstein J. Nanotechnol. 2021, 12, 995–1020, doi:10.3762/bjnano.12.75

• phenomenon caused by the migration of long-chain sodium polysulfides (Na2Sn) to the anode, facilitated by their high solubility in carbonate- and ether-based electrolytes [21]. At the anode, Na2Sn is further reduced to insoluble short-chain sodium polysulfides, which precipitate and passivate the electrode

• rather large (up to 170%) and may damage the cathode and lead to capacity loss [4]. Nanoscaling the cathode compounds and the concomitant introduction of porosity is a widely investigated strategy to mitigate the emerging mechanical tension and to prevent electrode failure [18][24]. Unlike sodium-ion

• because both Na2S8 and the reduction products, Na2Sn (4 < n < 8), show higher electrical conductivity than elemental sulfur and sodium sulfide Na2S and faster reaction kinetics with Na+ [42]. Therefore, by employing the S/Na2Sn redox couple as cathode, the electrode conductivity is enhanced, which

Uniform arrays of gold nanoelectrodes with tuneable recess depth

• Elena O. Gordeeva,
• Ilya V. Roslyakov,
• Alexey P. Leontiev,
• Alexey A. Klimenko and
• Kirill S. Napolskii

Beilstein J. Nanotechnol. 2021, 12, 957–964, doi:10.3762/bjnano.12.72

• pathways to further improve the recessed nanoelectrode arrays based on anodic alumina templates are discussed. Keywords: anodic alumina; gold; nanoelectrode array; recessed electrode; templated electrodeposition; Introduction A nanoelectrode array (NEA) is a set of regularly arranged isolated metal

• alternative approach includes bulk electrode structuring by deposition or etching techniques using self-assembled arrays of colloidal nanoparticles [15], liquid crystals [16], or track-etched membranes [17][18][19] as template or mask, respectively. Among porous templates, anodic aluminium oxide (AAO) allows

• current density is associated with the charging of the electric double layer, a decrease in the concentration of electroactive species near the electrode surface, and an increase in the diffusion layer thickness. Stage II corresponds to the growth of Cu segments inside the AAO at near constant current

Molecular assemblies on surfaces: towards physical and electronic decoupling of organic molecules

• Sabine Maier and
• Meike Stöhr

Beilstein J. Nanotechnol. 2021, 12, 950–956, doi:10.3762/bjnano.12.71

• such vertical tunneling through the interfacial layers can be undesirable since it prevents the current from flowing across electrode–molecule–electrode junctions [43] or leads to the charging of physisorbed molecules on top of such layers [18]. Hence, ultrathin insulating layers are often not

The role of deep eutectic solvents and carrageenan in synthesizing biocompatible anisotropic metal nanoparticles

• Nabojit Das,
• Akash Kumar and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2021, 12, 924–938, doi:10.3762/bjnano.12.69

• surface coating with nanoparticles through electrodeposition. A general electrodeposition setup consists of three electrodes, that is cathode, anode, and a reference electrode [78]. The solvation property and the conductivity of DESs also play a critical role in determining the physical structure, yield

In situ transport characterization of magnetic states in Nb/Co superconductor/ferromagnet heterostructures

• Olena M. Kapran,
• Roman Morari,
• Taras Golod,
• Evgenii A. Borodianskyi,
• Vladimir Boian,
• Andrei Prepelita,
• Nikolay Klenov,
• Anatoli S. Sidorenko and
• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2021, 12, 913–923, doi:10.3762/bjnano.12.68

• the whole electrode is measured in a four-probe manner using two separate wires bonded to each contact pad. Results Figure 1d shows Rxx(T) dependencies, normalized by the normal state resistance Rn (T ≥ Tc), for microbridges at S1 (blue) and S2 (red) MLs at H = 0. Resistances are measured with Iac

9.1% efficient zinc oxide/silicon solar cells on a 50 μm thick Si absorber

• Rafal Pietruszka,
• Bartlomiej S. Witkowski,
• Monika Ozga,
• Katarzyna Gwozdz,
• Ewa Placzek-Popko and
• Marek Godlewski

Beilstein J. Nanotechnol. 2021, 12, 766–774, doi:10.3762/bjnano.12.60

• , during the production process, chemicals that are harmful for the environment and for human life are used. For example, hydrofluoric acid is used to texture the top electrode to improve light harvesting. In this work, and also in recent ones, we report a way to obtain 3D textures on the top electrode by

• , allowing us to construct a 3D top electrode and to improve light collection/harvesting in cells with such electrodes. Figure 3 shows cross sections of the studied photovoltaic structures. The cell labeled as sample A contains ZnONR grown via the hydrothermal method. On the nanorods, an MZO film was

• of Zn, Mg, and O in the ZnMgO films. These concentrations were (52.0 ± 0.5)%, (46.6 ± 0.5)%, and (1.4 ± 0.5)% for zinc, oxygen, and magnesium, respectively. Aluminium-doped zinc oxide films were grown on top of the samples A and B as a transparent top electrode. Comparison of the cross sections

Recent progress in actuation technologies of micro/nanorobots

• Ke Xu and
• Bing Liu

Beilstein J. Nanotechnol. 2021, 12, 756–765, doi:10.3762/bjnano.12.59

• electrolyte spherical micro/nanorobots constrained by hydrodynamics can be polarized along the center line of the electrode, and the movement speed can be controlled. In addition, the micro/nanorobots moving in the same direction move in single file, while the micro/nanorobots moving in the opposite direction

Nanogenerator-based self-powered sensors for data collection

• Yicheng Shao,
• Maoliang Shen,
• Yuankai Zhou,
• Xin Cui,
• Lijie Li and
• Yan Zhang

Beilstein J. Nanotechnol. 2021, 12, 680–693, doi:10.3762/bjnano.12.54

• -electrode mode, the contact-sliding mode, and the freestanding-triboelectric-layer mode [2][65]. TENGs can be made of many different materials with low manufacturing cost, environmental friendliness, and low maintenance cost. TENG-based sensors can collect multidimensional and large-scale data, which are a

• approximately 100%) TENG (WP-TENG) based on a poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate) (PEDOT:PSS) electrode and installed the WP-TENG-based self-powered motion sensor at different positions of a human arm. The WP-TENG was placed on the skin above the muscles of the arm, as shown in Figure 2a

• signals, the researchers proposed a single-electrode TENG (SE-TENG) as an intelligent neuromorphic sensor using reduced graphene oxide [90]. Reduced graphene oxide can act as electronic trap, and the output information of the sensor contains real-time stimulation information and information about previous

Stability and activity of platinum nanoparticles in the oxygen electroreduction reaction: is size or uniformity of primary importance?

• Kirill O. Paperzh,
• Anastasia A. Alekseenko,
• Vadim A. Volochaev,
• Ilya V. Pankov,
• Olga A. Safronenko and
• Vladimir E. Guterman

Beilstein J. Nanotechnol. 2021, 12, 593–606, doi:10.3762/bjnano.12.49

• friendliness, low operating temperature, and high adaptability of specific characteristics [1][2][3]. The key components of PEMFC membrane–electrode assemblies (MEA) are the proton-exchange polymer membrane and porous electrode layers, in which current-forming reactions of oxygen electroreduction (ORR) and

• hydrogen oxidation or an organic reducing agent oxidation (e.g. methanol) occur [4][5]. The need to carry out high-rate electrode reactions requires electrocatalysts (i.e., platinum nanoparticles – NPs – or its alloys), deposited mainly onto nano/microparticles of carbon supports, which are currently the

• were plotted to determine the size of at least 400 randomly selected particles in the TEM images in different regions of the sample. Electrochemical investigation Electrochemical measurements were performed in a three-electrode cell on a VersaSTAT3 potentiostat using a rotating disk electrode (RDE

Impact of GaAs(100) surface preparation on EQE of AZO/Al₂O₃/p-GaAs photovoltaic structures

• Piotr Caban,
• Rafał Pietruszka,
• Jarosław Kaszewski,
• Monika Ożga,
• Bartłomiej S. Witkowski,
• Krzysztof Kopalko,
• Piotr Kuźmiuk,
• Katarzyna Gwóźdź,
• Ewa Płaczek-Popko,
• Krystyna Lawniczak-Jablonska and
• Marek Godlewski

Beilstein J. Nanotechnol. 2021, 12, 578–592, doi:10.3762/bjnano.12.48

• a 3D top electrode, 14% of efficiency was reached [2]. Consequently, we also turned out our attention towards gallium arsenide as a substrate/absorber for solar cells. The first results of the experiments made us aware of the potential and possible fields for improvement of ZnO/GaAs-based structures

Properties of graphene deposited on GaN nanowires: influence of nanowire roughness, self-induced nanogating and defects

• Jakub Kierdaszuk,
• Piotr Kaźmierczak,
• Justyna Grzonka,
• Aleksandra Krajewska,
• Aleksandra Przewłoka,
• Wawrzyniec Kaszub,
• Zbigniew R. Zytkiewicz,
• Marta Sobanska,
• Maria Kamińska,
• Andrzej Wysmołek and
• Aneta Drabińska

Beilstein J. Nanotechnol. 2021, 12, 566–577, doi:10.3762/bjnano.12.47

• absorption [9]. However, the interaction between corrugated nanowire substrate and graphene could substantially increase the scattering of carriers in a graphene electrode and decrease its conductivity. Therefore, detailed studies of the interaction between nanowire substrate and graphene are crucial to gain